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Different interfacial reactivity of lithium metal chloride electrolytes with high voltage cathodes determines solid-state battery performance

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Li+ conduction in aliovalent-substituted monoclinic Li2ZrCl6 for all-solid-state batteries: Li2+xZr1-xMxCl6 (M = In, Sc)
inferredcites →https://doi.org/10.1016/j.commatsci.2012.10.028openalex-snapshot
Python Materials Genomics (pymatgen): A robust, open-source python library for materials analysis
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Nonflammable Lithium Metal Full Cells with Ultra-high Energy Density Based on Coordinated Carbonate Electrolytes
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Assessment of all-solid-state lithium-ion batteries
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Interpretation of the Gerischer impedance in solid state ionics
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inferredcites →https://doi.org/10.1021/jacsau.1c00228openalex-snapshot
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inferredcites →https://doi.org/10.1038/nenergy.2016.141openalex-snapshot
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inferredcites →https://doi.org/10.1038/s41560-020-0634-5openalex-snapshot
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inferredcites →https://doi.org/10.1038/s41560-021-00952-0openalex-snapshot
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inferredcites →https://doi.org/10.1038/s41563-019-0576-0openalex-snapshot
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inferredcites →https://doi.org/10.1039/c5ta08574hopenalex-snapshot
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inferredcites →https://doi.org/10.1039/c9ee02311aopenalex-snapshot
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inferredcites →https://doi.org/10.1039/d0ee01017kopenalex-snapshot
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Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
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Springer Tracts in Modern Physics
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What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Cation disorder and lithium conductivity in mechanochemically synthesized chloride solid electrolytes
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The partial electronic conductivity of lithium halides and their role in SEI formation in solid-state batteries – Hebb-Wagner-type measurements
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High-performance Li3YCl3Br3 halide solid electrolyte synthesized using wet-chemistry route for all-solid-state battery
inferred← citeshttps://doi.org/10.1021/acs.chemmater.6c00993openalex-snapshot
Stable High-Areal-Capacity All-Solid-State Batteries Enabled by Ultrathin Li3YCl6-Based Coatings on Nickel-Rich Layered Cathodes
inferred← citeshttps://doi.org/10.1021/acs.chemrev.4c00584openalex-snapshot
Characterizing Electrode Materials and Interfaces in Solid-State Batteries
inferred← citeshttps://doi.org/10.1021/acs.chemrev.4c00894openalex-snapshot
Ductile Inorganic Solid Electrolytes for All-Solid-State Lithium Batteries
inferred← citeshttps://doi.org/10.1021/acs.chemrev.5c00320openalex-snapshot
Well-Defined Single-Crystal Layered Oxide Cathodes for High-Performance All-Solid-State Lithium Batteries
inferred← citeshttps://doi.org/10.1021/acs.chemrev.5c00586openalex-snapshot
Overcoming the Li + Ion Transport Limitation of Solid-State Composite Electrodes for Inorganic Solid-State Batteries
inferred← citeshttps://doi.org/10.1021/acs.chemrev.5c00679openalex-snapshot
Interfaces in All-Solid-State Li Metal Batteries: From Fundamental Research to Practical Applications
inferred← citeshttps://doi.org/10.1021/acs.iecr.6c00267openalex-snapshot
Electrochemical Behavior and Interfacial Failure of Li 2.22 Zr 1.11 Cl 5.33 O 0.67 in High-Performance All-Solid-State Batteries
inferred← citeshttps://doi.org/10.1021/acs.jpcc.2c07910openalex-snapshot
Investigation of Structure, Ionic Conductivity, and Electrochemical Stability of Halogen Substitution in Solid-State Ion Conductor Li 3 YBr x Cl 6– x
inferred← citeshttps://doi.org/10.1021/acs.jpcc.4c05759openalex-snapshot
Electrochemical Redox Potential of Li2SO4 Investigated Using the Appropriate All-Solid-State Cell Configuration
inferred← citeshttps://doi.org/10.1021/acs.nanolett.4c03502openalex-snapshot
Interface Degradation of LaCl3-Based Solid Electrolytes Coupled with Ultrahigh-Nickel Cathodes
inferred← citeshttps://doi.org/10.1021/acs.nanolett.5c03012openalex-snapshot
Achieving 766.5 Wh kg–1 Electrode-Level Energy Density via Solid-State Cathode Integrating Ultrahigh Nickel Oxide and Lithium Iron Chloride
inferred← citeshttps://doi.org/10.1021/acsaem.4c02948openalex-snapshot
Halide Lithium Conductors: From Design and Synthesis to Application for All-Solid-State Batteries
inferred← citeshttps://doi.org/10.1021/acsami.3c13002openalex-snapshot
Anion Engineering for Stabilizing Li Interstitial Sites in Halide Solid Electrolytes for All-Solid-State Li Batteries
inferred← citeshttps://doi.org/10.1021/acsami.4c07798openalex-snapshot
Enhancing Lithium Conductivity Using High-Valence Cations in Cubic Spinel Halide Solid Electrolytes
inferred← citeshttps://doi.org/10.1021/acsami.4c12938openalex-snapshot
Interface Stability and Reaction Mechanisms of Li 3 YCl 5 Br with High-Voltage Cathodes and Li Metal Anode: Insights from Ab Initio Simulations
inferred← citeshttps://doi.org/10.1021/acsami.5c15106openalex-snapshot
Constructing Stable and Efficient Solid Electrolytes Based on Zirconium-Doping on Li4Ti5O12 for Solid-State Lithium Metal Batteries
inferred← citeshttps://doi.org/10.1021/acsami.5c19063openalex-snapshot
High-Entropy-Driven Moderate Lattice Distortion Improves Ionic Conductivity and High-Voltage Stability of Halide Solid-State Electrolytes
inferred← citeshttps://doi.org/10.1021/acsami.6c07844openalex-snapshot
SEI Formation in Sulfide-Based Solid-State Batteries: Influence of Contact Conditions on Impedance-Derived Interphase Growth Kinetics
inferred← citeshttps://doi.org/10.1021/acsenergylett.3c00763openalex-snapshot
Li3–xZrx(Ho/Lu)1–xCl6 Solid Electrolytes Enable Ultrahigh-Loading Solid-State Batteries with a Prelithiated Si Anode
inferred← citeshttps://doi.org/10.1021/acsenergylett.4c00317openalex-snapshot
Halide Superionic Conductors for All-Solid-State Batteries: Effects of Synthesis and Composition on Lithium-Ion Conductivity
inferred← citeshttps://doi.org/10.1021/acsenergylett.4c01084openalex-snapshot
Ionocovalency of the Central Metal Halide Bond-Dependent Chemical Compatibility of Halide Solid Electrolytes with Li6PS5Cl
inferred← citeshttps://doi.org/10.1021/acsenergylett.4c02590openalex-snapshot
Compatibility of Halide Bilayer Separators for All-Solid-State Batteries
inferred← citeshttps://doi.org/10.1021/acsenergylett.4c03147openalex-snapshot
A Low-Strain Lithium Cathode Material Li 2–2 x Fe 1+ x Cl 4 for Halide-Based All-Solid-State Batteries
inferred← citeshttps://doi.org/10.1021/acsenergylett.5c00174openalex-snapshot
Visualizing Electron Transport and Interface Evolution of Li 3 InCl 6 -Based Composite Cathode for All-Solid-State Batteries
inferred← citeshttps://doi.org/10.1021/acsenergylett.5c02976openalex-snapshot
Insight into the Interfacial Evolutions between Halide and Sulfide Solid Electrolytes
inferred← citeshttps://doi.org/10.1021/acsenergylett.5c03415openalex-snapshot
Chloride-Based Solid Electrolytes from Crystal Structure to Electrochemical Performance
inferred← citeshttps://doi.org/10.1021/acsenergylett.5c03429openalex-snapshot
Navigating the Catholyte Landscape in All-Solid-State Batteries
inferred← citeshttps://doi.org/10.1021/acsenergylett.6c00623openalex-snapshot
Design Principles for Aqueous Stability of Lithium Halide and Oxyhalide Solid Electrolytes from First-Principles Pourbaix Analysis
inferred← citeshttps://doi.org/10.1021/acsenergylett.6c01247openalex-snapshot
Insights into the Transition from Ionic Insulator to Conductor for Li-Mn-Cl-Based Halospinel
inferred← citeshttps://doi.org/10.1021/acsmaterialslett.4c01923openalex-snapshot
Suppressing Atmospheric Degradation of Sulfide-Based Solid Electrolytes via Ultrathin Metal Oxide Layers
inferred← citeshttps://doi.org/10.1021/acsnano.4c02678openalex-snapshot
High-Voltage Long-Cycling All-Solid-State Lithium Batteries with High-Valent-Element-Doped Halide Electrolytes
inferred← citeshttps://doi.org/10.1021/acsnano.6c09375openalex-snapshot
Beyond Electrochemistry: Tailoring Mechanical Properties of Halogen-Substituted Argyrodites for Conformal Dry Coating and Enhanced Battery Performance
inferred← citeshttps://doi.org/10.1021/jacs.3c07343openalex-snapshot
Amorphous Oxyhalide Matters for Achieving Lithium Superionic Conduction
inferred← citeshttps://doi.org/10.1021/jacs.4c08115openalex-snapshot
Bulk/Interfacial Structure Design of Li-Rich Mn-Based Cathodes for All-Solid-State Lithium Batteries
inferred← citeshttps://doi.org/10.1021/jacs.5c00615openalex-snapshot
Local Cation-Ordered Superlattice Stabilizing Ni-Rich Single-Crystalline Cathodes
inferred← citeshttps://doi.org/10.1021/jacs.5c21351openalex-snapshot
Design for an Interface in Oxyhalide-Based All-Solid-State Lithium Metal Batteries
inferred← citeshttps://doi.org/10.1038/s41467-023-39522-1openalex-snapshot
A cost-effective, ionically conductive and compressible oxychloride solid-state electrolyte for stable all-solid-state lithium-based batteries
inferred← citeshttps://doi.org/10.1038/s41467-023-43792-0openalex-snapshot
Defective oxygen inert phase stabilized high-voltage nickel-rich cathode for high-energy lithium-ion batteries
inferred← citeshttps://doi.org/10.1038/s41467-024-45258-3openalex-snapshot
Designing lithium halide solid electrolytes
inferred← citeshttps://doi.org/10.1038/s41467-024-45864-1openalex-snapshot
Promoting high-voltage stability through local lattice distortion of halide solid electrolytes
inferred← citeshttps://doi.org/10.1038/s41467-025-58522-xopenalex-snapshot
Harnessing database-supported high-throughput screening for the design of stable interlayers in halide-based all-solid-state batteries
inferred← citeshttps://doi.org/10.1038/s41467-026-71876-0openalex-snapshot
Functional modules for enhanced amorphous composite halide solid electrolytes for low-temperature all-solid-state lithium batteries
inferred← citeshttps://doi.org/10.1038/s41560-025-01726-8openalex-snapshot
High-energy, long-life Ni-rich cathode materials with columnar structures for all-solid-state batteries
inferred← citeshttps://doi.org/10.1038/s41578-025-00822-1openalex-snapshot
Ionic potential for battery materials
inferred← citeshttps://doi.org/10.1038/s41586-024-08298-9openalex-snapshot
All-solid-state Li–S batteries with fast solid–solid sulfur reaction
inferred← citeshttps://doi.org/10.1039/d2qm01071bopenalex-snapshot
A review of all-solid-state electrolytes for lithium batteries: high-voltage cathode materials, solid-state electrolytes and electrode–electrolyte interfaces
inferred← citeshttps://doi.org/10.1039/d2ta08433copenalex-snapshot
Re-investigating the structure–property relationship of the solid electrolytes Li 3− x In 1− x Zr x Cl 6 and the impact of In–Zr( iv ) substitution
inferred← citeshttps://doi.org/10.1039/d3sc02093bopenalex-snapshot
Halide solid-state electrolytes for all-solid-state batteries: structural design, synthesis, environmental stability, interface optimization and challenges
inferred← citeshttps://doi.org/10.1039/d4ee00822gopenalex-snapshot
In situ polymerization of solid-state polymer electrolytes for lithium metal batteries: a review
inferred← citeshttps://doi.org/10.1039/d4ee01302fopenalex-snapshot
Unraveling the interfacial compatibility of ultrahigh nickel cathodes and chloride solid electrolyte for stable all-solid-state lithium batteries
inferred← citeshttps://doi.org/10.1039/d4ee04370gopenalex-snapshot
A multifunctional zeolite film enables stable high-voltage operation of a LiCoO 2 cathode
inferred← citeshttps://doi.org/10.1039/d4ta01912aopenalex-snapshot
Hierarchically coated halide layers: enhancing the performance at composite cathode interfaces in solid-state Li–metal batteries
inferred← citeshttps://doi.org/10.1039/d5cc01773dopenalex-snapshot
Boosting lithium compatibility and air stability of halide electrolytes through cyanamide substitution
inferred← citeshttps://doi.org/10.1039/d5nj00262aopenalex-snapshot
Effects of electrolyte interlayers on suppressing reactions with LiFePO 4 and argyrodite-based sulfides in solid-state batteries
inferred← citeshttps://doi.org/10.1039/d5nr01608hopenalex-snapshot
Soft acid Bi 3+ doping in Li 2 ZrCl 6 to enhance ionic conductivity and electrochemical stability
inferred← citeshttps://doi.org/10.1039/d5sc05307bopenalex-snapshot
Break it down to speed it up: Na 2 O–NaTaCl 6
inferred← citeshttps://doi.org/10.1039/d6ee04587aopenalex-snapshot
Electrolyte engineering for lithium–sulphur batteries with high energy density
inferred← citeshttps://doi.org/10.1039/d6mh00223dopenalex-snapshot
A moisture stable high-entropy halide electrolyte with performance recovery capability for all-solid-state batteries
inferred← citeshttps://doi.org/10.1134/s0021364023602592openalex-snapshot
Ab Initio Study of the Adsorption of Li and Na on the Surface of a MgCl2 Monolayer
inferred← citeshttps://doi.org/10.26434/chemrxiv-2023-p784wopenalex-snapshot
Water-mediated synthesis of halide solid electrolyte and conducting polymer hybrid materials for all solid-state batteries
inferred← citeshttps://doi.org/10.31857/s1234567823210097openalex-snapshot
Ab Initio Study of the Adsorption of Li and Na on the Surface of a MgCl2 Monolayer
inferred← citeshttps://doi.org/10.3390/cryst16050335openalex-snapshot
Unraveling the Underlying Mechanism of the Li+ Migration Inside Halide Solid-State Electrolytes: Structural Tuning and Defect Manipulation
inferred← citeshttps://doi.org/10.3390/en19122790openalex-snapshot
N-Doped Li2ZrCl6-Based Chloride Solid Electrolytes for Enhanced Li Ion Transport
inferred← citeshttps://doi.org/10.34133/energymatadv.0163openalex-snapshot
Insights into Interfacial Issues of Layered Oxide Cathodes and Inorganic Solid Electrolytes
inferred← citeshttps://doi.org/10.70675/6fdd6c58z35fcz4fddzaca0z58bfa5bdf25aopenalex-snapshot
Exploring solid-solid interfaces in Li6PS5Cl-based cathode composites for all solid state batteries
inferred← citeshttps://doi.org/10.70675/b94b7604z8585z4d59z9632z14c5e0ae2bb3openalex-snapshot
In search of the best solid electrolyte-layered oxide pair in all-solid-state batteries
inferred← citeshttps://doi.org/10.70675/f12b45ffz720az4557z99f4zae4f6c906f31openalex-snapshot
Liquid phase synthesis and application of sulfide solid electrolyte
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