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The confusion about S-scheme electron transfer: critical understanding and a new perspective

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Internal Electric Field on Steering Charge Migration: Modulations, Determinations and Energy‐Related Applications
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Boosting Photocatalytic Hydrogen Production via Interfacial Engineering on 2D Ultrathin Z‐Scheme ZnIn 2 S 4 /g‐C 3 N 4 Heterojunction
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Unique Step‐Scheme Heterojunction Photoelectrodes for Dual‐Utilization of Light and Chemical Neutralization Energy in Switchable Dual‐Mode Batteries
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Organic Planar Heterojunctions: From Models for Interfaces in Bulk Heterojunctions to High‐Performance Solar Cells
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An Inorganic/Organic S‐Scheme Heterojunction H 2 ‐Production Photocatalyst and its Charge Transfer Mechanism
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Emerging of Heterostructure Materials in Energy Storage: A Review
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Photocatalytic Z‐Scheme Overall Water Splitting: Recent Advances in Theory and Experiments
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Emerging S‐Scheme Photocatalyst
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Site‐Specific Electron‐Driving Observations of CO 2 ‐to‐CH 4 Photoreduction on Co‐Doped CeO 2 /Crystalline Carbon Nitride S‐Scheme Heterojunctions
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A Twin S‐Scheme Artificial Photosynthetic System with Self‐Assembled Heterojunctions Yields Superior Photocatalytic Hydrogen Evolution Rate
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2D Material‐Based Heterostructures for Rechargeable Batteries
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Electron Transfer Reactions in Chemistry: Theory and Experiment (Nobel Lecture)
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Photoelectrochemistry and heterogeneous photo-catalysis at semiconductors
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inferredcites →https://doi.org/10.1016/j.apcatb.2018.11.011openalex-snapshot
Ultrathin 2D/2D WO3/g-C3N4 step-scheme H2-production photocatalyst
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inferredcites →https://doi.org/10.1016/j.apcatb.2021.120179openalex-snapshot
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inferredcites →https://doi.org/10.1016/j.cclet.2023.108724openalex-snapshot
Effective strategies to promote Z(S)-scheme photocatalytic water splitting
inferredcites →https://doi.org/10.1016/j.ccr.2021.213953openalex-snapshot
Heterojunction catalyst in electrocatalytic water splitting
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Principles, synthesis and applications of dual Z-scheme photocatalysts
inferredcites →https://doi.org/10.1016/j.chempr.2020.06.010openalex-snapshot
S-Scheme Heterojunction Photocatalyst
inferredcites →https://doi.org/10.1016/j.jmst.2022.02.035openalex-snapshot
Review on g-C3N4-based S-scheme heterojunction photocatalysts
inferredcites →https://doi.org/10.1016/j.matt.2022.09.009openalex-snapshot
S-scheme heterojunction photocatalysts for CO2 reduction
inferredcites →https://doi.org/10.1016/j.mattod.2020.09.004openalex-snapshot
2D g-C3N4 for advancement of photo-generated carrier dynamics: Status and challenges
inferredcites →https://doi.org/10.1016/j.mattod.2021.02.017openalex-snapshot
A review of material aspects in developing direct Z-scheme photocatalysts
inferredcites →https://doi.org/10.1016/j.nanoen.2017.08.032openalex-snapshot
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inferredcites →https://doi.org/10.1016/j.nanoen.2023.108228openalex-snapshot
Internal electric field in carbon nitride-based heterojunctions for photocatalysis
inferredcites →https://doi.org/10.1016/j.physrep.2022.07.003openalex-snapshot
Z-scheme systems: From fundamental principles to characterization, synthesis, and photocatalytic fuel-conversion applications
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Emerging frontiers of Z-scheme photocatalytic systems
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Carbon Nitride-Based Heterojunction Photoelectrodes with Modulable Charge-Transfer Pathways toward Selective Biosensing
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inferredcites →https://doi.org/10.1021/acs.jpclett.8b02369openalex-snapshot
Direct Z-Scheme Water Splitting Photocatalyst Based on Two-Dimensional Van Der Waals Heterostructures
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inferredcites →https://doi.org/10.1021/acscatal.9b04753openalex-snapshot
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inferredcites →https://doi.org/10.1021/acsenergylett.1c02516openalex-snapshot
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Accelerated Ionic and Charge Transfer through Atomic Interfacial Electric Fields for Superior Sodium Storage
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Advanced Nanoarchitectures for Solar Photocatalytic Applications
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Molecular Z-Scheme for Solar Fuel Production via Dual Photocatalytic Cycles
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Charge Carrier Activity on Single-Particle Photo(electro)catalysts: Toward Function in Solar Energy Conversion
inferredcites →https://doi.org/10.1021/jacs.8b08309openalex-snapshot
Photoinduced Charge-Transfer Dynamics in WO3/BiVO4 Photoanodes Probed through Midinfrared Transient Absorption Spectroscopy
inferredcites →https://doi.org/10.1021/jacs.9b12835openalex-snapshot
Transient Absorption Spectroscopy Offers Mechanistic Insights for an Iridium/Nickel-Catalyzed C–O Coupling
inferredcites →https://doi.org/10.1038/ncomms7951openalex-snapshot
Impact of charge transport on current–voltage characteristics and power-conversion efficiency of organic solar cells
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Simple processing of back-contacted silicon heterojunction solar cells using selective-area crystalline growth
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inferredcites →https://doi.org/10.1038/s41467-021-25261-8openalex-snapshot
Anion-exchange-mediated internal electric field for boosting photogenerated carrier separation and utilization
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Perovskite phase heterojunction solar cells
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Inter-facet junction effects on particulate photoelectrodes
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Highly efficient photosynthesis of hydrogen peroxide in ambient conditions
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What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1016/j.cjsc.2025.100630openalex-snapshot
Polymeric carbon nitride for photocatalytic overall water splitting: Modification strategies and recent advances
inferred← citeshttps://doi.org/10.1016/j.cjsc.2026.100870openalex-snapshot
Localized Co3O4/In2S3 S-scheme heterojunction by polarization engineering for achieving an exceptional H2 efficiency
inferred← citeshttps://doi.org/10.1016/j.cjsc.2026.100889openalex-snapshot
g-C3N4-based S-scheme heterojunction photocatalyst and its application
inferred← citeshttps://doi.org/10.1016/j.cjsc.2026.101049openalex-snapshot
Perovskite-based S-scheme heterojunction photocatalysts: Mechanisms, activity-stability trade-offs, and rational design strategies
inferred← citeshttps://doi.org/10.1016/j.electacta.2026.149983openalex-snapshot
From Type‑I to S‑Scheme: Coordination-bridged CuInS₂-CdS heterojunction for enhanced photocathodic protection
inferred← citeshttps://doi.org/10.1016/j.enchem.2025.100159openalex-snapshot
Rational design and interfacial engineering of hierarchical S-scheme heterojunction and their photocatalytic applications
inferred← citeshttps://doi.org/10.1016/j.fuel.2025.138155openalex-snapshot
Spillover enhanced CexBi1-xVO4/ByC3-yN4 S-scheme heterojunction for sustainable hydrogen production
inferred← citeshttps://doi.org/10.1016/j.gee.2024.09.008openalex-snapshot
Fe-O-Bi efficient electron transfer channels and photo-Fenton synergy in S-scheme heterojunctions: Insights into interfacial interactions and ofloxacin degradation
inferred← citeshttps://doi.org/10.1016/j.ijhydene.2024.07.156openalex-snapshot
How to determine whether an electron transfer channel is type-II or S-scheme in g–C3N4–based photocatalysts? A critical review
inferred← citeshttps://doi.org/10.1016/j.ijhydene.2024.11.218openalex-snapshot
The polarization effect promotes 2D GeSe/XS2 (X=Sn, Zr, Hf) van der Waals heterostructure formed S-scheme photocatalyst
inferred← citeshttps://doi.org/10.1016/j.ijhydene.2025.06.047openalex-snapshot
Synthesis, photocatalytic hydrogen evolution performance of Zn0.5Cd0.5S/TiO2 S-scheme heterojunction nanofibers
inferred← citeshttps://doi.org/10.1016/j.ijhydene.2026.154656openalex-snapshot
Construction of Ni-doped CdS/MXene Ohmic heterojunction to enhance photocatalytic hydrogen evolution
inferred← citeshttps://doi.org/10.1016/j.ijhydene.2026.157409openalex-snapshot
NiS-to-Ti3C2 MXene interfacial electron transfer to weaken Ti-Hads bond via toward efficient photocatalytic hydrogen evolution
inferred← citeshttps://doi.org/10.1016/j.ijhydene.2026.157740openalex-snapshot
Rational design and performance parameter of direct Z-scheme heterojunction materials for efficient HER/OER photocatalytic water splitting
inferred← citeshttps://doi.org/10.1016/j.jallcom.2025.183382openalex-snapshot
Interfacial Ni–S bond mediated Z-scheme LaNiO3/Sv-ZnIn2S4 heterojunction for boosted photocatalytic H2 evolution
inferred← citeshttps://doi.org/10.1016/j.jallcom.2026.188095openalex-snapshot
Synergistic N − doping and In2O3 heterojunction engineering in Fe2O3 for enhanced charge separation toward efficient photocathodic protection
inferred← citeshttps://doi.org/10.1016/j.jcis.2024.07.223openalex-snapshot
Synchronous optimization of H2O and H adsorption on NiO1-Te nanodots for alkaline photocatalytic H2 evolution
inferred← citeshttps://doi.org/10.1016/j.jcis.2025.137383openalex-snapshot
The hierarchical assembly of ultra-thin polymeric carbon nitride nanosheet on LaOBr for enhanced photocatalytic overall water splitting
inferred← citeshttps://doi.org/10.1016/j.jcis.2025.138075openalex-snapshot
Microwave assisted rapid synthesis of TiO2 NFs@COF S-scheme heterojunction photocatalyst for highly efficient photocatalytic hydrogen evolution
inferred← citeshttps://doi.org/10.1016/j.jece.2025.118625openalex-snapshot
Interfacial engineering of ZnSn(OH)6/SnO2 S-scheme heterojunctions for high-performance solar-light-driven photocatalytic nitric oxide oxidation
inferred← citeshttps://doi.org/10.1016/j.jece.2025.120038openalex-snapshot
Preventing molecular catalyst aggregation in Z-scheme photocatalyst for unassisted CO2 reduction
inferred← citeshttps://doi.org/10.1016/j.jechem.2026.03.010openalex-snapshot
Unified light-thermal-diffusion coupling multi-mechanism kinetic model for gas-solid photocatalytic CO2 reduction with experimental and simulation validation
inferred← citeshttps://doi.org/10.1016/j.jechem.2026.05.001openalex-snapshot
In situ S-scheme heterojunction of CuO islands on 2D N-TiO2 with dynamic Cu2+/Cu+ sites for selective CO2-to-C2H4 photoreduction
inferred← citeshttps://doi.org/10.1016/j.jenvman.2024.123703openalex-snapshot
A comprehensive review on TiO2-based heterogeneous photocatalytic technologies for emerging pollutants removal from water and wastewater: From engineering aspects to modeling approaches
inferred← citeshttps://doi.org/10.1016/j.jhazmat.2025.138060openalex-snapshot
Dual-site Langmuir-Hinshelwood mechanism in ZnCr-LDH/NH2-UIO66 heterojunction for efficient photocatalytic NO oxidation
inferred← citeshttps://doi.org/10.1016/j.jhazmat.2025.140208openalex-snapshot
Photocatalytic mineralization of gaseous formaldehyde over silver-doped metal oxide/MOF heterostructure with a mediator-assisted hybridized step (MAH-S)-scheme charge configuration
inferred← citeshttps://doi.org/10.1016/j.jiec.2024.10.018openalex-snapshot
A review of Fe2O3-based S-scheme heterojunction photocatalysts for pollutant removal
inferred← citeshttps://doi.org/10.1016/j.jmat.2024.100982openalex-snapshot
Single-atom catalysts in the catalytic production of H2O2
inferred← citeshttps://doi.org/10.1016/j.jmat.2024.100998openalex-snapshot
Design of double oxygen vacancy-rich Bi2O2S0.8F0.4/BiOBr S-scheme heterojunction via tuning band structure for CO2 photoreduction
inferred← citeshttps://doi.org/10.1016/j.jmst.2025.02.056openalex-snapshot
CeO2/WO2.72 nanocomposites with S-scheme heterojunctions and oxygen vacancies for enhanced photocatalytic degradation of dichlorvos
inferred← citeshttps://doi.org/10.1016/j.jmst.2025.07.006openalex-snapshot
Investigating the charge transfer mechanism of 1D/2D ZnO/SnIn4S8 S-scheme heterojunction for efficient photocatalytic hydrogen evolution
inferred← citeshttps://doi.org/10.1016/j.matlet.2024.137324openalex-snapshot
One-step conversion of FeOCl/Fe2O3 to BiOCl/Fe2O3 for boosted visible-light-driven photocatalysis
inferred← citeshttps://doi.org/10.1016/j.mattod.2024.11.012openalex-snapshot
Quantum dots in S-scheme photocatalysts
inferred← citeshttps://doi.org/10.1016/j.mcat.2024.114700openalex-snapshot
Regulating electrons transfer through Pd-O-Bi bridges for boosting photocatalytic CO2 reduction
inferred← citeshttps://doi.org/10.1016/j.mcat.2026.116328openalex-snapshot
In situ construction of an s-scheme Bi2MoO6/Bi2WO6 heterojunction with dynamic oxygen vacancies for synergistic and efficient photocatalytic CO2 reduction
inferred← citeshttps://doi.org/10.1016/j.mseb.2025.118724openalex-snapshot
Novel design of mesoporous step-scheme CuMn2O4/ZnWO4 photocatalyst for visible-light-induced H2 evolution: Enhancing charge separation and expanding light photon absorption
inferred← citeshttps://doi.org/10.1016/j.pmatsci.2026.101663openalex-snapshot
Chalcogenide cocatalysts in photocatalytic H2 production
inferred← citeshttps://doi.org/10.1016/j.seppur.2024.129100openalex-snapshot
Enhanced photocatalytic CO2 conversion into reusable fuels with efficient solid-state proton donors
inferred← citeshttps://doi.org/10.1016/j.solener.2026.114758openalex-snapshot
Advances in SnO2 based S-scheme heterojunctions for photocatalytic energy conversion and environmental remediation
inferred← citeshttps://doi.org/10.1016/s1872-2067(24)60119-1openalex-snapshot
Activating d10 electronic configuration to regulate p-band centers as efficient active sites for solar energy conversion into H2 by surface atomic arrangement
inferred← citeshttps://doi.org/10.1016/s1872-2067(24)60159-2openalex-snapshot
Dynamic proton migration in dual linkage-engineered D-π-A system for photosynthesis H2O2 generation
inferred← citeshttps://doi.org/10.1016/s1872-2067(24)60257-3openalex-snapshot
Solar-driven H2O2 production by S-scheme heterojunction photocatalyst
inferred← citeshttps://doi.org/10.1016/s1872-2067(24)60265-2openalex-snapshot
Boosting charge transfer at inorganic/organic S-scheme interface for photo-Fenton degradation of antibiotics and bacterial inactivation
inferred← citeshttps://doi.org/10.1016/s1872-2067(26)65156-xopenalex-snapshot
Revealing the mechanism of asymmetric charge carrier extraction
inferred← citeshttps://doi.org/10.1016/s1872-2067(26)65190-xopenalex-snapshot
Organic-inorganic DVA-COF@TiO2 S-scheme heterojunction for highly selective photocatalytic reduction of CO2 to CO
inferred← citeshttps://doi.org/10.1021/acs.accounts.5c00899openalex-snapshot
S-Scheme Shapes Heterojunction Photocatalysis
inferred← citeshttps://doi.org/10.1021/acs.chemmater.5c00647openalex-snapshot
Synergism between Surface Engineering and S-Scheme Heterojunctions for Efficient Photocatalytic H 2 Evolution
inferred← citeshttps://doi.org/10.1021/acs.energyfuels.5c02891openalex-snapshot
Spontaneous Phase-Transformed Interface to Boost Tandem Reoxidation for CO2 Reduction and OTC Degradation via Synergistic Photothermal Effect
inferred← citeshttps://doi.org/10.1021/acsami.6c11516openalex-snapshot
In Situ Fabrication of a Highly Active Heterophase Junction for Photocatalytic Water Oxidation through Dual Modulation of Phase Composition and Micromorphology of BiVO4
inferred← citeshttps://doi.org/10.1021/acsami.6c13087openalex-snapshot
Interfacial Built-In Electric Field-Driven S-Scheme g-C3N4/S-Doped TiO2 Heterojunction for Boosting Photocatalytic NO Abatement
inferred← citeshttps://doi.org/10.1021/acsanm.5c02685openalex-snapshot
Static Internal Electric Field in Heterojunctions Composed of O–C3N4 Nanosheets Decorated with NH2-MIL-101(Cr) Nanoparticles for Photocatalytic Hydrogen Evolution
inferred← citeshttps://doi.org/10.1021/acscatal.5c07539openalex-snapshot
Coordination-Deficient Ni Sites Strengthen Orbital Coupling for Enhanced Photocatalytic H 2 O 2 Production
inferred← citeshttps://doi.org/10.1021/acsnano.5c08341openalex-snapshot
Enhancing CO Selectivity in CO 2 Photoreduction via Local Hydrophobic Modifications in S-Scheme Heterojunctions
inferred← citeshttps://doi.org/10.1021/acsnano.5c11198openalex-snapshot
Modulating Carrier Dynamics in Halide Perovskites through Lattice Strain Engineering of CsPb1–xCuxBr3 for Improved Photocatalytic CO2 Reduction
inferred← citeshttps://doi.org/10.1021/acssensors.6c00490openalex-snapshot
Harnessing Thermoelectric-Mediated Photoelectrochemical System to Address Sensitive Dopamine Detection via APE1-Amplified Triple-Helix Switching
inferred← citeshttps://doi.org/10.1038/s41467-026-71647-xopenalex-snapshot
Regulating interface electric field to stabilize high-voltage KVPO4F positive electrode for sustainable potassium-ion batteries
inferred← citeshttps://doi.org/10.1038/s41570-025-00698-3openalex-snapshot
Charge-transfer dynamics in S-scheme photocatalyst
inferred← citeshttps://doi.org/10.1039/d4qi00950aopenalex-snapshot
Recent advancements in graphitic carbon nitride based direct Z- and S-scheme heterostructures for photocatalytic H 2 O 2 production
inferred← citeshttps://doi.org/10.1039/d4sc05873aopenalex-snapshot
Strain-induced charge delocalization achieves ultralow exciton binding energy toward efficient photocatalysis
inferred← citeshttps://doi.org/10.1039/d4ta01857eopenalex-snapshot
A g-C 3 N 4 /rGO/Cs 3 Bi 2 Br 9 mediated Z-scheme heterojunction for enhanced photocatalytic CO 2 reduction
inferred← citeshttps://doi.org/10.1039/d5cy00838gopenalex-snapshot
Directional electron transfer from CoS 2 to Mo 2 C for weakening Mo–H bonds toward boosting photocatalytic H 2 production
inferred← citeshttps://doi.org/10.1039/d5ra02705eopenalex-snapshot
Advances in Co 3 O 4 nanomaterial-based photocatalysts for water purification: mechanisms, green synthesis, activation of oxidants, waste-derived sources, and computational insights
inferred← citeshttps://doi.org/10.1039/d5ra04984aopenalex-snapshot
Fe 2 O 3 /g-C 3 N 4 /CdS photocatalysts for complete sunlight-active detoxification of the tetracycline antibiotic and Congo red dye in water
inferred← citeshttps://doi.org/10.1039/d5ta03629aopenalex-snapshot
Multi-hydrogen adsorption of amorphous ReS x cocatalysts for boosting photocatalytic hydrogen evolution
inferred← citeshttps://doi.org/10.1039/d5tc03772gopenalex-snapshot
NiOOH-mediated electron injection into Ti 3 C 2 F x to weaken Ti–H bonds for accelerated photocatalytic hydrogen production
inferred← citeshttps://doi.org/10.1039/d6ay01094fopenalex-snapshot
NIR-driven ROS generation by carbon nitride heterojunctions enables selective detection of copper ions in whole blood
inferred← citeshttps://doi.org/10.1039/d6ra06664jopenalex-snapshot
ZrO 2 -based heterojunction engineering for enhanced visible-light photocatalysis: a review
inferred← citeshttps://doi.org/10.1039/d6ta04223fopenalex-snapshot
Sandwich-structured BiOBr–BiOI–BiOBr heterojunctions with an electron-type quantum well for tunable charge carrier migration
inferred← citeshttps://doi.org/10.21203/rs.3.rs-3993258/v1openalex-snapshot
Revealing the mechanism of charge storage induced hole catalysis
inferred← citeshttps://doi.org/10.3390/catal14060374openalex-snapshot
S-Scheme Heterojunction Photocatalysts for CO2 Reduction
inferred← citeshttps://doi.org/10.3866/pku.whxb202405019openalex-snapshot
Hierarchical S-Scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO2 Triggering Efficient Photocatalytic Hydrogen Production
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