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Microenvironment Engineering of Mo/HZSM-5 in Methane to Ethylene: Unraveling the Optimal Active Sites and Synergistic C-Mo Activation Mechanism

https://doi.org/10.2139/ssrn.6507308
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Outgoing claims: the papers this work cites, builds on, or argues with.

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Synthesis, Solid‐State Structure, and Bonding Analysis of a Homoleptic Beryllium Azide
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Tuning the Hybridization of Local Exciton and Charge‐Transfer States in Highly Efficient Organic Photovoltaic Cells
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Dual Active Sites on Molybdenum/ZSM‐5 Catalyst for Methane Dehydroaromatization: Insights from Solid‐State NMR Spectroscopy
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Molybdenum bound nitrogen‐doped graphene catalyst for reduction of N2 to NH3 and NH2NH2, using FLP as a co‐catalyst: A DFT study
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Progress in Developing a Structure‐Activity Relationship for the Direct Aromatization of Methane
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Methane Activation by Diatomic Molybdenum Carbide Cations
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Multiwfn: A multifunctional wavefunction analyzer
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Dehydro-oligomerization of Methane to Ethylene and Aromatics over Molybdenum/HZSM-5 Catalyst
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Dependence of metathesis activity of Mo-methylidene sites on their location on (100) γ-Al2O3—a theoretical study
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Elucidating the role of Fe-Mo interactions in the metal oxide precursors for Fe promoted Mo/ZSM-5 catalysts in non-oxidative methane dehydroaromatization
inferredcites →https://doi.org/10.1016/j.cej.2024.153616openalex-snapshot
Kinetic modeling of methane dehydroaromatization over Mo/ZSM-5 catalysts
inferredcites →https://doi.org/10.1016/j.fuel.2022.126765openalex-snapshot
Enhanced Catalytic Performance of the Hollow Mo/Hzsm-5 Nanocrystal for Methane Dehydroaromatization
inferredcites →https://doi.org/10.1016/j.jcat.2016.12.006openalex-snapshot
Stable Mo/HZSM-5 methane dehydroaromatization catalysts optimized for high-temperature calcination-regeneration
inferredcites →https://doi.org/10.1016/j.jcat.2019.01.013openalex-snapshot
A site-sensitive quasi-in situ strategy to characterize Mo/HZSM-5 during activation
inferredcites →https://doi.org/10.1016/j.jcat.2019.11.004openalex-snapshot
Influence of ethylene and acetylene on the rate and reversibility of methane dehydroaromatization on Mo/H-ZSM-5 catalysts
inferredcites →https://doi.org/10.1016/j.jcat.2020.06.035openalex-snapshot
Carbidic Mo is the sole kinetically-relevant active site for catalytic methane dehydroaromatization on Mo/H-ZSM-5
inferredcites →https://doi.org/10.1016/j.jcat.2023.06.034openalex-snapshot
Identification of reversible and irreversible deactivation of MDA catalysts: A key to design a viable process
inferredcites →https://doi.org/10.1016/j.jcat.2024.115619openalex-snapshot
Operando UV–Vis diffuse reflectance spectroscopy insights into the methane dehydroaromatization reaction over Mo/H-ZSM-5 catalysts
inferredcites →https://doi.org/10.1016/j.micromeso.2020.110000openalex-snapshot
Solid-state 29Si NMR spectra of pure silica zeolites for the International Zeolite Association Database of Zeolite Structures
inferredcites →https://doi.org/10.1016/s1381-1169(01)00373-9openalex-snapshot
Aromatization of methane over zeolite supported molybdenum: active sites and reaction mechanism
inferredcites →https://doi.org/10.1016/s2095-4956(13)60071-6openalex-snapshot
Direct conversion of natural gas to higher hydrocarbons: A review
inferredcites →https://doi.org/10.1021/acs.cgd.3c00802openalex-snapshot
Rational Tailoring of Metal Precursor Interactions with the Zeolite Support in the Mo/HZSM-5 Catalyst for Methane Dehydroaromatization
inferredcites →https://doi.org/10.1021/acs.jpcc.7b09275openalex-snapshot
Mechanistic Insights into the Activity of Mo-Carbide Clusters for Methane Dehydrogenation and Carbon–Carbon Coupling Reactions To Form Ethylene in Methane Dehydroaromatization
inferredcites →https://doi.org/10.1021/acscatal.2c04962openalex-snapshot
Transition-Metal Catalysts for Methane Dehydroaromatization (Mo, Re, Fe): Activity, Stability, Active Sites, and Carbon Deposits
inferredcites →https://doi.org/10.1021/acscatal.3c00854openalex-snapshot
Isomorphously Substituted [Fe,Al]ZSM-5 Catalysts for Methane Dehydroaromatization
inferredcites →https://doi.org/10.1021/acscatal.4c02300openalex-snapshot
Brønsted Acid Site Catalytic Role in Methane Dehydroaromatization over Mo/HZSM-5
inferredcites →https://doi.org/10.1021/acscatal.4c07228openalex-snapshot
Impact of Tungsten Loading on the Activation of Zeolite-Based Catalysts for Methane Dehydroaromatization
inferredcites →https://doi.org/10.1021/acscatal.5c00459openalex-snapshot
Machine Learning-Accelerated Prediction of Lewis Acid Site Positioning for Long-Chain Mono-olefin Aromatization on Zn2+/HZSM-5 Catalysts
inferredcites →https://doi.org/10.1021/acscatal.6b02497openalex-snapshot
Methane Dehydroaromatization by Mo/HZSM-5: Mono- or Bifunctional Catalysis?
inferredcites →https://doi.org/10.1021/acscatal.9b02213openalex-snapshot
Structure and Reactivity of the Mo/ZSM-5 Dehydroaromatization Catalyst: An Operando Computational Study
inferredcites →https://doi.org/10.1021/ie0609564openalex-snapshot
Study of Methane Dehydroaromatization on Impregnated Mo/ZSM-5 Catalysts and Characterization of Nanostructured Molybdenum Phases and Carbonaceous Deposits
inferredcites →https://doi.org/10.1021/ja102261mopenalex-snapshot
Quantum Chemical Modeling of Benzene Ethylation over H-ZSM-5 Approaching Chemical Accuracy: A Hybrid MP2:DFT Study
inferredcites →https://doi.org/10.1021/jacs.9b09710openalex-snapshot
Activity Descriptors Derived from Comparison of Mo and Fe as Active Metal for Methane Conversion to Aromatics
inferredcites →https://doi.org/10.1038/s41560-025-01834-5openalex-snapshot
Photocatalytic oxidative coupling of methane to C3+ hydrocarbons via nanopore-confined microenvironments
inferredcites →https://doi.org/10.1039/c7cy01789hopenalex-snapshot
Relevance of the Mo-precursor state in H-ZSM-5 for methane dehydroaromatization
inferredcites →https://doi.org/10.1039/c8sc01263fopenalex-snapshot
On the dynamic nature of Mo sites for methane dehydroaromatization
inferredcites →https://doi.org/10.1039/d2cp03306bopenalex-snapshot
Probing the nature of Lewis acid sites on oxide surfaces with 31 P(CH 3 ) 3 NMR: a theoretical analysis
inferredcites →https://doi.org/10.1126/science.aaa7048openalex-snapshot
Identification of molybdenum oxide nanostructures on zeolites for natural gas conversion
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