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Aryl/Hetero-Aryl Tosylates as Coupling Partners in Metal Mediated Suzuki and Hiyama Cross-Coupling Reactions in Ionic Liquids: Facile Synthesis of Biaryls/Heterobiaryls

https://doi.org/10.2139/ssrn.4847584
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Recent Applications of Palladium‐Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries
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Phosphane‐Free Hiyama Cross‐Coupling of Aryl and Heteroaryl Halides Catalyzed by Palladium Nanoparticles in Ionic Liquids
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Libraries of C‐5 Substituted Imidazoles and Oxazoles by Sequential Van Leusen (VL)–Suzuki, VL–Heck and VL–Sonogashira in Imidazolium‐ILs with Piperidine‐Appended‐IL as Base
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1‐Aryltriazenes in the Suzuki, Heck, and Sonogashira Reactions in Imidazolium‐ILs, with [BMIM(SO3H)][OTf] or Sc(OTf)3 as Promoter, and Pd(OAc)2 or NiCl2·glyme as Catalyst
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Syntheses of Natural Products
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Piperidine-appended imidazolium ionic liquid as task-specific basic-IL for Suzuki and Heck reactions and for tandem Wittig-Suzuki, Wittig-Heck, Horner-Emmons-Suzuki, and Horner-Emmons-Heck protocols
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Activation of aryl chlorides in water for Suzuki coupling with a hydrophilic salen-Pd(II) catalyst
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Palladium–benzimidazolium salt catalyst systems for Suzuki coupling: development of a practical and highly active palladium catalyst system for coupling of aromatic halides with arylboronic acids
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A nickel precatalyst for efficient cross-coupling reactions of aryl tosylates with arylboronic acids: vital role of dppf
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A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines
inferredcites →https://doi.org/10.1021/acs.joc.8b00140openalex-extracted
Accessing Heterobiaryls through Transition-Metal-Free C–H Functionalization
inferredcites →https://doi.org/10.1021/acs.joc.8b02766openalex-extracted
Synthesis of Aryl Trimethylstannane via BF3·OEt2-Mediated Cross-Coupling of Hexaalkyl Distannane Reagent with Aryl Triazene at Room Temperature
inferredcites →https://doi.org/10.1021/cr00039a007openalex-extracted
Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds
inferredcites →https://doi.org/10.1021/cr0505268openalex-extracted
Selected Patented Cross-Coupling Reaction Technologies
inferredcites →https://doi.org/10.1021/cr300100sopenalex-extracted
Synthesis of Heterocycles via Palladium-Catalyzed Carbonylations
inferredcites →https://doi.org/10.1021/ja00511a032openalex-extracted
Palladium-catalyzed coupling of tetraorganotin compounds with aryl and benzyl halides. Synthetic utility and mechanism
inferredcites →https://doi.org/10.1021/ja804672mopenalex-extracted
Palladium-Catalyzed Hiyama Cross-Couplings of Aryl Arenesulfonates with Arylsilanes
inferredcites →https://doi.org/10.1021/jo00239a056openalex-extracted
Cross-coupling of organosilanes with organic halides mediated by a palladium catalyst and tris(diethylamino)sulfonium difluorotrimethylsilicate
inferredcites →https://doi.org/10.1021/jo00979a024openalex-extracted
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
inferredcites →https://doi.org/10.1021/jo201437jopenalex-extracted
Hiyama Cross-Coupling of Arenediazonium Salts under Mild Reaction Conditions
inferredcites →https://doi.org/10.1021/jo8014819openalex-extracted
Suzuki−Miyaura Coupling of Aryl Tosylates Catalyzed by an Array of Indolyl Phosphine−Palladium Catalysts
inferredcites →https://doi.org/10.1021/ol016526lopenalex-extracted
NiCl2(PCy3)2: A Simple and Efficient Catalyst Precursor for the Suzuki Cross-Coupling of Aryl Tosylates and Arylboronic Acids
inferredcites →https://doi.org/10.1021/om0492395openalex-extracted
Catalytic Suzuki Coupling Reactions by Amido Phosphine Complexes of Palladium
inferredcites →https://doi.org/10.1038/nchem.862openalex-extracted
An efficient organocatalytic method for constructing biaryls through aromatic C–H activation
inferredcites →https://doi.org/10.1039/c0cc03107kopenalex-extracted
A pyridine-bridged bis-benzimidazolylidene pincer nickel(ii) complex: synthesis and practical catalytic application towards Suzuki–Miyaura coupling with less-activated electrophiles
inferredcites →https://doi.org/10.1039/c1cs15114bopenalex-extracted
Palladium-catalyzed cross-coupling reactions of aryl mesylates
inferredcites →https://doi.org/10.1039/c5nj01833aopenalex-extracted
Nickel–glycerol: an efficient, recyclable catalysis system for Suzuki cross coupling reactions using aryl diazonium salts
inferredcites →https://doi.org/10.1039/c5ob00139kopenalex-extracted
Palladium-catalyzed Hiyama coupling reaction of arylsulfonyl hydrazides under oxygen
inferredcites →https://doi.org/10.3390/catal7090267openalex-extracted
Heck Reaction—State of the Art
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