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Near-unity electrochemical conversion of nitrate to ammonia on crystalline nickel porphyrin-based covalent organic frameworks

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Restoring the Nitrogen Cycle by Electrochemical Reduction of Nitrate: Progress and Prospects

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What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1016/j.jallcom.2026.187155openalex-snapshot

La-doped carbon nanofibers loaded with Cu-Co nanocubes enable highly efficient series electrochemical catalysis for nitrate reduction in ammonia synthesis

inferred← citeshttps://doi.org/10.1016/j.jcis.2024.05.223openalex-snapshot

Fine tuning dual active sites in modulating cascade electrocatalytic nitrate reduction over covalent organic framework

inferred← citeshttps://doi.org/10.1016/j.jcis.2024.07.020openalex-snapshot

Understanding electron structure of covalent triazine framework embraced with gold nanoparticles for nitrogen reduction to ammonia

inferred← citeshttps://doi.org/10.1016/j.jcis.2025.02.002openalex-snapshot

Mn-N5 structure between poly-porphyrin manganese and 3D N-doped graphene to enhance bifunctional oxygen catalytic performance

inferred← citeshttps://doi.org/10.1016/j.jcis.2026.140432openalex-snapshot

Tailored covalent organic frameworks with metal sites enabling high-efficiency ammonia generation through nitrate electroreduction

inferred← citeshttps://doi.org/10.1016/j.jece.2026.124413openalex-snapshot

A bimetallic metal-organic framework for efficient electrocatalytic nitrate reduction to ammonia and energy conversion with a zinc-nitrate battery

inferred← citeshttps://doi.org/10.1016/j.jechem.2023.07.006openalex-snapshot

Recent progress and challenges in structural construction strategy of metal-based catalysts for nitrate electroreduction to ammonia

inferred← citeshttps://doi.org/10.1016/j.jechem.2023.12.024openalex-snapshot

Comprehensive understanding of the thriving electrocatalytic nitrate/nitrite reduction to ammonia under ambient conditions

inferred← citeshttps://doi.org/10.1016/j.mcat.2026.115971openalex-snapshot

Design, synthesis and photocatalytic applications of porphyrin-based covalent organic frameworks

inferred← citeshttps://doi.org/10.1016/j.mtcomm.2025.113845openalex-snapshot

Modular covalent organic frameworks (COFs): A sustainable treatment strategy for shipboard domestic sewage treatment

inferred← citeshttps://doi.org/10.1016/j.nanoen.2025.110683openalex-snapshot

Recent breakthroughs in electrocatalytic reduction of nitrogen-oxyanions for environmentally benign ammonia synthesis

inferred← citeshttps://doi.org/10.1016/j.pmatsci.2025.101538openalex-snapshot

When covalent organic frameworks meet metals: From opportunities toward applications

inferred← citeshttps://doi.org/10.1016/j.seppur.2025.136168openalex-snapshot

Pulse driven and polypyrrole mediated microenvironment regulation synergistically achieve efficient conversion of nitrate to ammonia by copper oxide electrocatalsis

inferred← citeshttps://doi.org/10.1016/s1872-2067(23)64456-0openalex-snapshot

Non-noble metal single atom catalysts for electrochemical energy conversion reactions

inferred← citeshttps://doi.org/10.1016/s1872-2067(23)64634-0openalex-snapshot

Unveiling the activity tendency of well-defined metal-N4 sites for electrocatalytic nitrate reduction

inferred← citeshttps://doi.org/10.1016/s1872-2067(26)64989-3openalex-snapshot

Steering product selectivity via metallic site-dependent pathways in porphyrin-based covalent organic frameworks for electrocatalytic nitrite reduction

inferred← citeshttps://doi.org/10.1021/acs.est.4c04014openalex-snapshot

Metal Doped Unconventional Phase IrNi Nanobranches: Tunable Electrochemical Nitrate Reduction Performance and Pollutants Upcycling

inferred← citeshttps://doi.org/10.1021/acs.est.6c09154openalex-snapshot

Interfacial Charge Reconfiguration Decouples Tandem Kinetics of Dilute Nitrate Electroreduction for Ammonia Recovery

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c02553openalex-snapshot

Cascade Electrocatalytic Reduction of Nitrate to Ammonia Using a Heterobimetallic Covalent Organic Framework Composed of Cu-Porphyrin and Co-Bipyridine

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c02578openalex-snapshot

Silver-π Interaction: A Diverse Approach to Hybrid Material and Its Efficacy in Electrocatalytic Reduction of Nitrate to Ammonia

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6c00320openalex-snapshot

Steam-Reformed Dispersive Sites with Cu 0 –Cu + Interface for Electroreduction of Nitrate to Ammonia

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6c02975openalex-snapshot

Odd-Nuclearity in Homologous Series of Ni-Tiara Clusters Unlocking Near-Unity NH3 Selectivity in Electrochemical Nitrate Reduction

inferred← citeshttps://doi.org/10.1021/acs.nanolett.5c01401openalex-snapshot

The In Situ Assembly of an Equipotential Cathode for Nitrite Enrichment Enabling Electrochemical Nitrate Reduction to N 2

inferred← citeshttps://doi.org/10.1021/acsami.5c03383openalex-snapshot

Anodic Oxidation-Induced Interfacial Regulation of Nanoporous Co2P/CoOOH for Electrocatalytic Nitrate Reduction to Ammonia

inferred← citeshttps://doi.org/10.1021/acsami.5c13804openalex-snapshot

Paired Electrocatalysis: Nitrate Reduction to Ammonia Coupled with Anodic Upcycling of Biomass and Plastic Waste

inferred← citeshttps://doi.org/10.1021/acsanm.6c01670openalex-snapshot

Interfacial Electronic Modulation in 1D Peapod-like CuO@TiO 2 Nanotubes for Accelerated Nitrate-to-Ammonia Electrosynthesis

inferred← citeshttps://doi.org/10.1021/acscatal.3c02740openalex-snapshot

Electrochemical Co-Production of Ammonia and Biodegradable Polymer Monomer Glycolic Acid via the Co-Electrolysis of Nitrate Wastewater and Waste Plastic

inferred← citeshttps://doi.org/10.1021/acscatal.4c03006openalex-snapshot

Porous Cu1/TiO2–x Catalytic Binding Pocket for Near-Unity Nitrate-to-Ammonia Conversion

inferred← citeshttps://doi.org/10.1021/acscatal.4c04340openalex-snapshot

Regulating the d-Band Center of Metal–Organic Frameworks for Efficient Nitrate Reduction Reaction and Zinc-Nitrate Battery

inferred← citeshttps://doi.org/10.1021/acscatal.4c05434openalex-snapshot

Interface Engineering on Heterostructural Nanosheets for Efficient Electrocatalytic-Paired Upcycling of Waste Plastics and Nitrate

inferred← citeshttps://doi.org/10.1021/acscatal.6c05600openalex-snapshot

How Far Does an Active Site Reach? Defining Interaction Radii in Covalent Organic Framework Electrocatalysts for Nitrate Reduction

inferred← citeshttps://doi.org/10.1021/acselectrochem.5c00278openalex-snapshot

Tuning Electrolyte Composition to Modulate Catalytic Performance in Molecularly Catalyzed Electrochemical Nitrate Reduction

inferred← citeshttps://doi.org/10.1021/acsnano.4c03995openalex-snapshot

Cascade Electrocatalytic Nitrate Reduction Reaching 100% Nitrate-N to Ammonia-N Conversion over Cu2O@CoO Yolk–Shell Nanocubes

inferred← citeshttps://doi.org/10.1021/acsnano.4c05422openalex-snapshot

Charge Redistribution in High-Entropy Perovskite Oxide Porous Nanotubes Boosts Nitrate Electroreduction to Ammonia

inferred← citeshttps://doi.org/10.1021/acsnano.4c06637openalex-snapshot

Facet-Dependent Evolution of Active Components on Spinel Co 3 O 4 for Electrochemical Ammonia Synthesis

inferred← citeshttps://doi.org/10.1021/acsnano.6c06638openalex-snapshot

Interface Coordination Nucleation of Copper Nanoclusters on Covalent Organic Frameworks for Electrocatalytic Ammonia Synthesis

inferred← citeshttps://doi.org/10.1021/acssuschemeng.5c09635openalex-snapshot

Unsaturated Cu Single-Atom Catalysts in COFs for Efficient Neutral Ammonia Electrosynthesis from Nitrate

inferred← citeshttps://doi.org/10.1021/acssuschemeng.6c07716openalex-snapshot

Biomass-Derived Fe–Ni Alginate Hydrogel Electrodes for Sustainable Nitrate Upcycling to Ammonia

inferred← citeshttps://doi.org/10.1021/cbe.4c00124openalex-snapshot

Optimizing Nitrate Electroreduction toward Nearly 100% Ammonia Selectivity through Synergistic RuCu Catalysts and Integrated Coupled Anodic Reaction for High-Value Products

inferred← citeshttps://doi.org/10.1021/jacs.6c12226openalex-snapshot

The Obligate Mutualism in Metal Nanoclusters

inferred← citeshttps://doi.org/10.1021/jacs.6c13313openalex-snapshot

Isotopological Modulation of Entanglement in 3D Covalent Organic Frameworks Unlocks a Fully Open Catalytic Architecture

inferred← citeshttps://doi.org/10.1038/s43246-024-00535-yopenalex-snapshot

Efficient electrochemical reduction of nitrate to ammonia over metal-organic framework single-atom catalysts

inferred← citeshttps://doi.org/10.1038/s44160-025-00742-6openalex-snapshot

Selective electrocatalytic synthesis of urea using entangled iron porphyrins in covalent organic frameworks

inferred← citeshttps://doi.org/10.1039/d2cs00931eopenalex-snapshot

Defect engineering of two-dimensional materials for advanced energy conversion and storage

inferred← citeshttps://doi.org/10.1039/d2ee03502bopenalex-snapshot

Molecular electrocatalysts for rapid and selective reduction of nitrogenous waste to ammonia

inferred← citeshttps://doi.org/10.1039/d3cc01428bopenalex-snapshot

In situ growth of a GDY–MnO x heterointerface for selective and efficient ammonia production

inferred← citeshttps://doi.org/10.1039/d3cy01441jopenalex-snapshot

Palladium-based nanocatalysts for NH 3 synthesis through nitrate electroreduction: nanocomposites, alloys, and atomically precise nanoclusters

inferred← citeshttps://doi.org/10.1039/d3ee01301dopenalex-snapshot

Laser-controlled tandem catalytic sites of CuNi alloys with ampere-level electrocatalytic nitrate-to-ammonia reduction activities for Zn–nitrate batteries

inferred← citeshttps://doi.org/10.1039/d3gc03823hopenalex-snapshot

A Cu loaded NiFe layered double hydroxide bifunctional electrocatalyst with a coupled interface structure for both the nitrate reduction reaction and oxygen evolution reaction

inferred← citeshttps://doi.org/10.1039/d3qi00568bopenalex-snapshot

Exploring the origin of the high electro-catalytic activity for nitrate-to-ammonia conversion on electrodeposited Ni/Ru hydroxide hybrids

inferred← citeshttps://doi.org/10.1039/d3qi01248dopenalex-snapshot

Molecular inspired electrocatalyst materials for environmental remediation

inferred← citeshttps://doi.org/10.1039/d4ee00222aopenalex-snapshot

Rethinking nitrate reduction: redirecting electrochemical efforts from ammonia to nitrogen for realistic environmental impacts

inferred← citeshttps://doi.org/10.1039/d4gc04640dopenalex-snapshot

Review of carbon-based catalysts for electrochemical nitrate reduction and green ammonia synthesis

inferred← citeshttps://doi.org/10.1039/d4qi01632gopenalex-snapshot

Octahedral CoS 2 electrocatalysts for efficient nitrate reduction to ammonia

inferred← citeshttps://doi.org/10.1039/d4ta00998copenalex-snapshot

Coupling electrocatalytic redox-active sites in a three-dimensional bimetalloporphyrin-based covalent organic framework for enhancing carbon dioxide reduction and oxygen evolution

inferred← citeshttps://doi.org/10.1039/d4ta08549copenalex-snapshot

Isomeric bipyridine-based covalent organic frameworks for efficient electrocatalytic nitrate reduction to ammonia

inferred← citeshttps://doi.org/10.1039/d5cc01680kopenalex-snapshot

Pd-based bimetallic nanosheets for a highly efficient nitrate reduction reaction

inferred← citeshttps://doi.org/10.1039/d5cy01336dopenalex-snapshot

pH-Dependent electrolyte manipulation in nitrate electroreduction to ammonia

inferred← citeshttps://doi.org/10.1039/d5ee05927eopenalex-snapshot

Dynamically forming a Cu 3 Mo 2 O 9 /Cu heterojunction for efficient nitrate reduction in Zn–nitrate batteries

inferred← citeshttps://doi.org/10.1039/d5nr04795aopenalex-snapshot

Synchronizing carrier extraction and dielectric coupling in a hierarchical homometallic plasmonic catalyst for light-driven nitrate reduction

inferred← citeshttps://doi.org/10.1039/d5sc03323copenalex-snapshot

Multi-enzyme reaction inspired photocatalysis for solar-driven CO 2 reduction to ethane

inferred← citeshttps://doi.org/10.1039/d5sc07183fopenalex-snapshot

Strong d–p orbital hybridization in cobalt porphyrin cages promotes electrochemical nitrate reduction to ammonia

inferred← citeshttps://doi.org/10.1039/d5ta07989fopenalex-snapshot

Efficient ammonia synthesis via electrocatalytic nitrate reduction over a [8 + 2]-connected three-dimensional metal-bipyridine covalent organic framework

inferred← citeshttps://doi.org/10.1039/d6cc01155aopenalex-snapshot

Porphyrin-based covalent organic frameworks for electrocatalytic NO x reduction and C–N coupling reactions

inferred← citeshttps://doi.org/10.1039/d6cc02827fopenalex-snapshot

High-performance electrocatalytic nitrate reduction to ammonia enabled by a copper-porphyrin-based porous aromatic framework

inferred← citeshttps://doi.org/10.1039/d6cc04024aopenalex-snapshot

Engineering the chelation microenvironment in isomeric covalent organic frameworks for efficient nitrate electroreduction

inferred← citeshttps://doi.org/10.1039/d6dt00996dopenalex-snapshot

Spin–lattice relaxation of copper and vanadyl porphyrins in extended molecular framework materials

inferred← citeshttps://doi.org/10.1039/d6ta04042jopenalex-snapshot

High-entropy materials for electrochemical nitrogen conversion: a new frontier in sustainable catalysis

inferred← citeshttps://doi.org/10.1073/pnas.2306461120openalex-snapshot

Atomic coordination environment engineering of bimetallic alloy nanostructures for efficient ammonia electrosynthesis from nitrate

inferred← citeshttps://doi.org/10.1073/pnas.2311149120openalex-snapshot

Constructing molecule-metal relay catalysis over heterophase metallene for high-performance rechargeable zinc-nitrate/ethanol batteries

inferred← citeshttps://doi.org/10.1126/sciadv.ado9664openalex-snapshot

Plasmonic Pd-Sb nanosheets for photothermal CH 4 conversion to HCHO and therapy

inferred← citeshttps://doi.org/10.1134/s0036023624600138openalex-snapshot

Synthesis and Design of Metalloporphyrin Oligomers with Temperature-Assisted Spectral-Luminescent Properties

inferred← citeshttps://doi.org/10.1134/s1070363225603783openalex-snapshot

Analysis and Research Progress of Nitrate Products in Electrocatalytic Reduction of Water (A Review)

inferred← citeshttps://doi.org/10.21203/rs.3.rs-5538574/v1openalex-snapshot

Multi-enzyme reaction inspired cascade photocatalysis for solar-driven CO2 reduction to ethane

inferred← citeshttps://doi.org/10.3390/catal14080532openalex-snapshot

Application of Different Waveforms of Pulsed Current in the Classical Electro-Cocatalytic Process for Effective Removal of Sulfamethoxazole: Oxidation Mechanisms

inferred← citeshttps://doi.org/10.3390/molecules30193910openalex-snapshot

Progress and Challenges in the Electrocatalytic Reduction of Nitrate to Ammonia

inferred← citeshttps://doi.org/10.3390/polym15041055openalex-snapshot

Synthesis and Design of Hybrid Metalloporphyrin Polymers Based on Palladium (II) and Copper (II) Cations and Axial Complexes of Pyridyl-Substituted Sn(IV)Porphyrins with Octopamine

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