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Low temperature thermal RAFT depolymerization: the effect of Z-group substituents on molecular weight control and yield

https://doi.org/10.1039/d4sc07518h
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/9783527821358.ch8openalex-snapshot
Dithioesters in RAFT Polymerization
inferredcites →https://doi.org/10.1002/ange.202309116openalex-snapshot
Solvent‐Free Chemical Recycling of Polymethacrylates made by ATRP and RAFT polymerization: High‐Yielding Depolymerization at Low Temperatures
inferredcites →https://doi.org/10.1002/ange.202402436openalex-snapshot
Photocatalytic Upcycling and Depolymerization of Vinyl Polymers
inferredcites →https://doi.org/10.1002/anie.202313232openalex-snapshot
Temporal Regulation of PET‐RAFT Controlled Radical Depolymerization
inferredcites →https://doi.org/10.1002/asia.201300262openalex-snapshot
RAFT Polymerization and Some of its Applications
inferredcites →https://doi.org/10.1002/marc.200500832openalex-snapshot
Computational Studies of RAFT Polymerization–Mechanistic Insights and Practical Applications
inferredcites →https://doi.org/10.1002/pi.2988openalex-snapshot
End‐functional polymers, thiocarbonylthio group removal/transformation and reversible addition–fragmentation–chain transfer (RAFT) polymerization
inferredcites →https://doi.org/10.1002/pol.20240255openalex-snapshot
Enhancing photothermal depolymerization with metalloporphyrin catalyst
inferredcites →https://doi.org/10.1007/s00894-009-0476-3openalex-snapshot
Theoretical evaluation of the order of reactivity of transfer agents utilized in RAFT polymerization: group Z
inferredcites →https://doi.org/10.1016/j.chempr.2023.07.004openalex-snapshot
Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer
inferredcites →https://doi.org/10.1016/j.chempr.2023.09.027openalex-snapshot
Controlled radical depolymerization: Structural differentiation and molecular weight control
inferredcites →https://doi.org/10.1016/j.eurpolymj.2019.08.008openalex-snapshot
Controlled radical depolymerization of chlorine-capped PMMA via reversible activation of the terminal group by ruthenium catalyst
inferredcites →https://doi.org/10.1016/j.eurpolymj.2023.112721openalex-snapshot
RAFT polymerization of renewable monomers with dithiobenzoates: Effect of Z-group substituents and reaction conditions
inferredcites →https://doi.org/10.1016/j.progpolymsci.2020.101311openalex-snapshot
Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications
inferredcites →https://doi.org/10.1021/acs.macromol.1c00415openalex-snapshot
Depolymerization of P(PDMS11MA) Bottlebrushes via Atom Transfer Radical Polymerization with Activator Regeneration
inferredcites →https://doi.org/10.1021/acs.macromol.1c02246openalex-snapshot
Copper(II) Chloride/Tris(2-pyridylmethyl)amine-Catalyzed Depolymerization of Poly(n-butyl methacrylate)
inferredcites →https://doi.org/10.1021/acs.macromol.2c01712openalex-snapshot
Depolymerization of Polymethacrylates by Iron ATRP
inferredcites →https://doi.org/10.1021/acs.macromol.7b00767openalex-snapshot
50th Anniversary Perspective : RAFT Polymerization─A User Guide
inferredcites →https://doi.org/10.1021/acsmacrolett.2c00506openalex-snapshot
Investigating the Effect of End-Group, Molecular Weight, and Solvents on the Catalyst-Free Depolymerization of RAFT Polymers: Possibility to Reverse the Polymerization of Heat-Sensitive Polymers
inferredcites →https://doi.org/10.1021/acsmacrolett.2c00603openalex-snapshot
Photoassisted Radical Depolymerization
inferredcites →https://doi.org/10.1021/acsmacrolett.3c00389openalex-snapshot
Fast Bulk Depolymerization of Polymethacrylates by ATRP
inferredcites →https://doi.org/10.1021/acsmacrolett.3c00418openalex-snapshot
Fate of the RAFT End-Group in the Thermal Depolymerization of Polymethacrylates
inferredcites →https://doi.org/10.1021/acsmacrolett.4c00286openalex-snapshot
Thermal Solution Depolymerization of RAFT Telechelic Polymers
inferredcites →https://doi.org/10.1021/cr00002a004openalex-snapshot
A survey of Hammett substituent constants and resonance and field parameters
inferredcites →https://doi.org/10.1021/jacs.2c00963openalex-snapshot
Reversing RAFT Polymerization: Near-Quantitative Monomer Generation Via a Catalyst-Free Depolymerization Approach
inferredcites →https://doi.org/10.1021/jacs.3c00589openalex-snapshot
Reversed Controlled Polymerization (RCP): Depolymerization from Well-Defined Polymers to Monomers
inferredcites →https://doi.org/10.1021/jacs.3c14179openalex-snapshot
Bulk Depolymerization of Methacrylate Polymers via Pendent Group Activation
inferredcites →https://doi.org/10.1021/jacs.4c05621openalex-snapshot
Open-Air Chemical Recycling: Fully Oxygen-Tolerant ATRP Depolymerization
inferredcites →https://doi.org/10.1021/ma020882hopenalex-snapshot
Thiocarbonylthio Compounds [SC(Ph)S−R] in Free Radical Polymerization with Reversible Addition-Fragmentation Chain Transfer (RAFT Polymerization). Role of the Free-Radical Leaving Group (R)
inferredcites →https://doi.org/10.1021/ma047814aopenalex-snapshot
Effect of Substituents on Radical Stability in Reversible Addition Fragmentation Chain Transfer Polymerization: An ab Initio Study
inferredcites →https://doi.org/10.1021/ma0480650openalex-snapshot
Searching for More Effective Agents and Conditions for the RAFT Polymerization of MMA: Influence of Dithioester Substituents, Solvent, and Temperature
inferredcites →https://doi.org/10.1021/ma0513970openalex-snapshot
Thermal Decomposition of Cumyl Dithiobenzoate
inferredcites →https://doi.org/10.1021/ma062897bopenalex-snapshot
Effects of Initiator Structure on Activation Rate Constants in ATRP
inferredcites →https://doi.org/10.1021/ma062919uopenalex-snapshot
Thiocarbonylthio End Group Removal from RAFT-Synthesized Polymers by Radical-Induced Reduction
inferredcites →https://doi.org/10.1021/ma300410vopenalex-snapshot
RAFT Agent Design and Synthesis
inferredcites →https://doi.org/10.1021/ma300616gopenalex-snapshot
Chain Transfer Kinetics of Acid/Base Switchable N-Aryl-N-Pyridyl Dithiocarbamate RAFT Agents in Methyl Acrylate, N-Vinylcarbazole and Vinyl Acetate Polymerization
inferredcites →https://doi.org/10.1038/s41467-024-46656-3openalex-snapshot
Light-driven polymer recycling to monomers and small molecules
inferredcites →https://doi.org/10.1038/s41570-021-00328-8openalex-snapshot
A comparison of RAFT and ATRP methods for controlled radical polymerization
inferredcites →https://doi.org/10.1039/b9py00340aopenalex-snapshot
End group removal and modification of RAFT polymers
inferredcites →https://doi.org/10.1039/c8py00446copenalex-snapshot
Reversible-addition fragmentation chain transfer (RAFT) mediated depolymerization of brush polymers
inferredcites →https://doi.org/10.1039/d0py01086copenalex-snapshot
Substituent effects in iniferter photopolymerization: can bond homolysis be enhanced by electronics?
inferredcites →https://doi.org/10.1039/d2py01383eopenalex-snapshot
Light-accelerated depolymerization catalyzed by Eosin Y
inferredcites →https://doi.org/10.1039/d3lp00279aopenalex-snapshot
Chemical recycling of bromine-terminated polymers synthesized by ATRP
inferredcites →https://doi.org/10.1039/d3sc05143aopenalex-snapshot
The thermodynamics and kinetics of depolymerization: what makes vinyl monomer regeneration feasible?
inferredcites →https://doi.org/10.1071/ch9850677openalex-snapshot
Concerning the Problem of the Isokinetic Relationship. III. The Temperature-Dependance of the hammett Equation
inferredcites →https://doi.org/10.1080/15583724.2011.568130openalex-snapshot
On the Critical Role of RAFT Agent Design in Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization
inferredcites →https://doi.org/10.31635/ccschem.022.202201987openalex-snapshot
Degradable and Recyclable Polymers by Reversible Deactivation Radical Polymerization

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← backgroundhttps://doi.org/10.5281/zenodo.16364844zenodo-depositor-declared
inferred← citeshttps://doi.org/10.1002/advs.77962openalex-snapshot
Controlled Atom Transfer Radical Depolymerization
inferred← citeshttps://doi.org/10.1002/ange.6957018openalex-snapshot
Chlorine‐Free Depolymerization of Commercial PMMA via Oxygen‐Centered Radicals
inferred← citeshttps://doi.org/10.1002/anie.6957018openalex-snapshot
Chlorine‐Free Depolymerization of Commercial PMMA via Oxygen‐Centered Radicals
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2026.115011openalex-snapshot
Visible-light HAT depolymerization of PMMA-based copolymers: Comonomer-dependent efficiency and selective monomer recovery
inferred← citeshttps://doi.org/10.1021/acs.macromol.6c01500openalex-snapshot
Lipoic Acid Without the Side Chain: Sublimable Homopolymers and Degradable Copolymers Based on 1,2-Dithiolane
inferred← citeshttps://doi.org/10.1021/acsmacrolett.5c00740openalex-snapshot
Depolymerization of Vinyl Polymers
inferred← citeshttps://doi.org/10.1021/jacs.5c18937openalex-snapshot
Depolymerization-Induced Morphological Transformation
inferred← citeshttps://doi.org/10.1039/d5py00576kopenalex-snapshot
Reversible addition–fragmentation chain transfer depolymerization of poly(methyl methacrylate) in toluene
inferred← citeshttps://doi.org/10.1039/d6cc04531fopenalex-snapshot
ATRP depolymerization of lignin-derived polymethacrylates
inferred← citeshttps://doi.org/10.1039/d6gc02089eopenalex-snapshot
C–H chlorination and bulk depolymerization of commercial poly(methyl methacrylate)
inferred← citeshttps://doi.org/10.1557/s43579-026-01013-xopenalex-snapshot
Synthesis of degradable polymers via RAFT polymerization
inferred← citeshttps://doi.org/10.2533/chimia.2025.484openalex-snapshot
Chemical Recycling of Polymethacrylates
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