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Rhodium(I)-Catalyzed Highly Enantioselective Insertion of Carbenoid into Si–H: Efficient Access to Functional Chiral Silanes

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Reactivity Enhancement for Chiral Dirhodium(II) Tetrakis(Carboxamidates)
inferredcites →https://doi.org/10.1002/adsc.201000908openalex-snapshot
Enantioselective Conjugate Silyl Additions to α,β‐Unsaturated Aldehydes Catalyzed by Combination of Transition Metal and Chiral Amine Catalysts
inferredcites →https://doi.org/10.1002/anie.200601747openalex-snapshot
Rhodium‐Catalyzed Enantioselective Conjugate Silyl Transfer: 1,4‐Addition of Silyl Boronic Esters to Cyclic Enones and Lactones
inferredcites →https://doi.org/10.1002/anie.200703612openalex-snapshot
Chiral Olefins as Steering Ligands in Asymmetric Catalysis
inferredcites →https://doi.org/10.1002/anie.200800361openalex-snapshot
Catalytic Asymmetric CSi Bond Formation to Acyclic α,β‐Unsaturated Acceptors by RhI‐Catalyzed Conjugate Silyl Transfer Using a SiB Linkage
inferredcites →https://doi.org/10.1002/anie.200803192openalex-snapshot
Copper‐Catalyzed Highly Enantioselective Carbenoid Insertion into SiH Bonds
inferredcites →https://doi.org/10.1002/anie.200906792openalex-snapshot
Chiral Tetrafluorobenzobarrelene Ligands for the Rhodium‐Catalyzed Asymmetric Cycloisomerization of Oxygen‐ and Nitrogen‐Bridged 1,6‐Enynes
inferredcites →https://doi.org/10.1002/anie.201003775openalex-snapshot
Asymmetric Cyclopropanation of Alkenes with Dimethyl Diazomalonate Catalyzed by Chiral Diene–Rhodium Complexes
inferredcites →https://doi.org/10.1002/anie.201106972openalex-snapshot
Rhodium‐Catalyzed, Highly Enantioselective 1,2‐Addition of Aryl Boronic Acids to α‐Ketoesters and α‐Diketones Using Simple, Chiral Sulfur–Olefin Ligands
inferredcites →https://doi.org/10.1002/anie.201209020openalex-snapshot
Copper‐Catalyzed Addition of Nucleophilic Silicon to Aldehydes
inferredcites →https://doi.org/10.1002/anie.201402086openalex-snapshot
Enantioselective Addition of Silicon Nucleophiles to Aldimines Using a Preformed NHC–Copper(I) Complex as the Catalyst
inferredcites →https://doi.org/10.1002/anie.201407740openalex-snapshot
An Ylide Transformation of Rhodium(I) Carbene: Enantioselective Three‐Component Reaction through Trapping of Rhodium(I)‐Associated Ammonium Ylides by β‐Nitroacrylates
inferredcites →https://doi.org/10.1016/0040-4039(96)01679-6openalex-snapshot
Asymmetric rhodium carbenoid insertion into the SiH bond
inferredcites →https://doi.org/10.1016/j.tetlet.2006.02.014openalex-snapshot
A method for the catalytic enantioselective synthesis of 6-silylated 2-cyclohexenones
inferredcites →https://doi.org/10.1016/s0040-4020(96)00038-5openalex-snapshot
The oxidation of the carbon-silicon bond
inferredcites →https://doi.org/10.1016/s0040-4039(96)02285-xopenalex-snapshot
Mechanism of metal-carbenoid insertion into the SiH bond
inferredcites →https://doi.org/10.1016/s0040-4039(97)00205-0openalex-snapshot
Rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed asymmetric insertions of vinyl- and phenylcarbenoids into the SiH bond
inferredcites →https://doi.org/10.1016/s0040-4039(98)01538-xopenalex-snapshot
Parallel synthesis techniques in the identification of new chiral dirhodium(II) carboxylates for asymmetric carbenoid insertion reactions
inferredcites →https://doi.org/10.1016/s0040-4039(98)02013-9openalex-snapshot
Carbenoid insertions into the siliconhydrogen bond catalyzed by chiral copper (I) schiff base complexes
inferredcites →https://doi.org/10.1016/s0957-4166(00)00384-0openalex-snapshot
Enantioselective SiH insertion of methyl phenyldiazoacetate catalyzed by dirhodium(II) carboxylates incorporating N-phthaloyl-(S)-amino acids as chiral bridging ligands
inferredcites →https://doi.org/10.1016/s0957-4166(03)00035-1openalex-snapshot
Asymmetric rhodium carbene insertion into the SiH bond: identification of new dirhodium(II) carboxylate catalysts using parallel synthesis techniques
inferredcites →https://doi.org/10.1016/s1359-6446(03)02726-0openalex-snapshot
Chemistry challenges in lead optimization: silicon isosteres in drug discovery
inferredcites →https://doi.org/10.1021/cr00037a011openalex-snapshot
Uses of Silicon-Containing Compounds in the Synthesis of Natural Products
inferredcites →https://doi.org/10.1021/cr941074uopenalex-snapshot
Stereochemical Control in Organic Synthesis Using Silicon-Containing Compounds
inferredcites →https://doi.org/10.1021/cs200571vopenalex-snapshot
Rhodium-Catalyzed Hydrosilylation of Ketones: Catalyst Development and Mechanistic Insights
inferredcites →https://doi.org/10.1021/ja044790eopenalex-snapshot
C2-Symmetric Bicyclo[2.2.2]octadienes as Chiral Ligands: Their High Performance in Rhodium-Catalyzed Asymmetric Arylation of N-Tosylarylimines
inferredcites →https://doi.org/10.1021/ja0710914openalex-snapshot
Design of C2-Symmetric Tetrahydropentalenes as New Chiral Diene Ligands for Highly Enantioselective Rh-Catalyzed Arylation of N-Tosylarylimines with Arylboronic Acids
inferredcites →https://doi.org/10.1021/ja100833hopenalex-snapshot
Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center
inferredcites →https://doi.org/10.1021/ja103747hopenalex-snapshot
Metallopeptides for Asymmetric Dirhodium Catalysis
inferredcites →https://doi.org/10.1021/ja3110818openalex-snapshot
Simple Branched Sulfur–Olefins as Chiral Ligands for Rh-Catalyzed Asymmetric Arylation of Cyclic Ketimines: Highly Enantioselective Construction of Tetrasubstituted Carbon Stereocenters
inferredcites →https://doi.org/10.1021/ja502229copenalex-snapshot
Enantioselective Insertion of a Carbenoid Carbon into a C–C Bond To Expand Cyclobutanols to Cyclopentanols
inferredcites →https://doi.org/10.1021/ja910989nopenalex-snapshot
Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes
inferredcites →https://doi.org/10.1021/jacs.5b00892openalex-snapshot
Rhodium(I)-Catalyzed Asymmetric Carbene Insertion into B–H Bonds: Highly Enantioselective Access to Functionalized Organoboranes
inferredcites →https://doi.org/10.1021/jm00022a022openalex-snapshot
.alpha.-Hydroxy Phosphinyl-Based Inhibitors of Human Renin
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Organosilicon Molecules with Medicinal Applications
inferredcites →https://doi.org/10.1021/jo00261a045openalex-snapshot
A new and general synthesis of .alpha.-silyl carbonyl compounds by silicon-hydrogen insertion from transition metal-catalyzed reactions of diazo esters and diazo ketones
inferredcites →https://doi.org/10.1021/jo0107352openalex-snapshot
A Kinetic Study on the Pairwise Competition Reaction of α-Diazo Esters with Rhodium(II) Catalysts: Implication for the Mechanism of Rh(II)-Carbene Transfer
inferredcites →https://doi.org/10.1021/jo047831yopenalex-snapshot
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inferredcites →https://doi.org/10.1021/jo3005638openalex-snapshot
Scalable Synthesis of Enantiomerically Pure Bicyclo[2.2.2]octadiene Ligands
inferredcites →https://doi.org/10.1021/jo961952jopenalex-snapshot
A Stereospecific Access to Allylic Systems Using Rhodium(II)−Vinyl Carbenoid Insertion into Si−H, O−H, and N−H Bonds
inferredcites →https://doi.org/10.1021/ol070345nopenalex-snapshot
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inferredcites →https://doi.org/10.1021/ol501143copenalex-snapshot
Catalytic Enantioselective Silylation of N -Sulfonylimines: Asymmetric Synthesis of α-Amino Acids from CO 2 via Stereospecific Carboxylation of α-Amino Silanes
inferredcites →https://doi.org/10.1021/om0003786openalex-snapshot
Speciation and Mechanistic Studies of Chiral Copper(I) Schiff Base Precursors Mediating Asymmetric Carbenoid Insertion Reactions of Diazoacetates into the Si−H Bond of Silanes
inferredcites →https://doi.org/10.1021/om300935uopenalex-snapshot
Synthesis, Structural Analysis, and Catalytic Properties of Tetrakis(binaphthyl or octahydrobinaphthyl phosphate) Dirhodium(II,II) Complexes
inferredcites →https://doi.org/10.1039/c2cc30441dopenalex-snapshot
Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand
inferredcites →https://doi.org/10.1039/c3cc49431dopenalex-snapshot
Simple sulfur–olefins as new promising chiral ligands for asymmetric catalysis
inferredcites →https://doi.org/10.1055/s-0030-1259710openalex-snapshot
Enantioselective Copper-Catalyzed O-H Insertion of α-Diazo Phosphonates
inferredcites →https://doi.org/10.1080/10426509108029443openalex-snapshot
BIOLOGICAL ACTIVITY OF AMINOPHOSPHONIC ACIDS

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Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1021/acs.chemrev.6b00373openalex-snapshot
λ5-Phosphorus-Containing α-Diazo Compounds: A Valuable Tool for Accessing Phosphorus-Functionalized Molecules
inferred← citeshttps://doi.org/10.1021/acs.joc.1c00876openalex-snapshot
Stereoselective Halo-Succinimide Facilitated α-Halogenations of Substituted α-Trialkylsilyl-β-Substituted-α,β-Unsaturated Esters
inferred← citeshttps://doi.org/10.1021/acs.joc.1c00967openalex-snapshot
Chiral Dirhodium Tetraphosphate-Catalyzed Enantioselective Si–H Bond Insertion of α-Aryldiazoacetates
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02734openalex-snapshot
Asymmetric Hydrosilylation of β-Silyl Styrenes Catalyzed by a Chiral Palladium Complex
inferred← citeshttps://doi.org/10.1021/acs.joc.2c00696openalex-snapshot
Experimental and Computational Mechanistic Study of Carbonazidate-Initiated Cascade Reactions
inferred← citeshttps://doi.org/10.1021/acs.joc.2c02624openalex-snapshot
Rhodium(I)-Catalyzed Direct Enantioselective C–H Functionalization of Indoles
inferred← citeshttps://doi.org/10.1021/acs.joc.2c02649openalex-snapshot
α-Aminocarbene-Mediated Si–H Insertion: Deoxygenative Silylation of Aromatic Amides with Silanes
inferred← citeshttps://doi.org/10.1021/acs.joc.3c02652openalex-snapshot
Rhodium(I)-Catalyzed O–H Insertions onO-Protected α-Diazo-β-Hydroxyesters
inferred← citeshttps://doi.org/10.1021/acs.joc.6b02998openalex-snapshot
Copper-Catalyzed Carbenoid Insertion Reactions of α-Diazoesters and α-Diazoketones into Si–H and S–H Bonds
inferred← citeshttps://doi.org/10.1021/acs.joc.7b00583openalex-snapshot
Access to Chiral Silicon Centers for Application to Circularly Polarized Luminescence Materials
inferred← citeshttps://doi.org/10.1021/acs.joc.7b02601openalex-snapshot
Role of Regioisomeric Bicyclo[3.3.0]octa-2,5-diene Ligands in Rh Catalysis: Synthesis, Structural Analysis, Theoretical Study, and Application in Asymmetric 1,2- and 1,4-Additions
inferred← citeshttps://doi.org/10.1021/acs.joc.7b02857openalex-snapshot
Switchable Synthesis of 3-Substituted 1H-Indazoles and 3,3-Disubstituted 3H-Indazole-3-phosphonates Tuned by Phosphoryl Groups
inferred← citeshttps://doi.org/10.1021/acs.joc.7b03118openalex-snapshot
Selective Construction of 2-Substituted Benzothiazoles from o-Iodoaniline Derivatives S8 and N-Tosylhydrazones
inferred← citeshttps://doi.org/10.1021/acs.joc.8b01209openalex-snapshot
Diastereoselective Syntheses of (E)-α-Trialkylsilyl α,β-Unsaturated Esters, α-Silane-Substituted Conjugated Silyl Ketene Acetals, and α,γ-Substituted Allylsilanes
inferred← citeshttps://doi.org/10.1021/acs.joc.9b02605openalex-snapshot
Metal-Free Insertion Reactions of Silanes with Aryldiazoacetates
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00268openalex-snapshot
cis-β-Ruthenium Complexes with Sterically Bulky Salen Ligands: Enantioselective Intermolecular Carbene Insertion into Si–H Bonds and X-ray Crystal Structure of cis-β-[RuII(salen)(CO)(CPh2)] Complex
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00310openalex-snapshot
Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions
inferred← citeshttps://doi.org/10.1021/acs.organomet.1c00403openalex-snapshot
Synthesis of Overloaded Cyclopentadienyl Rhodium(III) Complexes via Cyclotetramerization of tert-Butylacetylene
inferred← citeshttps://doi.org/10.1021/acs.organomet.6c00089openalex-snapshot
Di-Silyl Rhodium(III) and Iridium(III) Complexes as Catalysts in Carbene Insertion Reactions into Hydrosilanes
inferred← citeshttps://doi.org/10.1021/acs.organomet.6c00275openalex-snapshot
Chiral Rh Diene NHC Complexes and Their Application in Rh-Catalyzed Cycloisomerization of Enynes
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00889openalex-snapshot
Substituent Effects on Reactions of [RhCl(COD)]2 with Diazoalkanes
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c00145openalex-snapshot
C(sp2)–H Bond Multiple Functionalization in Air for Construction of Tetrahydrocarbazoles with Continuous Quaternary Carbons and Polycyclic Diversification
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c03589openalex-snapshot
Carbene-Catalyzed Enantioselective Synthesis of γ-Keto-β-silyl Esters and Amides
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c03619openalex-snapshot
Formation of β-Oxo-N-vinylimidates via Intermolecular Ester Incorporation in Huisgen Cyclization/Carbene Cascade Reactions
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c00183openalex-snapshot
Dearomative Synthesis of Chiral Dienes Enables Improved Late-Stage Ligand Diversification
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c01803openalex-snapshot
Electrosynthesis of Stabilized Diazo Compounds from Hydrazones
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c02321openalex-snapshot
Visible-Light-Induced [1+5] Annulation of Phosphoryl Diazomethylarenes and Pyridinium 1,4-Zwitterionic Thiolates
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b01183openalex-snapshot
Construction of Cyclic Sulfamidates Bearing Two gem-Diaryl Stereocenters through a Rhodium-Catalyzed Stepwise Asymmetric Arylation Protocol
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b02264openalex-snapshot
Rhodium(II)-Alkynyl Carbenoids Insertion into Si–H bonds: An Entry to Propargylic Geminal Bis(silanes)
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b02578openalex-snapshot
Sequential Deprotonation–Alkylation of Binaphthyloxy-Substituted Phosphonochalcogenoates: Chiral Tri- and Tetrasubstituted Carbon Centers Adjacent to a Phosphorus Atom
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b01668openalex-snapshot
Copper-Catalyzed Formal Carbene Migratory Insertion into Internal Olefinic C═C Bonds with N-Tosylhydrazones To Access Iminofuran and 2(3H)-Furanone Derivatives
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b02488openalex-snapshot
Iron-Catalyzed Carbene Insertion Reactions of α-Diazoesters into Si–H Bonds
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b02928openalex-snapshot
Catalytic Asymmetric Roskamp Reaction of Silyl Diazoalkane: Synthesis of Enantioenriched α-Silyl Ketone
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b03279openalex-snapshot
Copper-Catalyzed Substitution of α-Triflyloxy Nitriles and Esters with Silicon Nucleophiles under Inversion of the Configuration
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b00651openalex-snapshot
Rhodium-Catalyzed Enantioselective Alkenylation of Cyclic Ketimines: Synthesis of Multifunctional Chiral α,α-Disubstituted Allylic Amine Derivatives
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b01638openalex-snapshot
Au Nanoparticle-Catalyzed Insertion of Carbenes from α-Diazocarbonyl Compounds into Hydrosilanes
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b01931openalex-snapshot
Iron Porphyrin Catalyzed Insertion Reaction of N-Tosylhydrazone-Derived Carbenes into X–H (X = Si, Sn, Ge) Bonds
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b01988openalex-snapshot
Boron-Catalyzed O–H Bond Insertion of α-Aryl α-Diazoesters in Water
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b02555openalex-snapshot
Asymmetric Rh(I)-Catalyzed Functionalization of the 3-C(sp3)–H Bond of Benzofuranones with α-Diazoesters
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b02868openalex-snapshot
Iron-Catalyzed Enantioselective Si–H Bond Insertions
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b02864openalex-snapshot
Asymmetric Cyclization/Nucleophilic Tandem Reaction of o-Alkynylacetophenone with (Diazomethyl)phosphonate for the Synthesis of Functional Isochromenes
inferred← citeshttps://doi.org/10.1021/acscatal.4c02340openalex-snapshot
Asymmetric Cyclopropanation of Primary N-Vinylamides via Carbene Transfer Catalyzed by Cationic Rh(I)/Diene Complexes: An Unexpected Outer-Sphere Mechanism
inferred← citeshttps://doi.org/10.1021/acscatal.5c01823openalex-snapshot
Unprecedented Dual Radical Initiation in Visible-Light Photoredox-Catalyzed X–H (X = Si and B) Insertions of Sulfoxonium Ylides
inferred← citeshttps://doi.org/10.1021/acscatal.5c04323openalex-snapshot
Ligand-Controlled Regiodivergent Hydrosilylation of α,β-Unsaturated Esters
inferred← citeshttps://doi.org/10.1021/acscatal.5c06981openalex-snapshot
Rh 2 (II)-Catalyzed Asymmetric Si–H Insertion of α-Alkyl-Donor Carbene from Diynes: Constructing C/Si-Stereocenters by Outcompeting β-H Migration
inferred← citeshttps://doi.org/10.1021/acscatal.9b01187openalex-snapshot
Rhodium-Catalyzed Si–H Bond Insertion Reactions Using Functionalized Alkynes as Carbene Precursors
inferred← citeshttps://doi.org/10.1021/acscentsci.5c00232openalex-snapshot
Rh(I)-Catalyzed Modular Synthesis of Axially Chiral Alkylidene Azacycloalkanes
inferred← citeshttps://doi.org/10.1021/acscentsci.6c00925openalex-snapshot
Fischer Indole Synthesis Inspired De Novo and Modular Assembly of Indolines
inferred← citeshttps://doi.org/10.1021/acsomega.5c12690openalex-snapshot
Recent Advances in Transition-Metal-Catalyzed Selective Synthesis of π‑Conjugated Silacycles: A Mini-Review
inferred← citeshttps://doi.org/10.1021/jacs.0c04533openalex-snapshot
Enantioselective Si–H Insertion Reactions of Diarylcarbenes for the Synthesis of Silicon-Stereogenic Silanes
inferred← citeshttps://doi.org/10.1021/jacs.0c04725openalex-snapshot
Enantioselective Diarylcarbene Insertion into Si–H Bonds Induced by Electronic Properties of the Carbenes
inferred← citeshttps://doi.org/10.1021/jacs.0c13191openalex-snapshot
Regiospecific and Enantioselective Arylvinylcarbene Insertion of a C–H Bond of Aniline Derivatives Enabled by a Rh(I)-Diene Catalyst
inferred← citeshttps://doi.org/10.1021/jacs.1c01972openalex-snapshot
A New Ligand Design Based on London Dispersion Empowers Chiral Bismuth–Rhodium Paddlewheel Catalysts
inferred← citeshttps://doi.org/10.1021/jacs.1c02146openalex-snapshot
Origin and Control of Chemoselectivity in Cytochrome c Catalyzed Carbene Transfer into Si–H and N–H bonds
inferred← citeshttps://doi.org/10.1021/jacs.1c03435openalex-snapshot
Enantioselective Insertion of Alkynyl Carbenes into Si–H Bonds: An Efficient Access to Chiral Propargylsilanes and Allenylsilanes
inferred← citeshttps://doi.org/10.1021/jacs.1c03498openalex-snapshot
Stereodivergent Synthesis of Enantioenriched 2,3-Disubstituted Dihydrobenzofurans via a One-Pot C–H Functionalization/Oxa-Michael Addition Cascade
inferred← citeshttps://doi.org/10.1021/jacs.1c05422openalex-snapshot
Rh(II)-Catalyzed Alkynylcyclopropanation of Alkenes by Decarbenation of Alkynylcycloheptatrienes
inferred← citeshttps://doi.org/10.1021/jacs.1c05879openalex-snapshot
Palladium-Catalyzed Enantioselective Carbene Insertion into Carbon–Silicon Bonds of Silacyclobutanes
inferred← citeshttps://doi.org/10.1021/jacs.3c06906openalex-snapshot
Catalytic Asymmetric P–H Insertion Reactions
inferred← citeshttps://doi.org/10.1021/jacs.3c14386openalex-snapshot
Construction of Ge-Stereogenic Center by Desymmetric Carbene Insertion of Dihydrogermanes
inferred← citeshttps://doi.org/10.1021/jacs.5b13321openalex-snapshot
Structures of Reactive Donor/Acceptor and Donor/Donor Rhodium Carbenes in the Solid State and Their Implications for Catalysis
inferred← citeshttps://doi.org/10.1021/jacs.5c02996openalex-snapshot
Cu-Catalyzed Enantioselective Carbene Insertion into Ge–H and Si–H Bonds Enabled by SPSiBox with a Tunable Chiral Pocket
inferred← citeshttps://doi.org/10.1021/jacs.5c17554openalex-snapshot
Chemoenzymatic Diazo Synthesis Enabled by Enzymatic Halide Recycling with Vanadium-Dependent Haloperoxidases
inferred← citeshttps://doi.org/10.1021/jacs.7b04137openalex-snapshot
Highly Enantioselective Cobalt-Catalyzed Hydrosilylation of Alkenes
inferred← citeshttps://doi.org/10.1021/jacs.7b11707openalex-snapshot
Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling
inferred← citeshttps://doi.org/10.1021/jacs.8b01638openalex-snapshot
Iron-Catalyzed Highly Enantioselective Hydrosilylation of Unactivated Terminal Alkenes
inferred← citeshttps://doi.org/10.1038/s41467-022-34901-6openalex-snapshot
Regioselective Ni-Catalyzed reductive alkylsilylation of acrylonitrile with unactivated alkyl bromides and chlorosilanes
inferred← citeshttps://doi.org/10.1038/s41467-024-54532-3openalex-snapshot
Direct synthesis of α-functionalized amides via heteroatom–hydrogen insertion reactions using amide-sulfoxonium ylides
inferred← citeshttps://doi.org/10.1038/s41929-026-01481-3openalex-snapshot
Harnessing thia-Rh-carbenes for the enantioselective synthesis of chiral α,α-diheteroatomic carboxylic acids
inferred← citeshttps://doi.org/10.1039/9781837677931-00263openalex-snapshot
Green synthetic approaches in organophosphorus chemistry: Recent developments
inferred← citeshttps://doi.org/10.1039/c6cc09650fopenalex-snapshot
Silver( i )-promoted insertion into X–H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones
inferred← citeshttps://doi.org/10.1039/c7cc01070bopenalex-snapshot
Ru( ii )-Pheox-catalyzed Si–H insertion reaction: construction of enantioenriched carbon and silicon centers
inferred← citeshttps://doi.org/10.1039/c7ob00177kopenalex-snapshot
Iridium catalyzed acceptor/acceptor carbene insertion into N–H bonds in water
inferred← citeshttps://doi.org/10.1039/c7ob00807dopenalex-snapshot
Recent progress in the catalytic carbene insertion reactions into the silicon–hydrogen bond
inferred← citeshttps://doi.org/10.1039/c7qo00555eopenalex-snapshot
Highly enantioselective Rh/chiral sulfur-olefin-catalyzed arylation of alkyl-substituted non-benzofused cyclic N-sulfonyl ketimines
inferred← citeshttps://doi.org/10.1039/c7sc00257bopenalex-snapshot
A DFT calculation-inspired Rh( i )-catalyzed reaction via suppression of α-H shift in α-alkyldiazoacetates
inferred← citeshttps://doi.org/10.1039/c8cc06768fopenalex-snapshot
Palladium(0)-catalyzed C(sp 3 )–Si bond formation via formal carbene insertion into a Si–H bond
inferred← citeshttps://doi.org/10.1039/c8qo00703aopenalex-snapshot
A triple-functionalised metal centre-catalyzed enantioselective multicomponent reaction
inferred← citeshttps://doi.org/10.1039/c9gc03428eopenalex-snapshot
Catalytic O–H bond insertion reactions using surface modified sewage sludge as a catalyst
inferred← citeshttps://doi.org/10.1039/d0qo01401jopenalex-snapshot
Brønsted acid-catalyzed homogeneous O–H and S–H insertion reactions under metal- and ligand-free conditions
inferred← citeshttps://doi.org/10.1039/d1qo01265gopenalex-snapshot
Catalyst-free synthesis of α,α-disubstituted carboxylic acid derivatives under ambient conditions via a Wolff rearrangement reaction
inferred← citeshttps://doi.org/10.1039/d2cc01648fopenalex-snapshot
Asymmetric cyclopropanation of electron-rich alkenes by the racemic diene rhodium catalyst: the chiral poisoning approach
inferred← citeshttps://doi.org/10.1039/d2cc05483copenalex-snapshot
Microwave-mediated stereocontrolled annulations of diazo(aryl)methyl(diaryl)phosphine oxides with pyridinium 1,4-zwitterionic thiolates
inferred← citeshttps://doi.org/10.1039/d2qo00164kopenalex-snapshot
Rhodium( i )-catalyzed C–S bond formation via enantioselective carbenoid S–H insertion: catalytic asymmetric synthesis of α-thioesters
inferred← citeshttps://doi.org/10.1039/d3cc05436eopenalex-snapshot
CAMDOL-enabled diastereoselective synthesis of α-substituted phosphonates
inferred← citeshttps://doi.org/10.1039/d3qo00617dopenalex-snapshot
Silver-catalyzed vinylcarbene insertion into Si–H bonds with vinyl N -triftosylhydrazones leading to allylsilanes
inferred← citeshttps://doi.org/10.1039/d4md00169aopenalex-snapshot
The role of silicon in drug discovery: a review
inferred← citeshttps://doi.org/10.1039/d4qo00136bopenalex-snapshot
Fe-catalyzed B–H and Si–H insertion reactions of gem -dihaloalkanes
inferred← citeshttps://doi.org/10.1039/d4sc01271bopenalex-snapshot
Enantioselective copper-catalyzed B–H bond insertion reaction of α-diazo phosphonates to access chiral α-boryl phosphonates
inferred← citeshttps://doi.org/10.1039/d5cc04404aopenalex-snapshot
Heme-based catalysis for sustainable carbene transfer chemistry: computational mechanistic investigations
inferred← citeshttps://doi.org/10.1039/d5cc04968gopenalex-snapshot
G-quadruplex DNA/iron cationic porphyrin catalyzes enantioselective carbon–silicon bond formation
inferred← citeshttps://doi.org/10.1039/d5cs00195aopenalex-snapshot
Recent advances in catalytic asymmetric metalloid–hydrogen bond insertion of transition-metal carbenes
inferred← citeshttps://doi.org/10.1039/d5qo00835bopenalex-snapshot
Rh 2 ( ii )-catalyzed cyclization/ gem -hydrosilylation of benzene-fused 1,6-enynones
inferred← citeshttps://doi.org/10.1039/d6dt01671eopenalex-snapshot
Diversity-oriented functionalization of silanes via ruthenium phthalocyanine-catalyzed carbene Si–H insertion
inferred← citeshttps://doi.org/10.1055/a-1929-4890openalex-snapshot
State-of-the-Art Advances in Enantioselective Transition-Metal-Mediated Reactions of Silacyclobutanes
inferred← citeshttps://doi.org/10.1126/science.aah6219openalex-snapshot
Directed evolution of cytochrome c for carbon–silicon bond formation: Bringing silicon to life
inferred← citeshttps://doi.org/10.1126/science.aal1951openalex-snapshot
Teaching nature the unnatural
inferred← citeshttps://doi.org/10.1142/s1088424623500979openalex-snapshot
Protein-conjugated iron complexes for catalyzing asymmetric carbene insertions into S-H and Si-H bonds
inferred← citeshttps://doi.org/10.3390/sym16091171openalex-snapshot
Enantioselective Transfer Reactions of α-Heteroatom-Substituted Carbenes
inferred← citeshttps://doi.org/10.6023/cjoc202105002openalex-snapshot
N-Heterocyclic Carbene-Catalyzed [4+2] Annulation of Acetates and β-Silyl Enones: Highly Enantioselective Synthesis of β-Silyl δ-Lactones
inferred← citeshttps://doi.org/10.6023/cjoc202303025openalex-snapshot
Progress in the Syntheses of α-Boryl Carbonyl Compounds
inferred← citeshttps://doi.org/10.6023/cjoc202304030openalex-snapshot
Catalytic Enantioselective Preparation of Chiral Allylsilanes
inferred← citeshttps://doi.org/10.6023/cjoc202511017openalex-snapshot
Recent Advances in the Functionalization of para- C(sp2)—H Bonds of Anilines
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