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In situ elucidation of PO radical formation pathways in phosphonate flame retardants with different P–C linkage motifs

https://doi.org/10.2139/ssrn.6865208
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Outgoing claims: the papers this work cites, builds on, or argues with.

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DOPO‐VTS‐based coatings in the realm of fire retardants for cotton textile
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The Unimolecular Decomposition Mechanism of Trimethyl Phosphate
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Recyclable flame retardant phosphonated epoxy based thermosets enabled via a reactive approach
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Development of the detailed mechanism of pyrolysis and combustion of triphenyl phosphate: New quantum chemistry calculations and experimental data on structure of the H2/O2/Ar flame doped with TPP
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The influence of various oxygenated functional groups in carbonyl and ether compounds on compression ignition and exhaust gas emissions
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Preparation, identification, and low-temperature infrared spectra of two elusive crystalline nitrile ices
inferredcites →https://doi.org/10.1016/j.jaap.2025.107371openalex-snapshot
In-situ detection of phosphorus-containing gas phase species at steady-state pyrolysis of flame retardant coated cotton
inferredcites →https://doi.org/10.1016/j.polymdegradstab.2008.06.010openalex-snapshot
Studies of degradation enhancement of polystyrene by flame retardant additives
inferredcites →https://doi.org/10.1016/j.polymdegradstab.2012.05.030openalex-snapshot
Hybrid phosphorus-doped silica architectures derived from a multistep sol–gel process for improving thermal stability and flame retardancy of cotton fabrics
inferredcites →https://doi.org/10.1016/j.polymdegradstab.2013.11.020openalex-snapshot
Sol–gel derived architectures for enhancing cotton flame retardancy: Effect of pure and phosphorus-doped silica phases
inferredcites →https://doi.org/10.1016/j.polymdegradstab.2018.12.018openalex-snapshot
The chemical kinetics of the polymer combustion allows for inherent fire retardant synergism
inferredcites →https://doi.org/10.1016/j.polymdegradstab.2024.111107openalex-snapshot
Impact of phosphonate and phosphoramidate in Si/P/triazine hybrid flame retardants on cotton flammability
inferredcites →https://doi.org/10.1016/j.polymdegradstab.2025.111543openalex-snapshot
Thermal decomposition mechanisms of phosphorus flame retardants: A combined theoretical and experimental approach
inferredcites →https://doi.org/10.1016/j.polymdegradstab.2025.111629openalex-snapshot
Thermal decomposition of cellulosic materials: Insights into mechanisms and product evolution
inferredcites →https://doi.org/10.1016/j.polymer.2006.10.022openalex-snapshot
Influence of the oxidation state of phosphorus on the decomposition and fire behaviour of flame-retarded epoxy resin composites
inferredcites →https://doi.org/10.1016/j.proci.2006.07.120openalex-snapshot
Inhibition of atmospheric lean and rich CH4/O2/Ar flames by phosphorus-containing compound
inferredcites →https://doi.org/10.1039/c9py00737gopenalex-snapshot
Hyperbranched phosphorus flame retardants: multifunctional additives for epoxy resins
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First phosphorus AB 2 monomer for flame-retardant hyperbranched polyphosphoesters: AB 2 vs . A 2 + B 3
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The chemistry of combustion of organophosphorus compounds
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The Infrared Spectra of Nitriles and Related Compounds Frozen in Ar and H 2 O
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Pyrolytic Gas Generation of Cotton Cellulose With and Without Flame Retardants at Different Stages of Thermal Degradation: Effects of Nitrogen, Phosphorus, and Halogens
inferredcites →https://doi.org/10.3390/inorganics11070306openalex-snapshot
How to Address Flame-Retardant Technology on Cotton Fabrics by Using Functional Inorganic Sol–Gel Precursors and Nanofillers: Flammability Insights, Research Advances, and Sustainability Challenges
inferredcites →https://doi.org/10.3390/nano12193404openalex-snapshot
Functional Silane-Based Nanohybrid Materials for the Development of Hydrophobic and Water-Based Stain Resistant Cotton Fabrics Coatings
inferredcites →https://doi.org/10.3390/polym12051202openalex-snapshot
A Flame-Retardant Phytic-Acid-Based LbL-Coating for Cotton Using Polyvinylamine
inferredcites →https://doi.org/10.3390/polym17070924openalex-snapshot
The Gas- and Condensed-Phase Efficacy of Functionalized Phosphorus Flame Retardants for Cotton Fabric: Phenyl vs. Phenoxy Groups
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An Overview of Mode of Action and Analytical Methods for Evaluation of Gas Phase Activities of Flame Retardants
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