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Assessing WHAM/Model VII against field measurements of free metal ion concentrations: model performance and the role of uncertainty in parameters and inputs

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Speciation in Freshwaters
inferredcites →https://doi.org/10.1002/etc.518openalex-snapshot
TICKET-UWM: A coupled kinetic, equilibrium, and transport screening model for metals in lakes
inferredcites →https://doi.org/10.1002/etc.5620201034openalex-snapshot
BIOTIC LIGAND MODEL OF THE ACUTE TOXICITY OF METALS. 1. TECHNICAL BASIS
inferredcites →https://doi.org/10.1007/bf00877641openalex-snapshot
Free cupric ion concentrations and Cu complexation in selected Swiss lakes and rivers
inferredcites →https://doi.org/10.1007/s10498-006-9004-6openalex-snapshot
Effects of pH and Ca competition on complexation of cadmium by fulvic acids and by natural organic ligands from a river and a lake
inferredcites →https://doi.org/10.1007/s10498-008-9027-2openalex-snapshot
Determination of Free Nickel Ion Concentrations Using the Ion Exchange Technique: Application to Aqueous Mining and Municipal Effluents
inferredcites →https://doi.org/10.1007/s10498-008-9040-5openalex-snapshot
The Chemical Speciation of Fe(III) in Freshwaters
inferredcites →https://doi.org/10.1007/s10498-009-9074-3openalex-snapshot
Determination of Free Cd, Cu and Zn Concentrations in Lake Waters by In Situ Diffusion Followed by Column Equilibration Ion-exchange
inferredcites →https://doi.org/10.1016/0003-2670(94)85057-7openalex-snapshot
Zinc speciation in lake waters and its determination by ligand exchange with EDTA and differential pulse anodic stripping voltammetry
inferredcites →https://doi.org/10.1016/0016-7037(76)90092-2openalex-snapshot
Error propagation by the Monte Carlo method in geochemical calculations
inferredcites →https://doi.org/10.1016/0043-1354(91)90079-6openalex-snapshot
Humic substances in acid surface waters; modelling aluminium binding, contribution to ionic charge-balance, and control of pH
inferredcites →https://doi.org/10.1016/0098-3004(94)90038-8openalex-snapshot
WHAMC—A chemical equilibrium model and computer code for waters, sediments, and soils incorporating a discrete site/electrostatic model of ion-binding by humic substances
inferredcites →https://doi.org/10.1016/j.aca.2003.12.052openalex-snapshot
Speciation of copper and zinc in natural freshwater: comparison of voltammetric measurements, diffusive gradients in thin films (DGT) and chemical equilibrium models
inferredcites →https://doi.org/10.1016/j.aca.2004.10.003openalex-snapshot
Complexation of Ni, Cu, Zn, and Cd by DOC in some metal-impacted freshwater lakes: a comparison of approaches using electrochemical determination of free-metal-ion and labile complexes and a computer speciation model, WHAM V and VI
inferredcites →https://doi.org/10.1016/j.aca.2006.06.070openalex-snapshot
Speciation of nickel in surface waters measured with the Donnan membrane technique
inferredcites →https://doi.org/10.1016/j.envpol.2004.12.027openalex-snapshot
The United Kingdom Acid Waters Monitoring Network: a review of the first 15 years and introduction to the special issue
inferredcites →https://doi.org/10.1016/j.envpol.2005.08.019openalex-snapshot
Simulating the long-term chemistry of an upland UK catchment: Heavy metals
inferredcites →https://doi.org/10.1016/j.gca.2004.09.033openalex-snapshot
The effects of database parameter uncertainty on uranium(VI) equilibrium calculations
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Distinguishing between terrestrial and autochthonous organic matter sources in marine environments using fluorescence spectroscopy
inferredcites →https://doi.org/10.1016/j.scitotenv.2010.12.030openalex-snapshot
Aluminium speciation in streams and lakes of the UK Acid Waters Monitoring Network, modelled with WHAM
inferredcites →https://doi.org/10.1016/s0003-2670(00)00935-1openalex-snapshot
Determination of the chemical speciation of trace metals in aqueous systems by the Wageningen Donnan Membrane Technique
inferredcites →https://doi.org/10.1016/s0016-7037(02)00930-4openalex-snapshot
Al(III) and Fe(III) binding by humic substances in freshwaters, and implications for trace metal speciation
inferredcites →https://doi.org/10.1016/s0016-7037(03)00087-5openalex-snapshot
Competition between iron- and carbon-based colloidal carriers for trace metals in a freshwater assessed using flow field-flow fractionation coupled to ICPMS
inferredcites →https://doi.org/10.1016/s0016-7037(98)00183-5openalex-snapshot
An assemblage model for cation binding by natural particulate matter
inferredcites →https://doi.org/10.1016/s0016-7037(99)00253-7openalex-snapshot
Geochemical factors controlling free Cu ion concentrations in river water
inferredcites →https://doi.org/10.1016/s0016-7037(99)00270-7openalex-snapshot
The solubility of iron hydroxide in sodium chloride solutions
inferredcites →https://doi.org/10.1016/s0048-9697(00)00418-6openalex-snapshot
Solid-solution metal partitioning in the Humber rivers: application of WHAM and SCAMP
inferredcites →https://doi.org/10.1016/s1532-0456(02)00083-2openalex-snapshot
Comparison of measured and modelled copper binding by natural organic matter in freshwaters
inferredcites →https://doi.org/10.1021/es00002a022openalex-snapshot
Metal Ion Binding to Humic Substances: Application of the Non-Ideal Competitive Adsorption Model
inferredcites →https://doi.org/10.1021/es050367+openalex-snapshot
Kinetic Limitations in Measuring Stabilities of Metal Complexes by Competitive Ligand Exchange-Adsorptive Stripping Voltammetry (CLE-AdSV)
inferredcites →https://doi.org/10.1021/es051246copenalex-snapshot
Model Predictions of Metal Speciation in Freshwaters Compared to Measurements by In Situ Techniques
inferredcites →https://doi.org/10.1021/es051435vopenalex-snapshot
Measuring Free Metal Ion Concentrations in Situ in Natural Waters Using the Donnan Membrane Technique
inferredcites →https://doi.org/10.1021/es103425sopenalex-snapshot
HILIC-NMR: Toward the Identification of Individual Molecular Components in Dissolved Organic Matter
inferredcites →https://doi.org/10.1021/es103532aopenalex-snapshot
Metal Complexation Properties of Freshwater Dissolved Organic Matter Are Explained by Its Aromaticity and by Anthropogenic Ligands
inferredcites →https://doi.org/10.1021/es201716uopenalex-snapshot
Response to Comment on “HILIC-NMR: Toward the Identification of Individual Molecular Components in Dissolved Organic Matter”
inferredcites →https://doi.org/10.1021/es902615wopenalex-snapshot
Uncertainty Analysis of the Nonideal Competitive Adsorption−Donnan Model: Effects of Dissolved Organic Matter Variability on Predicted Metal Speciation in Soil Solution
inferredcites →https://doi.org/10.1021/es971018lopenalex-snapshot
Complexation of Cobalt by Natural Ligands in Freshwater
inferredcites →https://doi.org/10.1023/a:1009627214459openalex-snapshot
Humic Ion-Binding Model VI: An Improved Description of the Interactions of Protons and Metal Ions with Humic Substances
inferredcites →https://doi.org/10.1023/a:1009679819002openalex-snapshot
Comparison of the Complexation of Cu and Cd by Humic or Fulvic Acids and by Ligands Observed in Lake Waters
inferredcites →https://doi.org/10.1071/en08027openalex-snapshot
Assessing toxicity of mining effluents: equilibrium- and kinetics-based metal speciation and algal bioassay
inferredcites →https://doi.org/10.1071/en11016openalex-snapshot
Humic Ion-Binding Model VII: a revised parameterisation of cation-binding by humic substances
inferredcites →https://doi.org/10.1080/03067318408076957openalex-snapshot
A Procedure for the Fractionation of Aqueous Aluminum in Dilute Acidic Waters
inferredcites →https://doi.org/10.1080/03067319808035889openalex-snapshot
An Ion-Exchange Technique for Free-Metal Ion Measurements (Cd2+Zn2+): Applications to Complex Aqueous Media
inferredcites →https://doi.org/10.1897/02-626openalex-snapshot
Development and field validation of a biotic ligand model predicting chronic copper toxicity to Daphnia magna
inferredcites →https://doi.org/10.1897/04-229r.1openalex-snapshot
Bioavailability models for predicting acute and chronic toxicity of zinc to algae, daphnids, and fish in natural surface waters
inferredcites →https://doi.org/10.4319/lo.1993.38.6.1200openalex-snapshot
Free cupric ion concentration and Cu(II) speciation in a eutrophic lake
inferredcites →https://doi.org/10.4319/lo.2005.50.3.0995openalex-snapshot
Lead and copper speciation in remote mountain lakes

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Interaction between nickel and cobalt toxicity inEnchytraeus crypticusis due to competitive uptake
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inferred← citeshttps://doi.org/10.1021/es4045314openalex-snapshot
Comparative Examination of Effects of Binding of Different Metals on Chromophores of Dissolved Organic Matter
inferred← citeshttps://doi.org/10.1021/es500173eopenalex-snapshot
Mechanistic Insights from DGT and Soil Solution Measurements on the Uptake of Ni and Cd by Radish
inferred← citeshttps://doi.org/10.1021/es502243mopenalex-snapshot
Fractionation of Fulvic Acid by Iron and Aluminum Oxides─Influence on Copper Toxicity to Ceriodaphnia dubia
inferred← citeshttps://doi.org/10.1029/2023gl104957openalex-snapshot
Acidification Of Northeastern USA Lakes From Rising Anthropogenic‐Sourced Atmospheric Carbon Dioxide and Its Effects on Aluminum Speciation
inferred← citeshttps://doi.org/10.1039/c1em10407aopenalex-snapshot
Estimation of Model VII humic binding constants for Pd2+, Sn2+, U4+, NpO22+, Pu4+ and PuO22+
inferred← citeshttps://doi.org/10.1039/c3em00370aopenalex-snapshot
Lability, solubility and speciation of Cd, Pb and Zn in alluvial soils of the River Trent catchment UK
inferred← citeshttps://doi.org/10.1039/c5em00204dopenalex-snapshot
Photochemical behavior of antibiotics impacted by complexation effects of concomitant metals: a case for ciprofloxacin and Cu( ii )
inferred← citeshttps://doi.org/10.1071/en11156openalex-snapshot
Trace metal speciation predictions in natural aquatic systems: incorporation of dissolved organic matter (DOM) spectroscopic quality
inferred← citeshttps://doi.org/10.1071/en13153openalex-snapshot
Predicting PbII adsorption on soils: the roles of soil organic matter, cation competition and iron (hydr)oxides
inferred← citeshttps://doi.org/10.1071/en13216openalex-snapshot
Interpretation of heavy metal speciation in sequential extraction using geochemical modelling
inferred← citeshttps://doi.org/10.1071/en15111openalex-snapshot
Metal speciation from stream to open ocean: modelling v. measurement
inferred← citeshttps://doi.org/10.1071/en15136openalex-snapshot
Determination of the free-ion concentration of rare earth elements by an ion-exchange technique: implementation, evaluation and limits
inferred← citeshttps://doi.org/10.1071/en16039openalex-snapshot
PEST-ORCHESTRA, a tool for optimising advanced ion-binding model parameters: derivation of NICA-Donnan model parameters for humic substances reactivity
inferred← citeshttps://doi.org/10.1071/en19194openalex-snapshot
Estimation of WHAM7 constants for GaIII, InIII, SbIII and BiIII from linear free energy relationships, and speciation calculations for natural waters
inferred← citeshttps://doi.org/10.1071/en21100openalex-snapshot
POSSMs: a parsimonious speciation model for metals in soils
inferred← citeshttps://doi.org/10.1071/en23021openalex-snapshot
Nickel and copper complexation by natural dissolved organic matter – titration of two contrasting lake waters and comparison of measured and modelled free metal ion concentrations
inferred← citeshttps://doi.org/10.1071/en23049openalex-snapshot
Rare earth elements binding humic acids: NICA–Donnan modelling
inferred← citeshttps://doi.org/10.1071/en24054openalex-snapshot
Aqueous lead speciation determined using DNAzyme GR5
inferred← citeshttps://doi.org/10.1071/env8n5_foopenalex-snapshot
Introduction to a special issue on trace metal speciation – GEOSPEC 2010
inferred← citeshttps://doi.org/10.1080/09542299.2017.1404437openalex-snapshot
Is the computed speciation of copper in a wide range of Chinese soils reliable?
inferred← citeshttps://doi.org/10.1080/09542299.2018.1452635openalex-snapshot
Trace metal speciation in a wastewater wetland and its bioaccumulation in tilapia Oreochromis niloticus
inferred← citeshttps://doi.org/10.1081/e-ess3-120053724openalex-snapshot
Trace Metal Contamination
inferred← citeshttps://doi.org/10.1093/etojnl/vgaf230openalex-snapshot
Incorporation of metal speciation data into QICAR models and application to data-poor technology-critical elements
inferred← citeshttps://doi.org/10.1111/jfb.70157openalex-snapshot
The acute osmoregulatory effects of low pH and Cu, alone and in combination, on the dwarf cichlid ( Apistogramma agassizii ) in Rio Negro blackwater and Rio Solimões whitewater: Flux rates of ions, nitrogenous wastes and water
inferred← citeshttps://doi.org/10.1180/minmag.2012.076.8.52openalex-snapshot
Uranyl binding to humic acid under conditions relevant to cementitious geological disposal of radioactive wastes
inferred← citeshttps://doi.org/10.1366/13-07231openalex-snapshot
Modeling Metal Binding by Dissolved Humic Substance: A Revisit to the Fluorometric Titration Approach
inferred← citeshttps://doi.org/10.1366/14-07835openalex-snapshot
Combination of a Copper-Ion Selective Electrode and Fluorometric Titration for the Determination of Copper(II) Ion Conditional Stability Constants of Humic Substances
inferred← citeshttps://doi.org/10.2166/wst.2016.269openalex-snapshot
Assessing bioavailability levels of metals in effluent-affected rivers: effect of Fe(III) and chelating agents on the distribution of metal speciation
inferred← citeshttps://doi.org/10.3390/environments11040065openalex-snapshot
Dissolved Iron and Organic Matter in Boreal Rivers across a South–North Transect
inferred← citeshttps://doi.org/10.5539/ep.v2n3p92openalex-snapshot
Chemical Speciation: A Strategic Pathway for Insightful Risk Assessment and Decision Making for Remediation of Toxic Metal Contamination
inferred← citeshttps://doi.org/10.70675/5237edffzffb9z480fzb630z373f02306f2aopenalex-snapshot
Impact de la composition minéralogique des sédiments sur la biodisponibilité de l’Uranium ˸ Une approche intégrant laboratoire-terrain-bioindicateur-calcul de spéciation
inferred← citeshttps://doi.org/10.70675/55097d96zdd05z46dczaff0z167cd8a50f06openalex-snapshot
Aluminium geochemistry in coastal lowland acid sulfate soils (CLASS) : speciation, reactivity and mobility
inferred← citeshttps://doi.org/10.70675/79b9b5aczb281z49c8zabe3z30bb24f8492aopenalex-snapshot
Biodisponibilité du cuivre et du zinc pour les plantes et les vers de terre : interactions entre les effets de fertilisants organiques sur le long-terme et des organismes sur l'évolution des propriétés physico-chimiques du sol
inferred← citeshttps://doi.org/10.70675/d3e79930z6197z4af1z97e1z5ffea31ec2c9openalex-snapshot
Caractérisation et quantification de la charge polluante anthropique et industrielle dans le bassin du Sebou
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