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Aqueous Pyrite Oxidation and the Consequent Formation of Secondary Iron Minerals
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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Kinetics of the liquid‐phase oxidation of acid ferrous sulfate by the bacterium Thiobacillus ferrooxidens
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Biology ofThiobacillus ferrooxidans in relation to the microbiological leaching of sulphide ores
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The Electrochemistry of Sulphide Minerals
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Oxygen Reduction on Sulphide Minerals
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Jarosite-geoethite stabilities at 25 �C, 1 ATM
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The ecology of resource degradation and renewal
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Microbial biogeochemistry
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Supergene alteration of sulphides, I. A chemical model based on massive nickel sulphide deposits at Kambalda, Western Australia
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Oxidation of sulfide minerals, 4. Pyrite, chalcopyrite and pyrrhotite
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Anodic behaviour of pyrite in acid solutions
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Biogeochemistry and bacteriology of ferrous iron oxidation in geothermal habitats
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Water pollution microbiology
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Evaluation of pyritic oxidation by mossbauer spectrometry
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Effect of graphite on the enhancement of surficial geochemical anomalies originating from the oxidation of sulphides
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Minerals in soil environments
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METABOLIC MECHANISMS OF IRON-OXIDIZING THIOBACILLI
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The Biochemistry of Inorganic Compounds of Sulphur
inferredcites →https://doi.org/10.1021/bk-1979-0093.ch003openalex-snapshot
Redox Equilibria of Iron in Acid Mine Waters
inferredcites →https://doi.org/10.1021/es60068a001openalex-snapshot
pH-Dependent succession of iron bacteria
inferredcites →https://doi.org/10.1021/ja01600a004openalex-snapshot
Kinetics of the Ferrous Iron-Oxygen Reaction in Sulfuric Acid Solution
inferredcites →https://doi.org/10.1080/00138396808691156openalex-snapshot
ROMANTICISM IN ENGLISH POETRY
inferredcites →https://doi.org/10.1080/01490457909377742openalex-snapshot
Thiobacillus ferrooxidansand the formation of acidity in simulated coal mine environments
inferredcites →https://doi.org/10.1093/jaoac/58.6.1308openalex-snapshot
Aqueous-Environmental Chemistry of Metals
inferredcites →https://doi.org/10.1099/00221287-105-2-215openalex-snapshot
Nitrogen Fixation by Thiobacillus ferrooxidans
inferredcites →https://doi.org/10.1099/00221287-72-2-369openalex-snapshot
An Acid-tolerant Iron-oxidizing Metallogenium
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Oxidation of Pyrite
inferredcites →https://doi.org/10.1126/science.167.3921.1121openalex-snapshot
Acidic Mine Drainage: The Rate-Determining Step
inferredcites →https://doi.org/10.1126/science.175.4026.1124openalex-snapshot
Chalcocite Oxidation and Coupled Carbon Dioxide Fixation by Thiobacillus ferrooxidans
inferredcites →https://doi.org/10.1128/aem.32.4.567-571.1976openalex-snapshot
Ferric iron reduction by sulfur- and iron-oxidizing bacteria
inferredcites →https://doi.org/10.1128/aem.6.4.281-287.1958openalex-snapshot
Microorganisms in Leaching Sulfide Minerals
inferredcites →https://doi.org/10.1128/am.6.4.281-287.1958openalex-snapshot
Microorganisms in Leaching Sulfide Minerals
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Aerobic Heterotrophic Bacteria Indigenous to p H 2.8 Acid Mine Water: Microscopic Examination of Acid Streamers
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Aerobic Heterotrophic Bacteria Indigenous to p H 2.8 Acid Mine Water: Predominant Slime-Producing Bacteria in Acid Streamers
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STUDIES ON THE CHEMOAUTOTROPHIC IRON BACTERIUM FERROBACILLUS FERROOXIDANS
inferredcites →https://doi.org/10.1128/jb.85.1.78-83.1963openalex-snapshot
SULFATE REQUIREMENT FOR IRON OXIDATION BY THIOBACILLUS FERROOXIDANS
inferredcites →https://doi.org/10.1128/jb.94.4.1046-1051.1967openalex-snapshot
Mechanism of Bacterial Pyrite Oxidation
inferredcites →https://doi.org/10.1128/jb.96.4.1433-1434.1968openalex-snapshot
Direct sulfide oxidation in the solubilization of sulfide ores by Thiobacillus ferrooxidans
inferredcites →https://doi.org/10.1139/m74-023openalex-snapshot
Oxidation of metal sulfides by Thiobacillus ferrooxidans grown on different substrates
inferredcites →https://doi.org/10.1139/m75-040openalex-snapshot
Thiobacillus acidophilus sp. nov.; isolation and some physiological characteristics
inferredcites →https://doi.org/10.1146/annurev.pc.23.100172.002035openalex-snapshot
Kinetics of Heterogeneous Systems
inferredcites →https://doi.org/10.1149/1.2427160openalex-snapshot
Mechanisms of Inorganic Reactions; A Study of Metal Complexes in Solution
inferredcites →https://doi.org/10.1179/000844376795050462openalex-snapshot
Decomposition of pyrite in acids by pressure leaching and anodization: the case for an electrochemical mechanism
inferredcites →https://doi.org/10.14288/1.0106132openalex-snapshot
A kinetic study of the oxidation of pyrite in aqueous suspension.
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Oxidation of Elemental Sulfur in Soils
inferredcites →https://doi.org/10.2475/ajs.279.6.609openalex-snapshot
Behavior of major solutes during closed-basin brine evolution
inferredcites →https://doi.org/10.3133/pp285openalex-snapshot
Geology and base-metal deposits of West Shasta copper-zinc district, Shasta County, California
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Rates of reaction of pyrite and marcasite with ferric iron at pH 2
inferred← citeshttps://doi.org/10.1016/0016-7037(86)90325-xopenalex-snapshot
Oxidation of pyrite in low temperature acidic solutions: Rate laws and surface textures
inferred← citeshttps://doi.org/10.1016/0016-7037(87)90127-xopenalex-snapshot
Pyrite oxidation and reduction: Molecular orbital theory considerations
inferred← citeshttps://doi.org/10.1016/0016-7037(88)90262-1openalex-snapshot
Pyrite oxidation in carbonate-buffered solution: 1. Experimental kinetics
inferred← citeshttps://doi.org/10.1016/0016-7037(89)90356-6openalex-snapshot
Interpretation of sulfur and oxygen isotopes in biological and abiological sulfide oxidation
inferred← citeshttps://doi.org/10.1016/0016-7037(90)90009-aopenalex-snapshot
A poorly crystallized oxyhydroxysulfate of iron formed by bacterial oxidation of Fe(II) in acid mine waters
inferred← citeshttps://doi.org/10.1016/0016-7037(91)90005-popenalex-snapshot
Pyrite oxidation at circumneutral pH
inferred← citeshttps://doi.org/10.1016/0016-7037(91)90132-oopenalex-snapshot
A vibrational spectroscopic 18O tracer study of pyrite oxidation
inferred← citeshttps://doi.org/10.1016/0016-7037(92)90002-zopenalex-snapshot
Correlation between structure and thermodynamic properties of aqueous sulfur species
inferred← citeshttps://doi.org/10.1016/0016-7037(93)90406-mopenalex-snapshot
Stability relations of jarosite and natrojarosite at 150–250°C
inferred← citeshttps://doi.org/10.1016/0016-7037(94)90117-1openalex-snapshot
Interaction between aqueous uranium (VI) and sulfide minerals: Spectroscopic evidence for sorption and reduction
inferred← citeshttps://doi.org/10.1016/0016-7037(94)90473-1openalex-snapshot
analysis of supergene jarosite and alunite: Implications to the paleoweathering history of the western USA and West Africa
inferred← citeshttps://doi.org/10.1016/0016-7061(87)90013-9openalex-snapshot
Micromorphological and SEM analysis of cretaceous-paleogene petrosols from Eastern Montana and western North Dakota
inferred← citeshttps://doi.org/10.1016/0022-1694(94)90133-3openalex-snapshot
The interaction of acid mine drainage with a carbonate terrane: evidence from the Obey River, north-central Tennessee
inferred← citeshttps://doi.org/10.1016/0038-0717(91)90121-yopenalex-snapshot
Influence of biological inhibitors on the oxidation of pyritic mine spoil
inferred← citeshttps://doi.org/10.1016/0043-1354(94)00287-hopenalex-snapshot
Chemical conditions in acidic water in the Plain of Reeds, Viet Nam
inferred← citeshttps://doi.org/10.1016/0166-5162(83)90008-3openalex-snapshot
Observations on low-temperature oxidation of minerals in bituminous coals
inferred← citeshttps://doi.org/10.1016/0169-1368(91)90026-4openalex-snapshot
Geochemistry of secondary copper minerals from Proterozoic porphyry copper deposit, Malanjkhand, India
inferred← citeshttps://doi.org/10.1016/0169-7722(87)90002-7openalex-snapshot
Sulfate contamination in groundwater from a carbonate-hosted mine
inferred← citeshttps://doi.org/10.1016/0272-0590(92)90178-kopenalex-snapshot
Relative bioavailability of lead from mining waste soil in rats
inferred← citeshttps://doi.org/10.1016/0273-1223(96)00304-6openalex-snapshot
Leachate chemistry and precipitates mineralogy of rudolfsgruvan mine waste rock dump in central sweden
inferred← citeshttps://doi.org/10.1016/0304-386x(92)90080-jopenalex-snapshot
Natural release of copper and zinc into the aquatic environment
inferred← citeshttps://doi.org/10.1016/0304-3894(95)00003-dopenalex-snapshot
Acid-base account effectiveness for determination of mine waste potential acidity
inferred← citeshttps://doi.org/10.1016/0304-4203(88)90100-4openalex-snapshot
Seasonal cycling of sulfur and iron in porewaters of a Delaware salt marsh
inferred← citeshttps://doi.org/10.1016/0375-6742(92)90138-xopenalex-snapshot
Redox front geochemistry and weathering: theory with application to the Osamu Utsumi uranium mine, Poços de Caldas, Brazil
inferred← citeshttps://doi.org/10.1016/0883-2927(87)90026-6openalex-snapshot
Processes controlling the composition of acid sulfate solutions evolved from coal
inferred← citeshttps://doi.org/10.1016/0883-2927(91)90074-yopenalex-snapshot
Prediction of water-soluble metal concentrations in fluvially deposited tailings sediments, upper Clark Fork Valley, Montana, U.S.A.
inferred← citeshttps://doi.org/10.1016/0883-2927(94)90006-xopenalex-snapshot
The effects of historic abstraction of groundwater from the London Basin aquifers on groundwater quality
inferred← citeshttps://doi.org/10.1016/0883-2927(95)00070-4openalex-snapshot
Metal retention by iron oxide precipitation from acidic ground water in Dalarna, Sweden
inferred← citeshttps://doi.org/10.1016/0892-6875(95)00129-8openalex-snapshot
A review of passive systems for the treatment of acid mine drainage
inferred← citeshttps://doi.org/10.1016/b0-08-043751-6/05075-1openalex-snapshot
Reaction Kinetics of Primary Rock-forming Minerals under Ambient Conditions
inferred← citeshttps://doi.org/10.1016/b978-0-08-095975-7.00503-9openalex-snapshot
Reaction Kinetics of Primary Rock-Forming Minerals under Ambient Conditions
inferred← citeshttps://doi.org/10.1016/b978-0-08-095975-7.00905-0openalex-snapshot
The Geochemistry of Acid Mine Drainage
inferred← citeshttps://doi.org/10.1016/b978-0-08-095975-7.01317-6openalex-snapshot
Relating Weathering Fronts for Acid Neutralization and Oxidation to pCO2 and pO2
inferred← citeshttps://doi.org/10.1016/b978-0-444-63777-2.00004-9openalex-snapshot
Safety Aspects of Lithium Primary Batteries
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2003.11.006openalex-snapshot
Redox processes in the Oderbruch polder groundwater flow system in Germany
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2005.01.006openalex-snapshot
The impact of sulphide oxidation on dissolved metal (Cd, Zn, Cu, Cr, Co, Ni, U) inputs into the Lot–Garonne fluvial system (France)
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2006.03.002openalex-snapshot
Estimation of potential pollution of waste mining dumps at Peña del Hierro (Pyrite Belt, SW Spain) as a base for future mitigation actions
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2006.09.003openalex-snapshot
Effective diffusion and microbiologic activity as constraints describing pyrite oxidation in abandoned lignite mines
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2007.10.001openalex-snapshot
Environmental geochemistry of a Kuroko-type massive sulfide deposit at the abandoned Valzinco mine, Virginia, USA
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2007.10.006openalex-snapshot
Sulfide oxidation: Insights from experimental, theoretical, stable isotope, and predictive studies in the field and laboratory
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2007.11.012openalex-snapshot
Soil alteration by continued oxidation of pyrite tailings
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2008.10.001openalex-snapshot
The impact of pyrite variability, dispersive transport and precipitation of secondary phases on the sulphate release due to pyrite weathering
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2008.12.001openalex-snapshot
Mineralogy and geochemistry of trace metals and REE in volcanic massive sulfide host rocks, stream sediments, stream waters and acid mine drainage from the Lousal mine area (Iberian Pyrite Belt, Portugal)
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2009.08.002openalex-snapshot
Oxygen isotope evidence for sorption of molecular oxygen to pyrite surface sites and incorporation into sulfate in oxidation experiments
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2010.07.001openalex-snapshot
Aquifer geochemistry at potential aquifer storage and recovery sites in coastal plain aquifers in the New York city area, USA
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2010.08.014openalex-snapshot
The role of dissolved molecular oxygen in abiotic pyrite oxidation under acid pH conditions – Experiments with 18O-enriched molecular oxygen
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2011.01.030openalex-snapshot
Hydrochemistry, mineralogy and chemical fractionation of mine and processing wastes associated with porphyry copper mines: A case study from the Sarcheshmeh mine, SE Iran
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2011.06.002openalex-snapshot
Hydrogeochemical processes governing the origin, transport and fate of major and trace elements from mine wastes and mineralized rock to surface waters
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2011.12.005openalex-snapshot
Arsenic and antimony contamination of waters, stream sediments and soils in the vicinity of abandoned antimony mines in the Western Carpathians, Slovakia
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2012.03.004openalex-snapshot
Genetic geochemical model for mining affected groundwaters of the Lusatian post-mining district
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2012.11.006openalex-snapshot
Pressure solution of electrically conductive minerals in shallow crust-galvanic processes: A case study from pyrite under differential stress
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2015.01.009openalex-snapshot
Geochemical and mineralogical aspects of sulfide mine tailings
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2015.01.010openalex-snapshot
Preoperational assessment of solute release from waste rock at proposed mining operations
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2015.02.008openalex-snapshot
Hydrogeochemistry and microbiology of mine drainage: An update
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2015.02.014openalex-snapshot
The Diavik Waste Rock Project: Geochemical and microbiological characterization of drainage from low-sulfide waste rock: Active zone field experiments
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2015.02.015openalex-snapshot
Source and distribution of naturally occurring arsenic in groundwater from Alberta’s Southern Oil Sands Regions
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2017.03.005openalex-snapshot
Coupling effect of Fe3+(aq) and biological, nano-sized FeS-coated limestone on the removal of redox-sensitive contaminants (As, Sb and Cr): Implications for in situ passive treatment of acid mine drainage
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2017.03.016openalex-snapshot
A geochemical examination of humidity cell tests
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2017.05.001openalex-snapshot
Element release and reaction-induced porosity alteration during shale-hydraulic fracturing fluid interactions
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2017.12.027openalex-snapshot
Investigating monomineralic and polymineralic reactions during the oxidation of sulphide minerals in seawater: Implications for mining seafloor massive sulphide deposits
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2019.02.003openalex-snapshot
Induced geochemical reactions by compressed air energy storage in a porous formation in the North German Basin
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2020.104711openalex-snapshot
Formation of secondary mineral coatings and the persistence of reduced metal-bearing phases in soils developing on historic coal mine spoil
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2021.104899openalex-snapshot
Trace elements in sulfides and release to porewater from sulfide oxidation in a historical waste-rock pile, Ontario, Canada
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2021.105010openalex-snapshot
Mineralogical characterization and speciation of sulfur, zinc and lead in pyrite cinder from Bergvik, Sweden
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2023.105617openalex-snapshot
Lime slurry treatment of soils developing on abandoned coal mine spoil: Linking contaminant transport from the micrometer to pedon-scale
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2026.107025openalex-snapshot
Investigating iron–sulphur–phosphate transformation dynamics during redox-controlled microaeration of digested sludge towards improved resource recovery
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2026.107104openalex-snapshot
Halotrichite-group sulfates as mineralogical and spectral indicators of Cu, Co and As enrichment in mining environmental liabilities
inferred← citeshttps://doi.org/10.1016/j.apgeochem.2026.107120openalex-snapshot
The influence of abandoned coal mines on the spatial and temporal variability in metal concentration and distribution in an Appalachian stream
inferred← citeshttps://doi.org/10.1016/j.catena.2010.06.009openalex-snapshot
Paleolandscape and paleoenvironmental interpretation of spring-deposited sediments in Dakhleh Oasis, Western Desert of Egypt
inferred← citeshttps://doi.org/10.1016/j.cemconcomp.2010.08.002openalex-snapshot
Coupled effects of sulphate and temperature on the strength development of cemented tailings backfills: Portland cement-paste backfill
inferred← citeshttps://doi.org/10.1016/j.chemer.2005.06.002openalex-snapshot
Rare earth element patterns: A tool for understanding processes in remediation of acid mine drainage
inferred← citeshttps://doi.org/10.1016/j.chemer.2016.05.001openalex-snapshot
Thermodynamic properties of tooeleite, Fe63+(As3+O3)4(SO4)(OH)4·4H2O
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2004.06.044openalex-snapshot
Sulfate-mineral crusts from pyrite weathering and acid rock drainage in the Dakota Formation and Graneros Shale, Jefferson County, Nebraska
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2004.10.001openalex-snapshot
Major and trace element composition of copiapite-group minerals and coexisting water from the Richmond mine, Iron Mountain, California
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2007.05.021openalex-snapshot
Acid drainage generation and seasonal recycling in disturbed permafrost near Eagle Plains, northern Yukon Territory, Canada
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2007.10.006openalex-snapshot
Oxidation of pyrite during extraction of carbonate associated sulfate
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2008.06.006openalex-snapshot
Sulfur dynamics in boreal acid sulfate soils rich in metastable iron sulfide—The role of artificial drainage
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2008.08.001openalex-snapshot
Geochemistry and stable isotope composition of fresh alkaline porphyry copper tailings: Implications on sources and mobility of elements during transport and early stages of deposition
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2009.03.012openalex-snapshot
Interaction between smectite and bacteria: Implications for bentonite as backfill material in the disposal of nuclear waste
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2012.02.015openalex-snapshot
Cu isotopes and concentrations during weathering of black shale of the Marcellus Formation, Huntingdon County, Pennsylvania (USA)
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2015.10.020openalex-snapshot
The potential role of aluminium hydroxysulphates in the removal of contaminants in acid mine drainage
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2020.120043openalex-snapshot
Spectral and Chemical Characterization of Copiapite and Rozenite from Padinjarathara in Wayanad, Southern India: Implications for Mars Exploration
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2022.121011openalex-snapshot
Oxidation of pyrite during barite extraction
inferred← citeshttps://doi.org/10.1016/j.chemosphere.2008.07.028openalex-snapshot
Trace element mobility in soils seven years after the Aznalcóllar mine spill
inferred← citeshttps://doi.org/10.1016/j.chemosphere.2019.06.066openalex-snapshot
Tracing and quantifying contributions of end members to karst water at a coalfield in southwest China
inferred← citeshttps://doi.org/10.1016/j.chemosphere.2025.144662openalex-snapshot
Evaluation of boreal plant and microbe communities on tailings solvent recovery unit (TSRU) tailings: A meso-scale greenhouse study
inferred← citeshttps://doi.org/10.1016/j.coal.2011.04.006openalex-snapshot
Mobility of elements in long-term leaching tests on Illinois #6 coal rejects
inferred← citeshttps://doi.org/10.1016/j.coal.2013.12.005openalex-snapshot
Mineralogy and trace element geochemistry of gas shales in the United States: Environmental implications
inferred← citeshttps://doi.org/10.1016/j.compgeo.2020.103605openalex-snapshot
Computational modelling to predict the longevity of a permeable reactive barrier in an acidic floodplain
inferred← citeshttps://doi.org/10.1016/j.earscirev.2021.103811openalex-snapshot
Schwertmannite: A review of its occurrence, formation, structure, stability and interactions with oxyanions
inferred← citeshttps://doi.org/10.1016/j.envpol.2007.06.020openalex-snapshot
Use of the modified BCR three-step sequential extraction procedure for the study of trace element dynamics in contaminated soils
inferred← citeshttps://doi.org/10.1016/j.envpol.2018.08.027openalex-snapshot
Microstructural characteristics of naturally formed hardpan capping sulfidic copper-lead-zinc tailings
inferred← citeshttps://doi.org/10.1016/j.envres.2026.124381openalex-snapshot
Potentially toxic and radiogenic elements associated serious health risks to human around a gold and uranium mines, Blesbokspruit wetland, Johannesburg, South Africa
inferred← citeshttps://doi.org/10.1016/j.envres.2026.125865openalex-snapshot
Analysis of Carbon Cycle Interference Mechanisms in Karst Rivers under the Combined Influence of Acid Mine Drainage and Multi-source Anthropogenic Pollution
inferred← citeshttps://doi.org/10.1016/j.gca.2009.11.026openalex-snapshot
Impact of isostatic land uplift and artificial drainage on oxidation of brackish-water sediments rich in metastable iron sulfide
inferred← citeshttps://doi.org/10.1016/j.gca.2010.05.009openalex-snapshot
Mobility of iridium in terrestrial environments: Implications for the interpretation of impact-related mass-extinctions
inferred← citeshttps://doi.org/10.1016/j.gca.2011.10.022openalex-snapshot
Oxygen and sulfur isotope systematics of sulfate produced during abiotic and bacterial oxidation of sphalerite and elemental sulfur
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