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Deprotonation of a Borohydride: Synthesis of a Carbene‐Stabilized Boryl Anion

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/ange.200501841openalex-snapshot
Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron‐Rich Ligands for Transition‐Metal Catalysts: A Quaternary Carbon Atom Makes the Difference
inferredcites →https://doi.org/10.1002/ange.200600987openalex-snapshot
CO Fixation to Stable Acyclic and Cyclic Alkyl Amino Carbenes: Stable Amino Ketenes with a Small HOMO–LUMO Gap
inferredcites →https://doi.org/10.1002/ange.200604119openalex-snapshot
A 9‐Borylated Acridinyl Radical
inferredcites →https://doi.org/10.1002/ange.200605083openalex-snapshot
Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs)
inferredcites →https://doi.org/10.1002/ange.200702299openalex-snapshot
Structural Changes Accompanying the Stepwise Population of a BC π Bond
inferredcites →https://doi.org/10.1002/ange.200702369openalex-snapshot
Boryl Anion Attacks Transition‐Metal Chlorides To Form Boryl Complexes: Syntheses, Spectroscopic, and Structural Studies on Group 11 Borylmetal Complexes
inferredcites →https://doi.org/10.1002/ange.200703518openalex-snapshot
Transition‐Metal Complexes Featuring Z‐Type Ligands: Agreement or Discrepancy between Geometry and d n Configuration?
inferredcites →https://doi.org/10.1002/ange.200705024openalex-snapshot
Metallaboratranes Derived from a Triphosphanyl–Borane: Intrinsic C 3 Symmetry Supported by a Z‐Type Ligand
inferredcites →https://doi.org/10.1002/ange.200801848openalex-snapshot
Ein linearer anionischer Dimetallborylenkomplex
inferredcites →https://doi.org/10.1002/ange.200904774openalex-snapshot
Ein dreikerniger Boridkomplex mit einer fluktuierenden Gold‐Bor‐Bindung
inferredcites →https://doi.org/10.1002/ange.200906884openalex-snapshot
Synthese und Struktur eines Carben‐stabilisierten π‐Boryl‐Anions
inferredcites →https://doi.org/10.1002/ange.201000165openalex-snapshot
Stabile cyclische Carbene und verwandte Spezies jenseits der Diaminocarbene
inferredcites →https://doi.org/10.1002/ange.201004215openalex-snapshot
Generation and Reactions of an Unsubstituted N‐Heterocyclic Carbene Boryl Anion
inferredcites →https://doi.org/10.1002/ange.201005667openalex-snapshot
Borylcyanocuprate in a One‐Pot Carboboration by a Sequential Reaction with an Electron‐Deficient Alkyne and an Organic Carbon Electrophile
inferredcites →https://doi.org/10.1002/ange.201005698openalex-snapshot
Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center
inferredcites →https://doi.org/10.1002/ange.201102717openalex-snapshot
Komplexe von N‐heterocyclischen Carbenen mit Boranen: Synthese und Reaktionen
inferredcites →https://doi.org/10.1002/ange.201105848openalex-snapshot
“Umpolung” von Bor im [B(CN)4]− Anion durch Reduktion zum Dianion [B(CN)3]2−
inferredcites →https://doi.org/10.1002/ange.201200954openalex-snapshot
Organoaluminium‐Boryl‐Komplexe
inferredcites →https://doi.org/10.1002/ange.201209109openalex-snapshot
31P NMR Chemical Shifts of Carbene–Phosphinidene Adducts as an Indicator of the π‐Accepting Properties of Carbenes
inferredcites →https://doi.org/10.1002/anie.200501841openalex-snapshot
Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron‐Rich Ligands for Transition‐Metal Catalysts: A Quaternary Carbon Atom Makes the Difference
inferredcites →https://doi.org/10.1002/anie.200600987openalex-snapshot
CO Fixation to Stable Acyclic and Cyclic Alkyl Amino Carbenes: Stable Amino Ketenes with a Small HOMO–LUMO Gap
inferredcites →https://doi.org/10.1002/anie.200604119openalex-snapshot
A 9‐Borylated Acridinyl Radical
inferredcites →https://doi.org/10.1002/anie.200605083openalex-snapshot
Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs)
inferredcites →https://doi.org/10.1002/anie.200702299openalex-snapshot
Structural Changes Accompanying the Stepwise Population of a BC π Bond
inferredcites →https://doi.org/10.1002/anie.200702369openalex-snapshot
Boryl Anion Attacks Transition‐Metal Chlorides To Form Boryl Complexes: Syntheses, Spectroscopic, and Structural Studies on Group 11 Borylmetal Complexes
inferredcites →https://doi.org/10.1002/anie.200703518openalex-snapshot
Transition‐Metal Complexes Featuring Z‐Type Ligands: Agreement or Discrepancy between Geometry and d n Configuration?
inferredcites →https://doi.org/10.1002/anie.200705024openalex-snapshot
Metallaboratranes Derived from a Triphosphanyl–Borane: Intrinsic C 3 Symmetry Supported by a Z‐Type Ligand
inferredcites →https://doi.org/10.1002/anie.200801848openalex-snapshot
A Linear, Anionic Dimetalloborylene Complex
inferredcites →https://doi.org/10.1002/anie.200904774openalex-snapshot
A Trimetallic Gold Boride Complex with a Fluxional Gold–Boron Bond
inferredcites →https://doi.org/10.1002/anie.200906884openalex-snapshot
Synthesis and Structure of a Carbene‐Stabilized π‐Boryl Anion
inferredcites →https://doi.org/10.1002/anie.201000165openalex-snapshot
Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes
inferredcites →https://doi.org/10.1002/anie.201004215openalex-snapshot
Generation and Reactions of an Unsubstituted N‐Heterocyclic Carbene Boryl Anion
inferredcites →https://doi.org/10.1002/anie.201005667openalex-snapshot
Borylcyanocuprate in a One‐Pot Carboboration by a Sequential Reaction with an Electron‐Deficient Alkyne and an Organic Carbon Electrophile
inferredcites →https://doi.org/10.1002/anie.201005698openalex-snapshot
Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center
inferredcites →https://doi.org/10.1002/anie.201102717openalex-snapshot
Synthesis and Reactions of N‐Heterocyclic Carbene Boranes
inferredcites →https://doi.org/10.1002/anie.201105848openalex-snapshot
“Umpolung” at Boron by Reduction of [B(CN)4]− and Formation of the Dianion [B(CN)3]2−
inferredcites →https://doi.org/10.1002/anie.201200954openalex-snapshot
Organoaluminum Boryl Complexes
inferredcites →https://doi.org/10.1002/anie.201209109openalex-snapshot
31P NMR Chemical Shifts of Carbene–Phosphinidene Adducts as an Indicator of the π‐Accepting Properties of Carbenes
inferredcites →https://doi.org/10.1002/ejic.201200812openalex-snapshot
Modern 1,3,2‐Diazaborole Chemistry – A Metamorphosis from Electrophilic to Nucleophilic Boron
inferredcites →https://doi.org/10.1002/ejoc.201100373openalex-snapshot
One‐Pot Carboboration of Alkynes Using Lithium Borylcyanocuprate and the Subsequent Suzuki–Miyaura Cross‐Coupling of the Resulting Tetrasubstituted Alkenylborane
inferredcites →https://doi.org/10.1021/ic200533eopenalex-snapshot
NHC-Stabilized 1-Hydro-1H-borole and Its Nondegenerate Sigmatropic Isomers
inferredcites →https://doi.org/10.1021/ja00242a064openalex-snapshot
Isolation and x-ray crystal structure of the boron methylidenide ion [Mes2BCH2]- (Mes = 2,4,6-Me3C6H2): a boron-carbon double bonded alkene analog
inferredcites →https://doi.org/10.1021/ja0637494openalex-snapshot
On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligands o -R 2 P(Ph)BR‘ 2
inferredcites →https://doi.org/10.1021/ja107025yopenalex-snapshot
Substitution Reactions at Tetracoordinate Boron: Synthesis of N-Heterocyclic Carbene Boranes with Boron−Heteroatom Bonds
inferredcites →https://doi.org/10.1021/ja310895wopenalex-snapshot
Ditopic Ambiphilicity of an Anionic Dimetalloborylene Complex
inferredcites →https://doi.org/10.1021/ja905950gopenalex-snapshot
Group-4 Transition-Metal Boryl Complexes: Syntheses, Structures, Boron−Metal Bonding Properties, and Application as a Polymerization Catalyst
inferredcites →https://doi.org/10.1021/om200115yopenalex-snapshot
Mechanisms of Reactions of a Lithium Boryl with Organohalides
inferredcites →https://doi.org/10.1021/om200650xopenalex-snapshot
A Brief Survey of Our Contribution to Stable Carbene Chemistry
inferredcites →https://doi.org/10.1039/c2cs15291fopenalex-snapshot
Trivalent boron nucleophile as a new tool in organic synthesis: reactivity and asymmetric induction
inferredcites →https://doi.org/10.1126/science.1131914openalex-snapshot
Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion
inferredcites →https://doi.org/10.1126/science.1141474openalex-snapshot
Facile Splitting of Hydrogen and Ammonia by Nucleophilic Activation at a Single Carbon Center
inferredcites →https://doi.org/10.1126/science.1207573openalex-snapshot
Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines
inferredcites →https://doi.org/10.1246/bcsj.20110123openalex-snapshot
Creation of Nucleophilic Boryl Anions and Their Properties
inferredcites →https://doi.org/10.1351/pac-con-11-10-06openalex-snapshot
Nucleophilic boron strikes back
inferredcites →https://doi.org/10.5059/yukigoseikyokaishi.68.359openalex-snapshot
Boryl Anion: Syntheses and Properties of Novel Borylmetals

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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A New Type Medicine Candidate Utilizing Silver(I)-Nhc Complexes and in Vitro Their Antibacterial Properties
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The Chemistry of Multibonded Organoboron Compounds
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Carbenes and Nitrenes
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Chemistry of Boryl Anions
inferred← citeshttps://doi.org/10.1002/ange.201402175openalex-snapshot
Zur Brønsted‐Basizität von Diaminoboryl‐Anionen: Reaktivität gegenüber methylierten Benzolverbindungen und Wasserstoff
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Isolierung eines neutralen, Bor‐haltigen Radikals, stabilisiert durch ein cyclisches (Alkyl)(amino)carben
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Diborabutatrien: ein elektronenarmes Cumulen
inferred← citeshttps://doi.org/10.1002/ange.201405201openalex-snapshot
Isolation of a Bis(oxazol‐2‐ylidene)–Phenylborylene Adduct and its Reactivity as a Boron‐Centered Nucleophile
inferred← citeshttps://doi.org/10.1002/ange.201409513openalex-snapshot
Bor als überaus starkes Reduktionsmittel: Synthese eines Bor‐ zentrierten Radikalanionen‐Radikalkationen‐Paares
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A Phosphine‐Coordinated Boron‐Centered Gomberg‐Type Radical
inferred← citeshttps://doi.org/10.1002/ange.201509289openalex-snapshot
Dative Wechselwirkungen einer Bor‐zentrierten Lewis‐Base mit Gruppe‐13‐Elementen
inferred← citeshttps://doi.org/10.1002/ange.201605645openalex-snapshot
Spontaneous Reduction of a Hydroborane To Generate a B−B Single Bond by the Use of a Lewis Pair
inferred← citeshttps://doi.org/10.1002/ange.201605838openalex-snapshot
Phosphan‐stabilisierte Borylene und Boryl‐Anionen als Liganden? Redoxaktivität in Bor‐basierten Pinzetten‐Komplexen
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Erzeugung zweifach koordinierter Bor(I)‐Einheiten durch Fragmentierung eines molekularen Tetra‐Bor(I)‐Quadrats
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Synthese und Reaktivität von Verbindungen mit elektronenpräzisen B‐B‐Einfach‐ und B‐B‐Mehrfachbindungen
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Deprotonierung eines Hydridoborat‐Anions
inferred← citeshttps://doi.org/10.1002/ange.201700721openalex-snapshot
Eine Geschichte über zwei Elemente: die Umpolung der Lewis‐Acidität/Basizität von Bor und Phosphor
inferred← citeshttps://doi.org/10.1002/ange.201702148openalex-snapshot
Cyclische Alkylaminocarbene (CAACs): Neues von guten Bekannten
inferred← citeshttps://doi.org/10.1002/ange.201702393openalex-snapshot
Deprotonation of a Seemingly Hydridic Diborane(6) To Build a B−B Bond
inferred← citeshttps://doi.org/10.1002/ange.201703235openalex-snapshot
A Molecular Boroauride: A Donor–Acceptor Complex of Anionic Gold
inferred← citeshttps://doi.org/10.1002/ange.201705153openalex-snapshot
Borylene: eine aufstrebende Verbindungsklasse
inferred← citeshttps://doi.org/10.1002/ange.201705561openalex-snapshot
Vom Boran zum Borylen ohne Reduktion: ambiphiles Verhalten einer monovalenten Silylisonitril‐Borverbindung
inferred← citeshttps://doi.org/10.1002/ange.201809733openalex-snapshot
Boranchemie aus einer neuen Perspektive: Nukleophilie der B‐H‐Bindungselektronen
inferred← citeshttps://doi.org/10.1002/ange.201809983openalex-snapshot
Einfacher Zugang zum ersten stabilen {BH2}− Dihydroborylanion
inferred← citeshttps://doi.org/10.1002/ange.201914219openalex-snapshot
The 9H‐9‐Borafluorene Dianion: A Surrogate for Elusive Diarylboryl Anion Nucleophiles
inferred← citeshttps://doi.org/10.1002/ange.201915618openalex-snapshot
Ein elektronenreiches cyclisches (Alkyl)(amino)carben auf Au(111)‐, Ag(111)‐ und Cu(111)‐Oberflächen
inferred← citeshttps://doi.org/10.1002/ange.202100919openalex-snapshot
Group 11 Borataalkene Complexes: Models for Alkene Activation
inferred← citeshttps://doi.org/10.1002/ange.202202516openalex-snapshot
Isolation of Stable Borepin Radicals and Anions
inferred← citeshttps://doi.org/10.1002/ange.202202882openalex-snapshot
Dismutation von Tricyanoborblei‐Verbindungen: Das homoleptische Tetrakis(tricyanoboryl)plumbat‐Tetraanion
inferred← citeshttps://doi.org/10.1002/ange.202401681openalex-snapshot
Lewis‐Säure‐dekorierte Hexacyanodiboran(6)‐Dianionen
inferred← citeshttps://doi.org/10.1002/ange.202411099openalex-snapshot
Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO2 Hydrogenation
inferred← citeshttps://doi.org/10.1002/ange.202504316openalex-snapshot
Einfacher Zugang zu chelatbildenden CAArC‐Phosphin (CAArCPhos)‐Palladiumkomplexen
inferred← citeshttps://doi.org/10.1002/ange.202518214openalex-snapshot
Anionic Iminoborane as Boryl Anion Synthon
inferred← citeshttps://doi.org/10.1002/anie.201402175openalex-snapshot
Assessing the Brønsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen
inferred← citeshttps://doi.org/10.1002/anie.201403514openalex-snapshot
Isolation of a Neutral Boron‐Containing Radical Stabilized by a Cyclic (Alkyl)(Amino)Carbene
inferred← citeshttps://doi.org/10.1002/anie.201403888openalex-snapshot
Diborabutatriene: An Electron‐Deficient Cumulene
inferred← citeshttps://doi.org/10.1002/anie.201405201openalex-snapshot
Isolation of a Bis(oxazol‐2‐ylidene)–Phenylborylene Adduct and its Reactivity as a Boron‐Centered Nucleophile
inferred← citeshttps://doi.org/10.1002/anie.201409513openalex-snapshot
Boron as a Powerful Reductant: Synthesis of a Stable Boron‐Centered Radical‐Anion Radical‐Cation Pair
inferred← citeshttps://doi.org/10.1002/anie.201504502openalex-snapshot
A Phosphine‐Coordinated Boron‐Centered Gomberg‐Type Radical
inferred← citeshttps://doi.org/10.1002/anie.201509289openalex-snapshot
Dative Bonding between Group 13 Elements Using a Boron‐Centered Lewis Base
inferred← citeshttps://doi.org/10.1002/anie.201605645openalex-snapshot
Spontaneous Reduction of a Hydroborane To Generate a B−B Single Bond by the Use of a Lewis Pair
inferred← citeshttps://doi.org/10.1002/anie.201605838openalex-snapshot
Phosphine‐Stabilized Borylenes and Boryl Anions as Ligands? Redox Reactivity in Boron‐Based Pincer Complexes
inferred← citeshttps://doi.org/10.1002/anie.201608429openalex-snapshot
Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra‐Boron(I) Molecular Square
inferred← citeshttps://doi.org/10.1002/anie.201610072openalex-snapshot
Formation and Reactivity of Electron‐Precise B−B Single and Multiple Bonds
inferred← citeshttps://doi.org/10.1002/anie.201611899openalex-snapshot
Deprotonation of a Hydridoborate Anion
inferred← citeshttps://doi.org/10.1002/anie.201700721openalex-snapshot
A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and Phosphorus
inferred← citeshttps://doi.org/10.1002/anie.201702148openalex-snapshot
Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments
inferred← citeshttps://doi.org/10.1002/anie.201702393openalex-snapshot
Deprotonation of a Seemingly Hydridic Diborane(6) To Build a B−B Bond
inferred← citeshttps://doi.org/10.1002/anie.201703235openalex-snapshot
A Molecular Boroauride: A Donor–Acceptor Complex of Anionic Gold
inferred← citeshttps://doi.org/10.1002/anie.201705153openalex-snapshot
Borylenes: An Emerging Class of Compounds
inferred← citeshttps://doi.org/10.1002/anie.201705561openalex-snapshot
From Borane to Borylene without Reduction: Ambiphilic Behavior of a Monovalent Silylisonitrile Boron Species
inferred← citeshttps://doi.org/10.1002/anie.201809733openalex-snapshot
A New Perspective on Borane Chemistry: The Nucleophilicity of the B−H Bonding Pair Electrons
inferred← citeshttps://doi.org/10.1002/anie.201809983openalex-snapshot
Facile Synthesis of a Stable Dihydroboryl {BH2}− Anion
inferred← citeshttps://doi.org/10.1002/anie.201914219openalex-snapshot
The 9H‐9‐Borafluorene Dianion: A Surrogate for Elusive Diarylboryl Anion Nucleophiles
inferred← citeshttps://doi.org/10.1002/anie.201915618openalex-snapshot
An Electron‐Rich Cyclic (Alkyl)(Amino)Carbene on Au(111), Ag(111), and Cu(111) Surfaces
inferred← citeshttps://doi.org/10.1002/anie.202100919openalex-snapshot
Group 11 Borataalkene Complexes: Models for Alkene Activation
inferred← citeshttps://doi.org/10.1002/anie.202202516openalex-snapshot
Isolation of Stable Borepin Radicals and Anions
inferred← citeshttps://doi.org/10.1002/anie.202202882openalex-snapshot
Dismutation of Tricyanoboryllead Compounds: The Homoleptic Tetrakis(tricyanoboryl)plumbate Tetraanion
inferred← citeshttps://doi.org/10.1002/anie.202401681openalex-snapshot
Lewis Acid Decorated Hexacyanodiborane(6) Dianion
inferred← citeshttps://doi.org/10.1002/anie.202411099openalex-snapshot
Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO 2 Hydrogenation
inferred← citeshttps://doi.org/10.1002/anie.202504316openalex-snapshot
Facile Access to Chelating CAArC‐Phosphine (CAArCPhos) Palladium Complexes
inferred← citeshttps://doi.org/10.1002/anie.202518214openalex-snapshot
Anionic Iminoborane as Boryl Anion Synthon
inferred← citeshttps://doi.org/10.1002/anie.2903979openalex-snapshot
Bisphosphane‐Stabilized Borylenes: Unlocking Borylene Transfer Reactivities
inferred← citeshttps://doi.org/10.1002/anie.7517492openalex-snapshot
Mild Generation of Highly Nucleophilic N ‐Heterocyclic Carbene Boryl Anion From Neutral sp 2 –sp 3 Diboron Reagents and Its Applications in Nucleophilic Borylation
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Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes
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Redox‐Active Frustrated Lewis Pair‐Mediated B─H Bond Activation: From Proton Transfer to THF Ring Opening
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A DFT Study on the Stabilization of the B≡B Triple Bond in a Metallaborocycle: Contrasting Electronic Structures of Boron and Carbon Analogues
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Umpolung at Boron: Ancillary‐Ligand‐Induced Formation of Boron‐Based Donor Ligands from Phosphine‐Boranes
inferred← citeshttps://doi.org/10.1002/chem.201803139openalex-snapshot
Coordination of Asymmetric Diborenes towards Cationic Coinage Metals (Au, Ag, Cu)
inferred← citeshttps://doi.org/10.1002/chem.201804599openalex-snapshot
B–B Coupling and B–B Catenation: Computational Study of the Structure and Reactions of Metal–Bis(borylene) Complexes
inferred← citeshttps://doi.org/10.1002/chem.202101025openalex-snapshot
Boron‐ versus Nitrogen‐Centered Nucleophilic Reactivity of (Cyano)hydroboryl Anions: Synthesis of Cyano(hydro)organoboranes and 2‐Aza‐1,4‐diborabutatrienes
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Electron‐Precise Dicationic Tetraboranes: Syntheses, Structures and Rearrangement to an Alkylidene Borate‐Borenium Zwitterion and a 1,3‐Azaborinine
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Persistent and Predominantly Localized Boron Radical from the Reduction of a Three‐Dimensional Analogue of NHC‐Stabilized Borafluorenium
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Unprecedented Borylene Insertion into a C–N Bond
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Formation of a Carbene–Phosphinidene Adduct by NHC‐Induced P–P Bond Cleavage in Sodium Tetramesityltetraphosphanediide
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Titanium Imido Complexes by Displacement of –SiMe3 and C–H Bond Activation in a TiIII Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC)
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1,3,2‐Diazaborolyl Anions – From Laboratory Curiosities to Versatile Reagents in Synthesis
inferred← citeshttps://doi.org/10.1002/ejic.201800031openalex-snapshot
Nucleophilic Neutral Diborane(4) Compounds with sp3–sp3‐Hybridized Boron Atoms
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Cyanoborates
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Anionic Organoboranes: Delicate Flowers Worth Caring for
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Anorganische Chemie 2013
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Boryl Anions
inferred← citeshttps://doi.org/10.1007/978-3-319-18690-0_4openalex-snapshot
Gold: Migratory Insertion at Au(I)
inferred← citeshttps://doi.org/10.1016/b978-0-12-409547-2.14913-3openalex-snapshot
Boroles
inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00023-8openalex-snapshot
Boron Complexes in Organic Synthesis
inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00125-6openalex-snapshot
Recent Development in the Solution-State Chemistry of Boranes and Diboranes
inferred← citeshttps://doi.org/10.1016/b978-0-443-31482-7.00011-4openalex-snapshot
Doubly Bonded Metalloid Functions, R1C(X)=SiR22, R1C(X)=BR2, R1C(X)=GeR22
inferred← citeshttps://doi.org/10.1016/bs.adomc.2022.03.003openalex-snapshot
Cyclic (alkyl)(amino)carbene (CAAC) ligands: Electronic structure and application as chemically- and redox-non-innocent ligands and chromophores
inferred← citeshttps://doi.org/10.1016/j.cclet.2021.12.016openalex-snapshot
Recent advances on carborane-based ligands in low-valent group 13 and group 14 elements chemistry
inferred← citeshttps://doi.org/10.1016/j.ccr.2022.214837openalex-snapshot
Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms
inferred← citeshttps://doi.org/10.1016/j.poly.2021.115049openalex-snapshot
The flourishing chemistry of carbene stabilized compounds of group 13 and 14 elements
inferred← citeshttps://doi.org/10.1016/j.tet.2023.133469openalex-snapshot
The multiple bond character of the carbon−boron bond in boron trapped N-heterocyclic carbenes (NHCs) and cyclic(alkyl)(amino)carbenes (CAACs) on the magnetic criterion
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00079openalex-snapshot
NHCs in Main Group Chemistry
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00791openalex-snapshot
N-Heterocyclic Carbene Adducts of Main Group Elements and Their Use as Ligands in Transition Metal Chemistry
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c00785openalex-snapshot
Synthesis and Coordination of a Bisphosphine-[NHC-borane] Compound: A Ligand Framework for Bimetallic Structure Featuring a Boron-Bridging Moiety
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6b02336openalex-snapshot
Cp*-Substituted Boron Cations: The Effect of NHC, NHO, and CAAC Ligands
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6b02993openalex-snapshot
Formation of Boron–Main-Group Element Bonds by Reactions with a Tricoordinate Organoboron L2PhB: (L = Oxazol-2-ylidene)
inferred← citeshttps://doi.org/10.1021/acs.organomet.6b00792openalex-snapshot
Controlled cis Labilization of CO from Manganese(I) Mixed Carbonyl/Isocyanide Complexes: An Entry Point to Coordinatively Unsaturated Metallo-Lewis Acids
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00408openalex-snapshot
Magnesium-Mediated Nucleophilic Borylation of Carbonyl Electrophiles
inferred← citeshttps://doi.org/10.1021/acs.organomet.9b00317openalex-snapshot
Extending the Library of Boron Bases: A Contribution from Theory
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b01101openalex-snapshot
Synthesis and Suzuki Reactions of N-Heterocyclic Carbene Difluoro(aryl)-boranes
inferred← citeshttps://doi.org/10.1021/acscatal.9b00882openalex-snapshot
Redox-Active, Boron-Based Ligands in Iron Complexes with Inverted Hydride Reactivity in Dehydrogenation Catalysis
inferred← citeshttps://doi.org/10.1021/ar5003494openalex-snapshot
Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise
inferred← citeshttps://doi.org/10.1021/ja4120852openalex-snapshot
The Elusive Three-Coordinate Dicationic Hydrido Boron Complex
inferred← citeshttps://doi.org/10.1021/ja502521bopenalex-snapshot
Isolation of Neutral Mononuclear Copper Complexes Stabilized by Two Cyclic (Alkyl)(amino)carbenes
inferred← citeshttps://doi.org/10.1021/ja508887sopenalex-snapshot
Coinage Metals Binding as Main Group Elements: Structure and Bonding of the Carbene Complexes [TM(cAAC)2] and [TM(cAAC)2]+(TM = Cu, Ag, Au)
inferred← citeshttps://doi.org/10.1021/jacs.1c06152openalex-snapshot
Boraiminolithium: An Iminoborane-Transfer Reagent
inferred← citeshttps://doi.org/10.1021/jacs.4c01934openalex-snapshot
Cyclic (Alkyl)(Amino)Carbene-Iminoboryl Compounds with Three Formal Oxidation States
inferred← citeshttps://doi.org/10.1021/jacs.5b04677openalex-snapshot
Radical Reactions of N-Heterocyclic Carbene Boranes with Organic Nitriles: Cyanation of NHC-Boranes and Reductive Decyanation of Malononitriles
inferred← citeshttps://doi.org/10.1021/jacs.5c00974openalex-snapshot
Copper-Catalyzed C–B(sp3) Bond Formation through the Intermediacy of Cu–B(sp3) Complex
inferred← citeshttps://doi.org/10.1021/jacs.5c05883openalex-snapshot
Unlocking the Ambiphilicity of the Boryl Anion: Synthesis and Reactivity of an Anionic Diazoborane
inferred← citeshttps://doi.org/10.1021/jacs.5c19343openalex-snapshot
Boryl Homolytic Aromatic Substitution Enables Radical Borylation via Inverted B–H Polarity of Hydroborane
inferred← citeshttps://doi.org/10.1021/jacs.6b03432openalex-snapshot
Isolation of 1,2,4,3-Triazaborol-3-yl-metal (Li, Mg, Al, Au, Zn, Sb, Bi) Derivatives and Reactivity toward CO and Isonitriles
inferred← citeshttps://doi.org/10.1021/jacs.8b06141openalex-snapshot
Alkyl Isosteres
inferred← citeshttps://doi.org/10.1021/jacs.9b02598openalex-snapshot
Quantifying the Donor Strength of Ligand-Stabilized Main Group Fragments
inferred← citeshttps://doi.org/10.1021/jacs.9b07991openalex-snapshot
Single and Double Hydroboration of B–B Triple Bonds and Convergent Routes to a Cationic Tetraborane
inferred← citeshttps://doi.org/10.1038/nature13384openalex-snapshot
An overview of N-heterocyclic carbenes
inferred← citeshttps://doi.org/10.1038/ncomms15022openalex-snapshot
Easy access to nucleophilic boron through diborane to magnesium boryl metathesis
inferred← citeshttps://doi.org/10.1038/s41467-025-64017-6openalex-snapshot
Synthesis, reactivity and nucleophilicity of carboranyl-B-Mg compound
inferred← citeshttps://doi.org/10.1038/s41557-019-0365-zopenalex-snapshot
An alkyl-substituted aluminium anion with strong basicity and nucleophilicity
inferred← citeshttps://doi.org/10.1038/s41565-026-02150-zopenalex-snapshot
Room-temperature hydrogen storage of boron nanoclusters
inferred← citeshttps://doi.org/10.1039/c4cc03497jopenalex-snapshot
An efficient synthetic route to stable bis(carbene)borylenes [(L 1 )(L 2 )BH]
inferred← citeshttps://doi.org/10.1039/c5dt02237aopenalex-snapshot
Mono- and di-cationic hydrido boron compounds
inferred← citeshttps://doi.org/10.1039/c5sc00404gopenalex-snapshot
Diverse reactivity of a tricoordinate organoboron L 2 PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors
inferred← citeshttps://doi.org/10.1039/c5sc01077bopenalex-snapshot
Generation of 1,2-azaboretidines via reduction of ADC borane adducts
inferred← citeshttps://doi.org/10.1039/c7cc02335aopenalex-snapshot
Donor ligands based on tricoordinate boron formed by B–H-activation of bis(phosphine)boronium salts
inferred← citeshttps://doi.org/10.1039/c7cc07616aopenalex-snapshot
A snapshot of inorganic Janovsky complex analogues featuring a nucleophilic boron center
inferred← citeshttps://doi.org/10.1039/c7sc02238gopenalex-snapshot
Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC–B(CN) 2 −
inferred← citeshttps://doi.org/10.1039/c7sc02249bopenalex-snapshot
Borylation of fluorinated arenes using the boron-centred nucleophile B(CN) 3 2− – a unique entry to aryltricyanoborates
inferred← citeshttps://doi.org/10.1039/c7sc03193aopenalex-snapshot
Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor
inferred← citeshttps://doi.org/10.1039/c7sc04789dopenalex-snapshot
Closely related yet different: a borylene and its dimer are non-interconvertible but connected through reactivity
inferred← citeshttps://doi.org/10.1039/c8cc01331dopenalex-snapshot
An umpolung of Lewis acidity/basicity at nitrogen by deprotonation of a cyclic (amino)(aryl)nitrenium cation
inferred← citeshttps://doi.org/10.1039/c8cc01580eopenalex-snapshot
Direct access to a cAAC-supported dihydrodiborene and its dianion
inferred← citeshttps://doi.org/10.1039/c8cc03433hopenalex-snapshot
Selective one- and two-electron reductions of a haloborane enabled by a π-withdrawing carbene ligand
inferred← citeshttps://doi.org/10.1039/c8cc05013aopenalex-snapshot
Reversible 1,1-hydroaluminations and C–H activation in reactions of a cyclic (alkyl)(amino) carbene with alane
inferred← citeshttps://doi.org/10.1039/c8dt01451eopenalex-snapshot
Diborane heterolysis: breaking and making B–B bonds at magnesium
inferred← citeshttps://doi.org/10.1039/c8sc00743hopenalex-snapshot
A redox-active diborane platform performs C(sp 3 )–H activation and nucleophilic substitution reactions
inferred← citeshttps://doi.org/10.1039/c9sc01039dopenalex-snapshot
Synthesis and reduction chemistry of mixed-Lewis-base-stabilised chloroborylenes
inferred← citeshttps://doi.org/10.1039/c9sc02087jopenalex-snapshot
Snapshots of magnesium-centred diborane heterolysis by an outer sphere S N 2 process
inferred← citeshttps://doi.org/10.1039/c9sc05026dopenalex-snapshot
Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
inferred← citeshttps://doi.org/10.1039/d0sc04826gopenalex-snapshot
Phosphinoborylenes as stable sources of fleeting borylenes
inferred← citeshttps://doi.org/10.1039/d1cc04729aopenalex-snapshot
Advances in silylation and borylation of fluoroarenes and gem -difluoroalkenes via C–F bond cleavage
inferred← citeshttps://doi.org/10.1039/d2sc02244copenalex-snapshot
From a Möbius-aromatic interlocked Mn 2 B 10 H 10 wheel to the metal-doped boranaphthalenes M 2 @B 10 H 8 and M 2 B 5 2D-sheets (M = Mn and Fe): a molecules to materials continuum using DFT studies
inferred← citeshttps://doi.org/10.1039/d3cs00730hopenalex-snapshot
Borataalkenes, boraalkenes, and the η 2 -B,C coordination mode in coordination chemistry and catalysis
inferred← citeshttps://doi.org/10.1039/d3qo00796kopenalex-snapshot
The BC bond: some recent developments
inferred← citeshttps://doi.org/10.1039/d3tc00681fopenalex-snapshot
Influence of the defect density on the ordering of an NHC monolayer on a silicon surface
inferred← citeshttps://doi.org/10.1039/d4dt02997fopenalex-snapshot
Evidence of boride–borylene ligand-tautomerism leading to a remote C–C-bond and concomitant boryl ligand formation
inferred← citeshttps://doi.org/10.1039/d5sc00047eopenalex-snapshot
An N -phosphinoamidinato borasilenide: a vinyl-analogous anion containing a base-stabilised BSi double bond
inferred← citeshttps://doi.org/10.1039/d5sc01996fopenalex-snapshot
Synthesis and reactivity of a parent phosphathioethynolato-borane and a boraarsaketene
inferred← citeshttps://doi.org/10.1055/a-1405-7012openalex-snapshot
Perspective on Organoboron Chemistry
inferred← citeshttps://doi.org/10.1055/sos-sd-101-00511openalex-snapshot
6.1.42 Product Subclass 42: N-Heterocyclic Carbene Borane Complexes
inferred← citeshttps://doi.org/10.3390/inorganics7050061openalex-snapshot
Comparing the Acidity of (R3P)2BH-Based Donor Groups in Iridium Pincer Complexes
inferred← citeshttps://doi.org/10.5560/znb.2013-3202openalex-snapshot
Synthesis of a Tri(gold)boride Complex (Cy3P)B[AuP(o-Tol)3]3
inferred← citeshttps://doi.org/10.70675/c6bb6d89zaaf6z4defzb847zcaacfa6a4099openalex-snapshot
NHC-Boranes : amorceurs de photopolymérisation en émulsion et nouveaux matériaux énergétiques
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