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Combined Use of Total Fluorine and Oxidative Fingerprinting for Quantitative Determination of Side-Chain Fluorinated Polymers in Textiles

https://doi.org/10.1021/acs.estlett.1c00822
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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PFAS Exposure Pathways for Humans and Wildlife: A Synthesis of Current Knowledge and Key Gaps in Understanding
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Perfluoroalkyl and polyfluoroalkyl substances in the environment: Terminology, classification, and origins
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Concentrations and trends of perfluorinated chemicals in potential indoor sources from 2007 through 2011 in the US
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Facing the rain after the phase out: Performance evaluation of alternative fluorinated and non-fluorinated durable water repellents for outdoor fabrics
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The effect of weathering on per- and polyfluoroalkyl substances (PFASs) from durable water repellent (DWR) clothing
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Microbial degradation of polyfluoroalkyl chemicals in the environment: A review
inferredcites →https://doi.org/10.1016/j.envint.2014.04.013openalex-snapshot
Global emission inventories for C4–C14 perfluoroalkyl carboxylic acid (PFCA) homologues from 1951 to 2030, Part I: production and emissions from quantifiable sources
inferredcites →https://doi.org/10.1016/j.envint.2016.02.035openalex-snapshot
Properties, performance and associated hazards of state-of-the-art durable water repellent (DWR) chemistry for textile finishing
inferredcites →https://doi.org/10.1016/j.envpol.2020.114940openalex-snapshot
Total oxidizable precursor assay in the determination of perfluoroalkyl acids in textiles collected from the United States
inferredcites →https://doi.org/10.1016/j.envpol.2020.115477openalex-snapshot
Side-chain fluorotelomer-based polymers in children car seats
inferredcites →https://doi.org/10.1016/j.nimb.2017.05.052openalex-snapshot
PIGE as a screening tool for Per- and polyfluorinated substances in papers and textiles
inferredcites →https://doi.org/10.1016/j.polymdegradstab.2009.10.004openalex-snapshot
Evaluation of PFO formation from the biodegradation of a fluorotelomer-based urethane polymer product in aerobic soils
inferredcites →https://doi.org/10.1021/acs.est.5b03686openalex-snapshot
Abiotic Hydrolysis of Fluorotelomer-Based Polymers as a Source of Perfluorocarboxylates at the Global Scale
inferredcites →https://doi.org/10.1021/acs.est.5b06237openalex-snapshot
Release of Per- and Polyfluoroalkyl Substances (PFASs) from Carpet and Clothing in Model Anaerobic Landfill Reactors
inferredcites →https://doi.org/10.1021/acs.est.6b04021openalex-snapshot
Degradation of Fluorotelomer-Based Polymers Contributes to the Global Occurrence of Fluorotelomer Alcohol and Perfluoroalkyl Carboxylates: A Combined Dynamic Substance Flow and Environmental Fate Modeling Analysis
inferredcites →https://doi.org/10.1021/acs.est.6b04806openalex-snapshot
A Never-Ending Story of Per- and Polyfluoroalkyl Substances (PFASs)?
inferredcites →https://doi.org/10.1021/acs.est.7b02080openalex-snapshot
Closing the Mass Balance on Fluorine on Papers and Textiles
inferredcites →https://doi.org/10.1021/acs.est.9b04165openalex-snapshot
Release of Side-Chain Fluorinated Polymer-Containing Microplastic Fibers from Functional Textiles During Washing and First Estimates of Perfluoroalkyl Acid Emissions
inferredcites →https://doi.org/10.1021/acs.estlett.0c00410openalex-snapshot
Another Pathway for Firefighter Exposure to Per- and Polyfluoroalkyl Substances: Firefighter Textiles
inferredcites →https://doi.org/10.1021/acs.estlett.0c00798openalex-snapshot
Reconstructing the Composition of Per- and Polyfluoroalkyl Substances in Contemporary Aqueous Film-Forming Foams
inferredcites →https://doi.org/10.1021/acs.estlett.1c00822openalex-snapshot
Combined Use of Total Fluorine and Oxidative Fingerprinting for Quantitative Determination of Side-Chain Fluorinated Polymers in Textiles
inferredcites →https://doi.org/10.1021/acs.estlett.8b00700openalex-snapshot
Total Fluorine Measurements in Food Packaging: How Do Current Methods Perform?
inferredcites →https://doi.org/10.1021/acs.estlett.9b00525openalex-snapshot
Fate of Per- and Polyfluoroalkyl Ether Acids in the Total Oxidizable Precursor Assay and Implications for the Analysis of Impacted Water
inferredcites →https://doi.org/10.1021/es0512475openalex-snapshot
Sources, Fate and Transport of Perfluorocarboxylates
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Investigation of the Biodegradation Potential of a Fluoroacrylate Polymer Product in Aerobic Soils
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Oxidative Conversion as a Means of Detecting Precursors to Perfluoroalkyl Acids in Urban Runoff
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Investigating the Biodegradability of a Fluorotelomer-Based Acrylate Polymer in a Soil–Plant Microcosm by Indirect and Direct Analysis
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Decades-Scale Degradation of Commercial, Side-Chain, Fluorotelomer-Based Polymers in Soils and Water
inferredcites →https://doi.org/10.1021/es505931vopenalex-snapshot
Matrix Normalized MALDI-TOF Quantification of a Fluorotelomer-Based Acrylate Polymer
inferredcites →https://doi.org/10.1021/es9002668openalex-snapshot
Degradability of an Acrylate-Linked, Fluorotelomer Polymer in Soil
inferredcites →https://doi.org/10.1039/c8em00368hopenalex-snapshot
Per- and polyfluoroalkyl substances and fluorine mass balance in cosmetic products from the Swedish market: implications for environmental emissions and human exposure
inferredcites →https://doi.org/10.1039/c9em00169gopenalex-snapshot
Closing the gap – inclusion of ultrashort-chain perfluoroalkyl carboxylic acids in the total oxidizable precursor (TOP) assay protocol
inferredcites →https://doi.org/10.1039/d0em00291gopenalex-snapshot
An overview of the uses of per- and polyfluoroalkyl substances (PFAS)
inferredcites →https://doi.org/10.1039/d0em00355gopenalex-snapshot
The high persistence of PFAS is sufficient for their management as a chemical class

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Enhancing Total Oxidizable Precursor Assay for Characterization of Per- and Polyfluoroalkyl Substances: Uv Versus Heat Activation
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Emerging Strategies for Comprehensive Analysis of Per‐ and Polyfluoroalkyl Substances (PFAS) in Complex Product and Industrial Matrices
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Emerging Strategies for Comprehensive Analysis of Per‐ and Polyfluoroalkyl Substances (PFAS) in Complex Product and Industrial Matrices
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Latest trends in the environmental analysis of PFAS including nontarget analysis and EOF-, AOF-, and TOP-based methodologies
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The quest for the perfect “total PFAS” method: how can the total oxidisable precursor (TOP) assay be made reliable?
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Development of a certified reference material for per- and polyfluoroalkyl substances (PFAS) in textiles
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A quantitative framework for optimization, interpretation, and quality control of the PFAS total oxidizable precursor assay
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A critical evaluation and optimization of combustion ion chromatography (CIC) for total fluorine quantification in plastic matrices relevant to PFAS regulation
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PFAS in municipal landfill leachate: Occurrence, transformation, and sources
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Investigation of pH-dependent extraction methods for PFAS in (fluoropolymer-based) consumer products: A comparative study between targeted and sum parameter analysis
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Ways to improve understanding of PFAS contamination - A case study within a waste management facility
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Revealing overlooked per- and polyfluoroalkyl substances (PFAS) in the Pearl River estuary using a comprehensive analytical approach
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PFAS in landfill leachate: Practical considerations for treatment and characterization
inferred← citeshttps://doi.org/10.1016/j.jhazmat.2026.141977openalex-snapshot
Per- and polyfluoroalkyl substances (PFAS) analysis in plastics and other polymer-based materials for recycling: Progress, limitations, and regulatory implications
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Wide-spectrum target and total oxidizable precursor PFAS quantification with online enrichment and LC-HRMS: Overcoming analytical and matrix complexity in wastewater and sludge
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Beyond PFAS: Fluorine-free materials for sustainable high-performance surface and barrier materials
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Radiation induced graft polymerization of fluorinated monomers onto flax fabrics for the control of hydrophobic and oleophobic properties
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Per- and polyfluoroalkyl substances (PFAS) in sludge from wastewater treatment plants in Sweden — First findings of novel fluorinated copolymers in Europe including temporal analysis
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Applying the modified UV-activated TOP assay to complex matrices impacted by aqueous film-forming foams
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Advancing PFAS characterization: Development and optimization of a UV-H2O2-TOP assay for improved PFCA chain length preservation and organic matter tolerance
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Persulfate-based total oxidizable precursor (TOP) assay approaches for advanced PFAS assessment in the environment – A review
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Fluoropolymers in Medical Applications: Recent Progress and Development
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Per- and Polyfluoroalkyl Substances in North American School Uniforms
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PhotoTOP: PFAS Precursor Characterization by UV/TiO2 Photocatalysis
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Are Geotextiles Silent Contributors of Ultrashort Chain PFASs to the Environment?
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Exploring Perfluoroalkyl and Polyfluoroalkyl Substance Presence and Potential Leaching from Reverse Osmosis Membranes: Implications for Drinking Water Treatment
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Nonpolymeric Per- and Polyfluoroalkyl Substances (PFAS) and Side-Chain Fluorinated Polymers in Canadian Building Products
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Per- and Polyfluoroalkyl Substances Leaching from Micro- and Nanoplastics and the Associated Influence of the Plastisphere
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Spatial and Temporal Analysis of Fluorine Mass Balance in Swedish Sludge and the Impact of Sample Treatment on Extractable Organofluorine
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Validation of a Rapid Screening Method for Textile Additives with Applications to Firefighter Station Wear
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Per- and Polyfluoroalkyl Substances in Reusable Feminine Hygiene Products
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Colloidal Side-Chain Fluorinated Polymer Nanoparticles Are a Significant Source of Polyfluoroalkyl Substance Contamination in Textile Wastewater
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Residential Wastewater as a Major Source of Per- and Polyfluoroalkyl Substances to Municipal Wastewater
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Per- and Polyfluoroalkyl Substances (PFAS) and Metals in Wild and Farmed Oysters of a Minimally Developed Coastal Region in the Southeastern United States
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Use and release of per- and polyfluoroalkyl substances (PFASs) in consumer food packaging in U.S. and Canada
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Non-extractable PFAS in functional textiles – characterization by complementary methods: oxidation, hydrolysis, and fluorine sum parameters
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Fluorine mass balance in commercial stone sealers from the US market and evaluation of PFAS-free alternatives
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Digging deep—implementation, standardisation and interpretation of a total oxidisable precursor (TOP) assay within the regulatory context of per- and polyfluoroalkyl substances (PFASs) in soil
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Per- and Polyfluoroalkyl Substances (PFAS) in Consumer Products: An Overview of the Occurrence, Migration, and Exposure Assessment
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One-Step Multifunctionalization of Flax Fabrics for Simultaneous Flame-Retardant and Hydro-Oleophobic Properties Using Radiation-Induced Graft Polymerization
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