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A Protocol for Safe Lithiation Reactions Using Organolithium Reagents

https://doi.org/10.3791/54705
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/0470084960openalex-snapshot
March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
inferredcites →https://doi.org/10.1002/9780470740859openalex-snapshot
Superbases for Organic Synthesis
inferredcites →https://doi.org/10.1002/9783527667512openalex-snapshot
Lithium Compounds in Organic Synthesis
inferredcites →https://doi.org/10.1002/ange.201400889openalex-snapshot
Introducing Deep Eutectic Solvents to Polar Organometallic Chemistry: Chemoselective Addition of Organolithium and Grignard Reagents to Ketones in Air
inferredcites →https://doi.org/10.1002/anie.201400889openalex-snapshot
Introducing Deep Eutectic Solvents to Polar Organometallic Chemistry: Chemoselective Addition of Organolithium and Grignard Reagents to Ketones in Air
inferredcites →https://doi.org/10.1002/chin.201448255openalex-snapshot
ChemInform Abstract: “The Great Beauty” of Organolithium Chemistry: A Land Still Worth Exploring
inferredcites →https://doi.org/10.1002/ejoc.201500757openalex-snapshot
Reactivity of Polar Organometallic Compounds in Unconventional Reaction Media: Challenges and Opportunities
inferredcites →https://doi.org/10.1016/0040-4020(96)00734-xopenalex-snapshot
Synthesis of 3-alkylpyrrolidines by anionic cyclization
inferredcites →https://doi.org/10.1016/j.tet.2004.12.047openalex-snapshot
Tandem intramolecular carbolithiation–transmetallation: from lithium to copper or boron chemistry
inferredcites →https://doi.org/10.1016/s0022-328x(00)83259-3openalex-snapshot
The analysis of organolithium compounds
inferredcites →https://doi.org/10.1021/cr400187uopenalex-snapshot
Role of Organolithium Aggregates and Mixed Aggregates in Organolithium Mechanisms
inferredcites →https://doi.org/10.1021/ja00026a012openalex-snapshot
Bond dissociation energies in DMSO related to the gas phase values
inferredcites →https://doi.org/10.1021/ja001699bopenalex-snapshot
Grignard-Type Carbonyl Phenylation in Water and under an Air Atmosphere
inferredcites →https://doi.org/10.1021/ja00186a021openalex-snapshot
Synthesis of dialkyl- and alkyl(acyl)rhenium complexes by alkylation of anionic rhenium complexes at the metal center. Mechanism of a double carbonylation reaction that proceeds via the formation of free methyl radicals in solution
inferredcites →https://doi.org/10.1021/ja00225a020openalex-snapshot
Electrochemical behavior of lithium dialkylamides: the effect of aggregation
inferredcites →https://doi.org/10.1021/ja981020sopenalex-snapshot
Unexpected Barbier−Grignard Allylation of Aldehydes with Magnesium in Water
inferredcites →https://doi.org/10.1021/jo00263a052openalex-snapshot
Simple direct titration of organolithium reagents using N-pivaloyl-o-toluidine and/or N-pivaloyl-o-benzylaniline
inferredcites →https://doi.org/10.1021/jo00872a047openalex-snapshot
A convenient method for estimation of alkyllithium concentrations
inferredcites →https://doi.org/10.1021/jo3005155openalex-snapshot
What’s Going on with These Lithium Reagents?
inferredcites →https://doi.org/10.1021/op800246zopenalex-snapshot
Optimization of Organolithium Reactions
inferredcites →https://doi.org/10.1039/c4cc03149kopenalex-snapshot
Regioselective desymmetrization of diaryltetrahydrofurans via directed ortho-lithiation: an unexpected help from green chemistry
inferredcites →https://doi.org/10.1039/c4dt01004copenalex-snapshot
“The Great Beauty” of organolithium chemistry: a land still worth exploring
inferredcites →https://doi.org/10.1039/c5cc02884aopenalex-snapshot
Unexpected lateral-lithiation-induced alkylative ring opening of tetrahydrofurans in deep eutectic solvents: synthesis of functionalised primary alcohols
inferredcites →https://doi.org/10.1039/c5sc03436aopenalex-snapshot
Water opens the door to organolithiums and Grignard reagents: exploring and comparing the reactivity of highly polar organometallic compounds in unconventional reaction media towards the synthesis of tetrahydrofurans
inferredcites →https://doi.org/10.1039/cc9960002321openalex-snapshot
Novel octameric structure of the lithium primary amide [{ButN(H)Li}8] and its implication for the directed synthesis of heterometallic imide cages
inferredcites →https://doi.org/10.1134/s0006297910110167openalex-snapshot
Handbook of Biochemistry and Molecular Biology
inferredcites →https://doi.org/10.2174/138527211796150589openalex-snapshot
Non-Deprotonating Methodologies for Organolithium Reagents Starting from Non-Halogenated Materials. Part 2: Transmetallation and Addition to Multiple Bonds

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4765835openalex-extracted
Polyfunctionalized Organoselenides: New Synthetic Approach from Seleno-Containing Cyanohydrins and Anti-Melanoma Activity
inferred← citeshttps://doi.org/10.1016/j.jcis.2023.05.157openalex-snapshot
Spontaneous clustering of exfoliated two-dimensional materials at the air-water interface
inferred← citeshttps://doi.org/10.1016/j.jpowsour.2026.239882openalex-snapshot
A review of chemical relithiation strategies for complete recovery of LiFePO4
inferred← citeshttps://doi.org/10.1039/c9na00493aopenalex-snapshot
Hydrochromic carbon dots as smart sensors for water sensing in organic solvents
inferred← citeshttps://doi.org/10.1039/d0gc01116aopenalex-snapshot
Developing benign syntheses using ion pairs via solvent-free mechanochemistry
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