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Methylaluminoxane’s Molecular Cousin: A Well-defined and “Complete” Al-Activator for Molecular Olefin Polymerization Catalysts

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Investigations on ternary metallocene-based catalyst systems
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Polymerisation von Äthylen und anderen Olefinen
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Halogen‐Free Soluble Ziegler Catalysts for the Polymerization of Ethylene. Control of Molecular Weight by Choice of Temperature
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Monomer–Dimer Equilibria in Homo‐ and Heterodinuclear Cationic Alkylzirconium Complexes and Their Role in Polymerization Catalysis
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Nonconventional Catalysts for Isotactic Propene Polymerization in Solution Developed by Using High‐Throughput‐Screening Technologies
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H2 Activation and Hydride Transfer to Olefins by Al(C6F5)3‐Based Frustrated Lewis Pairs
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Isolation of an N‐Heterocyclic Carbene Complex of a Borasilene
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Methylalumoxane – History, Production, Properties, and Applications
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Reactivity of a Monomeric Aluminium Hydrazide towards Isocyanates and Isothiocyanates: Active Lewis Pair Behaviour versus Classical Insertion Reactions
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Interaction of Neutral Donors with Methylaluminoxane
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On the Nature of the Lewis Acidic Sites in “TMA‐Free” Phenol‐Modified Methylaluminoxane
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N‐Acyl‐ and N‐Sulfonylformamidines from Cyanamides and Carbodiimides by Hydroalumination and Subsequent Treatment with Electrophiles
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Backbone rearrangement during olefin capture as the rate limiting step in molecular olefin polymerization catalysis and its effect on comonomer affinity
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Thirty years of continuum solvation chemistry: a review, and prospects for the near future
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Binuclear zirconocene cations with μ-CH3-bridges in homogeneous Ziegler-Natta catalyst systems
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Catalyst activation and the dimerization energy of alkylaluminium compounds
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inferredcites →https://doi.org/10.1016/j.jorganchem.2020.121366openalex-snapshot
Kinetics and mechanism of ethylene and propylene polymerizations catalyzed with ansa-zirconocene activated by borate/TIBA
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Hydrodefluorination of non-activated C–F bonds by diisobutyl-aluminiumhydride via the aluminium cation [i-Bu2Al]+
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Advances in Organometallic Chemistry
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inferredcites →https://doi.org/10.1021/acs.chemrev.5b00310openalex-snapshot
From Multisite Polymerization Catalysis to Sustainable Materials and All-Polyolefin Composites
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High-Throughput Experimentation in Olefin Polymerization Catalysis: Facing the Challenges of Miniaturization
inferredcites →https://doi.org/10.1021/acs.iecr.9b02801openalex-snapshot
High Throughput Experimentation Protocol for Quantitative Measurements of Regioselectivity in Ziegler–Natta Polypropylene Catalysis
inferredcites →https://doi.org/10.1021/acs.inorgchem.0c00533openalex-snapshot
Reactivity Trends of Lewis Acidic Sites in Methylaluminoxane and Some of Its Modifications
inferredcites →https://doi.org/10.1021/acs.macromol.0c01771openalex-snapshot
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Discrete Ionic Complexes of Highly Isoselective Zirconocenes. Solution Dynamics, Trimethylaluminum Adducts, and Implications in Propylene Polymerization
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Accurate Prediction of Copolymerization Statistics in Molecular Olefin Polymerization Catalysis: The Role of Entropic, Electronic, and Steric Effects in Catalyst Comonomer Affinity
inferredcites →https://doi.org/10.1021/acscatal.7b01232openalex-snapshot
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inferredcites →https://doi.org/10.1021/acscatal.8b00841openalex-snapshot
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inferredcites →https://doi.org/10.1021/j100624a025openalex-snapshot
Self-diffusion in normal and heavy water in the range 1-45.deg.
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Three-Coordinate Aluminum Is Not a Prerequisite for Catalytic Activity in the Zirconocene-Alumoxane Polymerization of Ethylene
inferredcites →https://doi.org/10.1021/ja00230a046openalex-snapshot
C-H bond activation in Cp2ZrIIICH2PPh2: evidence for an unexpected mechanistic pathway
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inferredcites →https://doi.org/10.1021/ja01611a109openalex-snapshot
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inferredcites →https://doi.org/10.1021/ja048861lopenalex-snapshot
Catalytic Oligomerization of Ethylene to Higher Linear α-Olefins Promoted by the Cationic Group 4 [(η5-Cp-(CMe2-bridge)-Ph)MII(ethylene)2]+(M = Ti, Zr, Hf) Active Catalysts: A Density Functional Investigation of the Influence of the Metal on the Catalytic Activity and Selectivity
inferredcites →https://doi.org/10.1021/ja1050428openalex-snapshot
Cationic Alkylaluminum-Complexed Zirconocene Hydrides: NMR-Spectroscopic Identification, Crystallographic Structure Determination, and Interconversion with Other Zirconocene Cations
inferredcites →https://doi.org/10.1021/ja963834jopenalex-snapshot
Very Large Counteranion Modulation of Cationic Metallocene Polymerization Activity and Stereoregulation by a Sterically Congested (Perfluoroaryl)fluoroaluminate
inferredcites →https://doi.org/10.1021/ja990082vopenalex-snapshot
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inferredcites →https://doi.org/10.1021/ma202453uopenalex-snapshot
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inferredcites →https://doi.org/10.1021/om000573kopenalex-snapshot
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inferredcites →https://doi.org/10.1021/om030589lopenalex-snapshot
Bulky Siloxyaluminum Alkyls as Models for Al2Me6-Treated Silica Gel Surfaces. Characterization of a Dimethylaniline-Stabilized Dimethylaluminum Cation
inferredcites →https://doi.org/10.1021/om049139zopenalex-snapshot
rac-Me2Si(2-Me-4-t-Bu-C5H2)2ZrMe+: An Alkyl Zirconocenium Cation Stabilized by Steric Shielding against Interaction with Ancillary Ligands
inferredcites →https://doi.org/10.1021/om0606136openalex-snapshot
Synthesis and Ethylene Polymerization Capability of Metallocene-like Imido Titanium Dialkyl Compounds and Their Reactions with AliBu3
inferredcites →https://doi.org/10.1021/om1004447openalex-snapshot
The Chemistry of Catalyst Activation: The Case of Group 4 Polymerization Catalysts
inferredcites →https://doi.org/10.1021/om200369uopenalex-snapshot
Structure, Dynamics, and Polymerization Activity of Zirconocenium Ion Pairs Generated with Boron-C6F5 Compounds and Al2R6
inferredcites →https://doi.org/10.1021/om4002878openalex-snapshot
Probing the Structure of Methylalumoxane (MAO) by a Combined Chemical, Spectroscopic, Neutron Scattering, and Computational Approach
inferredcites →https://doi.org/10.1021/om800664popenalex-snapshot
Formation and Structures of Hafnocene Complexes in MAO- and AlBu i 3 /CPh 3 [B(C 6 F 5 ) 4 ]-Activated Systems
inferredcites →https://doi.org/10.1021/om9802313openalex-snapshot
Mechanistic Aspects of the Reactions of Bis(pentafluorophenyl)borane with the Dialkyl Zirconocenes Cp2ZrR2(R = CH3, CH2SiMe3, and CH2C6H5)
inferredcites →https://doi.org/10.1021/om980400jopenalex-snapshot
Reaction of AlR3 with [CPh3][B(C6F5)4]: Facile Degradation of [B(C6F5)4]- by Transient “[AlR2]+”
inferredcites →https://doi.org/10.1038/s41929-018-0224-0openalex-snapshot
Highly branched polyethylene oligomers via group IV-catalysed polymerization in very nonpolar media
inferredcites →https://doi.org/10.1039/a903788hopenalex-snapshot
New weakly coordinating counter anions for high activity polymerisation catalysts: [(C6F5)3B–CN–B(C6F5)3]− and [Ni{CNB(C6F5)3}4]2−
inferredcites →https://doi.org/10.1039/c9dt04896kopenalex-snapshot
C 1 -Symmetric Si-bridged (2-indenyl)(1-indenyl) ansa -metallocenes as efficient ethene/1-hexene copolymerization catalysts
inferredcites →https://doi.org/10.1063/1.1679012openalex-snapshot
Coulombic potential energy integrals and approximations
inferredcites →https://doi.org/10.1063/1.1998907openalex-snapshot
Systematically convergent basis sets for transition metals. I. All-electron correlation consistent basis sets for the 3d elements Sc–Zn
inferredcites →https://doi.org/10.1063/1.2335444openalex-snapshot
Basis set limit electronic excitation energies, ionization potentials, and electron affinities for the 3d transition metal atoms: Coupled cluster and multireference methods
inferredcites →https://doi.org/10.1063/1.2647019openalex-snapshot
Energy-consistent relativistic pseudopotentials and correlation consistent basis sets for the 4d elements Y–Pd
inferredcites →https://doi.org/10.1103/physrevlett.91.146401openalex-snapshot
Climbing the Density Functional Ladder: Nonempirical Meta–Generalized Gradient Approximation Designed for Molecules and Solids
inferredcites →https://doi.org/10.1149/1.2885016openalex-snapshot
Electrodeposition of Al–Mg Alloy Powders
inferredcites →https://doi.org/10.3390/polym12051005openalex-snapshot
An Integrated High Throughput Experimentation/Predictive QSAR Modeling Approach to ansa-Zirconocene Catalysts for Isotactic Polypropylene
inferredcites →https://doi.org/10.5860/choice.43-2825openalex-snapshot
Polypropylene handbook

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Chiral Templated Synthesis of Methylalumoxane and its Catalytic Properties in Alkene Oligomerization
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Chiral Templated Synthesis of Methylalumoxane and its Catalytic Properties in Alkene Oligomerization
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Improvement of catalytic activity for α ‐diimine nickel complex with active sites stabilized by bulky boron counterions at elevated temperature
inferred← citeshttps://doi.org/10.1002/cctc.202101918openalex-snapshot
Activation of Substituted Metallocene Catalysts Using Methylaluminoxane
inferred← citeshttps://doi.org/10.1002/cctc.202200578openalex-snapshot
Cocatalyst Effect in Transition Metal Catalyzed Ethylene Polymerization and Copolymerization
inferred← citeshttps://doi.org/10.1002/chem.202102463openalex-snapshot
Formation and Structure of Hydrolytic Methylaluminoxane Activators
inferred← citeshttps://doi.org/10.1002/cphc.202100268openalex-snapshot
Are Methylaluminoxane Activators Sheets?
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Ionization of Cp 2 ZrMe 2 and Lewis Bases by Methylaluminoxane: Computational Insights
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Sheet Models for Methylaluminoxane (MAO) Activators? A Theoretical Case Study involving rac ‐Me 2 Si(η 5 ‐C 9 H 6 ) 2 Zr (SBIZr) Complexes
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From Cages to Sheets: Computational Elucidation of Methylaluminoxane Structure and Reactivity
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Effect of Borate Co‐Catalyst on Ethylene‐Propylene Binary/Ternary Copoly‐Merization with Bisindenyl Zirconocene
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Effects of Catalyst Activation, Deactivation, and Active Site Physical Residential Environment on Ethylene− α ‐Olefin Elastomeric Copolymerization
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Alkylaluminum/Urea Hybrid Cocatalysts and Their Use in Iron‐Catalyzed Oligomerization of Ethylene
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Metallocene‐Catalyzed Ethylene–Norbornene Copolymerization Employing Triisobutylaluminum/Borate Synergistic Cocatalyst Systems: High‐Efficiency Synthesis and Property Modulation
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Research Progress of Iron Catalysts with N,N,N‐tridentate Ligands for Ethylene Polymerization
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Alkylaluminium/Borate systems for activation of metallocene catalysts in ethylene polymerization: ligand effects and reaction parameter optimization
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Synthesis of low-entangled UHMWiPP using Hf-pyridyl amido catalyst activated by trityl tetrakis (pentafluorophenyl) borate
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Role of organometallic complexes in olefin polymerization: a review report
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Chiral templated synthesis of methylalumoxane and its catalytic properties in alkene oligomerization
inferred← citeshttps://doi.org/10.1016/j.mcat.2022.112542openalex-snapshot
A competetive way to low-viscosity PAO base stocks via heterocene-catalyzed oligomerization of dec-1-ene
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Effects of ancillary ligands on molecular structure and catalytic properties of tridentate α-sulfonate-β-diimine nickel complexes toward ethylene (co)polymerization
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Control of coordination polymerization behavior by counter-anionic effects
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Methylaluminoxane’s Molecular Cousins : Well-Defined Aluminum-Alkyl Borate Salts as Cocatalysts for Olefin Polymerization
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c00906openalex-snapshot
Borate Salts of Aluminum-Alkyl Cations Stabilized by P-, O-, and C-Donors: Synthesis, Characterization and Application as Cocatalysts
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c03732openalex-snapshot
Ligand-Assisted Formation of Heterobimetallic Adducts of AlMe 3 and ZnMe 2 with Zr and Hf Salan Catalysts for Olefin Polymerization
inferred← citeshttps://doi.org/10.1021/acs.organomet.2c00440openalex-snapshot
Impact of Methylaluminoxane Oxidation on Ethylene Polymerization Using Ni Catalysts
inferred← citeshttps://doi.org/10.1021/acs.organomet.4c00459openalex-snapshot
Methyl-Branched Polyethylene Produced by Hafnocene Complexes Exhibiting Unconventional Dialkoxy Bridges
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Air-Stable Single-Component Pd-Catalysts for Vinyl-Addition Polymerization of Functionalized Norbornenes
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Impact of Labile Ligands on Catalyst Initiation and Chain Propagation in Ni-Catalyzed Ethylene/Acrylate Copolymerization
inferred← citeshttps://doi.org/10.1021/acscatal.5c05698openalex-snapshot
Mechanism of Action of MAO’s Molecular Cousin
inferred← citeshttps://doi.org/10.1021/acscentsci.1c00466openalex-snapshot
Active Sites in a Heterogeneous Organometallic Catalyst for the Polymerization of Ethylene
inferred← citeshttps://doi.org/10.1021/acsorginorgau.2c00020openalex-snapshot
Effect of Borate Cocatalysts toward Activity and Comonomer Incorporation in Ethylene Copolymerization by Half-Titanocene Catalysts in Methylcyclohexane
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Polymethylaluminoxane organic frameworks (sMAOF) – highly active supports for slurry phase ethylene polymerisation
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Rapid kinetic evaluation of homogeneous single-site metallocene catalysts and cyclic diene: how do the catalytic activity, molecular weight, and diene incorporation rate of olefins affect each other?
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Cocatalyst effects in Hf-catalysed olefin polymerization: taking well-defined Al–alkyl borate salts into account
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Elucidation of the nano-sized molecular structure of methylaluminoxane using synchrotron X-ray total scattering
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Al-alkyl borate salt cocatalysts for olefin polymerization: exploration of N-donor ligand variations
inferred← citeshttps://doi.org/10.1039/d5qi01957eopenalex-snapshot
Structure of the most stable methylaluminoxane anion [(MeAlO) 16 (Me 3 Al) 6 Me] − and its precursor
inferred← citeshttps://doi.org/10.1039/d6dt01509copenalex-snapshot
Rediscovering methylaluminoxane
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rac-Et(2-MeInd)2ZrMe2/Octylaluminum Aryloxide Catalysts in Homopolymerization and Copolymerization of Ethylene, Propylene, and 5-Ethylidene-2-Norbornene
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Olefin polymerization cocatalysts: Development, applications, and prospects
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Research progress and applications of novel perfluoroaryl borate in polymerization
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Syntheses of Silylene-Bridged Thiophene-Fused Cyclopentadienyl ansa-Metallocene Complexes for Preparing High-Performance Supported Catalyst
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Preparation of High-Purity Ammonium Tetrakis(pentafluorophenyl)borate for the Activation of Olefin Polymerization Catalysts
inferred← citeshttps://doi.org/10.3390/molecules27217164openalex-snapshot
Transition Metal–(μ-Cl)–Aluminum Bonding in α-Olefin and Diene Chemistry
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The Dimerization and Oligomerization of Alkenes Catalyzed with Transition Metal Complexes: Catalytic Systems and Reaction Mechanisms
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A Hydrocarbon Soluble, Molecular and “Complete” Al-Cocatalyst for High Temperature Olefin Polymerization
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MAO- and Borate-Free Activating Supports for Group 4 Metallocene and Post-Metallocene Catalysts of α-Olefin Polymerization and Oligomerization
inferred← citeshttps://doi.org/10.3390/polym16121689openalex-snapshot
Ammonium Tetrakis(pentafluorophenyl)borate: Preparation and Application in Olefin Coordination Polymerization as the Cocatalyst Compound
inferred← citeshttps://doi.org/10.3390/polym17010046openalex-snapshot
α-Olefin Oligomerization Mediated by Group 4 Metallocene Catalysts: An Extreme Manifestation of the Multisite Nature of Methylaluminoxane
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Promising route to aryl(polyfluoroorganyl)borates: aryltris(pentafluorophenyl)borates
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