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Reactions of carbon radicals generated by 1,5-transposition of reactive centers

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/anie.196405251openalex-snapshot

Intramolecular Free‐Radical Reactions

inferredcites →https://doi.org/10.1002/hlca.19620450431openalex-snapshot

Reaktionen von Steroid‐Hypojoditen II. Über die Herstellung 18‐oxygenierter Pregnanverbindungen. Über Steroide, 187. Mitteilung

inferredcites →https://doi.org/10.1002/hlca.19620450651openalex-snapshot

Reaktionen von Steroid‐Hypojoditen III. Sterische Effekte bei 6β‐Hydroxysteroiden Über Steroide, 191. Mitt.

inferredcites →https://doi.org/10.1002/hlca.19720550205openalex-snapshot

Eine neuartige radikalinduzierte intramolekulare Gruppenübertragung. Synthese von 18‐Cyan‐corticosteroiden. Über Steroide, 225. Mitteilung

inferredcites →https://doi.org/10.1002/hlca.200390258openalex-snapshot

Synthesis of Scopin Acetate and 6,7‐Didehydrohyoscyamin. Intramolecular Phenylsulfenylation of a Nonactivated Methylene Group of Ethyl N‐Demethyl‐3‐O‐(phenylthio)tropine‐N‐carboxylate

inferredcites →https://doi.org/10.1016/0040-4020(72)88137-7openalex-snapshot

The reaction of lead tetraacetate with alicyclic alcohols—VI

inferredcites →https://doi.org/10.1016/0040-4020(78)88391-4openalex-snapshot

Vicinal phenyl group shift in the lead tetraacetate and related oxidations of 5,5,5-triphenyl-1-pentanol

inferredcites →https://doi.org/10.1016/0040-4020(81)85021-1openalex-snapshot

Ferrous ion induced decomposition of alkyl hypochlorites

inferredcites →https://doi.org/10.1016/0040-4020(95)00406-xopenalex-snapshot

Remote intramolecular free radical functionalizations: An update

inferredcites →https://doi.org/10.1016/s0040-4020(01)82671-5openalex-snapshot

The reaction of lead tetra-acetate with some unbranched α,ω-diols

inferredcites →https://doi.org/10.1016/s0040-4020(02)01477-1openalex-snapshot

Regioselective free radical phenylsulfenation of a non-activated δ-carbon atom by the photolysis of alkyl benzenesulfenate

inferredcites →https://doi.org/10.1016/s0040-4020(03)01202-xopenalex-snapshot

Reactions of δ-carbon radicals generated by 1,5-hydrogen transfer to alkoxyl radicals

inferredcites →https://doi.org/10.1016/s0040-4020(98)01110-7openalex-snapshot

Alkylation of remote non-activated δ-carbon atoms: Addition of δ-carbon radicals, generated by 1,5-hydrogen transfer in alkoxy radical intermediates, to activated olefins

inferredcites →https://doi.org/10.1016/s0040-4039(00)00933-3openalex-snapshot

Exclusive 1,4-aryl migration in a stereoselective cyclization of N-benzylalk-4-enylaminyl radicals

inferredcites →https://doi.org/10.1016/s0040-4039(00)77910-xopenalex-snapshot

Formation of remote double bonds by cupric acetate catalyzed photolysis of alkyl nitrites

inferredcites →https://doi.org/10.1016/s0040-4039(00)78896-4openalex-snapshot

Radical cyclisation of some 1,2,6-trideoxy-3,4-di-O-benzyl-6-halogeno--arabino-hex-1-ynitol derivatives

inferredcites →https://doi.org/10.1016/s0040-4039(00)80319-6openalex-snapshot

Intramolecular cyclization of alkenyl radicals generated by 1,5-hydrogen transfer to alkoxy radicals

inferredcites →https://doi.org/10.1016/s0040-4039(00)87708-4openalex-snapshot

Functionallization of the δ-carbon atom by the ferrous ion induced decomposition of alkyl hydroperoxides in the presence of cupric salts

inferredcites →https://doi.org/10.1016/s0040-4039(01)95383-3openalex-snapshot

Synthesis of the 2-aza-7-oxatricyclo[4.3.2.04,8]undecane nucleus of some gelsemium alkaloids

inferredcites →https://doi.org/10.1016/s0040-4039(96)02357-xopenalex-snapshot

Free radical alkylation of the remote nonactivated δ-carbon atom

inferredcites →https://doi.org/10.1016/s0040-4039(96)02430-6openalex-snapshot

Radical rearrangements of α-iodoalkyl phenyl sulfones involving 1,5 hydrogen atom transfer reactions

inferredcites →https://doi.org/10.1016/s0040-4039(98)01373-2openalex-snapshot

New intramolecular cyclization and rearrangement processes based on the radical aryl-aryl coupling of arylsubstituted 2-azetidinones

inferredcites →https://doi.org/10.1021/cr00006a006openalex-snapshot

Radical reactions in natural product synthesis

inferredcites →https://doi.org/10.1021/ja00158a075openalex-snapshot

Intramolecular .alpha.-amidoyl-to-aryl 1,5-hydrogen atom transfer reactions. Heteroannulation and .alpha.-nitrogen functionalization by radical translocation

inferredcites →https://doi.org/10.1021/ja00260a045openalex-snapshot

The total synthesis of the aglycon of avermectin A1a

inferredcites →https://doi.org/10.1021/ja00447a041openalex-snapshot

Photolysis of .alpha.-peracetoxynitriles. 2. A comparison of two synthetic approaches to 18-cyano-20-ketosteroids

inferredcites →https://doi.org/10.1021/ja00816a059openalex-snapshot

Formation of remote double bonds by ferrous sulfate-cupric acetate promoted decomposition of alkyl hydroperoxides

inferredcites →https://doi.org/10.1021/ja00861a015openalex-snapshot

The Synthesis of 19-Noraldosterone Acetate and Related 19-Substituted Steroids

inferredcites →https://doi.org/10.1021/ja00948a036openalex-snapshot

Some Radical Exchange Reactions during Nitrite Ester Photolysis1

inferredcites →https://doi.org/10.1021/ja01045a032openalex-snapshot

Syntheses of the (-)-.alpha.-and (+)-.beta.-cis-bergamotenes

inferredcites →https://doi.org/10.1021/ja01086a043openalex-snapshot

Silver-Catalyzed Decomposition of Hypobromites

inferredcites →https://doi.org/10.1021/ja01480a031openalex-snapshot

A Synthesis of Aldosterone Acetate1

inferredcites →https://doi.org/10.1021/ja01495a062openalex-snapshot

A SYNTHESIS OF ALDOSTERONE ACETATE

inferredcites →https://doi.org/10.1021/jo000041dopenalex-snapshot

Stereoselective Radical Aryl Migration from Silicon to Carbon

inferredcites →https://doi.org/10.1021/jo00073a005openalex-snapshot

Free-radical annelation in the synthesis of bicyclic .beta.-lactams. 7. A one-pot, four-step, sequential reaction

inferredcites →https://doi.org/10.1021/jo00100a049openalex-snapshot

Synthesis of (+)-8-Deoxyvernolepin

inferredcites →https://doi.org/10.1021/jo00126a021openalex-snapshot

Ring Closure Reactions of Substituted 4-Pentenyl-1-oxy Radicals. The Stereoselective Synthesis of Functionalized Disubstituted Tetrahydrofurans

inferredcites →https://doi.org/10.1021/jo00171a066openalex-snapshot

Intramolecular functionalization of nonactivated carbons by amidylphosphate radicals. Synthesis of 1,4-epimine compounds

inferredcites →https://doi.org/10.1021/jo00227a024openalex-snapshot

Consecutive ring closure and neophyl rearrangement of some alkenylaryl radicals

inferredcites →https://doi.org/10.1021/jo00243a011openalex-snapshot

The relationship between proximity and reactivity. An ab initio study of the flexibility of the OH.bul. + CH4 hydrogen abstraction transition state and a force-field model for the transition states of intramolecular hydrogen abstractions

inferredcites →https://doi.org/10.1021/jo00795a026openalex-snapshot

.delta.-Chloro alcohols and tetrahydrofurans from primary and secondary alkyl hypochlorites

inferredcites →https://doi.org/10.1021/jo980205eopenalex-snapshot

Short Syntheses of Polyhydroxylated α-Alkylated Amino Acids

inferredcites →https://doi.org/10.1021/jo9904260openalex-snapshot

5-Endo-Trig Radical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes

inferredcites →https://doi.org/10.1021/ol005661fopenalex-snapshot

Synthesis of Biaryls by Intramolecular Radical Aryl Migration from Silicon to Carbon

inferredcites →https://doi.org/10.1021/ol0062401openalex-snapshot

Annulation of the Cyclohexane Ring by Tandem Free Radical Alkylation of a Nonactivated δ-Carbon Atom−Intramolecular Carbanion Cycloalkylation

inferredcites →https://doi.org/10.1039/b000705fopenalex-snapshot

Radical translocation reactions in synthesis

inferredcites →https://doi.org/10.1039/j39680001657openalex-snapshot

Adamantane chemistry. Part I. The synthesis of 1,2-disubstituted adamantanes

inferredcites →https://doi.org/10.1039/j39690000336openalex-snapshot

Photochemical transformations. Part XXVI. Some 19-substituted lanostane derivatives

inferredcites →https://doi.org/10.1039/jr9650000181openalex-snapshot

28. Photochemical transformations. Part XVI. A novel synthesis of lactones

inferredcites →https://doi.org/10.1039/p19750002252openalex-snapshot

Synthesis of 11-deoxy-18-hydroxycorticosterone and 18-hydroxycorticosterone 21-acetates

inferredcites →https://doi.org/10.1039/p19810002363openalex-snapshot

Radical-induced ring opening of epoxides. A convenient alternative to the wharton rearrangement

inferredcites →https://doi.org/10.1039/p19820000229openalex-snapshot

Electrochemical reactions. Part 24. Reductive cyclisation of i-(2-halogenophenyl)-j-phenyl compounds: a general reaction

inferredcites →https://doi.org/10.1055/s-1971-21765openalex-snapshot

Die Hypojodit-Reaktion (Verfahren zur intramolekularen Substitution an nicht-aktivierten C-Atomen)

inferredcites →https://doi.org/10.1055/s-1999-2658openalex-snapshot

Synthesis of Acetyl Scopine. Intramolecular Reactions of N-Carbethoxy Nortropine-3α-benzenesulfenate

inferredcites →https://doi.org/10.2298/jsc0410737popenalex-snapshot

Stereoselective free radical phenylsulfenylation of a nonactivated δ-carbon atom

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4670490openalex-extracted

Generation and Radical-Radical Cross-Coupling of Alkenyloxy Radical: Ester and Ketone Synthesis

inferred← citeshttps://doi.org/10.1002/adsc.201801198openalex-snapshot

Iminyl Radical‐Mediated Controlled Hydroxyalkylation of Remote C(sp3)‐H Bond via Tandem 1,5‐HAT and Difunctionalization of Aryl Alkenes

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Visible‐Light‐Driven Remote C−H Chlorination of Aliphatic Sulfonamides with Sodium Hypochlorite

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Generation of Alkoxyl Radicals by Photoredox Catalysis Enables Selective C(sp3)−H Functionalization under Mild Reaction Conditions

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Catalytic Asymmetric C−H Functionalization under Photoredox Conditions by Radical Translocation and Stereocontrolled Alkene Addition

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Komplementäre Strategien für die dirigierte C(sp3)‐H‐Funktionalisierung: ein Vergleich von übergangsmetallkatalysierter Aktivierung, Wasserstoffatomtransfer und Carben‐ oder Nitrentransfer

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Donor–Acceptor Complex Enables Alkoxyl Radical Generation for Metal‐Free C(sp3)–C(sp3) Cleavage and Allylation/Alkenylation

inferred← citeshttps://doi.org/10.1002/ange.201710322openalex-snapshot

Sulfamate Esters Guide Selective Radical‐Mediated Chlorination of Aliphatic C−H Bonds

inferred← citeshttps://doi.org/10.1002/ange.201710790openalex-snapshot

Photoinduced Remote Functionalisations by Iminyl Radical Promoted C−C and C−H Bond Cleavage Cascades

inferred← citeshttps://doi.org/10.1002/ange.201712775openalex-snapshot

Palladium‐Catalyzed Atom‐Transfer Radical Cyclization at Remote Unactivated C(sp3)−H Sites: Hydrogen‐Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates

inferred← citeshttps://doi.org/10.1002/ange.201806522openalex-snapshot

Alkoxyl Radicals Generated under Photoredox Catalysis: A Strategy for anti‐Markovnikov Alkoxylation Reactions

inferred← citeshttps://doi.org/10.1002/ange.202016666openalex-snapshot

Recent Advances in Photoredox‐Mediated Radical Conjugate Addition Reactions: An Expanding Toolkit for the Giese Reaction

inferred← citeshttps://doi.org/10.1002/ange.202101266openalex-snapshot

Direct Activation of a Remote C(sp3)–H Bond Enabled by a Visible‐Light Photosensitized Allene Moiety

inferred← citeshttps://doi.org/10.1002/anie.201510014openalex-snapshot

Generation of Alkoxyl Radicals by Photoredox Catalysis Enables Selective C(sp 3 )−H Functionalization under Mild Reaction Conditions

inferred← citeshttps://doi.org/10.1002/anie.201607305openalex-snapshot

Catalytic Asymmetric C−H Functionalization under Photoredox Conditions by Radical Translocation and Stereocontrolled Alkene Addition

inferred← citeshttps://doi.org/10.1002/anie.201703743openalex-snapshot

Complementary Strategies for Directed C(sp 3 )−H Functionalization: A Comparison of Transition‐Metal‐Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer

inferred← citeshttps://doi.org/10.1002/anie.201707171openalex-snapshot

Donor–Acceptor Complex Enables Alkoxyl Radical Generation for Metal‐Free C(sp 3 )–C(sp 3 ) Cleavage and Allylation/Alkenylation

inferred← citeshttps://doi.org/10.1002/anie.201710322openalex-snapshot

Sulfamate Esters Guide Selective Radical‐Mediated Chlorination of Aliphatic C−H Bonds

inferred← citeshttps://doi.org/10.1002/anie.201710790openalex-snapshot

Photoinduced Remote Functionalisations by Iminyl Radical Promoted C−C and C−H Bond Cleavage Cascades

inferred← citeshttps://doi.org/10.1002/anie.201712775openalex-snapshot

Palladium‐Catalyzed Atom‐Transfer Radical Cyclization at Remote Unactivated C(sp3)−H Sites: Hydrogen‐Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates

inferred← citeshttps://doi.org/10.1002/anie.201806522openalex-snapshot

Alkoxyl Radicals Generated under Photoredox Catalysis: A Strategy for anti‐Markovnikov Alkoxylation Reactions

inferred← citeshttps://doi.org/10.1002/anie.202016666openalex-snapshot

Recent Advances in Photoredox‐Mediated Radical Conjugate Addition Reactions: An Expanding Toolkit for the Giese Reaction

inferred← citeshttps://doi.org/10.1002/anie.202101266openalex-snapshot

Direct Activation of a Remote C(sp 3 )–H Bond Enabled by a Visible‐Light Photosensitized Allene Moiety

inferred← citeshttps://doi.org/10.1002/chem.201403951openalex-snapshot

1, n ‐Hydrogen‐Atom Transfer (HAT) Reactions in Which n ≠5: An Updated Inventory

inferred← citeshttps://doi.org/10.1002/chin.200550233openalex-snapshot

Reactions of Carbon Radicals Generated by 1,5‐trans Position of Reactive Centers

inferred← citeshttps://doi.org/10.1002/ejoc.201200300openalex-snapshot

C–C Bond Formation by Sequential Intramolecular Hydrogen Atom Transfer/Intermolecular Radical Allylation Reaction in Carbohydrate Systems

inferred← citeshttps://doi.org/10.1007/7081_2018_19openalex-snapshot

Heteroatom-Centred Radicals for the Synthesis of Heterocyclic Compounds

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Carbohydrate Spiro-heterocycles via Radical Chemistry

inferred← citeshttps://doi.org/10.1007/s10593-014-1405-7openalex-snapshot

Preparation of 2-azabicyclo[3.3.1]nonan-3-ones by a Radical C-Carbonylation of Methylcyclo-Hexylamines

inferred← citeshttps://doi.org/10.1016/b978-0-443-18941-8.00002-xopenalex-snapshot

Five-membered O- and O,O-heterocycles

inferred← citeshttps://doi.org/10.1016/b978-0-443-18941-8.00012-2openalex-snapshot

Five-membered N-heterocycles–Part I

inferred← citeshttps://doi.org/10.1016/j.cclet.2017.08.005openalex-snapshot

N -9 Alkylation of purines via light-promoted and metal-free radical relay

inferred← citeshttps://doi.org/10.1016/j.isci.2019.100755openalex-snapshot

Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp3)-H Bond Allylation

inferred← citeshttps://doi.org/10.1016/j.molstruc.2013.02.020openalex-snapshot

Stabilization of long-chain intermediates in solution. Octyl radicals and cations

inferred← citeshttps://doi.org/10.1016/j.molstruc.2014.11.030openalex-snapshot

Stabilization of long-chain intermediates in solution. Tridecyl radicals and cations

inferred← citeshttps://doi.org/10.1016/j.tet.2008.04.040openalex-snapshot

An efficient, metal-free, room temperature aromatization of Hantzsch-1,4-dihydropyridines with urea–hydrogen peroxide adduct, catalyzed by molecular iodine

inferred← citeshttps://doi.org/10.1016/j.tet.2009.11.113openalex-snapshot

Efficiency of alkoxyl radical product formation from 5-substituted 3-alkoxy-4-methylthiazole-2(3H)-thiones

inferred← citeshttps://doi.org/10.1016/j.tet.2009.12.023openalex-snapshot

Radicals in organic synthesis: part 2

inferred← citeshttps://doi.org/10.1016/j.tet.2026.135354openalex-snapshot

Radical translocation by intramolecular hydrogen atom transfer: Occurrences and opportunities in natural product total synthesis

inferred← citeshttps://doi.org/10.1016/j.tetlet.2008.06.070openalex-snapshot

Stereoselective synthesis of C-ketosides by sequential intramolecular hydrogen atom transfer–intermolecular allylation reaction

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Intramolecular Photoreactions of (5S)-5-Oxymethyl-2(5H)-furanones as a Tool for the Stereoselective Generation of Diverse Polycyclic Scaffolds

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Carbanion Translocations via Intramolecular Proton Transfers: A Quantum Chemical Study

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Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes

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Sulfonamide as Photoinduced Hydrogen-Atom Transfer Catalyst for Regioselective Alkylation of C(sp 3 )–H Bonds Adjacent to Heteroatoms

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Tuning the Reactivity of Alkoxyl Radicals from Cyclization to 1,2-Silyl Transfer: Stereoselective Synthesis of β-Substituted Cycloalcohols

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Radical C(sp3)–H Heck-type Reaction of N-Alkoxybenzimidoyl Chlorides with Styrenes to Construct Alkenols

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Remote Nucleophilic Substitution at a C(sp3)–H Bond of α-Bromocarboxamides via 1,4-Hydrogen Atom Transfer To Access N-Acyl-N,O-acetal Compounds

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Generation and Radical–Radical Cross-Coupling of Alkenyloxy Radical

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Controllable Intramolecular Unactivated C(sp3)-H Amination and Oxygenation of Carbamates

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Visible Light Driven Alkylation of C(sp3)–H Bonds Enabled by 1,6-Hydrogen Atom Transfer/Radical Relay Addition

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Engineering Molecular Iodine Catalysis for Alkyl–Nitrogen Bond Formation

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Cyclic Ether Synthesis via Palladium-Catalyzed Directed Dehydrogenative Annulation at Unactivated Terminal Positions

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Iron-Catalyzed, Fluoroamide-Directed C–H Fluorination

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Directed γ-C(sp 3 )–H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis

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Alkoxy Radical Cyclizations onto Silyl Enol Ethers Relative to Alkene Cyclization, Hydrogen Atom Transfer, and Fragmentation Reactions

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Mechanistic Investigation of Enediyne-Connected Amino Ester Rearrangement. Theoretical Rationale for the Exclusive Preference for 1,6- or 1,5-Hydrogen Atom Transfer Depending on the Substrate. A Potential Route to Chiral Naphthoazepines

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Copper-Catalyzed Oxaziridine-Mediated Oxidation of C–H Bonds

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Strategies to Control Alkoxy Radical-Initiated Relay Cyclizations for the Synthesis of Oxygenated Tetrahydrofuran Motifs

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Tetramerization of 3-Methyl-cyclopropene-3-carbonitrile: A Novel CN-Alder-ene Reaction

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Strained Polycycles by H5C5xFree-Radical Cascades

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An Approach toward Constructing the Trioxadispiroketal Core in the DEF-Ring of (+)-Spirastrellolide A

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Construction of Carbo- and Heterocycles Using Radical Relay Cyclizations Initiated by Alkoxy Radicals

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Amide-directed photoredox-catalysed C–C bond formation at unactivated sp3 C–H bonds

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Synthetic use of the primary kinetic isotope effect in hydrogen atom transfer 2: generation of captodatively stabilised radicals

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Phosphine-catalyzed remote α-C–H bond activation of alcohols or amines triggered by the radical trifluoromethylation of alkenes: reaction development and mechanistic insights

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Heterocyclization involving benzylic C(sp 3 )–H functionalization enabled by visible light photoredox catalysis

inferred← citeshttps://doi.org/10.1039/c9sc02616aopenalex-snapshot

A dual photoredox-nickel strategy for remote functionalization via iminyl radicals: radical ring-opening-arylation, -vinylation and -alkylation cascades

inferred← citeshttps://doi.org/10.1039/d4qo01245copenalex-snapshot

Photoredox copper-catalyzed regioselective syntheses of allenols via HAT-mediated propargyl radical generation

inferred← citeshttps://doi.org/10.1055/sos-sd-234-00177openalex-snapshot

1.9 Oxygen-Centered Radicals

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Effect of Brønsted acids on the thiophenol-mediated radical addition–translocation–cyclization process for the preparation of pyrrolidine derivatives

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Structural Analysis of Oxidized Cerebrosides from the Extract of Deep-Sea Sponge Aulosaccus sp.: Occurrence of Amide-Linked Allylically Oxygenated Fatty Acids

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