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Bulky monophosphite ligands for ethene hydroformylation

https://doi.org/10.1016/j.jcat.2012.11.031

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Erste effiziente Hydroaminomethylierung mit Ammoniak: mit dualen Metallkatalysatoren und Zweiphasenkatalyse zu primären Aminen

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Assembly of Encapsulated Transition Metal Catalysts

inferredcites →https://doi.org/10.1002/9783527635993openalex-snapshot

Homogeneous Catalysts

inferredcites →https://doi.org/10.1002/adsc.201100707openalex-snapshot

Formation of Acetals under Rhodium‐Catalyzed Hydroformylation Conditions in Alcohols

inferredcites →https://doi.org/10.1002/anie.200903620openalex-snapshot

Supramolecular Catalyst for Aldehyde Hydrogenation and Tandem Hydroformylation–Hydrogenation

inferredcites →https://doi.org/10.1002/anie.200906553openalex-snapshot

Cover Picture: The Nature of the Extraordinary Finish of Stradivari’s Instruments (Angew. Chem. Int. Ed. 1/2010)

inferredcites →https://doi.org/10.1002/anie.201001926openalex-snapshot

Continuous Rhodium‐Catalyzed Hydroformylation of 1‐Octene with Polyhedral Oligomeric Silsesquioxanes (POSS) Enlarged Triphenylphosphine

inferredcites →https://doi.org/10.1002/anie.201101653openalex-snapshot

Supramolecular Control of Ligand Coordination and Implications in Hydroformylation Reactions

inferredcites →https://doi.org/10.1002/cctc.200900088openalex-snapshot

Fast and Selective Hydroaminomethylation Using Xanthene‐Based Amino‐Functionalized Ligands

inferredcites →https://doi.org/10.1002/cctc.200900313openalex-snapshot

Rhodium‐Catalyzed Hydroformylation Using Hindered Phosphine Ligands: An In Situ Study

inferredcites →https://doi.org/10.1002/chem.200700727openalex-snapshot

The Rate‐Determining Step in the Rhodium–Xantphos‐Catalysed Hydroformylation of 1‐Octene

inferredcites →https://doi.org/10.1002/chem.201003646openalex-snapshot

Bioinspired Catalyst Design and Artificial Metalloenzymes

inferredcites →https://doi.org/10.1007/0-306-46947-2_4openalex-snapshot

Phosphines as ligands

inferredcites →https://doi.org/10.1007/0-306-46947-2_8openalex-snapshot

Process aspects of rhodium-catalyzed hydroformylation

inferredcites →https://doi.org/10.1007/1-4020-4087-3openalex-snapshot

Catalyst Separation, Recovery and Recycling

inferredcites →https://doi.org/10.1016/0022-328x(95)05748-eopenalex-snapshot

Rhodium-catalysed hydroformylation of branched 1-alkenes; bulky phosphite vs. triphenylphosphine as modifying ligand

inferredcites →https://doi.org/10.1016/0304-5102(90)85016-bopenalex-snapshot

Copolymerization of ethylene and carbon monoxide by rhodium carbonyls

inferredcites →https://doi.org/10.1016/1381-1169(95)00130-1openalex-snapshot

Progress in hydroformylation and carbonylation

inferredcites →https://doi.org/10.1016/j.catcom.2011.05.001openalex-snapshot

Reactive separation of dilute ethylene by hydroformylation using slurried rhodium catalysts on phosphinated resins and silica

inferredcites →https://doi.org/10.1016/j.fluid.2005.02.010openalex-snapshot

The experiments and correlations of the solubility of ethylene in toluene solvent

inferredcites →https://doi.org/10.1016/j.jorganchem.2005.02.026openalex-snapshot

Supraphos: A supramolecular strategy to prepare bidentate ligands

inferredcites →https://doi.org/10.1016/s0022-328x(00)99279-9openalex-snapshot

Hydroformylation of less reactive olefins with modified rhodium catalysts

inferredcites →https://doi.org/10.1016/s0040-4020(02)00211-9openalex-snapshot

Hydroformylation of higher olefins by rhodium/tris-((1H,1H,2H,2H-perfluorodecyl)phenyl)phosphites complexes in a fluorocarbon/hydrocarbon biphasic medium: effects of fluorinated groups on the activity and stability of the catalytic system

inferredcites →https://doi.org/10.1016/s1351-4180(11)70444-5openalex-snapshot

Homogeneous Catalysts: Activity – Stability – Deactivation

inferredcites →https://doi.org/10.1021/ar7001039openalex-snapshot

Ligands for Practical Rhodium-Catalyzed Asymmetric Hydroformylation

inferredcites →https://doi.org/10.1021/cr00039a008openalex-snapshot

Asymmetric Hydroformylation

inferredcites →https://doi.org/10.1021/cr1002497openalex-snapshot

Phosphite-Containing Ligands for Asymmetric Catalysis

inferredcites →https://doi.org/10.1021/cr970413ropenalex-snapshot

Tandem Reaction Sequences under Hydroformylation Conditions: New Synthetic Applications of Transition Metal Catalysis

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Hydroformylation with Cobalt Carbonyl and Cobalt Carbonyl-Tributylphosphine Catalysts

inferredcites →https://doi.org/10.1021/ic701547hopenalex-snapshot

Quantitative Assessment of the Stereoelectronic Profile of Phosphine Ligands

inferredcites →https://doi.org/10.1021/ie0509701openalex-snapshot

Asymmetric Hydroformylation of Styrene in Supercritical Carbon Dioxide

inferredcites →https://doi.org/10.1021/ie970497uopenalex-snapshot

Kinetics of Hydroformylation of Ethylene in a Homogeneous Medium: Comparison in Organic and Aqueous Systems

inferredcites →https://doi.org/10.1021/ja029499iopenalex-snapshot

The Rh4(CO)12-Catalyzed Hydroformylation of 3,3-Dimethylbut-1-ene Promoted with HMn(CO)5. Bimetallic Catalytic Binuclear Elimination as an Origin for Synergism in Homogeneous Catalysis

inferredcites →https://doi.org/10.1021/ja030143wopenalex-snapshot

Amines Made Easily: A Highly Selective Hydroaminomethylation of Olefins

inferredcites →https://doi.org/10.1021/ja106674nopenalex-snapshot

Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands

inferredcites →https://doi.org/10.1021/ja208589copenalex-snapshot

“Cofactor”-Controlled Enantioselective Catalysis

inferredcites →https://doi.org/10.1021/ja9738337openalex-snapshot

Molecular Engineering in Homogeneous Catalysis: One-Phase Catalysis Coupled with Biphase Catalyst Separation. The Fluorous-Soluble HRh(CO){P[CH2CH2(CF2)5CF3]3}3 Hydroformylation System

inferredcites →https://doi.org/10.1021/ja980729wopenalex-snapshot

Rhodium-Catalyzed Hydroformylation in Supercritical Carbon Dioxide

inferredcites →https://doi.org/10.1021/ol801247vopenalex-snapshot

Highly Regioselective Isomerization−Hydroformylation of Internal Olefins to Linear Aldehyde Using Rh Complexes with Tetraphosphorus Ligands

inferredcites →https://doi.org/10.1021/om00001a010openalex-snapshot

Hydroformylation with a Rhodium/Bulky Phosphite Modified Catalyst. A Comparison of the Catalyst Behavior for Oct-1-ene, Cyclohexene, and Styrene

inferredcites →https://doi.org/10.1021/om00006a057openalex-snapshot

New Diphosphine Ligands Based on Heterocyclic Aromatics Inducing Very High Regioselectivity in Rhodium-Catalyzed Hydroformylation: Effect of the Bite Angle

inferredcites →https://doi.org/10.1021/om020854nopenalex-snapshot

Rhodium-Catalyzed Hydroformylation of Alkenes Using in Situ High-Pressure IR and Polymer Matrix Techniques

inferredcites →https://doi.org/10.1021/om030202eopenalex-snapshot

Homogeneous Hydroformylation of Ethylene Catalyzed by Rh4(CO)12. The Application of BTEM to Identify a New Class of Rhodium Carbonyl Spectra: RCORh(CO)3(π-C2H4)

inferredcites →https://doi.org/10.1021/om100250ropenalex-snapshot

Isostructural Phosphine−Phosphite Ligands in Rhodium-Catalyzed Asymmetric Hydroformylation

inferredcites →https://doi.org/10.1021/om2000508openalex-snapshot

A New Diphosphite Promoting Highly Regioselective Rhodium-Catalyzed Hydroformylation

inferredcites →https://doi.org/10.1021/om980531kopenalex-snapshot

The Unmodified Homogeneous Rhodium-Catalyzed Hydroformylation of Cyclohexene and the Search for Monometallic Catalytic Binuclear Elimination

inferredcites →https://doi.org/10.1021/om990523jopenalex-snapshot

New Phosphacyclic Diphosphines for Rhodium-Catalyzed Hydroformylation

inferredcites →https://doi.org/10.1021/om990734oopenalex-snapshot

Origin of the Bite Angle Effect on Rhodium Diphosphine Catalyzed Hydroformylation

inferredcites →https://doi.org/10.1039/b416917dopenalex-snapshot

Rhodium hydride formation in the presence of a bulky monophosphite ligand: a spectroscopic and solid-state investigation

inferredcites →https://doi.org/10.1039/b616186copenalex-snapshot

Supported ionic liquid phase catalysis with supercritical flow

inferredcites →https://doi.org/10.1039/b913778eopenalex-snapshot

Rational design of diphosphorus ligands – a route to superior catalysts

inferredcites →https://doi.org/10.1039/c2cy00450jopenalex-snapshot

“On-water” rhodium-catalysed hydroformylation for the production of linear alcohols

inferredcites →https://doi.org/10.1039/c39910001096openalex-snapshot

Hydroformylation of oct-1-ene with extremely high rates using rhodium catalysts containing bulky phosphites

inferredcites →https://doi.org/10.1039/dt9960001161openalex-snapshot

Direct formation of alcohols by hydrocarbonylation of alkenes under mild conditions using rhodium trialkylphosphine catalysts

inferredcites →https://doi.org/10.1039/p29870001597openalex-snapshot

Structural characterisation in solution of intermediates in rhodium-catalysed hydroformylation and their interconversion pathways

inferredcites →https://doi.org/10.1111/j.1749-6632.1974.tb25314.xopenalex-snapshot

HYDROFORMYLATION OF OLEFINS WITH RHODIUM CARBONYLS AS CATALYSTS. IV. MECHANISM OF THE REACTION

inferredcites →https://doi.org/10.1126/science.1074801openalex-snapshot

Internal Olefins to Linear Amines

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4673734openalex-extracted

Triphenylphosphine-Derived Ligands for Rhodium-Catalyzed High Olefin Hydroformylations: From Traditional Molecules to Modern Cage Ligands

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Propanal

inferred← citeshttps://doi.org/10.1002/14356007.a22_173.pub3openalex-snapshot

Propanols

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References

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Confining Phosphanes Derived from Cyclodextrins for Efficient Regio‐ and Enantioselective Hydroformylation

inferred← citeshttps://doi.org/10.1002/anie.201311291openalex-snapshot

Confining Phosphanes Derived from Cyclodextrins for Efficient Regio‐ and Enantioselective Hydroformylation

inferred← citeshttps://doi.org/10.1002/cctc.202201204openalex-snapshot

Understanding Rh‐catalysed Hydroformylation with Phosphite Ligands through Catalyst Speciation Analysis by Operando FlowNMR Spectroscopy

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An Operando FTIR Spectroscopic and Kinetic Study of Carbon Monoxide Pressure Influence on Rhodium‐Catalyzed Olefin Hydroformylation

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Impact of the P‐Ligand Concentration on the Formation of Hydroformylation Catalysts: An in situ FTIR Spectroscopic Study

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Palladium‐Catalyzed Alkoxycarbonylation of sec‐Benzylic Ethers

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Ambient Pressure Hydroformylation – A Key Step to Meso‐Alkyl BODIPYs

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Efficient and Recyclable RuCl3 ⋅ 3H2O Catalyst Modified with Ionic Diphosphine for the Alkoxycarbonylation of Aryl Halides

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Hydroformylation of post-metathesis product using commercial rhodium-based catalysts

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Rhodium-Catalyzed Hydroformylation

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Bicyclic Systems With Bridgehead (Ring Junction): Phosphorus, Arsenic, Antimony, or Bismuth Atoms

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Synthesis of fragrance compounds from acyclic monoterpenes: Rhodium catalyzed hydroformylation and tandem hydroformylation/acetalization of linalool and β-citronellene

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Phospholes as efficient ancillaries for the rhodium-catalyzed hydroformylation and hydroaminomethylation of estragole

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Hydroformylation of recalcitrating biorenewable compounds containing trisubstituted double bonds

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Tandem hydroformylation/isomerization/hydrogenation of bio-derived 1-arylbutadienes for the regioselective synthesis of branched aldehydes

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Hydroformylation and one-pot hydroformylation/epoxy ring cleavage of limonene oxide: A sustainable access to biomass-based multi-functional fragrances

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Production of diacetates from propenylphenols: A one-pot two-step approach involving hydroformylation/hydrogenation/O-acylation

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Tandem hydroformylation-acetalization of renewable terpenes and propenylbenzenes using glycerol: A potential route to fuels additives

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Adjacent MnOx clusters enhance the hydroformylation activity of rhodium single-atom catalysts

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New scents using eco-friendly solvents: Oxo synthesis of aldehydes from caryophyllane sesquiterpenes

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One-pot hydroformylation/O-acylation of propenylbenzenes for the synthesis of polyfunctionalized fragrances

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Novel fragrant aldehydes from (1R,5R)-sabinene: An experimental study supported by DFT calculations revealing an unusual hydroformylation mechanism

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Ethylene as a synthon in carbonylative synthesis

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Xantphos doped Rh/POPs-PPh3 catalyst for highly selective long-chain olefins hydroformylation: Chemical and DFT insights into Rh location and the roles of Xantphos and PPh3

inferred← citeshttps://doi.org/10.1016/j.jcat.2018.10.012openalex-snapshot

Heterogeneous Rh/CPOL-BP&P(OPh)3 catalysts for hydroformylation of 1-butene: The formation and evolution of the active species

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Phosphine-ligated Ir(III)-complex as a bi-functional catalyst for one-pot tandem hydroformylation-acetalization

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Enhanced regioselectivity in propylene hydroformylation using Xantphos-modified single-atom Rh/CeO2 catalyst

inferred← citeshttps://doi.org/10.1016/j.jcat.2025.115955openalex-snapshot

Two-step one-pot Johnson-Claisen rearrangement/hydroformylation of renewable feedstocks

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Intramolecular C–H activation by air-stable Pt(II) phosphite complexes

inferred← citeshttps://doi.org/10.1016/j.jorganchem.2021.122231openalex-snapshot

Hydroformylation of olefins by metals other than rhodium

inferred← citeshttps://doi.org/10.1016/j.mcat.2017.01.030openalex-snapshot

Composition of catalyst resting states of hydroformylation catalysts derived from bulky mono-phosphorus ligands, rhodium dicarbonyl acetylacetonate and syngas

inferred← citeshttps://doi.org/10.1016/j.mcat.2017.11.008openalex-snapshot

Development of highly electron-deficient and less sterically-hindered phosphine ligands possessing 1,3,5-triazinyl groups

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Hydroformylation of biomass-based hydroxyolefins in eco-friendly solvents: New fragrances from myrtenol and nopol

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Boosting the hydrolytic stability of phosphite ligand in hydroformylation by the construction of superhydrophobic porous framework

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Promotion of diphosphine ligands (PPh2(CH2) PPh2, n = 1, 2, 3, 5, 6) for supported Rh/SiO2 catalysts in heterogeneous ethene hydroformylation

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Oxo synthesis of novel fragrant aldehydes from biomass-based cis-jasmone and cis-jasmone lactone in green solvents

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Ionic Rh(I)-complexes containing π-accepting and hemilabile P,N-ligands as efficient catalysts for hydroformylation of 1-octene

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Promotion effect of water on hydroformylation of styrene and its derivatives with presence of amphiphilic zwitterionic phosphines

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Effect of positive-charges in diphosphino-imidazolium salts on the structures of Ir-complexes and catalysis for hydroformylation

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Highly efficient Rh(I)/tris-H8-binaphthyl monophosphite catalysts for hydroformylation of dicyclopentadiene to dialdehydes

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Enhancing the activity, selectivity, and recyclability of Rh/PPh3 system-catalyzed hydroformylation reactions through the development of a PPh3-derived quasi-porous organic cage as a ligand

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Displacement of P-Stereogenic Phosphiranes from Rhodium by CO in Hydroformylation Catalysis

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Cobalt-Catalyzed Carbonylative Synthesis of 4-Oxobutanoates from Formamide and Ethylene

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Insights into the Activity Screening and Hydroformylation Kinetics of Rh-Based Bimetallic Phosphides

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Interplay between Catalyst Complexes and Dormant States: In Situ Spectroscopic Investigations on a Catalyst System for Alkene Hydroformylation

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Cobalt-Catalyzed Hydroformylation under Mild Conditions in the Presence of Phosphine Oxides

inferred← citeshttps://doi.org/10.1039/c3cy01104fopenalex-snapshot

Rhodium catalyzed hydroformylation of nerolidol

inferred← citeshttps://doi.org/10.1039/c5cy01827gopenalex-snapshot

Phosphonium-based aminophosphines as bifunctional ligands for sequential catalysis of one-pot hydroformylation–acetalization of olefins

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Immobilization of a rhodium catalyst using a diphosphine-functionalized ionic liquid in RTIL for the efficient and recyclable biphasic hydroformylation of 1-octene

inferred← citeshttps://doi.org/10.1039/c5gc02127hopenalex-snapshot

Co-catalysis of a bi-functional ligand containing phosphine and Lewis acidic phosphonium for hydroformylation–acetalization of olefins

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Efficient and recyclable Ir( i )-catalysts with the involvement of π-acceptor phosphines for N-alkylation of aryl amines with alcohols

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Anisole: a further step to sustainable hydroformylation

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Palladium-catalyzed carbonylations of highly substituted olefins using CO-surrogates

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The first one-pot metathesis–hydroformylation procedure: a straight synthesis of 2-arylpropanals from renewable 1-propenylbenzenes

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Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications

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In situ FTIR spectroscopic investigations on rhodium carbonyl complexes in the absence of phosphorus ligands under hydroformylation conditions

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1.1.1 Hydroformylation of Alkenes

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Experimental investigation of the complex liquid liquid equilibrium in the system pure/technical grade nonionic surfactant + water + oil

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PGMs IN THE LAB: New Diphosphines for Molecular and Nanoparticle Catalysis

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Monofluorophos–Metal Complexes: Ripe for Future Discoveries in Homogeneous Catalysis

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Phosphinocyclodextrins as confining units for catalytic metal centres. Applications to carbon–carbon bond forming reactions

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Novel Ir-Complexes for Hydroformylation of Olefins with H2O as the Hydrogen Source

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