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Programmed fluorine binding engineering in anion-pillared metal-organic framework for record trace acetylene capture from ethylene

https://doi.org/10.1126/sciadv.adh0135
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/adma.201704210openalex-snapshot
An Ideal Molecular Sieve for Acetylene Removal from Ethylene with Record Selectivity and Productivity
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A Chemically Stable Hofmann‐Type Metal−Organic Framework with Sandwich‐Like Binding Sites for Benchmark Acetylene Capture
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Designer Metal–Organic Frameworks for Size‐Exclusion‐Based Hydrocarbon Separations: Progress and Challenges
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Thermodynamics of mixed‐gas adsorption
inferredcites →https://doi.org/10.1002/anie.201107534openalex-snapshot
High Propene/Propane Selectivity in Isostructural Metal–Organic Frameworks with High Densities of Open Metal Sites
inferredcites →https://doi.org/10.1002/anie.201804442openalex-snapshot
Separation of Acetylene from Carbon Dioxide and Ethylene by a Water‐Stable Microporous Metal–Organic Framework with Aligned Imidazolium Groups inside the Channels
inferredcites →https://doi.org/10.1002/anie.201806732openalex-snapshot
Robust Ultramicroporous Metal–Organic Frameworks with Benchmark Affinity for Acetylene
inferredcites →https://doi.org/10.1002/anie.201904160openalex-snapshot
Induced Fit of C 2 H 2 in a Flexible MOF Through Cooperative Action of Open Metal Sites
inferredcites →https://doi.org/10.1002/anie.202009446openalex-snapshot
Efficient Trapping of Trace Acetylene from Ethylene in an Ultramicroporous Metal–Organic Framework: Synergistic Effect of High‐Density Open Metal and Electronegative Sites
inferredcites →https://doi.org/10.1002/anie.202013988openalex-snapshot
An Unprecedented Pillar‐Cage Fluorinated Hybrid Porous Framework with Highly Efficient Acetylene Storage and Separation
inferredcites →https://doi.org/10.1002/anie.202015861openalex-snapshot
Precise Pore Space Partitions Combined with High‐Density Hydrogen‐Bonding Acceptors within Metal–Organic Frameworks for Highly Efficient Acetylene Storage and Separation
inferredcites →https://doi.org/10.1002/anie.202016225openalex-snapshot
A MOF‐based Ultra‐Strong Acetylene Nano‐trap for Highly Efficient C2H2/CO2 Separation
inferredcites →https://doi.org/10.1002/anie.202016673openalex-snapshot
Host–Guest Interaction Modulation in Porous Coordination Polymers for Inverse Selective CO2/C2H2Separation
inferredcites →https://doi.org/10.1002/anie.202102585openalex-snapshot
Tetrazole‐Functionalized Zirconium Metal‐Organic Cages for Efficient C 2 H 2 /C 2 H 4 and C 2 H 2 /CO 2 Separations
inferredcites →https://doi.org/10.1002/anie.202106263openalex-snapshot
Benchmark Acetylene Binding Affinity and Separation through Induced Fit in a Flexible Hybrid Ultramicroporous Material
inferredcites →https://doi.org/10.1002/anie.202114132openalex-snapshot
Three‐in‐One C2H2‐Selectivity‐Guided Adsorptive Separation across an Isoreticular Family of Cationic Square‐Lattice MOFs
inferredcites →https://doi.org/10.1002/anie.202116145openalex-snapshot
The First Sulfate‐Pillared Hybrid Ultramicroporous Material, SOFOUR‐1‐Zn, and Its Acetylene Capture Properties
inferredcites →https://doi.org/10.1002/anie.202218274openalex-snapshot
Molecular Mechanisms behind Acetylene Adsorption and Selectivity in Functional Porous Materials
inferredcites →https://doi.org/10.1016/j.chempr.2016.10.009openalex-snapshot
Benchmark C2H2/CO2 and CO2/C2H2 Separation by Two Closely Related Hybrid Ultramicroporous Materials
inferredcites →https://doi.org/10.1016/j.chempr.2020.12.025openalex-snapshot
Tuning the gating energy barrier of metal-organic framework for molecular sieving
inferredcites →https://doi.org/10.1016/j.energy.2005.04.001openalex-snapshot
Olefins from conventional and heavy feedstocks: Energy use in steam cracking and alternative processes
inferredcites →https://doi.org/10.1016/j.eng.2017.02.006openalex-snapshot
New Trends in Olefin Production
inferredcites →https://doi.org/10.1016/j.fuel.2016.01.047openalex-snapshot
Thermal/catalytic cracking of liquid hydrocarbons for the production of olefins: A state-of-the-art review II: Catalytic cracking review
inferredcites →https://doi.org/10.1016/j.fuel.2019.04.127openalex-snapshot
Thermal/catalytic cracking of hydrocarbons for the production of olefins; a state-of-the-art review III: Process modeling and simulation
inferredcites →https://doi.org/10.1016/j.jechem.2022.05.023openalex-snapshot
Cascade adsorptive separation of light hydrocarbons by commercial zeolites
inferredcites →https://doi.org/10.1021/acs.accounts.1c00707openalex-snapshot
Reticular Chemistry for Highly Porous Metal–Organic Frameworks: The Chemistry and Applications
inferredcites →https://doi.org/10.1021/acs.cgd.5b01632openalex-snapshot
Crystal Engineering of a 4,6-c fsc Platform That Can Serve as a Carbon Dioxide Single-Molecule Trap
inferredcites →https://doi.org/10.1021/acs.chemmater.9b01691openalex-snapshot
Multipurpose Metal–Organic Framework for the Adsorption of Acetylene: Ethylene Purification and Carbon Dioxide Removal
inferredcites →https://doi.org/10.1021/acs.iecr.8b00950openalex-snapshot
Hexafluorogermanate (GeFSIX) Anion-Functionalized Hybrid Ultramicroporous Materials for Efficiently Trapping Acetylene from Ethylene
inferredcites →https://doi.org/10.1021/ja0113192openalex-snapshot
Framework Engineering by Anions and Porous Functionalities of Cu(II)/4,4‘-bpy Coordination Polymers
inferredcites →https://doi.org/10.1021/ja200553mopenalex-snapshot
Kinetic Separation of Propene and Propane in Metal−Organic Frameworks: Controlling Diffusion Rates in Plate-Shaped Crystals via Tuning of Pore Apertures and Crystallite Aspect Ratios
inferredcites →https://doi.org/10.1021/jacs.0c02594openalex-snapshot
Optimizing Pore Space for Flexible-Robust Metal–Organic Framework to Boost Trace Acetylene Removal
inferredcites →https://doi.org/10.1021/jacs.1c05564openalex-snapshot
Low-Valent Metal Ions as MOF Pillars: A New Route Toward Stable and Multifunctional MOFs
inferredcites →https://doi.org/10.1021/jacs.1c10620openalex-snapshot
Metal–Organic Framework Based Hydrogen-Bonding Nanotrap for Efficient Acetylene Storage and Separation
inferredcites →https://doi.org/10.1021/jacs.7b01682openalex-snapshot
Water Vapor Sorption in Hybrid Pillared Square Grid Materials
inferredcites →https://doi.org/10.1021/jacs.7b06397openalex-snapshot
M 2 ( m -dobdc) (M = Mn, Fe, Co, Ni) Metal–Organic Frameworks as Highly Selective, High-Capacity Adsorbents for Olefin/Paraffin Separations
inferredcites →https://doi.org/10.1021/jacs.8b13463openalex-snapshot
Metal–Organic Framework Containing Planar Metal-Binding Sites: Efficiently and Cost-Effectively Enhancing the Kinetic Separation of C2H2/C2H4
inferredcites →https://doi.org/10.1021/jacs.9b06582openalex-snapshot
Designing Open Metal Sites in Metal–Organic Frameworks for Paraffin/Olefin Separations
inferredcites →https://doi.org/10.1021/jacs.9b12924openalex-snapshot
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inferredcites →https://doi.org/10.1038/nature11893openalex-snapshot
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inferredcites →https://doi.org/10.1038/nchem.2114openalex-snapshot
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inferredcites →https://doi.org/10.1038/ncomms5228openalex-snapshot
Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture
inferredcites →https://doi.org/10.1038/ncomms8328openalex-snapshot
Microporous metal–organic framework with dual functionalities for highly efficient removal of acetylene from ethylene/acetylene mixtures
inferredcites →https://doi.org/10.1038/ncomms8575openalex-snapshot
A porous metal-organic framework with ultrahigh acetylene uptake capacity under ambient conditions
inferredcites →https://doi.org/10.1038/s41467-020-20101-7openalex-snapshot
Simultaneous interlayer and intralayer space control in two-dimensional metal−organic frameworks for acetylene/ethylene separation
inferredcites →https://doi.org/10.1038/s41563-022-01237-xopenalex-snapshot
Trace removal of benzene vapour using double-walled metal–dipyrazolate frameworks
inferredcites →https://doi.org/10.1038/s41570-019-0073-7openalex-snapshot
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inferredcites →https://doi.org/10.1038/s41586-021-03627-8openalex-snapshot
Orthogonal-array dynamic molecular sieving of propylene/propane mixtures
inferredcites →https://doi.org/10.1039/c6cy01886fopenalex-snapshot
Crude oil to chemicals: light olefins from crude oil
inferredcites →https://doi.org/10.1039/c7cs00153copenalex-snapshot
Gas/vapour separation using ultra-microporous metal–organic frameworks: insights into the structure/separation relationship
inferredcites →https://doi.org/10.1039/c7ta06658aopenalex-snapshot
Porphyrinic coordination lattices with fluoropillars
inferredcites →https://doi.org/10.1126/sciadv.abn9231openalex-snapshot
Synergistic binding sites in a hybrid ultramicroporous material for one-step ethylene purification from ternary C 2 hydrocarbon mixtures
inferredcites →https://doi.org/10.1126/science.1217544openalex-snapshot
Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
inferredcites →https://doi.org/10.1126/science.aaf2458openalex-snapshot
Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene
inferredcites →https://doi.org/10.1126/science.aaf6323openalex-snapshot
A metal-organic framework–based splitter for separating propylene from propane
inferredcites →https://doi.org/10.1126/science.aam7232openalex-snapshot
Controlling guest conformation for efficient purification of butadiene
inferredcites →https://doi.org/10.1126/science.aam8310openalex-snapshot
Hydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydration
inferredcites →https://doi.org/10.1126/science.aay8447openalex-snapshot
Control of zeolite pore interior for chemoselective alkyne/olefin separations
inferredcites →https://doi.org/10.1126/science.abj7659openalex-snapshot
Discrimination of xylene isomers in a stacked coordination polymer

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1002/ange.202417072openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ange.202505355openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ange.202506055openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ange.202522675openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ange.3036478openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ange.3781455openalex-snapshot
“Two‐in‐One” Anion Engineering Strategy for One‐Step Ethylene Purification From a Ternary Mixture
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Supramolecular Entanglement in a Hydrogen‐Bonded Organic Framework Enables Flexible‐Robust Porosity for Highly Efficient Purification of Natural Gas
inferred← citeshttps://doi.org/10.1002/anie.202411744openalex-snapshot
Achieving Record C 2 H 2 Packing Density for Highly Efficient C 2 H 2 /C 2 H 4 Separation with a Metal–Organic Framework Prepared by a Scalable Synthesis in Water
inferred← citeshttps://doi.org/10.1002/anie.202417072openalex-snapshot
In Situ Stimulus Response Study on the Acetylene/Ethylene Purification Process in MOFs
inferred← citeshttps://doi.org/10.1002/anie.202505355openalex-snapshot
Electrostatic Potential Matching in an Anion‐Pillared Framework for Benchmark Hexafluoroethane Purification from Ternary Mixture
inferred← citeshttps://doi.org/10.1002/anie.202506055openalex-snapshot
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Microporous Metal‐Containing Hydrogen‐Bonded Organic Frameworks with Benchmark C 2 H 2 Storage Density for Efficient C 2 H 2 /C 2 H 4 and C 2 H 2 /CO 2 Separations
inferred← citeshttps://doi.org/10.1002/anie.202518996openalex-snapshot
Tailored Synergistic Binding Environment in Metal‐Organic Frameworks for Record One‐Step Ethylene Purification from Multicomponent Mixtures
inferred← citeshttps://doi.org/10.1002/anie.202522675openalex-snapshot
Programmed Pore Engineering in an Isoreticular Triazole–MOF Series for One‐Step Ethylene Separation
inferred← citeshttps://doi.org/10.1002/anie.202524692openalex-snapshot
Optimal Host–Guest Fit in Metal‐Organic Frameworks to Achieve Record C 2 H 2 Packing Density for Trace Acetylene Capture
inferred← citeshttps://doi.org/10.1002/anie.202524721openalex-snapshot
Reticular Chemistry‐Guided Topology Engineering of Pillar‐Layer Metal−Organic Frameworks for Boosting SF 6 /N 2 Separation
inferred← citeshttps://doi.org/10.1002/anie.3036478openalex-snapshot
Engineering Frustrated Packing of Porous Organic Cages for Precision Acetylene–Ethylene Separation
inferred← citeshttps://doi.org/10.1002/anie.3781455openalex-snapshot
“Two‐in‐One” Anion Engineering Strategy for One‐Step Ethylene Purification From a Ternary Mixture
inferred← citeshttps://doi.org/10.1002/anie.4927904openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.7710650openalex-snapshot
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inferred← citeshttps://doi.org/10.1021/acscentsci.4c01125openalex-snapshot
Ultra-High Purity and Productivity Separation of CO 2 and C 2 H 2 from CH 4 in Rigid Layered Ultramicroporous Material
inferred← citeshttps://doi.org/10.1021/acsmaterialslett.4c02383openalex-snapshot
A Highly Stable Anion-Functionalized Cage-like Framework for Efficient Separation of MTO Products under Harsh Conditions
inferred← citeshttps://doi.org/10.1021/acsmaterialslett.5c00287openalex-snapshot
Immobilizing Functional Sites into Isoreticular Zinc-Based MOFs To Tune Pore Environment for Highly Efficient Methanol-to-Olefins (MTO) Product Separation
inferred← citeshttps://doi.org/10.1021/acsmaterialslett.5c00803openalex-snapshot
Flexible Pillar-Linkers in Metal–Organic Frameworks for C2H2/CO2 and C2H2/C2H4 Separation
inferred← citeshttps://doi.org/10.1021/cbe.3c00094openalex-snapshot
Sulfate-Pillared Adsorbent for Efficient Acetylene Separation from Carbon Dioxide and Ethylene
inferred← citeshttps://doi.org/10.1021/cbe.3c00115openalex-snapshot
Recent Advances of Multidentate Ligand-Based Anion-Pillared MOFs for Enhanced Separation and Purification Processes
inferred← citeshttps://doi.org/10.1021/cbe.4c00102openalex-snapshot
An MOF-Based Single-Molecule Propylene Nanotrap for Benchmark Propylene Capture from Ethylene
inferred← citeshttps://doi.org/10.1021/jacs.4c18209openalex-snapshot
Pore Space Partition Enabled by Lithium(I) Chelation of a Metal–Organic Framework for Benchmark C2H2/CO2 Separation
inferred← citeshttps://doi.org/10.1021/jacs.6c01019openalex-snapshot
Photo Capture of Water by Single Crystals of a Nonporous Metal–Organic Material
inferred← citeshttps://doi.org/10.1039/d3cs01163aopenalex-snapshot
Ionic porous materials: from synthetic strategies to applications in gas separation and catalysis
inferred← citeshttps://doi.org/10.1039/d3sc06076dopenalex-snapshot
Water-stable metal–organic frameworks (MOFs): rational construction and carbon dioxide capture
inferred← citeshttps://doi.org/10.1039/d4ay02147aopenalex-snapshot
A “turn-on” fluorescent sensor for the selective detection of erythromycin in aqueous solution
inferred← citeshttps://doi.org/10.1039/d4ce01250jopenalex-snapshot
Fine-tuning of gas uptake and selectivity in a hexafluorozirconate pillared coordination network that features two porous phases
inferred← citeshttps://doi.org/10.1039/d4dt02592jopenalex-snapshot
Two amino-functionalized metal–organic frameworks with different topologies for C 2 H 2 /C 2 H 4 separation
inferred← citeshttps://doi.org/10.1039/d4qi01511hopenalex-snapshot
Responsive structural adaptability in ultra-microporous frameworks: guest recognition and macroscopic shape transformations induced by spin transitions within single crystals
inferred← citeshttps://doi.org/10.1039/d4ta00330fopenalex-snapshot
Recent advances on metal–organic frameworks for deep purification of olefins
inferred← citeshttps://doi.org/10.1039/d4ta04528aopenalex-snapshot
A novel microporous hydrogen-bonded organic framework with electron-rich alkynyl groups for highly efficient C 2 H 6 /C 2 H 4 separation
inferred← citeshttps://doi.org/10.1039/d4ta06511eopenalex-snapshot
Engineering the pore size of interpenetrated metal–organic frameworks for molecular sieving separation of C 2 H 2 /C 2 H 4
inferred← citeshttps://doi.org/10.1039/d4ta07584fopenalex-snapshot
Highly efficient separation of C 2 H 2 from CO 2 and C 2 H 4 enabled by an anion-pillared metalloporphyrin MOF with sandwich-like binding sites
inferred← citeshttps://doi.org/10.1039/d4tc02284jopenalex-snapshot
Construction of urchin-like porous Co/CoO/C composites enabling high-performance wideband electromagnetic wave absorption
inferred← citeshttps://doi.org/10.1039/d5sc00697jopenalex-snapshot
A new type of C 2 H 2 binding site in a cis -bridging hexafluorosilicate ultramicroporous material that offers trace C 2 H 2 capture
inferred← citeshttps://doi.org/10.1039/d5sc01755fopenalex-snapshot
Oriented design and engineering of advanced metal–organic frameworks for light hydrocarbon separations
inferred← citeshttps://doi.org/10.1039/d5ta00248fopenalex-snapshot
Solvent-induced structural rearrangement in hydrogen-bonded organic frameworks for efficient ethane/ethylene separation
inferred← citeshttps://doi.org/10.1039/d5ta06693jopenalex-snapshot
Targeted tuning of water adsorption at P / P 0 = 0.2 in multivariate metal–organic frameworks for boosting water-sorption-driven refrigeration
inferred← citeshttps://doi.org/10.1039/d5tc02190aopenalex-snapshot
Fabrication of rod-like porous Co@graphene/CNT composites for superior wideband electromagnetic wave absorption
inferred← citeshttps://doi.org/10.1039/d6ta01944gopenalex-snapshot
A vinylene-linked covalent organic framework with optimized functional sites for efficient C 2 H 2 /C 2 H 4 separation
inferred← citeshttps://doi.org/10.1093/nsr/nwaf548openalex-snapshot
Supramolecular linker-directed assembly of a ‘trap-and-diffusion’ MOF for one-step purification of polymer-grade C2H4 from C2 hydrocarbons
inferred← citeshttps://doi.org/10.26599/nr.2025.94907617openalex-snapshot
Small changes, big impacts: Ultra-fine tuning of ultra-microporous MOFs with remarkable C 2H 2 selectivity
inferred← citeshttps://doi.org/10.26599/nr.2026.94908523openalex-snapshot
A V-shaped microporous metal-organic framework with multiple binding sites for highly efficient ethane/ethylene separation
inferred← citeshttps://doi.org/10.3390/foods14152580openalex-snapshot
Advances in Nanozyme Catalysis for Food Safety Detection: A Comprehensive Review on Progress and Challenges
inferred← citeshttps://doi.org/10.34133/research.0458openalex-snapshot
Single-Molecule Traps in Covalent Organic Frameworks for Selective Capture of C 2 H 2 from C 2 H 4 -Rich Gas Mixtures
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