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Efficient Ruthenium-Catalysed Synthesis of 3-Hydroxy-1-propen-1-yl Benzoates: En Route to an Improved Isomerization of 2-Propyn-1-ols into α,β-Unsaturated Aldehydes
Isomerization of Propargylic Alcohols into α,β‐Unsaturated Carbonyl Compounds Catalyzed by the Sixteen‐Electron Allyl‐Ruthenium(II) Complex [Ru(η3‐2‐C3H4Me)(CO)(dppf)][SbF6]
Ruthenium‐Catalyzed Cycloisomerization of Aromatic Homo‐ and Bis‐Homopropargylic Amines/Amides: Formation of Indoles, Dihydroisoquinolines and Dihydroquinolines
Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper‐Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles
Desilylation‐Activated Propargylic Transformation: Enantioselective Copper‐Catalyzed [3+2] Cycloaddition of Propargylic Esters with β‐Naphthol or Phenol Derivatives
Novel Ruthenium‐ and Platinum‐Catalyzed Sequential Reactions: Synthesis of Tri‐ and Tetrasubstituted Furans and Pyrroles from Propargylic Alcohols and Ketones
Cooperative Catalytic Reactions Using Organocatalysts and Transition‐Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Aldehydes
Enantioselective Synthesis of Highly Functionalized Dihydrofurans through Copper‐Catalyzed Asymmetric Formal [3+2] Cycloaddition of β‐Ketoesters with Propargylic Esters
Cooperative Catalysis: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Enecarbamates Using Ruthenium/Phosphoramide Hybrid Catalysts
Desilylation‐Activated Propargylic Transformation: Enantioselective Copper‐Catalyzed [3+2] Cycloaddition of Propargylic Esters with β‐Naphthol or Phenol Derivatives
Construction of Chiral Tri‐ and Tetra‐Arylmethanes Bearing Quaternary Carbon Centers: Copper‐Catalyzed Enantioselective Propargylation of Indoles with Propargylic Esters
Rhenium(I)‐Catalyzed Generation of α,β‐Unsaturated Carbene Complex Intermediates from Propargyl Ethers for the Preparation of Cycloheptadiene Derivatives
Fulvene Synthesis by Rhodium(I)‐Catalyzed [2+2+1] Cycloaddition: Synthesis and Catalytic Activity of Tunable Cyclopentadienyl Rhodium(III) Complexes with Pendant Amides
Utilization of N,N‐Dialkylcarbamic Acid Derived from Secondary Amines and Supercritical Carbon Dioxide: Stereoselective Synthesis of Z Alkenyl Carbamates with a CO2‐Soluble Ruthenium–P(OC2H5)3 Catalyst
Enantioselective Copper‐Catalysed Propargylic Substitution: Synthetic Scope Study and Application in Formal Total Syntheses of (+)‐Anisomycin and (−)‐Cytoxazone
Gold‐Catalyzed Cyclization of Diynes: Controlling the Mode of 5‐endo versus 6‐endo Cyclization—An Experimental and Theoretical Study by Utilizing Diethynylthiophenes
Highly Diastereo‐ and Enantioselective Synthesis of Tetrahydro‐5H‐Indolo[2,3‐b]quinolines through Copper‐Catalyzed Propargylic Dearomatization of Indoles
Efficient endo Cycloisomerization of Terminal Alkynols Catalyzed by a New Ruthenium Complex with 8‐(Diphenylphosphino)quinoline Ligand and Mechanistic Investigation
The Origins of the Differences between Alkyne Hydroalkoxylations Catalyzed by 8‐Quinolinolato‐ and Dipyrrinato‐Ligated RhI Complexes: A DFT Mechanistic Study
Ruthenium‐Catalyzed Addition of Carboxylic Acids to Propargylic Alcohols: An Easy Route to O ‐Dienyl Esters and Their Tandem Atom‐Transfer Radical Polymerization
Synthesis and structure of [Ru(dppe)2(CH3CN)Cl][BPh4] and its catalytic application to anti-Markovnikov addition of carboxylic acids to terminal alkynes
E-Selective dimerization of phenylacetylene catalyzed by cationic tris(μ-hydroxo)diruthenium(II) complex and the mechanistic insight: The role of two ruthenium centers in catalysis
Discovery of the tungsten carbonyl-catalyzed endo-selective alkynyl alcohol cycloisomerization reaction: applications to stereoselective syntheses of d-olivose, d-olivose disaccharide substructures of landomycin and mithramycin
Enantioselective synthesis of chiral phosphonylated 2,3-dihydrofurans by copper catalyzed asymmetric formal [3+2] cycloaddition of propargylic esters with β-keto phosphonates
Synthesis and Reactivity of Phosphine-Quinolinolato Rhodium Complexes: Intermediacy of Vinylidene and (Amino)carbene Complexes in the Catalytic Hydroamination of Terminal Alkynes
Enantioselective Copper-Catalyzed Formal [4 + 2] Cycloaddition of o-Aminophenol Derivatives with Propargylic Esters for Synthesis of Optically Active 3,4-Dihydro-2H-1,4-benzoxazines
Asymmetric Catalytic [4 + 2] Cycloaddition via Cu–Allenylidene Intermediate: Stereoselective Synthesis of Tetrahydroquinolines Fused with a γ-Lactone Moiety
Copper-Catalyzed Asymmetric Formal [3 + 2] Cycloaddition of Propargylic Acetates with Hydrazines: Enantioselective Synthesis of Optically Active 2-Pyrazolines
Assessing Ligand and Counterion Effects in the Noble Metal Catalyzed Cycloisomerization Reactions of 1,6-Allenynes: a Combined Experimental and Theoretical Approach
Alkylidenecarbenes, Alkylidenecarbenoids, and Competing Species: Which Is Responsible for Vinylic Nucleophilic Substitution, [1 + 2] Cycloadditions, 1,5-CH Insertions, and the Fritsch−Buttenberg−Wiechell Rearrangement?
Carbon–Carbon Bond Formation via Catalytically Generated Aminocarbene Complexes: Rhodium‐Catalyzed Hydroaminative Cyclization of Enynes with Secondary Amines
Construction of Tricyclic Nitrogen Heterocycles by a Gold(I)‐Catalyzed Cascade Cyclization of Allenynes and Application to Polycyclic π‐Electron Systems
Carbon–Carbon Bond Formation via Catalytically Generated Aminocarbene Complexes: Rhodium‐Catalyzed Hydroaminative Cyclization of Enynes with Secondary Amines
Construction of Tricyclic Nitrogen Heterocycles by a Gold(I)‐Catalyzed Cascade Cyclization of Allenynes and Application to Polycyclic π‐Electron Systems
Novel Zinc(II) 2,6-dimethoxybenzamidine Schiff Base Complexes: Design, Synthesis, X-ray Crystal Structure, Fluorescence Properties and Density Functional Theory Calculations
Ruthenium-catalyzed hydrosilylation of alkynes with preservation of the Si–Si bond of hydrooligosilanes: Regio- and stereoselective synthesis of (Z)-alkenyloligosilanes and carbonyl-functionalized alkenyldisilanes
A focused review on the unconventional alkyne activations by ruthenium(II) and osmium(II) complexes supported by 1,2-bis(diphenylphosphino)methane (dppm)
Synthesis of the new water soluble vinyl ruthenium complex [RuCp(=C=CPh)(PPh3)(mPTA2](CF3SO3) (mPTA = N-methyl-1,3,5-triaza-7-phosphaadamantane): chemical reactivity and catalytic properties for redox isomerization of allylic alcohols
Addition of Amine-Substituted Heteroaromatic Rings to Alkynyl Bridging Ligands to Generate Phosphorescent Emitters Incorporating Iridaimidazoles with Fused Heterocyclic Rings
Chemoselective Ru-Catalyzed Oxidative Lactamization vs Hydroamination of Alkynylamines: Insights from Experimental and Density Functional Theory Studies
Ruthenium Vinylidene Complexes Generated by Selective 1,2-Migration of P- and S-Substituents: Synthesis, Structures, and Dichromism Arising from an Intramolecular CH···O Hydrogen Bond
Palladium-Catalyzed Chemo- and Regiocontrolled Tandem Cyclization/Cross-Coupling of 2-Benzyl-3-alkynyl Chromones with Aryl Iodides for the Synthesis of 4H-Furo[3,2-c]chromenes and Xanthones
Copper-Catalyzed Diastereo- and Enantioselective Decarboxylative [3 + 2] Cyclization of Alkyne-Substituted Cyclic Carbamates with Azlactones: Access to γ-Butyrolactams Bearing Two Vicinal Tetrasubstituted Carbon Stereocenters
Copper-Catalyzed Asymmetric Propargylic [3 + 2] Cycloaddition: Synthesis of Enantioenriched Dihydrofuro[3,2-c]coumarins and its Quinolinone and Thiocoumarin Analogues
Diastereo- and Enantioselective Copper-Catalyzed Decarboxylative Ring-Opening [3 + 2] Annulation of Tertiary Propargylic Carbamates through Regioselective α-Attack of γ-Butenolides
Copper-Catalyzed Asymmetric Propargylic Alkylation with Oxindoles: Diastereo- and Enantioselective Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters
Optimizing ligand structure for low-loading and fast catalysis for alkynyl-alcohol and -amine cyclization
showing the first 200 of 259
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