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Iron-Catalyzed Carbene Insertion Reactions of α-Diazoesters into Si–H Bonds
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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Asymmetric NH Insertion of Secondary and Primary Anilines under the Catalysis of Palladium and Chiral Guanidine Derivatives
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Enantioselective Insertion of Metal Carbenes into NH Bonds: A Potentially Versatile Route to Chiral Amine Derivatives
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Sustainable Metal Catalysis with Iron: From Rust to a Rising Star?
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Copper‐Catalyzed Highly Enantioselective Carbenoid Insertion into SiH Bonds
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Catalytic Activation of Diazo Compounds Using Electron‐Rich, Defined Iron Complexes for Carbene‐Transfer Reactions
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Enantioselective Copper‐Catalyzed Intramolecular Phenolic OH Bond Insertion: Synthesis of Chiral 2‐Carboxy Dihydrobenzofurans, Dihydrobenzopyrans, and Tetrahydrobenzooxepines
inferredcites →https://doi.org/10.1002/anie.201308501openalex-snapshot
Asymmetric NH Insertion of Secondary and Primary Anilines under the Catalysis of Palladium and Chiral Guanidine Derivatives
inferredcites →https://doi.org/10.1002/anie.201309820openalex-snapshot
Enantioselective Palladium‐Catalyzed Insertion of α‐Aryl‐α‐diazoacetates into the OH Bonds of Phenols
inferredcites →https://doi.org/10.1002/anie.201511954openalex-snapshot
Copper‐Catalyzed Insertion into Heteroatom–Hydrogen Bonds with Trifluorodiazoalkanes
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Iron‐ and Bismuth‐Catalyzed Asymmetric Mukaiyama Aldol Reactions in Aqueous Media
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Iron(III) Corroles and Porphyrins as Superior Catalysts for the Reactions of Diazoacetates with Nitrogen‐ or Sulfur‐Containing Nucleophilic Substrates: Synthetic Uses and Mechanistic Insights
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Enantioselective Aromatic Sulfide Oxidation and Tandem Kinetic Resolution Using Aqueous H2O2 and Chiral Iron–Bis(oxazolinyl)bipyridine Catalysts
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Enantioselective Iron Catalysts
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Reaction of dihydrosilanes with ethyl diazoacetate: synthesis of 3,3-disubstituted 3-silaglutarates
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Synthesis of α-(Alkoxysilyl)acetic esters. A route to 1,2 diols
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Rhodium(II)-vinylcarbenoid insertion into the SiH bond. A new stereospecific synthesis of allylsilanes
inferredcites →https://doi.org/10.1016/0040-4039(96)01679-6openalex-snapshot
Asymmetric rhodium carbenoid insertion into the SiH bond
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Carbene X H bond insertions catalyzed by copper(I) macrocyclic pyridine-containing ligand (PcL) complexes
inferredcites →https://doi.org/10.1016/j.tet.2008.04.074openalex-snapshot
Recent studies on the reactions of α-diazocarbonyl compounds
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A method for the catalytic enantioselective synthesis of 6-silylated 2-cyclohexenones
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Regioselectivity in Lewis acids catalyzed X–H (O, S, N) insertions of methyl styryldiazoacetate with benzyl alcohol, benzyl thiol, and aniline
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Asymmetric intermolecular cyclopropanation of alkenes by diazoketones catalyzed by Halterman iron porphyrins
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The reaction of organosilicon hydrides with carbomethoxycarbene generated from methyl diazoacetate
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Preparation of optically active α-silylcarbonyl compounds using asymmetric alkylation of α-silylacetic esters and asymmetric metal-carbene insertion into the SiH bond
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A one pot synthesis of α-(alkoxysilyl)acetic esters
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Asymmetric metal carbene insertion into the SiH bond
inferredcites →https://doi.org/10.1016/s0040-4039(02)00489-6openalex-snapshot
Indium triflate: a mild and efficient Lewis acid catalyst for O–H insertion reactions of α-diazo ketones
inferredcites →https://doi.org/10.1016/s0040-4039(96)02285-xopenalex-snapshot
Mechanism of metal-carbenoid insertion into the SiH bond
inferredcites →https://doi.org/10.1016/s0040-4039(97)00205-0openalex-snapshot
Rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed asymmetric insertions of vinyl- and phenylcarbenoids into the SiH bond
inferredcites →https://doi.org/10.1016/s0040-4039(98)02013-9openalex-snapshot
Carbenoid insertions into the siliconhydrogen bond catalyzed by chiral copper (I) schiff base complexes
inferredcites →https://doi.org/10.1016/s0957-4166(00)00384-0openalex-snapshot
Enantioselective SiH insertion of methyl phenyldiazoacetate catalyzed by dirhodium(II) carboxylates incorporating N-phthaloyl-(S)-amino acids as chiral bridging ligands
inferredcites →https://doi.org/10.1021/acs.chemrev.5b00121openalex-snapshot
Modern Organic Synthesis with α-Diazocarbonyl Compounds
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Copper-Catalyzed Carbenoid Insertion Reactions of α-Diazoesters and α-Diazoketones into Si–H and S–H Bonds
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Iron-Catalyzed Cross-Coupling Reactions of Arylmagnesium Reagents with Aryl Chlorides and Tosylates: Influence of Ligand Structural Parameters and Identification of a General N-Heterocyclic Carbene Ligand
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Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions
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Diastereoselective Reactions of Chiral Allyl and Allenyl Silanes with Activated C:X .pi.-Bonds
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Iron-Catalyzed Reactions in Organic Synthesis
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Chiral Iron Catalysts for Asymmetric Synthesis
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Iron Catalysis in Organic Synthesis
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Catalytic Carbene Insertion into C−H Bonds
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Recent Advances in Asymmetric Catalytic Metal Carbene Transformations
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Magnetically Separable Microporous Fe–Porphyrin Networks for Catalytic Carbene Insertion into N–H Bonds
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Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center
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Metallopeptides for Asymmetric Dirhodium Catalysis
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Rhodium(I)-Catalyzed Highly Enantioselective Insertion of Carbenoid into Si–H: Efficient Access to Functional Chiral Silanes
inferredcites →https://doi.org/10.1021/jacs.6b08171openalex-snapshot
Iron-Catalyzed, Fluoroamide-Directed C–H Fluorination
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Total Synthesis of (−)-Virginiamycin M2: Application of Crotylsilanes Accessed by Enantioselective Rh(II) or Cu(I) Promoted Carbenoid Si–H Insertion
inferredcites →https://doi.org/10.1021/jo961952jopenalex-snapshot
A Stereospecific Access to Allylic Systems Using Rhodium(II)−Vinyl Carbenoid Insertion into Si−H, O−H, and N−H Bonds
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Vinylogous Aldol Products from Chiral Crotylsilanes Obtained by Enantioselective Rh(II) and Cu(I) Carbenoid Si−H Insertion
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Speciation and Mechanistic Studies of Chiral Copper(I) Schiff Base Precursors Mediating Asymmetric Carbenoid Insertion Reactions of Diazoacetates into the Si−H Bond of Silanes
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Synthesis, Structural Analysis, and Catalytic Properties of Tetrakis(binaphthyl or octahydrobinaphthyl phosphate) Dirhodium(II,II) Complexes
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Catalytic C−H Insertions Using Iron(III) Porphyrin Complexes
inferredcites →https://doi.org/10.1038/nchem.651openalex-snapshot
Enantioselective iron-catalysed O–H bond insertions
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Catalytic and enantioselective allylic C–H activation with donor–acceptor-substituted carbenoids
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Iron porphyrins catalyze the synthesis of non-protected amino acid esters from ammonia and diazoacetates
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Application of donor/acceptor-carbenoids to the synthesis of natural products
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Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes
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Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand
inferredcites →https://doi.org/10.1039/c2dt31460fopenalex-snapshot
Silver-catalyzed silicon–hydrogen bond functionalization by carbene insertion
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Determination of orientational isomerism in rhodium(ii) metallopeptides by pyrene fluorescence
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Catalytic X–H insertion reactions based on carbenoids
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Recent development of direct asymmetric functionalization of inert C–H bonds
inferredcites →https://doi.org/10.1039/c3sc52535jopenalex-snapshot
Cytochrome P450-catalyzed insertion of carbenoids into N–H bonds
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Rational development of iron catalysts for asymmetric transfer hydrogenation
inferredcites →https://doi.org/10.1039/c4gc01866dopenalex-snapshot
When iron met phosphines: a happy marriage for reduction catalysis
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Non-heme iron catalysts for epoxidation and aziridination reactions of challenging terminal alkenes: towards sustainability
inferredcites →https://doi.org/10.1039/c5cy01357gopenalex-snapshot
Iron bis(oxazoline) complexes in asymmetric catalysis
inferredcites →https://doi.org/10.1039/c6cc09650fopenalex-snapshot
Silver( i )-promoted insertion into X–H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones
inferredcites →https://doi.org/10.1039/c6gc03589bopenalex-snapshot
Atom economical synthesis of N-alkylbenzamides via the iron( iii ) sulfate catalyzed rearrangement of 2-alkyl-3-aryloxaziridines in water and in the presence of a surfactant
inferredcites →https://doi.org/10.1039/c7cc01070bopenalex-snapshot
Ru( ii )-Pheox-catalyzed Si–H insertion reaction: construction of enantioenriched carbon and silicon centers
inferredcites →https://doi.org/10.1039/jr9630003604openalex-snapshot
679. The reaction of diazoalkanes with Group IV hydrides
inferredcites →https://doi.org/10.1055/s-2006-939035openalex-snapshot
Iron Corroles and Porphyrins as Very Efficient and Highly Selective Catalysts for the Reactions of α-Diazo Esters with Amines
inferredcites →https://doi.org/10.1093/nsr/nwu019openalex-snapshot
Iron-catalyzed transformations of diazo compounds
inferredcites →https://doi.org/10.1351/pac-con-10-10-18openalex-snapshot
Halodiazoacetates as useful tools for selective halo-functionalization
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Recent Advances in Iron‐Catalyzed Chemical and Enzymatic Carbene‐Transfer Reactions
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Rapid Synthesis of Functionalized Hydrocarbazolones via Indole C2−H Activation Using Enone Functionality as a Directing Group/Electrophilic Species
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Unsupported Nanoporous Copper Catalyzed Insertion of Carbenes from α‐Diazo Compounds into Hydrosilanes
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TfOH‐Catalyzed Regioselective Alkylation of Hydroxybenzotriazole with Diazo Compounds and Further Base‐Facilitated Elimination under Batch and Flow Conditions
inferred← citeshttps://doi.org/10.1002/ange.201813512openalex-snapshot
Donor Rhodium Carbenes by Retro‐Buchner Reaction
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Synthesis of Functionalized Silsesquioxane Nanomaterials by Rhodium‐Catalyzed Carbene Insertion into Si−H Bonds
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Donor Rhodium Carbenes by Retro‐Buchner Reaction
inferred← citeshttps://doi.org/10.1002/anie.202110417openalex-snapshot
Synthesis of Functionalized Silsesquioxane Nanomaterials by Rhodium‐Catalyzed Carbene Insertion into Si−H Bonds
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Scope and Limitations of TBA[Fe]‐Catalyzed Carbene Transfer to X−H‐bonds – Indication of a Mechanistic Dichotomy
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Iron‐porphyrin Catalyzed Carbene Transfer Reactions – an Evolution from Biomimetic Catalysis towards Chemistry‐inspired Non‐natural Reactivities of Enzymes
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Improving the Long‐term Enantioselectivity of a Silicon‐Carbon Bond‐Forming Enzyme
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Regio‐ and Diasteroselective C‐Silylation of Enolate Enabled by a β‐Boronyl Group
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Fe(OTf)2‐Catalyzed Thia‐Michael Addition Reaction: A Green Synthetic Approach to β‐Thioethers
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Convenient Approach to 2‐Substituted (Thio)morpholin‐3‐ones from α‐Diazoacetates via X‐H Carbene Insertion – Lactamization Sequence
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Recent Advances in Zinc‐Catalyzed Carbon‐Heteroatom Bond Formation
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Catalysts Based on the C−H⋅⋅⋅M Weak Interaction: Synthesis, Characterization and Catalytic Application of Bis(pyrazolyl)borate Cu(I) Complexes in Carbene Insertion into Heteroatom Hydrogen Bonds
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Catalyst Free Chemoselective Carbene Insertion Into COO─H Bond Over ─OH of Salicylic Acid
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Catalytic asymmetric silicon-carbon bond-forming transformations based on Si-H functionalization
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Synthesis of Organosilanes, Silyl Ethers, and Silanols
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The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2017
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A stable Copper-Modified silica microsphere catalyst for the synthesis of N-substituted carbazoles and organosilanes
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Turning Waste into Valuable Catalysts: Application of Surface-Modified Sewage Sludge in N–H Insertion Reaction
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Engineering Corrole and Porphyrin-Based Multivariate Metal–Organic Frameworks for Si–H Bond Insertion
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Gold-Catalyzed Diastereoselective Formal Intermolecular [4 + 2 + 1] Cycloaddition of 1,3-Dien-8-yne with Diazo Ester
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Synthesis of 3-Azabicyclo[m.2.0] Ring Systems via a Copper-Catalyzed Cascade Reaction of Diazo Compounds with 1,n-Allenynes
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Catalytic Asymmetric Diarylphosphine Addition to α-Diazoesters for the Synthesis of P-Stereogenic Phosphinates via P*—N Bond Formation
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TfOH-Catalyzed Cascade C–H Activation/Lactonization of Phenols with α-Aryl-α-diazoesters: Rapid Access to α-Aryl Benzofuranones
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Gold-Catalyzed Sigmatropic Rearrangement Reactions via Carbene Transfer Reactions
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α-Aminocarbene-Mediated Si–H Insertion: Deoxygenative Silylation of Aromatic Amides with Silanes
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Visible-Light-Mediated Azidation of α-Diazoesters with TMSN3 via Direct Photoexcitation and SH2 Mechanism
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Chemoselective Cyclopropanation over Carbene Y–H Insertion Catalyzed by an Engineered Carbene Transferase
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Metal-Free Insertion Reactions of Silanes with Aryldiazoacetates
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Catalytic Bismuth(V)-Mediated Oxidation of Hydrazones into Diazo Compounds
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c01803openalex-snapshot
Electrosynthesis of Stabilized Diazo Compounds from Hydrazones
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b01638openalex-snapshot
Au Nanoparticle-Catalyzed Insertion of Carbenes from α-Diazocarbonyl Compounds into Hydrosilanes
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Iron Porphyrin Catalyzed Insertion Reaction of N-Tosylhydrazone-Derived Carbenes into X–H (X = Si, Sn, Ge) Bonds
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Iron-Catalyzed Enantioselective Si–H Bond Insertions
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Asymmetric CuI-Catalyzed Insertion Reaction of 1-Aryl-2,2,2-trifluoro-1-diazoethanes into Si–H Bonds
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Iron: A Worthy Contender in Metal Carbene Chemistry
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Iron-Carbene Initiated O–H Insertion/Aldol Cascade for the Stereoselective Synthesis of Functionalized Tetrahydrofurans
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Iron-Carbene-Mediated Catalytic Activation of Conventional Thioglycosides for Stereoselective 1,2-cis-Furanosylations
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Blue Light-Promoted Cross-Coupling of α-Diazo Esters with Isocyanides: Synthesis of Ester-Functionalized Ketenimines
inferred← citeshttps://doi.org/10.1021/acsomega.7b01637openalex-snapshot
Rh(III)-Catalyzed C–H Activation/Intramolecular Cyclization: Access to N -Acyl-2,3-dihydro-1 H -carbazol-4(9 H )-ones from Cyclic 2-Diazo-1,3-diketones and N -Arylamides
inferred← citeshttps://doi.org/10.1021/acsomega.8b02633openalex-snapshot
Copper-Catalyzed Coupling of Thioamides and Donor/Acceptor-Substituted Carbenoids: Synthesis of Enamino Esters and Enaminones
inferred← citeshttps://doi.org/10.1021/acsorginorgau.1c00027openalex-snapshot
Emerging Applications of Aryl Trifluoromethyl Diazoalkanes and Diazirines in Synthetic Transformations
inferred← citeshttps://doi.org/10.1021/acssuschemeng.1c01976openalex-snapshot
Lightening Diazo Compounds?
inferred← citeshttps://doi.org/10.1021/jacs.5c17554openalex-snapshot
Chemoenzymatic Diazo Synthesis Enabled by Enzymatic Halide Recycling with Vanadium-Dependent Haloperoxidases
inferred← citeshttps://doi.org/10.1039/c8cc06768fopenalex-snapshot
Palladium(0)-catalyzed C(sp 3 )–Si bond formation via formal carbene insertion into a Si–H bond
inferred← citeshttps://doi.org/10.1039/c8ob01991fopenalex-snapshot
Iron-catalysed carbene-transfer reactions of diazo acetonitrile
inferred← citeshttps://doi.org/10.1039/c9gc03428eopenalex-snapshot
Catalytic O–H bond insertion reactions using surface modified sewage sludge as a catalyst
inferred← citeshttps://doi.org/10.1039/c9ob00261hopenalex-snapshot
α-Thiocarbonyl synthesis via the Fe II -catalyzed insertion reaction of α-diazocarbonyls into S–H bonds
inferred← citeshttps://doi.org/10.1039/c9ra04098fopenalex-snapshot
Recyclable iron( ii ) caffeine-derived ionic salt catalyst in the Diels–Alder reaction of cyclopentadiene and α,β-unsaturated N -acyl-oxazolidinones in dimethyl carbonate
inferred← citeshttps://doi.org/10.1039/c9ra07203aopenalex-snapshot
Fe II -catalysed insertion reaction of α-diazocarbonyls into X–H bonds (X = Si, S, N, and O) in dimethyl carbonate as a suitable solvent alternative
inferred← citeshttps://doi.org/10.1039/d0cc05970fopenalex-snapshot
Nickel-catalyzed insertions of vinylidenes into Si–H bonds
inferred← citeshttps://doi.org/10.1039/d0cs00688bopenalex-snapshot
Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts
inferred← citeshttps://doi.org/10.1039/d1ob00811kopenalex-snapshot
Copper on charcoal: Cu 0 nanoparticle catalysed aerobic oxidation of α-diazo esters
inferred← citeshttps://doi.org/10.1039/d1qo00188dopenalex-snapshot
Efficient stereoselective synthesis of chiral 3,3′-dimethyl-(2,2′-bipyridine)-diol ligand and applications in Fe II -catalysis
inferred← citeshttps://doi.org/10.1039/d2ob01069kopenalex-snapshot
Synthesis of functionalized S -benzyl dithiocarbamates from diazo-compounds via multi-component reactions with carbon disulfide and secondary amines
inferred← citeshttps://doi.org/10.1039/d3qo01112gopenalex-snapshot
Atom-economical synthesis of bicyclo[3.1.0]hexane silanes by gold-catalyzed Si–H bond insertion reaction of 1,6-enynes with hydrosilanes
inferred← citeshttps://doi.org/10.1039/d6dt01671eopenalex-snapshot
Diversity-oriented functionalization of silanes via ruthenium phthalocyanine-catalyzed carbene Si–H insertion
inferred← citeshttps://doi.org/10.1055/a-2457-0146openalex-snapshot
Visible-Light-Induced Three-Component Reactions of α-Diazoesters, Indazoles, and Cyclic Ethers
inferred← citeshttps://doi.org/10.1055/s-0039-1690864openalex-snapshot
One-Pot Synthesis of α-Halo β-Amino Acid Derivatives via the Difunctional Coupling of Ethyl α-Diazoacetate with Silyl Halides and N,O-Acetals or Aromatic Tertiary Amines
inferred← citeshttps://doi.org/10.1055/s-0040-1707272openalex-snapshot
The Power of Iron Catalysis in Diazo Chemistry
inferred← citeshttps://doi.org/10.1080/00397911.2018.1460670openalex-snapshot
Iron-catalyzed deoxygenation and 2-sulfonylation of quinoline N-oxides by sodium sulfinates towards 2-sulfonyl quinolines
inferred← citeshttps://doi.org/10.1126/sciadv.aay1537openalex-snapshot
Expedient synthesis of E -hydrazone esters and 1 H -indazole scaffolds through heterogeneous single-atom platinum catalysis
inferred← citeshttps://doi.org/10.1142/s1088424623500979openalex-snapshot
Protein-conjugated iron complexes for catalyzing asymmetric carbene insertions into S-H and Si-H bonds
inferred← citeshttps://doi.org/10.2174/1385272826666220516113815openalex-snapshot
Application of Aromatic Substituted 2,2,2-Trifluoro Diazoethanes in Organic Reactions
inferred← citeshttps://doi.org/10.6023/cjoc202201045openalex-snapshot
Blue Light Induced Insertion of Carbene into C(CO)—C Bonds of 1,3-Diones
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