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Catalytic asymmetric synthesis of enantioenriched α-deuterated pyrrolidine derivatives

https://doi.org/10.1039/d2sc00826b
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Outgoing claims: the papers this work cites, builds on, or argues with.

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Catalytic Stereoinversion of L ‐Alanine to Deuterated D ‐Alanine
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Enantiospecific CH Activation Using Ruthenium Nanocatalysts
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Deuterium‐ and Tritium‐Labelled Compounds: Applications in the Life Sciences
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C−H Functionalisation for Hydrogen Isotope Exchange
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Stable isotopically labeled internal standards in quantitative bioanalysis using liquid chromatography/mass spectrometry: necessity or not?
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Mechanistic considerations on catalytic H/D exchange mediated by organometallic transition metal complexes
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Photoredox-Catalyzed Enantioselective α-Deuteration of Azaarenes with D2O
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A new chiral catalyst for the enantioselective synthesis of secondary alcohols and deuterated primary alcohols by carbonyl reduction
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Enantioselective synthesis of α-carbon deuterium-labelled l -α-amino acids
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Catalytic Asymmetric Reactions with N -Metallated Azomethine Ylides
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Recent Developments for the Deuterium and Tritium Labeling of Organic Molecules
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Switching Diastereoselectivity in Catalytic Enantioselective (3+2) Cycloadditions of Azomethine Ylides Promoted by Metal Salts and Privileged Segphos-Derived Ligands
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inferredcites →https://doi.org/10.1021/acs.oprd.7b00227openalex-snapshot
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inferredcites →https://doi.org/10.1021/acs.orglett.0c00112openalex-snapshot
Asymmetric Umpolung Hydrogenation and Deuteration of Alkenes Catalyzed by Nickel
inferredcites →https://doi.org/10.1021/acs.orglett.0c00154openalex-snapshot
Synthesis of Enantioenriched α-Deuterated α-Amino Acids Enabled by an Organophotocatalytic Radical Approach
inferredcites →https://doi.org/10.1021/acscatal.0c03437openalex-snapshot
Hybrid Chemo-, Bio-, and Electrocatalysis for Atom-Efficient Deuteration of Cofactors in Heavy Water
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The Deuterium Isotope Effect
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Complex Induced Proximity Effects: Enantioselective Syntheses Based on Asymmetric Deprotonations of N-Boc-pyrrolidines
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β-Substituted Alkenyl Heteroarenes as Dipolarophiles in the Cu(I)-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Ylides Empowered by a Dual Activation Strategy: Stereoselectivity and Mechanistic Insight
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Stereoretentive Deuteration of α-Chiral Amines with D 2 O
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Small-Molecule Inhibitors of the MDM2–p53 Protein–Protein Interaction (MDM2 Inhibitors) in Clinical Trials for Cancer Treatment
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inferredcites →https://doi.org/10.1039/c1ob06319gopenalex-snapshot
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inferredcites →https://doi.org/10.1039/c2cc31443fopenalex-snapshot
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inferredcites →https://doi.org/10.1039/c7ob02686bopenalex-snapshot
Catalytic asymmetric construction of spiropyrrolidines via 1,3-dipolar cycloaddition of azomethine ylides
inferredcites →https://doi.org/10.1039/c9cc05238kopenalex-snapshot
Stereochemical diversity in pyrrolidine synthesis by catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides
inferredcites →https://doi.org/10.1039/d1cc01610eopenalex-snapshot
Enantioselective decarboxylative protonation and deuteration of β-ketocarboxylic acids
inferredcites →https://doi.org/10.1073/pnas.1417832112openalex-snapshot
Differentiation of antiinflammatory and antitumorigenic properties of stabilized enantiomers of thalidomide analogs
inferredcites →https://doi.org/10.1126/science.147.3657.463openalex-snapshot
Chemistry of Isotopes

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1002/ange.202301091openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202301091openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/chem.202300296openalex-snapshot
Catalytic Enantioselective [3+2] Cycloaddition of N‐Metalated Azomethine Ylides
inferred← citeshttps://doi.org/10.1002/chem.202402045openalex-snapshot
Binary Catalytic Hydrogen/Deuterium Exchange of Free α‐Amino Acids and Derivatives
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Natural product synthesis facilitated by the deuterium isotope effects (DIE)
inferred← citeshttps://doi.org/10.1016/j.gresc.2024.06.003openalex-snapshot
Electrochemical selective deuterium labelling of N-heteroarenes
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2023.122831openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/j.tchem.2026.100164openalex-snapshot
Recent advances in catalytic α-deuteration of carbonyl compounds
inferred← citeshttps://doi.org/10.1021/acs.joc.4c02860openalex-snapshot
Nickel-Catalyzed One-Pot H/D Exchange and Asymmetric Michael Addition in the Presence of D2O
inferred← citeshttps://doi.org/10.1021/acs.joc.6c00493openalex-snapshot
Accessing NH -Pyrrolidines from 1,4-Dicarbonyl Compounds via Catalytic Dioxime Cyclization
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c02102openalex-snapshot
Stereodivergent Synthesis of Enantioenriched α-Deuterated α-Amino Acids via Cascade Cu(I)-Catalyzed H–D Exchange and Dual Cu- and Ir-Catalyzed Allylation
inferred← citeshttps://doi.org/10.1021/acsomega.3c09974openalex-snapshot
Site-Selective Deuteration of α‑Amino Esters with 2‑Hydroxynicotinaldehyde as a Catalyst
inferred← citeshttps://doi.org/10.1038/s41467-025-57098-wopenalex-snapshot
Access to N-α-deuterated amino acids and DNA conjugates via Ca(II)-HFIP-mediated reductive deutero-amination of α-oxo-carbonyl compounds
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Catalytic asymmetric deuterosilylation of exocyclic olefins with mannose-derived thiols and deuterium oxide
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Electron-rich benzofulvenes as effective dipolarophiles in copper( i )-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides
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Metal catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides: structural diversity at the dipole partner
inferred← citeshttps://doi.org/10.1039/d4qo01728eopenalex-snapshot
Visible-light-induced thiol-mediated transfer hydrogenation/deuteration of activated alkenes, imines and azo compounds
inferred← citeshttps://doi.org/10.1039/d5cc02730fopenalex-snapshot
Lanthanide complexes of aminopolycarboxylates reveal deuteration of aminoacetate carbons in alkaline aqueous media
inferred← citeshttps://doi.org/10.1039/d5cc04336kopenalex-snapshot
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Atroposelective [4+1] annulation for the synthesis of isotopic isoindolinones bearing both central and axial chirality
inferred← citeshttps://doi.org/10.1055/a-2508-3790openalex-snapshot
Nickel(II)-Catalyzed Cycloisomerization of 1,6-Dienes
inferred← citeshttps://doi.org/10.3390/catal13040648openalex-snapshot
Straightforward and Efficient Deuteration of Terminal Alkynes with Copper Catalysis
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Brønsted Base-Catalyzed Assembly of Sulfochromeno[4,3-b]-pyrrolidines via Michael-Mannich-SuFEx Tandem Reaction of o-Hydroxy Schiff Bases and Vinylsulfonyl Fluorides
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