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A Cobalt Templated Chiral Outer Sphere Hydrogen Bond Donor Catalyst Derived from 2-Guanidinobenzimidazole: Synthesis, Applications in Carbon-Carbon Bond Forming Reactions, Structure

https://doi.org/10.2139/ssrn.4825419
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Chiral-at-Metal Ruthenium Complexes with Guanidinobenzimidazole and Pentaphenylcyclopentadienyl Ligands: Synthesis, Resolution, and Preliminary Screening as Enantioselective Second Coordination Sphere Hydrogen Bond Donor Catalysts
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Post-Modification of Octahedral Chiral-at-Metal Cobalt(III) Complexes by Suzuki–Miyaura Cross-Coupling and Evaluation of Their Catalytic Activity
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Chiral Cobalt(III) Tris(1,2-diamine) Catalysts That Incorporate Nitrogenous Base Containing Anions for the Bifunctional Activation of Nucleophiles and Electrophiles in Enantioselective Addition Reactions
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Chiral Tricationic Tris(1,2-diphenylethylenediamine) Cobalt(III) Hydrogen Bond Donor Catalysts with Defined Carbon/Metal Configurations; Matched/Mismatched Effects upon Enantioselectivities with Enantiomeric Chiral Counter Anions
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Utilization of Guanidine-Based Ancillary Ligands in Arene–Ruthenium Complexes for Selective Cytotoxicity
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Highly Active Families of Catalysts for the Ring-Opening Polymerization of Lactide: Metal Templated Organic Hydrogen Bond Donors Derived from 2-Guanidinobenzimidazole
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Kinetics and Mechanisms of Methyl Vinyl Ketone Hydroalkoxylation Catalyzed by Palladium(II) Complexes
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Metal-Templated Hydrogen Bond Donors as “Organocatalysts” for Carbon–Carbon Bond Forming Reactions: Syntheses, Structures, and Reactivities of 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes
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Rendering classical hydrophilic enantiopure Werner salts [M(en) 3 ] n+ n X − lipophilic (M/ n = Cr/3, Co/3, Rh/3, Ir/3, Pt/4); new chiral hydrogen bond donor catalysts and enantioselectivities as a function of metal and charge
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Recent Advancements in Typical Friedel–Crafts Alkylation Reactions Focused on Targeting Arene Nucleophiles
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Single-crystal structure validation with the program PLATON
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OLEX2 : a complete structure solution, refinement and analysis program
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