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Probing the heterogeneous amorphous network of phosphate geopolymers: insights from advanced multidimensional multinuclear SSNMR and DFT modeling

https://doi.org/10.2139/ssrn.5572966
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Modelling one‐ and two‐dimensional solid‐state NMR spectra
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31P solid-state nuclear magnetic resonance spectroscopy of aluminum phosphate minerals
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Structural study of synthetic mica–montmorillonite by means of 2D MAS NMR experiments
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Phosphate-based geopolymers: a critical review
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Calcium Phosphates and Hydroxyapatite: Solid-State NMR Experiments and First-Principles Calculations
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High resolution 1H spectra of powdered solids observed by Hahn echo pulse sequence with magic-angle spinning
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Recent progress in low-carbon binders
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Advanced solid-state 1H/31P NMR characterization of pyrophosphate-doped calcium phosphate cements for biomedical applications: The structural role of pyrophosphate
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Phosphate-based geopolymer: Influence of municipal solid waste fly ash introduction on structure and compressive strength
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Olivine dissolution rates: A critical review
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Interaction of metakaolin-phosphoric acid and their structural evolution at high temperature
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Molecular level investigations of phosphate sorption on corundum (α-Al2O3) by 31P solid state NMR, ATR-FTIR and quantum chemical calculation
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Atomic structure and dehydration mechanism of amorphous silica: Insights from 29Si and 1H solid-state MAS NMR study of SiO2 nanoparticles
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Microstructural evolution of amorphous silica following alkali–silica reaction
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Influence of various metakaolin raw materials on the water and fire resistance of geopolymers prepared in phosphoric acid
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Acid-based geopolymers: Understanding of the structural evolutions during consolidation and after thermal treatments
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Investigation of Phosphate based geopolymers formation mechanism
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Relation between working properties and structural properties from 27Al, 29Si and 31P NMR and XRD of acid-based geopolymers from 25 to 1000°C
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A comprehensive collection of solid-state 31P NMR spectra of aluminophosphate zeolites
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Solid-state nuclear magnetic resonance spectroscopy of cements
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Multinuclear NMR studies on the sol–gel preparation of sodium aluminophosphate glasses
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Calcium environment in silicate and aluminosilicate glasses probed by 43Ca MQMAS NMR experiments and MD-GIPAW calculations
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Atomic-Scale Structure and Its Impact on Chemical Properties of Aluminum Oxide Layers Prepared by Atomic Layer Deposition on Silica
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Environmental Impacts of Alternative Cement Binders
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Understanding the Microstructure Connectivity in Photopolymerizable Aluminum-Phosphate-Silicate Sol–Gel Hybrid Materials for Additive Manufacturing
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New Structural Model of Hydrous Sodium Aluminosilicate Gels and the Role of Charge-Balancing Extra-Framework Al
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Nanostructure of CaO-(Na 2 O)-Al 2 O 3 -SiO 2 -H 2 O Gels Revealed by Multinuclear Solid-State Magic Angle Spinning and Multiple Quantum Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy
inferredcites →https://doi.org/10.1021/acs.jpclett.7b03050openalex-snapshot
ZSM-5 Zeolite: Complete Al Bond Connectivity and Implications on Structure Formation from Solid-State NMR and Quantum Chemistry Calculations
inferredcites →https://doi.org/10.1021/acscatal.1c02135openalex-snapshot
Structural Characterization of Phosphate Species Adsorbed on γ-Alumina by Combining DNP Surface Enhanced NMR Spectroscopy and DFT Calculations
inferredcites →https://doi.org/10.1021/cm3016935openalex-snapshot
Elucidation of the Al/Si Ordering in Gehlenite Ca2Al2SiO7 by Combined 29Si and 27Al NMR Spectroscopy/Quantum Chemical Calculations
inferredcites →https://doi.org/10.1021/jp056335qopenalex-snapshot
Solid-State NMR Spectroscopy of Anionic Framework Aluminophosphates: A New Method to Determine the Al/P Ratio
inferredcites →https://doi.org/10.1021/jp206237nopenalex-snapshot
Solid-State 31 P and 1 H NMR Investigations of Amorphous and Crystalline Calcium Phosphates Grown Biomimetically From a Mesoporous Bioactive Glass
inferredcites →https://doi.org/10.1021/la062765bopenalex-snapshot
31P Solid-State Nuclear Magnetic Resonance Study of the Sorption of Phosphate onto Gibbsite and Kaolinite
inferredcites →https://doi.org/10.1021/la304795wopenalex-snapshot
DFT Modeling of 45S5 and 77S Soda-Lime Phospho-Silicate Glass Surfaces: Clues on Different Bioactivity Mechanism
inferredcites →https://doi.org/10.1039/b102105mopenalex-snapshot
1H–31P CP/MAS NMR studies of mesostructured aluminophosphates
inferredcites →https://doi.org/10.1039/b400651hopenalex-snapshot
Sol–gel synthesis of Al 2 O 3 –P 2 O 5 glasses: mechanistic studies by solution and solid state NMR
inferredcites →https://doi.org/10.1039/b516599gopenalex-snapshot
Sol-gel preparation of AlPO4–SiO2 glasses with high surface mesoporous structure
inferredcites →https://doi.org/10.1039/b815397copenalex-snapshot
Sol-gel synthesis of sodium-modified AlPO4–SiO2 glasses and structural characterization by solid state NMR
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The structure of fluoride-containing bioactive glasses: new insights from first-principles calculations and solid state NMR spectroscopy
inferredcites →https://doi.org/10.1039/c5cs00109aopenalex-snapshot
Phosphorus promotion and poisoning in zeolite-based materials: synthesis, characterisation and catalysis
inferredcites →https://doi.org/10.1039/c5nj02838hopenalex-snapshot
Dehydration of AlPO 4 -34 studied by variable-temperature NMR, XRD and first-principles calculations
inferredcites →https://doi.org/10.1063/5.0239498openalex-snapshot
Heterogeneous dynamics in aging phosphate-based geopolymer
inferredcites →https://doi.org/10.1111/j.1551-2916.2009.03468.xopenalex-snapshot
Proton Distributions and Hydrogen Bonding in Crystalline and Glassy Hydrous Silicates and Related Inorganic Materials: Insights from High‐Resolution Solid‐State Nuclear Magnetic Resonance Spectroscopy
inferredcites →https://doi.org/10.1111/jace.17929openalex-snapshot
Study of the formation of acid‐based geopolymer networks and their resistance to water by time/temperature treatments
inferredcites →https://doi.org/10.1127/0077-7757/2007/0087openalex-snapshot
Polymorphism and solid solution in the system SiO2-AlPO4(-H2O): a review and new synthesis experiments up to 3.5 GPa and 1573 K
inferredcites →https://doi.org/10.1139/v95-204openalex-snapshot
Investigations of aluminum hydroxyphosphates and activated sludge by 27Al and 31P MAS NMR
inferredcites →https://doi.org/10.1146/annurev-matsci-070813-113515openalex-snapshot
Geopolymers and Related Alkali-Activated Materials
inferredcites →https://doi.org/10.1180/mgm.2020.57openalex-snapshot
Crystal chemistry of the variscite and metavariscite groups: Crystal structures of synthetic CrAsO4⋅2H2O, TlPO4⋅2H2O, MnSeO4⋅2H2O, CdSeO4⋅2H2O and natural bonacinaite, ScAsO4⋅2H2O
inferredcites →https://doi.org/10.2138/am-2022-8119openalex-snapshot
Crystal structure determination of orthorhombic variscite2Oand its derivative AlPO4 structure at high temperature
inferredcites →https://doi.org/10.3390/nano13172387openalex-snapshot
Water–Aluminum Interaction as Driving Force of Linde Type A Aluminophosphate Hydration
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