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Enantioselective Total Synthesis of Hyperforin and Pyrohyperforin
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Acrylat-assistierter Aren-Chrom-Bindungsbruch: Bildung eines [Cr(CO)2]-Fragments unter milden Reaktionsbedingungen
inferredcites →https://doi.org/10.1002/(sici)1521-3773(19981204)37:22<3146::aid-anie3146>3.0.co;2-mopenalex-snapshot
Acrylate-Assisted Arene-Chromium Bond Cleavage: Generation of a [Cr(CO)2] Fragment under Mild Conditions*
inferredcites →https://doi.org/10.1002/ange.200500776openalex-snapshot
Construction of Highly Functionalized Medium‐Sized Rings: Synthesis of Hyperforin and Perforatumone Model Systems
inferredcites →https://doi.org/10.1002/ange.200703886openalex-snapshot
Differentiation of Nonconventional “Carbanions”—The Total Synthesis of Nemorosone and Clusianone
inferredcites →https://doi.org/10.1002/ange.200906678openalex-snapshot
Catalytic Asymmetric Total Synthesis of ent‐Hyperforin
inferredcites →https://doi.org/10.1002/ange.201005183openalex-snapshot
Catalytic Enantioselective Claisen Rearrangements of O‐Allyl β‐Ketoesters
inferredcites →https://doi.org/10.1002/ange.201103873openalex-snapshot
Die Chemie der polycyclischen polyprenylierten Acylphloroglucine
inferredcites →https://doi.org/10.1002/ange.201304609openalex-snapshot
Synthesis of ent ‐Kaurane and Beyerane Diterpenoids by Controlled Fragmentations of Overbred Intermediates
inferredcites →https://doi.org/10.1002/ange.201306256openalex-snapshot
Die bidirektionale Totalsynthese von Sampsonion P und Hyperibon I
inferredcites →https://doi.org/10.1002/ange.201403939openalex-snapshot
Total Syntheses of Hyperforin and Papuaforins A–C, and Formal Synthesis of Nemorosone through a Gold(I)‐Catalyzed Carbocyclization
inferredcites →https://doi.org/10.1002/ange.201404437openalex-snapshot
Asymmetric, Stereodivergent Synthesis of (−)‐Clusianone Utilizing a Biomimetic Cationic Cyclization
inferredcites →https://doi.org/10.1002/ange.201410350openalex-snapshot
Rhodium‐Catalyzed (5+1) Annulations Between 2‐Alkenylphenols and Allenes: A Practical Entry to 2,2‐Disubstituted 2H‐Chromenes
inferredcites →https://doi.org/10.1002/ange.201707069openalex-snapshot
Polycyclische, polyprenylierte Acylphloroglucinole – eine Klasse nicht‐peptidbasierter MRSA‐ und VRE‐aktiver Antibiotika
inferredcites →https://doi.org/10.1002/ange.201910710openalex-snapshot
Biomimetic Synthesis of Meroterpenoids by Dearomatization‐Driven Polycyclization
inferredcites →https://doi.org/10.1002/ange.202011171openalex-snapshot
Exploiting the Potential of Meroterpenoid Cyclases to Expand the Chemical Space of Fungal Meroterpenoids
inferredcites →https://doi.org/10.1002/ange.202104014openalex-snapshot
Enantioselective Total Synthesis of Berkeleyone A and Preaustinoids
inferredcites →https://doi.org/10.1002/ange.202109193openalex-snapshot
Enantioselective Total Synthesis of (+)‐Garsubellin A
inferredcites →https://doi.org/10.1002/anie.200500776openalex-snapshot
Construction of Highly Functionalized Medium‐Sized Rings: Synthesis of Hyperforin and Perforatumone Model Systems
inferredcites →https://doi.org/10.1002/anie.200703886openalex-snapshot
Differentiation of Nonconventional “Carbanions”—The Total Synthesis of Nemorosone and Clusianone
inferredcites →https://doi.org/10.1002/anie.200906678openalex-snapshot
Catalytic Asymmetric Total Synthesis of ent‐Hyperforin
inferredcites →https://doi.org/10.1002/anie.201005183openalex-snapshot
Catalytic Enantioselective Claisen Rearrangements of O‐Allyl β‐Ketoesters
inferredcites →https://doi.org/10.1002/anie.201103873openalex-snapshot
The Chemistry of the Polycyclic Polyprenylated Acylphloroglucinols
inferredcites →https://doi.org/10.1002/anie.201304609openalex-snapshot
Synthesis of ent ‐Kaurane and Beyerane Diterpenoids by Controlled Fragmentations of Overbred Intermediates
inferredcites →https://doi.org/10.1002/anie.201306256openalex-snapshot
The Bidirectional Total Synthesis of Sampsonione P and Hyperibone I
inferredcites →https://doi.org/10.1002/anie.201403939openalex-snapshot
Total Syntheses of Hyperforin and Papuaforins A–C, and Formal Synthesis of Nemorosone through a Gold(I)‐Catalyzed Carbocyclization
inferredcites →https://doi.org/10.1002/anie.201404437openalex-snapshot
Asymmetric, Stereodivergent Synthesis of (−)‐Clusianone Utilizing a Biomimetic Cationic Cyclization
inferredcites →https://doi.org/10.1002/anie.201410350openalex-snapshot
Rhodium‐Catalyzed (5+1) Annulations Between 2‐Alkenylphenols and Allenes: A Practical Entry to 2,2‐Disubstituted 2H‐Chromenes
inferredcites →https://doi.org/10.1002/anie.201707069openalex-snapshot
Polycyclic Polyprenylated Acylphloroglucinols: An Emerging Class of Non‐Peptide‐Based MRSA‐ and VRE‐Active Antibiotics
inferredcites →https://doi.org/10.1002/anie.201910710openalex-snapshot
Biomimetic Synthesis of Meroterpenoids by Dearomatization‐Driven Polycyclization
inferredcites →https://doi.org/10.1002/anie.202011171openalex-snapshot
Exploiting the Potential of Meroterpenoid Cyclases to Expand the Chemical Space of Fungal Meroterpenoids
inferredcites →https://doi.org/10.1002/anie.202104014openalex-snapshot
Enantioselective Total Synthesis of Berkeleyone A and Preaustinoids
inferredcites →https://doi.org/10.1002/anie.202109193openalex-snapshot
Enantioselective Total Synthesis of (+)‐Garsubellin A
inferredcites →https://doi.org/10.1002/chem.201406077openalex-snapshot
Total Synthesis and Absolute Configuration Assignment of MRSA Active Garcinol and Isogarcinol
inferredcites →https://doi.org/10.1002/ejoc.200300568openalex-snapshot
Oxidative Fragmentation of the Bridged β‐Triketone Core of Hyperforin
inferredcites →https://doi.org/10.1002/ejoc.201101629openalex-snapshot
A Chiral‐Pool‐Based Approach to the Core Structure of (+)‐Hyperforin
inferredcites →https://doi.org/10.1002/ejoc.201300815openalex-snapshot
Chemistry and Biology of the Polycyclic Polyprenylated Acylphloroglucinol Hyperforin
inferredcites →https://doi.org/10.1002/pca.718openalex-snapshot
Structural investigations of isomeric oxidised forms of hyperforin by HPLC‐NMR and HPLC‐MS n
inferredcites →https://doi.org/10.1007/978-3-540-79220-8openalex-snapshot
Elements of Synthesis Planning
inferredcites →https://doi.org/10.1016/j.bmcl.2011.02.074openalex-snapshot
Asymmetric total synthesis of (+)- and (−)-clusianone and (+)- and (−)-clusianone methyl enol ether via ACC alkylation and evaluation of their anti-HIV activity
inferredcites →https://doi.org/10.1016/j.cmet.2021.02.007openalex-snapshot
The phytochemical hyperforin triggers thermogenesis in adipose tissue via a Dlat-AMPK signaling axis to curb obesity
inferredcites →https://doi.org/10.1016/j.lfs.2005.12.027openalex-snapshot
Hyperforin: More than an antidepressant bioactive compound?
inferredcites →https://doi.org/10.1016/j.tet.2010.05.086openalex-snapshot
The first catalytic asymmetric total synthesis of ent-hyperforin
inferredcites →https://doi.org/10.1016/j.tet.2011.06.079openalex-snapshot
Synthetic efforts toward [3.3.1] bridged bicyclic phloroglucinol natural products
inferredcites →https://doi.org/10.1016/j.tet.2018.04.036openalex-snapshot
Functionalized cyclopentanes via Sc(III)-catalyzed intramolecular enolate alkylation
inferredcites →https://doi.org/10.1016/j.tetlet.2010.07.171openalex-snapshot
Synthetic studies toward the PPAP natural products, prolifenones A and B and hyperforin: an Effenberger cyclization approach
inferredcites →https://doi.org/10.1016/j.tetlet.2013.02.021openalex-snapshot
Stereoselective total synthesis of (±)-hyperforin via intramolecular cyclopropanation
inferredcites →https://doi.org/10.1016/s0031-9422(97)00903-5openalex-snapshot
Oxidation products of hyperforin from Hypericum perforatum
inferredcites →https://doi.org/10.1016/s0040-4020(98)00149-5openalex-snapshot
Alkylation of lithium dienediolates of butenoic acids. Regioselectivity effects of structure and leaving group of the alkylating agent
inferredcites →https://doi.org/10.1016/s0040-4039(00)75241-5openalex-snapshot
The structure of hyperforin
inferredcites →https://doi.org/10.1016/s0040-4039(02)02693-xopenalex-snapshot
Synthesis of the core bicyclic system of hyperforin and nemorosone
inferredcites →https://doi.org/10.1016/s0140-6736(99)00214-7openalex-snapshot
Antibacterial activity of hyperforin from St John's wort, against multiresistant Staphylococcus aureus and gram-positive bacteria
inferredcites →https://doi.org/10.1016/s0957-4166(01)00152-5openalex-snapshot
Enantioselective α-alkylation of unsaturated carboxylic acids using a chiral lithium amide
inferredcites →https://doi.org/10.1021/acs.chemrev.7b00551openalex-snapshot
Research Progress of Polycyclic Polyprenylated Acylphloroglucinols
inferredcites →https://doi.org/10.1021/acs.joc.8b00426openalex-snapshot
Modular Total Syntheses of Hyperforin, Papuaforins A, B, and C via Gold(I)-Catalyzed Carbocyclization
inferredcites →https://doi.org/10.1021/acs.orglett.1c01139openalex-snapshot
Stereodivergent Strategy in Structural Determination: Asymmetric Total Synthesis of Garcinol, Cambogin, and Related Analogues
inferredcites →https://doi.org/10.1021/acs.orglett.5b01121openalex-snapshot
Total Synthesis of (−)-Nemorosone and (+)-Secohyperforin
inferredcites →https://doi.org/10.1021/acs.orglett.9b00587openalex-snapshot
Direct Enantioselective and Regioselective Alkylation of β,γ-Unsaturated Carboxylic Acids with Chiral Lithium Amides as Traceless Auxiliaries
inferredcites →https://doi.org/10.1021/acs.orglett.9b03078openalex-snapshot
Me2AlSEt-Promoted Domino Dieckmann Cyclization Enables the Total Synthesis of Polycyclic Polyprenylated Acylphloroglucinols
inferredcites →https://doi.org/10.1021/acs.orglett.9b03095openalex-snapshot
Total Synthesis of Naphterpin and Marinone Natural Products
inferredcites →https://doi.org/10.1021/cr0500582openalex-snapshot
Polycyclic Polyprenylated Acylphloroglucinols
inferredcites →https://doi.org/10.1021/ja003360vopenalex-snapshot
Preparation of Cyclopropanediol: Novel [2 + 1] Cycloaddition Reaction of Bis(iodozincio)methane with 1,2-Diketones
inferredcites →https://doi.org/10.1021/ja00766a077openalex-snapshot
Metal reduction of malonates. Formation and isolation of 3,3-dimethyl-cis-1,2-cyclopropanediol
inferredcites →https://doi.org/10.1021/ja00783a034openalex-snapshot
Nuclear magnetic resonance enantiomer regents. Configurational correlations via nuclear magnetic resonance chemical shifts of diastereomeric mandelate, O-methylmandelate, and .alpha.-methoxy-.alpha.-trifluoromethylphenylacetate (MTPA) esters
inferredcites →https://doi.org/10.1021/ja036026iopenalex-snapshot
Biomimetic Synthesis of (±)-Pinnatal and (±)-Sterekunthal A
inferredcites →https://doi.org/10.1021/ja050092yopenalex-snapshot
Biomimetic Synthesis of Antimalarial Naphthoquinones
inferredcites →https://doi.org/10.1021/ja0762339openalex-snapshot
Rapid Access to Polyprenylated Phloroglucinols via Alkylative Dearomatization−Annulation: Total Synthesis of (±)-Clusianone
inferredcites →https://doi.org/10.1021/ja1057828openalex-snapshot
Catalytic Enantioselective Alkylative Dearomatization−Annulation: Total Synthesis and Absolute Configuration Assignment of Hyperibone K
inferredcites →https://doi.org/10.1021/ja205107xopenalex-snapshot
Highly Enantioselective Direct Alkylation of Arylacetic Acids with Chiral Lithium Amides as Traceless Auxiliaries
inferredcites →https://doi.org/10.1021/ja312150dopenalex-snapshot
Enantioselective Total Synthesis of Hyperforin
inferredcites →https://doi.org/10.1021/ja403076uopenalex-snapshot
Enediolate–Dilithium Amide Mixed Aggregates in the Enantioselective Alkylation of Arylacetic Acids: Structural Studies and a Stereochemical Model
inferredcites →https://doi.org/10.1021/ja500063aopenalex-snapshot
The Total Syntheses of Guttiferone A and 6-epi-Guttiferone A
inferredcites →https://doi.org/10.1021/jacs.0c09520openalex-snapshot
Total Synthesis of (−)-Mitrephorone A Enabled by Stereoselective Nitrile Oxide Cycloaddition and Tetrasubstituted Olefin Synthesis
inferredcites →https://doi.org/10.1021/jacs.5b12778openalex-snapshot
Asymmetric Syntheses of the Flavonoid Diels–Alder Natural Products Sanggenons C and O
inferredcites →https://doi.org/10.1021/jacs.6b09727openalex-snapshot
Syntheses of (+)-30-epi-, (−)-6-epi-, (±)-6,30-epi-13,14-Didehydroxyisogarcinol and (±)-6,30-epi-Garcimultiflorone A Utilizing Highly Diastereoselective, Lewis Acid-Controlled Cyclizations
inferredcites →https://doi.org/10.1021/jacs.9b04508openalex-snapshot
Total Synthesis of (+)-Granatumine A and Related Bislactone Limonoid Alkaloids via a Pyran to Pyridine Interconversion
inferredcites →https://doi.org/10.1021/jacs.9b05600openalex-snapshot
Regiodivergent Photocyclization of Dearomatized Acylphloroglucinols: Asymmetric Syntheses of (−)-Nemorosone and (−)-6-epi-Garcimultiflorone A
inferredcites →https://doi.org/10.1021/jf0490596openalex-snapshot
Instability of St. John's Wort (Hypericum perforatum L.) and Degradation of Hyperforin in Aqueous Solutions and Functional Beverage
inferredcites →https://doi.org/10.1021/jm0209782openalex-snapshot
Biosynthesis of Hyperforin in Hypericum perforatum
inferredcites →https://doi.org/10.1021/jo00195a056openalex-snapshot
Stereospecific synthesis of exo-trisubstituted olefins. The highly efficient synthesis of carbacyclins
inferredcites →https://doi.org/10.1021/jo300646jopenalex-snapshot
Stereoselective Total Synthesis of Nemorosone
inferredcites →https://doi.org/10.1021/jo500027kopenalex-snapshot
Biomimetic Total Synthesis of (±)-Doitunggarcinone A and (+)-Garcibracteatone
inferredcites →https://doi.org/10.1021/jo5026699openalex-snapshot
Enantioselective Approach to Polycyclic Polyprenylated Acylphloroglucinols via Catalytic Asymmetric Intramolecular Cyclopropanation
inferredcites →https://doi.org/10.1021/np000362kopenalex-snapshot
Three New Hyperforin Analogues from Hypericum perforatum
inferredcites →https://doi.org/10.1021/np0105681openalex-snapshot
Synthesis and Biological Evaluation of Hyperforin Analogues. Part I. Modification of the Enolized Cyclohexanedione Moiety
inferredcites →https://doi.org/10.1021/ol101380aopenalex-snapshot
Biomimetic Synthesis of Polycyclic Polyprenylated Acylphloroglucinol Natural Products Isolated from Hypericum papuanum
inferredcites →https://doi.org/10.1021/ol1022728openalex-snapshot
Development of a Strategy for the Asymmetric Synthesis of Polycyclic Polyprenylated Acylphloroglucinols via N-Amino Cyclic Carbamate Hydrazones: Application to the Total Synthesis of (+)-Clusianone
inferredcites →https://doi.org/10.1021/ol300386topenalex-snapshot
Total Synthesis of (±)-7-epi-Nemorosone
inferredcites →https://doi.org/10.1021/ol302524qopenalex-snapshot
Biomimetic Total Synthesis of (±)-Garcibracteatone
inferredcites →https://doi.org/10.1021/ol901781nopenalex-snapshot
A Short Biomimetic Approach to the Fully Functionalized Bicyclic Framework of Type A Acylphloroglucinols
inferredcites →https://doi.org/10.1023/a:1020990301927openalex-snapshot
Stereospecific 1,4-cis-hydrogenation of conjugated dienes, dienynes, and dienediynes catalyzed by chromium carbonyl complexes in stereocontrolled syntheses of physiologically active olefins
inferredcites →https://doi.org/10.1038/ja.2012.125openalex-snapshot
Stereoselective total synthesis of garsubellin A
inferredcites →https://doi.org/10.1038/nchem.1170openalex-snapshot
The total synthesis of hyperpapuanone, hyperibone L, epi-clusianone and oblongifolin A
inferredcites →https://doi.org/10.1038/s41467-020-14354-5openalex-snapshot
Programmable meroterpene synthesis
inferredcites →https://doi.org/10.1038/sj.leu.2404301openalex-snapshot
Hyperforin, a new lead compound against the progression of cancer and leukemia?
inferredcites →https://doi.org/10.1038/sj.onc.1205190openalex-snapshot
Inhibition of tumour cell growth by hyperforin, a novel anticancer drug from St. John's wort that acts by induction of apoptosis
inferredcites →https://doi.org/10.1039/b002343oopenalex-snapshot
Synthesis of (3S*,4R*,6E,10Z )-3,4,7,11-tetramethyltrideca-6,10-dienal (faranal) using stereospecific 1,4-cis-hydrogenation of conjugated double bonds
inferredcites →https://doi.org/10.1039/b914364popenalex-snapshot
Phloroglucinol compounds of natural origin: Synthetic aspects
inferredcites →https://doi.org/10.1039/c2cc37914gopenalex-snapshot
Adventures in bridgehead substitution chemistry: synthesis of polycyclic polyprenylated acylphloroglucinols (PPAPs)
inferredcites →https://doi.org/10.1039/c39870000656openalex-snapshot
Asymmetric synthesis using chiral bases: enantioselective α-alkylation of carboxylic acids
inferredcites →https://doi.org/10.1039/c39920000418openalex-snapshot
Photochemical reaction of β-hydroxyketones. Formation of cyclopropane-1,2-diols
inferredcites →https://doi.org/10.1055/s-0029-1219371openalex-snapshot
Synthesis of Nemorosone via a Difficult Bridgehead Substitution Reaction
inferredcites →https://doi.org/10.1055/s-0035-1561619openalex-snapshot
The Total Synthesis of Hyperforin
inferredcites →https://doi.org/10.1055/s-0036-1591528openalex-snapshot
An Atom-Economic and Stereospecific Access to Trisubstituted Olefins through Enyne Cross Metathesis Followed by 1,4-Hydrogenation
inferredcites →https://doi.org/10.1055/s-2000-6323openalex-snapshot
Regioselective Alkylation of Lithium Dienediolates of α,β-Unsaturated Carboxylic Acids
inferredcites →https://doi.org/10.1073/pnas.130155097openalex-snapshot
St. John's wort induces hepatic drug metabolism through activation of the pregnane X receptor
inferredcites →https://doi.org/10.1248/cpb.39.309openalex-snapshot
Stereocontrolled synthesis of exocyclic olefins using arene tricarbonyl chromium complex-catalyzed hydrogenation. I. Efficient synthesis of carbacyclin and its analogs.
inferredcites →https://doi.org/10.1248/cpb.45.2122openalex-snapshot
Enantioselective .ALPHA.-Alkylation of Phenylacetic Acid Using a Chiral Bidentate Lithium Amide as a Chiral Auxiliary.
inferredcites →https://doi.org/10.2174/157017808785982112openalex-snapshot
Photochemical Degradation of Hyperforin
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
inferred← citeshttps://doi.org/10.1016/j.phytochem.2022.113526zenodo-depositor-declared
Hyperforin: A natural lead compound with multiple pharmacological activities
inferred← citeshttps://doi.org/10.1002/ange.202203311openalex-snapshot
Intramolecular Tricarbonyl‐Ene Reactions and α‐Hydroxy‐β‐Diketone Rearrangements Inspired by the Biosynthesis of Polycyclic Polyprenylated Acylphloroglucinols
inferred← citeshttps://doi.org/10.1002/ange.8854855openalex-snapshot
NiH‐Catalyzed Enantioconvergent α ‐Alkenylation of Carbonyl Compounds via Markovnikov Alkyne Hydronickellation
inferred← citeshttps://doi.org/10.1002/anie.202203311openalex-snapshot
Intramolecular Tricarbonyl‐Ene Reactions and α‐Hydroxy‐β‐Diketone Rearrangements Inspired by the Biosynthesis of Polycyclic Polyprenylated Acylphloroglucinols
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c01836openalex-snapshot
The Total Synthesis of Hyperfirin via a Cyclooctadiene Strategy
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c00243openalex-snapshot
Transannular Acylation Facilitates C5–C9 Bond Formation in Hyperforin Total Synthesis
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