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In situ FTIR spectroscopic investigations on rhodium carbonyl complexes in the absence of phosphorus ligands under hydroformylation conditions

https://doi.org/10.1039/d4nj02288b
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Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/1521-3773(20021018)41:20<3785::aid-anie3785>3.0.co;2-0openalex-snapshot
Rhodium Tetracarbonyl Hydride: The Elusive Metal Carbonyl Hydride
inferredcites →https://doi.org/10.1002/3527605134.ch4openalex-snapshot
Processing Spectroscopic Data
inferredcites →https://doi.org/10.1002/9783527635993openalex-snapshot
Homogeneous Catalysts
inferredcites →https://doi.org/10.1002/cctc.200900292openalex-snapshot
A Comparative In Situ HP‐FTIR Spectroscopic Study of Bi‐ and Monodentate Phosphite‐Modified Hydroformylation
inferredcites →https://doi.org/10.1002/cem.1273openalex-snapshot
Pure component spectral recovery and constrained matrix factorizations: concepts and applications
inferredcites →https://doi.org/10.1002/cem.2463openalex-snapshot
Model‐free multivariate curve resolution combined with model‐based kinetics: algorithm and applications
inferredcites →https://doi.org/10.1002/chem.201200603openalex-snapshot
Exploring Between the Extremes: Conversion‐Dependent Kinetics of Phosphite‐Modified Hydroformylation Catalysis
inferredcites →https://doi.org/10.1002/chem.201402515openalex-snapshot
An Operando FTIR Spectroscopic and Kinetic Study of Carbon Monoxide Pressure Influence on Rhodium‐Catalyzed Olefin Hydroformylation
inferredcites →https://doi.org/10.1007/s11244-009-9311-4openalex-snapshot
A Review of BTEM Analysis for Catalytic Studies and a Recent Homogeneous Catalytic Example
inferredcites →https://doi.org/10.1007/s13738-015-0727-4openalex-snapshot
Peak group analysis for the extraction of pure component spectra
inferredcites →https://doi.org/10.1016/j.cattod.2009.10.019openalex-snapshot
Combining operando spectroscopy with experimental design, signal processing and advanced chemometrics
inferredcites →https://doi.org/10.1016/j.chemolab.2017.02.002openalex-snapshot
Comparative multivariate curve resolution study in the area of feasible solutions
inferredcites →https://doi.org/10.1016/j.focat.2016.02.034openalex-snapshot
Hydroformylation: Fundamentals, Processes, and Applications in Organic Synthesis
inferredcites →https://doi.org/10.1016/j.jcat.2012.11.031openalex-snapshot
Bulky monophosphite ligands for ethene hydroformylation
inferredcites →https://doi.org/10.1016/j.mcat.2017.01.030openalex-snapshot
Composition of catalyst resting states of hydroformylation catalysts derived from bulky mono-phosphorus ligands, rhodium dicarbonyl acetylacetonate and syngas
inferredcites →https://doi.org/10.1016/j.vibspec.2006.01.013openalex-snapshot
The combination of deconvolution and density functional theory for the mid-infrared vibrational spectra of stable and unstable rhodium carbonyl clusters
inferredcites →https://doi.org/10.1016/s0021-9517(02)00009-xopenalex-snapshot
Spectral reconstruction of in situ FTIR spectroscopic reaction data using band-target entropy minimization (BTEM): application to the homogeneous rhodium catalyzed hydroformylation of 3,3-dimethylbut-1-ene using Rh4(CO)12
inferredcites →https://doi.org/10.1016/s0022-328x(00)00443-5openalex-snapshot
The homogeneous rhodium catalyzed hydroformylation of ethylene starting with tetrarhodium dodecacarbonyl—the observation of a new type of rhodium carbonyl spectrum
inferredcites →https://doi.org/10.1016/s0926-860x(00)00844-9openalex-snapshot
Decomposition pathways of homogeneous catalysts
inferredcites →https://doi.org/10.1016/s1351-4180(12)70467-1openalex-snapshot
Catalysis: from Principles to Applications
inferredcites →https://doi.org/10.1021/acscatal.2c06320openalex-snapshot
Interplay between Catalyst Complexes and Dormant States: In Situ Spectroscopic Investigations on a Catalyst System for Alkene Hydroformylation
inferredcites →https://doi.org/10.1021/acscatal.6b02185openalex-snapshot
Hydrolysis Stability of Bidentate Phosphites Utilized as Modifying Ligands in the Rh-Catalyzed n -Regioselective Hydroformylation of Olefins
inferredcites →https://doi.org/10.1021/acscatal.8b05066openalex-snapshot
In Situ Infrared Spectroscopy as a Tool for Monitoring Molecular Catalyst for Hydroformylation in Continuous Processes
inferredcites →https://doi.org/10.1021/cs3004209openalex-snapshot
Four Criteria for Evaluating Pure Component Spectral Estimates and the Subsequent Identification of Intermediates in Homogeneous Catalysis
inferredcites →https://doi.org/10.1021/cs300470uopenalex-snapshot
Strong π-Acceptor Ligands in Rhodium-Catalyzed Hydroformylation of Ethene and 1-Octene: Operando Catalysis
inferredcites →https://doi.org/10.1021/cs300471sopenalex-snapshot
Operando Spectroscopy in Catalytic Carbonylation Reactions
inferredcites →https://doi.org/10.1021/ic50215a049openalex-snapshot
Rhodium carbonyl cluster chemistry under high pressure of carbon monoxide and hydrogen. 3. Synthesis, characterization, and reactivity of HRh(CO)4
inferredcites →https://doi.org/10.1021/ja00827a013openalex-snapshot
Synthesis using transition metal diatomic molecules. Dirhodium octacarbonyl and diiridium octacarbonyl
inferredcites →https://doi.org/10.1021/ja029499iopenalex-snapshot
The Rh4(CO)12-Catalyzed Hydroformylation of 3,3-Dimethylbut-1-ene Promoted with HMn(CO)5. Bimetallic Catalytic Binuclear Elimination as an Origin for Synergism in Homogeneous Catalysis
inferredcites →https://doi.org/10.1021/om00008a034openalex-snapshot
Mechanistic Aspects of a Highly Regioselective Catalytic Alkene Hydroformylation using a Rhodium Chelating Bis(phosphite) Complex
inferredcites →https://doi.org/10.1021/om00052a014openalex-snapshot
Kinetics of the formation and hydrogenolysis of acylrhodium tetracarbonyl
inferredcites →https://doi.org/10.1021/om020854nopenalex-snapshot
Rhodium-Catalyzed Hydroformylation of Alkenes Using in Situ High-Pressure IR and Polymer Matrix Techniques
inferredcites →https://doi.org/10.1021/om030202eopenalex-snapshot
Homogeneous Hydroformylation of Ethylene Catalyzed by Rh4(CO)12. The Application of BTEM to Identify a New Class of Rhodium Carbonyl Spectra: RCORh(CO)3(π-C2H4)
inferredcites →https://doi.org/10.1021/om990230qopenalex-snapshot
Unmodified Rhodium-Catalyzed Hydroformylation of Alkenes Using Tetrarhodium Dodecacarbonyl. The Infrared Characterization of 15 Acyl Rhodium Tetracarbonyl Intermediates
inferredcites →https://doi.org/10.1039/b500044kopenalex-snapshot
Spectral resolution of fluxional organometallics. The observation and FTIR characterization of all-terminal [Rh4(CO)12]
inferredcites →https://doi.org/10.1039/b814580fopenalex-snapshot
Binuclear homoleptic rhodium carbonyls: Structures, energetics, and vibrational spectra
inferredcites →https://doi.org/10.1039/d1cs00161bopenalex-snapshot
Metal carbonyl clusters of groups 8–10: synthesis and catalysis
inferredcites →https://doi.org/10.1039/d1gc04383hopenalex-snapshot
Operando monitoring of mechanisms and deactivation of molecular catalysts
inferredcites →https://doi.org/10.1039/d2cy01807aopenalex-snapshot
Operando characterization of rhodium catalyst degradation in hydroformylation
inferredcites →https://doi.org/10.3390/catal9121036openalex-snapshot
Effects of Substitution Pattern in Phosphite Ligands Used in Rhodium-Catalyzed Hydroformylation on Reactivity and Hydrolysis Stability

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Thermoresponsive surface functionalization of FeRh alloy through PNIPAM grafting
inferred← citeshttps://doi.org/10.1002/cem.70121openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/cem.70131openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/cite.202400088openalex-snapshot
Impact of the P‐Ligand Concentration on the Formation of Hydroformylation Catalysts: An in situ FTIR Spectroscopic Study
inferred← citeshttps://doi.org/10.1016/j.checat.2025.101571openalex-snapshot
Understanding the formation and stability of cobalt-based catalysts for homogeneous carbonylation reactions
inferred← citeshttps://doi.org/10.1016/j.chemolab.2025.105565openalex-snapshot
Sampling-based computation of the sets of feasible solutions and feasible bands for noisy data
inferred← citeshttps://doi.org/10.1016/j.jechem.2026.01.042openalex-snapshot
Controlling the dynamic structural changes of catalysts for COx hydrogenation
inferred← citeshttps://doi.org/10.1016/j.mcat.2025.115654openalex-snapshot
Polyurethane-based heterogeneous catalysts with highly dispersed Rh single sites for reductive hydroformylation of olefins
inferred← citeshttps://doi.org/10.1021/acs.analchem.5c05154openalex-snapshot
In-Line NMR Diagnostics of Hydroformylation Provided by the Segmented-Flow Microfluidic Regime
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c04480openalex-snapshot
Rhodium Carbonyl Complexes within the Tunable Microenvironments of UiO-66 Analogues
inferred← citeshttps://doi.org/10.1021/acscatal.6c00812openalex-snapshot
Tuning Extrinsic Stability of Rhodium Catalysts in Heterogeneous Hydroformylation
inferred← citeshttps://doi.org/10.1021/jacs.6c15582openalex-snapshot
Electrochemical Hydroformylation with a Homogeneous Rhodium Catalyst
inferred← citeshttps://doi.org/10.1039/d6gc01402jopenalex-snapshot
Rhodium catalyst immobilization in trialkylamine-functionalized ionic liquids as a new efficient way to promote biphasic reductive hydroformylation of methyl 10-undecenoate
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