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The Effect of a Hydroxy Protecting Group on the PtCl2-Catalyzed Cyclization of Dienynes—A Novel, Efficient, and Selective Synthesis of Carbocycles Acknowledgement is made to the EU for the COST D12 Action “Cascade Free Radical Reactions” and for a short-term scientific mission to Madrid (EM). We…
The Effect of a Hydroxy Protecting Group on the PtCl2-Catalyzed Cyclization of Dienynes—A Novel, Efficient, and Selective Synthesis of Carbocycles Acknowledgement is made to the EU for the COST D12 Action “Cascade Free Radical Reactions” and for a short-term scientific mission to Madrid (EM). We…
Novel Ruthenium‐ and Platinum‐Catalyzed Sequential Reactions: Synthesis of Tri‐ and Tetrasubstituted Furans and Pyrroles from Propargylic Alcohols and Ketones
Novel Ruthenium‐ and Platinum‐Catalyzed Sequential Reactions: Synthesis of Tri‐ and Tetrasubstituted Furans and Pyrroles from Propargylic Alcohols and Ketones
Reaction of Enol Ethers with Alkynes Catalyzed by Transition Metals: 5exo‐dig versus 6endo‐dig Cyclizations via Cyclopropyl Platinum or Gold Carbene Complexes
ChemInform Abstract: PHOTOCYCLIZATION OF 1,2‐DIARYLETHYLENES IN PRIMARY AMINES. A CONVENIENT METHOD FOR THE SYNTHESIS OF DIHYDRO AROMATIC COMPOUNDS AND A MEANS OF REDUCING TH LOSS OF METHYL GROUPS DURING THE CYCLIZATION OF O‐METHYLSTILBENES
Chromium- and Tungsten-Triggered Valence Isomerism of cis-1-Acyl-2-ethynylcyclopropanes via [3,3]Sigmatropy of (2-Acylcyclopropyl)vinylidene−Metal Intermediates
Ruthenium-Catalyzed Aromatization of Aromatic Enynes via the 1,2-Migration of Halo and Aryl Groups: A New Process Involving Electrocyclization and Skeletal Rearrangement
Platinum- and Acid-Catalyzed Enyne Metathesis Reactions: Mechanistic Studies and Applications to the Syntheses of Streptorubin B and Metacycloprodigiosin
Construction of Novel Polycyclic Ring Systems by Transition-Metal-Catalyzed Cycloisomerization of Ene−Ene−Ynes. Interception of a Carbenoid Intermediate in Skeletal Reorganization of Enynes
Ru(II)- and Pt(II)-Catalyzed Cycloisomerization of ω-Aryl-1-alkynes. Generation of Carbocationic Species from Alkynes and Transition Metal Halides and Its Interception by an Aromatic Ring
Selective Cross-Coupling of 2-Naphthol and 2-Naphthylamine Derivatives. A Facile Synthesis of 2,2',3-Trisubstituted and 2,2',3,3'-Tetrasubstituted 1,1'-Binaphthyls
Chiral cooperativity: the nature of the diastereoselective and enantioselective step in the gold(I)-catalyzed aldol reaction utilizing chiral ferrocenylamine ligands
Photocyclization of 1,2-diarylethylenes in primary amines. A convenient method for the synthesis of dihydro aromatic compounds and a means of reducing the loss of methyl groups during the cyclization of o-methylstilbenes
Synthesis of Dihydrodiol Metabolites Implicated in the Mechanism of Carcinogenesis of Phenanthro[4,3-b][1]benzothiophene and Phenanthro[3,4-b][1]benzothiophene, the Polycyclic Sulfur Heterocycles with a “Fjord” Structure
Formation of 4-Methylphenanthrenes in Palladium-Catalyzed Annulation of Diethyl 2,2‘-Diiodo-4,4‘-biphenyldicarboxylate with Internal Alkynes, Using Methyl Nitrobenzoates as the Methylating Agent
Platinum(II)-Catalyzed Reaction of 2-Alkynylbenzoates or Benzothioates with Vinyl Ethers: A Concise Method for Synthesis of 1-Acyl-4-alkoxy- or 1-Acyl-4-alkylsulfanylnaphthalene Derivatives
Acetylenes and noble metal compounds. Part XI. Reactions of di-methyl acetylenedicarboxylate with dibenzylideneacetone–palladium and –platinum complexes: pallada- and platina-cyclopentadienes
Gold‐ and Silver‐Catalyzed Intramolecular Hydroamination of Terminal Alkynes: Water‐Triggered Chemo‐ and Regioselective Synthesis of Fused Tricyclic Xanthines
Platinum(IV)‐Catalyzed Regioselective Synthesis of Highly Substituted 4H‐Cyclopenta[b]furans via Cascade Hetero‐ cyclization of 2‐(1‐Alkynyl)‐3‐aryl‐2‐propenals with Arylethenes
Indium(III)‐Catalyzed Cyclization of Aromatic 5‐Enynamides: Facile Synthesis of 2‐Aminonaphthalenes, 2‐Amino‐1 H ‐indenes, and 2,3‐Dihydro‐1 H ‐indeno[2,1‐ b ]pyridines
Iron‐Promoted Tandem Cyclization of 1,3‐Diynyl Chalcogen Derivatives with Diorganyl Dichalcogenides for the Synthesis of Benzo[b]furan‐Fused Selenophenes
Ruthenium(II)‐Catalyzed Synthesis of Indolo[2,1‐a]isoquinolines through Double Oxidative Annulation Reaction of Phenyl Isocyanates with Di(hetero)aryl Alkynes
Palladium‐Catalyzed Domino Process to Construct 2,3,9,9a‐Tetrahydro‐1H‐Fluorene Derivatives:Transient σ‐Alkylpalladium(II) Complex Mediated C(sp2)‐H Bond Activation
Goldkatalysierte, regiospezifische C‐H‐Anellierung von ortho‐Ethinylbiarylen mit Anthranilen: π‐Extension durch Ringerweiterung auf dem Weg zu N‐haltigen PAKs
A green, chemoselective, and efficient protocol for Paal–Knorr pyrrole and bispyrrole synthesis using biodegradable polymeric catalyst PEG‐SO3H in water
Platinum‐ and Gold‐Catalyzed Rearrangement Reactions of Propargyl Acetates: Total Syntheses of (−)‐α‐Cubebene, (−)‐Cubebol, Sesquicarene and Related Terpenes
Controllable Cyclization Reactions of 2‐(2′,3′‐Allenyl)acetylacetates Catalyzed by Gold and Palladium Affording Substituted Cyclopentene and 4,5‐Dihydrofuran Derivatives with Distinct Selectivity
Triggering the Directional Selectivity of a Ring‐Closure Reaction Leads to Pyridoazacarbazoles with Anticancer Properties
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