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Direct Air Capture with Solid-Sorbent: An Integrated Review of Adsorbent Design, Process Engineering, and CO2 Conversion

https://doi.org/10.2139/ssrn.6096497
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Oxidation‐Resistant, Cost‐Effective Epoxide‐Modified Polyamine Adsorbents for CO2 Capture from Various Sources Including Air
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Density Functional Theory for Electrocatalysis
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Analysis of direct capture of $${\hbox {CO}}_{2}$$ from ambient air via steam-assisted temperature–vacuum swing adsorption
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The impact of design and operational parameters on the optimal performance of direct air capture units using solid sorbents
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Linker-defect assisted catalytic fixation of CO2 in a dual-linker metal–organic framework
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Research needs targeting direct air capture of carbon dioxide: Material & process performance characteristics under realistic environmental conditions
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A sorbent-focused techno-economic analysis of direct air capture
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Technical, economic and lifecycle greenhouse gas emissions analyses of solid sorbent direct air capture technologies
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Heat and mass transfer of temperature–vacuum swing desorption for CO2 capture from air
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Experimental comparison of regeneration methods for CO2 concentration from air using amine-based adsorbent
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CO2 capture (including direct air capture) and natural gas desulfurization of amine-grafted hierarchical bimodal silica
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Operating temperatures affect direct air capture of CO2 in polyamine-loaded mesoporous silica
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Optimum relative humidity enhances CO2 uptake in diamine-appended M2(dobpdc)
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Process-performance of solid sorbents for Direct Air Capture (DAC) of CO2 in optimized temperature-vacuum swing adsorption (TVSA) cycles
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Direct air CO2 capture in an internally circulating fluidized bed reactor: Evaluating adsorption performance of Al2O3 and K2CO3/Al2O3 sorbents
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Characterization of K-MER and 13X zeolites for humid direct air capture of CO2 under equilibrium and cycling conditions
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A comprehensive review on different approaches for CO2 utilization and conversion pathways
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A novel contactor for reducing the cost of direct air capture of CO2
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Direct Air capture (DAC) deployment: A review of the industrial deployment
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Analytical review of the current state of knowledge of adsorption materials and processes for direct air capture
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CO2 capture via adsorption in amine-functionalized sorbents
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Optimization of direct air capture processes using reactive transport models of adsorption-desorption cycles
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CO2 Utilization Pathways: Techno-Economic Assessment and Market Opportunities
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Design Strategy for CO2 Adsorption from Ambient Air Using a Supported Amine Based Sorbent in a Fixed Bed Reactor
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Creating a carbon dioxide removal solution by combining rapid mineralization of CO2 with direct air capture
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Development of biomass derived highly porous fast adsorbents for post-combustion CO2 capture
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CO 2 absorption mechanism in amine solvents and enhancement of CO 2 capture capability in blended amine solvent
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Process optimization of a fixed bed reactor system for direct air capture
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Experimentation of a novel sequential moving-bed DAC System
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Current status and pillars of direct air capture technologies
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Absorption of carbon dioxide in alkanolamine and vegetable oil mixture and isolation of 2-amino-2-methyl-1-propanol carbamate
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Direct air capture of CO2 by KOH-activated bamboo biochar
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A comparative energy and costs assessment and optimization for direct air capture technologies
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Facile synthesis of structured adsorbent with enhanced hydrophobicity and low energy consumption for CO2 capture from the air
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CoRE MOF DB: A curated experimental metal-organic framework database with machine-learned properties for integrated material-process screening
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Metallated porphyrinic metal−organic frameworks for CO2 conversion to HCOOH: A computational screening and mechanistic study
inferredcites →https://doi.org/10.1016/j.seppur.2024.127997openalex-snapshot
Investigation of effectiveness of KOH-activated olive pomace biochar for efficient direct air capture of CO2
inferredcites →https://doi.org/10.1016/j.spc.2022.04.004openalex-snapshot
Environmental performance of different sorbents used for direct air capture
inferredcites →https://doi.org/10.1021/acs.accounts.3c00367openalex-snapshot
Amine Chemistry of Porous CO 2 Adsorbents
inferredcites →https://doi.org/10.1021/acs.cgd.0c01530openalex-snapshot
Chemical Fixation of CO 2 Under Solvent and Co-Catalyst-free Conditions Using a Highly Porous Two-fold Interpenetrated Cu(II)-Metal–Organic Framework
inferredcites →https://doi.org/10.1021/acs.chemmater.9b01474openalex-snapshot
Aminopolymer-Impregnated Hierarchical Silica Structures: Unexpected Equivalent CO 2 Uptake under Simulated Air Capture and Flue Gas Capture Conditions
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Understanding the Effect of Water on CO 2 Adsorption
inferredcites →https://doi.org/10.1021/acs.chemrev.6b00173openalex-snapshot
Direct Capture of CO2 from Ambient Air
inferredcites →https://doi.org/10.1021/acs.energyfuels.4c01156openalex-snapshot
How Would Ideal Sorbents Improve the Technical and Economic Performance of Adsorption-Based Direct Air Capture?
inferredcites →https://doi.org/10.1021/acs.energyfuels.4c01328openalex-snapshot
Amine Sorbents for Sustainable Direct Air Capture: Long-Term Stability and Extended Aging Study
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CO 2 Post-combustion Capture: A Critical Review of Current Technologies and Future Directions
inferredcites →https://doi.org/10.1021/acs.est.3c10041openalex-snapshot
Assessment of Potential and Techno-Economic Performance of Solid Sorbent Direct Air Capture with CO 2 Storage in Europe
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Optimal Design and Operation of Solid Sorbent Direct Air Capture Processes at Varying Ambient Conditions
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Developing Versatile Contactors for Direct Air Capture of CO 2 through Amine Grafting onto Alumina Pellets and Alumina Wash-Coated Monoliths
inferredcites →https://doi.org/10.1021/acs.iecr.4c01392openalex-snapshot
On Comparing Packed Beds and Monoliths for CO 2 Capture from Air Through Experiments, Theory, and Modeling
inferredcites →https://doi.org/10.1021/acs.iecr.4c02303openalex-snapshot
Exploring Geometric Properties and Cycle Design in Packed Bed and Monolith Contactors Using Temperature-Vacuum Swing Adsorption Modeling for Direct Air Capture
inferredcites →https://doi.org/10.1021/acs.iecr.5c00462openalex-snapshot
Performance Degradation of Amine-Infused Fiber Sorbents for Direct Air Capture: Mechanisms and Solutions
inferredcites →https://doi.org/10.1021/acs.iecr.6b03887openalex-snapshot
Systems Design and Economic Analysis of Direct Air Capture of CO 2 through Temperature Vacuum Swing Adsorption Using MIL-101(Cr)-PEI-800 and mmen-Mg 2 (dobpdc) MOF Adsorbents
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The Role of Water in CO2 Capture by Amine
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CO2 Capture from Air Using Pelletized Polyethylenimine Impregnated MCF Silica
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Moving Beyond Adsorption Capacity in Design of Adsorbents for CO 2 Capture from Ultradilute Feeds: Kinetics of CO 2 Adsorption in Materials with Stepped Isotherms
inferredcites →https://doi.org/10.1021/acs.iecr.9b03140openalex-snapshot
Desorption Process for Capturing CO 2 from Air with Supported Amine Sorbent
inferredcites →https://doi.org/10.1021/acs.iecr.9b05228openalex-snapshot
Amine-Grafted Silica Gels for CO 2 Capture Including Direct Air Capture
inferredcites →https://doi.org/10.1021/acs.inorgchem.0c03527openalex-snapshot
Properties and Detailed Adsorption of CO 2 by M 2 (dobpdc) with N , N -Dimethylethylenediamine Functionalization
inferredcites →https://doi.org/10.1021/acs.inorgchem.2c00569openalex-snapshot
Dynamic Metal–Iodide Bonds in a Tetracoordinated Cadmium-Based Metal–Organic Framework Boosting Efficient CO2 Cycloaddition under Solvent- and Cocatalyst-Free Conditions
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Construction of 3-Fold-Interpenetrated Three-Dimensional Metal–Organic Frameworks of Nickel(II) for Highly Efficient Capture and Conversion of Carbon Dioxide
inferredcites →https://doi.org/10.1021/acs.inorgchem.7b02443openalex-snapshot
From Zn(II)-Carboxylate to Double-Walled Zn(II)-Carboxylato Phosphate MOF: Change in the Framework Topology, Capture and Conversion of CO2, and Catalysis of Strecker Reaction
inferredcites →https://doi.org/10.1021/acs.inorgchem.7b03099openalex-snapshot
Porous Metal–Organic Frameworks with Chelating Multiamine Sites for Selective Adsorption and Chemical Conversion of Carbon Dioxide
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Adenine-Based Zn(II)/Cd(II) Metal–Organic Frameworks as Efficient Heterogeneous Catalysts for Facile CO 2 Fixation into Cyclic Carbonates: A DFT-Supported Study of the Reaction Mechanism
inferredcites →https://doi.org/10.1021/acs.jpca.5c03392openalex-snapshot
Computational Screening of Amino-Functionalized Molecules for Direct Air Capture of CO2
inferredcites →https://doi.org/10.1021/acs.jpcc.0c01088openalex-snapshot
Alternative Pathway of CO2 Hydrogenation by Lewis-Pair-Functionalized UiO-66 MOF Revealed by Metadynamics Simulations
inferredcites →https://doi.org/10.1021/acs.jpcc.0c02457openalex-snapshot
Interfacial Engineering of PdAg/TiO2 with a Metal–Organic Framework to Promote the Hydrogenation of CO2 to Formic Acid
inferredcites →https://doi.org/10.1021/acs.jpcc.1c06924openalex-snapshot
Computational Screening of MOFs and Zeolites for Direct Air Capture of Carbon Dioxide under Humid Conditions
inferredcites →https://doi.org/10.1021/acs.jpcc.6b08808openalex-snapshot
The Mechanism of CO2 Adsorption under Dry and Humid Conditions in Mesoporous Silica-Supported Amine Sorbents
inferredcites →https://doi.org/10.1021/acs.jpcc.7b07930openalex-snapshot
Effect of Humidity on the CO2 Adsorption of Tertiary Amine Grafted SBA-15
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How Does CO2 React with Styrene Oxide in Co-MOF-74 and Mg-MOF-74? Catalytic Mechanisms Proposed by QM/MM Calculations
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Probing Intramolecular versus Intermolecular CO2 Adsorption on Amine-Grafted SBA-15
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Mechanism for CO2 Fixation with Aziridines Synergistically Catalyzed by HKUST-1 and TBAB: A DFT Study
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A Highly Efficient and Stable Composite of Polyacrylate and Metal–Organic Framework Prepared by Interface Engineering for Direct Air Capture
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Facile One-Pot Synthesis of Zn/Mg-MOF-74 with Unsaturated Coordination Metal Centers for Efficient CO 2 Adsorption and Conversion to Cyclic Carbonates
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Rules Describing CO 2 Activation on Single-Atom Alloys from DFT-Meta-GGA Calculations and Artificial Intelligence
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Amine-Functionalized Quasi-MOF for Direct Air Capture of CO 2
inferredcites →https://doi.org/10.1021/acsomega.0c03727openalex-snapshot
A Unified Approach to CO2–Amine Reaction Mechanisms
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CO2 Adsorption and Activation on the (110) Chalcopyrite Surfaces: A Dispersion-Corrected DFT + U Study
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Template Removal from SBA-15 by Ionic Liquid for Amine Grafting: Applications to CO 2 Capture and Natural Gas Desulfurization
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Metal-Free Amine-Anchored Triazine-Based Covalent Organic Polymers for Selective CO 2 Adsorption and Conversion to Cyclic Carbonates Under Mild Conditions
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Direct Air Capture and Integrated Conversion of Carbon Dioxide into Cyclic Carbonates with Basic Organic Salts
inferredcites →https://doi.org/10.1021/acssuschemeng.6b01692openalex-snapshot
Direct Air Capture of CO 2 Using Amine Functionalized MIL-101(Cr)
inferredcites →https://doi.org/10.1021/cm1029563openalex-snapshot
Adsorption and Activation of CO 2 by Amine-Modified Nanoporous Materials Studied by Solid-State NMR and 13 CO 2 Adsorption
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Carbon Dioxide Capture in Metal–Organic Frameworks
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Energy and Material Balance of CO2 Capture from Ambient Air
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Amine-Based Nanofibrillated Cellulose As Adsorbent for CO2 Capture from Air
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Concurrent Separation of CO 2 and H 2 O from Air by a Temperature-Vacuum Swing Adsorption/Desorption Cycle
inferredcites →https://doi.org/10.1021/es401731popenalex-snapshot
Stability of Amine-Functionalized Cellulose during Temperature-Vacuum-Swing Cycling for CO2 Capture from Air
inferredcites →https://doi.org/10.1021/es404430gopenalex-snapshot
Single-Component and Binary CO2 and H2O Adsorption of Amine-Functionalized Cellulose
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Post-Combustion CO 2 Capture Using Solid Sorbents: A Review
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Poly(allylamine)–Mesoporous Silica Composite Materials for CO2 Capture from Simulated Flue Gas or Ambient Air
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Analysis of Equilibrium-Based TSA Processes for Direct Capture of CO2 from Air
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Kinetics of carbamate formation and breakdown
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Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg 2 (dobpdc)
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Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach
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Influence of Defects and H2O on the Hydrogenation of CO2 to Methanol over Pt Nanoparticles in UiO-67 Metal–Organic Framework
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Carbon Dioxide Capture Chemistry of Amino Acid Functionalized Metal–Organic Frameworks in Humid Flue Gas
inferredcites →https://doi.org/10.1021/jacs.2c12707openalex-snapshot
Support Pore Structure and Composition Strongly Influence the Direct Air Capture of CO 2 on Supported Amines
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Water-Enhanced Direct Air Capture of Carbon Dioxide in Metal–Organic Frameworks
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Metal Variance in Multivariate Metal–Organic Frameworks for Boosting Catalytic Conversion of CO 2
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Integrated CO2 Capture and Conversion by a Robust Cu(I)-Based Metal–Organic Framework
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A Triazole-Containing Metal–Organic Framework as a Highly Effective and Substrate Size-Dependent Catalyst for CO 2 Conversion
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Design of Aminopolymer Structure to Enhance Performance and Stability of CO2 Sorbents: Poly(propylenimine) vs Poly(ethylenimine)
inferredcites →https://doi.org/10.1021/jacs.7b05858openalex-snapshot
Controlling Cooperative CO 2 Adsorption in Diamine-Appended Mg 2 (dobpdc) Metal–Organic Frameworks
inferredcites →https://doi.org/10.1021/jacs.7b06382openalex-snapshot
The Chemistry of CO 2 Capture in an Amine-Functionalized Metal–Organic Framework under Dry and Humid Conditions
inferredcites →https://doi.org/10.1021/jacsau.1c00414openalex-snapshot
Sub-Ambient Temperature Direct Air Capture of CO 2 using Amine-Impregnated MIL-101(Cr) Enables Ambient Temperature CO 2 Recovery
inferredcites →https://doi.org/10.1021/jz300328jopenalex-snapshot
Modification of the Mg/DOBDC MOF with Amines to Enhance CO2 Adsorption from Ultradilute Gases
inferredcites →https://doi.org/10.1021/jz502032copenalex-snapshot
Effect of Amine Surface Coverage on the Co-Adsorption of CO 2 and Water: Spectral Deconvolution of Adsorbed Species
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Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
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An inter-model assessment of the role of direct air capture in deep mitigation pathways
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Revealing carbon capture chemistry with 17-oxygen NMR spectroscopy
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Direct synthesis of urea from carbon dioxide and ammonia
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Porous materials for carbon dioxide separations
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The technological and economic prospects for CO2 utilization and removal
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Carbon dioxide capture from open air using covalent organic frameworks
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Diamine-functionalized metal–organic framework: exceptionally high CO 2 capacities from ambient air and flue gas, ultrafast CO 2 uptake rate, and adsorption mechanism
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Carbon dioxide (CO 2 ) as sustainable feedstock for polyurethane production
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An lcy-topology amino acid MOF as eco-friendly catalyst for cyclic carbonate synthesis from CO 2 : Structure-DFT corroborated study
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On the potential of phase-change adsorbents for CO 2 capture by temperature swing adsorption
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Putting an ultrahigh concentration of amine groups into a metal–organic framework for CO 2 capture at low pressures
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Hybrid ultramicroporous materials (HUMs) with enhanced stability and trace carbon capture performance
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Pyrrolizidines for direct air capture and CO 2 conversion
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Computational design of a metal-based frustrated Lewis pair on defective UiO-66 for CO 2 hydrogenation to methanol
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Unravelling moisture-induced CO 2 chemisorption mechanisms in amine-modified sorbents at the molecular scale
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Recent advances in direct air capture by adsorption
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Direct air capture: process technology, techno-economic and socio-political challenges
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An overview of porous silica immobilized amines for direct air CO 2 capture
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Recent trends in covalent organic frameworks (COFs) for carbon dioxide reduction
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Designing optimal core–shell MOFs for direct air capture
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An amine decorated MOF for direct capture of CO 2 from ambient air
inferredcites →https://doi.org/10.1039/d3sc02554copenalex-snapshot
Suitability of a diamine functionalized metal–organic framework for direct air capture
inferredcites →https://doi.org/10.1039/d3ta07909kopenalex-snapshot
Ambient and sub-ambient temperature direct air CO 2 capture (DAC) by novel supported in situ polymerized amines
inferredcites →https://doi.org/10.1039/d4dd00010bopenalex-snapshot
Inverse design of metal–organic frameworks for direct air capture of CO 2 via deep reinforcement learning
inferredcites →https://doi.org/10.1039/d4ee00616jopenalex-snapshot
Tuning sorbent properties to reduce the cost of direct air capture
inferredcites →https://doi.org/10.1039/d5cc02508gopenalex-snapshot
Recent progress of the electrocatalytic CO 2 reduction reaction using porous materials
inferredcites →https://doi.org/10.1039/d5cy00658aopenalex-snapshot
Advances in CO 2 capture and utilization: the role of DFT in understanding CO 2 activation and its conversion mechanisms for methanol and cyclic carbonates production
inferredcites →https://doi.org/10.1039/d5su00162eopenalex-snapshot
Negative emission technologies: a way forward?
inferredcites →https://doi.org/10.1088/1748-9326/aabf9fopenalex-snapshot
Negative emissions—Part 2: Costs, potentials and side effects
inferredcites →https://doi.org/10.1126/science.1176731openalex-snapshot
Amine Scrubbing for CO 2 Capture
inferredcites →https://doi.org/10.1126/science.abb3976openalex-snapshot
Cooperative carbon capture and steam regeneration with tetraamine-appended metal–organic frameworks
inferredcites →https://doi.org/10.3389/fceng.2020.596555openalex-snapshot
CO2 Capture From Air in a Radial Flow Contactor: Batch or Continuous Operation?
inferredcites →https://doi.org/10.3389/fclim.2019.00010openalex-snapshot
The Role of Direct Air Capture in Mitigation of Anthropogenic Greenhouse Gas Emissions
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