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Discovery of Methylaluminoxane as Cocatalyst for Olefin Polymerization
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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Ethene/propene copolymerisation by [Me2C(3-RCp)(Flu)]ZrCl2/MAO (R = H, Me,isoPr,tertBu)
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Copolymerization of ethene with methyl acrylate and ethyl 10-undecenoate using a cationic palladium diimine catalyst
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Use of metallocenes in the polymerization-filling technique with production of polyolefin-based composites
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Polymerization of 1-hexene with bis[N-(3-tert-butylsalicylidene)phenylaminato]titanium(IV) dichloride using iBu3Al/Ph3CB(C6F5)4 as a cocatalyst
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Late Transition Metal Polymerization Catalysis
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Stereospecific α‐Olefin Polymerization with Heterogeneous Catalysts
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Das Mülheimer Normaldruck‐Polyäthylen‐Verfahren
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Zum Ablauf der Niederdruckpolymerisation der α‐Olefine. Komplexpolymerisation I
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Bildung von Poly(methyl‐methylen‐aluminium)
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Die stereospezifische Polymerisation von Propylen: Ein Überblick 25 Jahre nach ihrer Entdeckung
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Asymmetrische Oligomerisation von Propen und 1‐Buten mit einem Zirconocen/Aluminoxan‐Katalysator
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„Nicht‐koordinierende” Anionen: unterschätzte Liganden
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Stereospezifische Olefinpolymerisation mit chiralen Metallocenkatalysatoren
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Halogen‐Free Soluble Ziegler Catalysts for the Polymerization of Ethylene. Control of Molecular Weight by Choice of Temperature
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“Living Polymers” on Polymerization with Extremely Productive Ziegler Catalysts
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Polymerization of Propene and Butene with a Chiral Zirconocene and Methylalumoxane as Cocatalyst
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Cover Picture (Angew. Chem. Int. Ed. Engl. 10/1995)
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Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts
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Ethyleninsertion durch lösliche Ziegler‐Katalysatoren. Direkter Einblick durch reagierendes Ethylen‐13C mit Hilfe der 13C‐NMR‐Spektroskopie
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Cycloolefin‐copolymere: Eine neue klasse transparenter thermoplaste
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Preparation of nanopolyethylene wire with carbon nanotubes‐supported Cp2ZrCl2 catalyst
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Mehrfach durch Metalle substituierte Äthane
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Der Einfluß von Wasser auf die katalytische Aktivität von Bis(π‐cyclopentadienyl)titandichlorid‐Dimethylaluminiumchlorid zur Polymerisation von Äthylen
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Zur kinetik der niederdruckpolymerisation von äthylen mit löslichen Z IEGLER ‐katalysatoren
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Die Bildung von Dimetalloalkylenen, eine unvermeidliche Nebenreaktion homogener Z IEGLER ‐Katalysatoren
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Copolymerization of cycloalkenes with ethylene in presence of chiral zirconocene catalysts
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Trends in Polyolefin Chemistry
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Long‐Chain Branches in Syndiotactic Polypropene Induced by Vinyl Chloride
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Ethylene polymerization by supported vanadium catalyst. effect of carrier on activity and relationship between concentration of v(iii) and activity
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New polymers by homogenous zirconocene/aluminoxane catalysts
inferredcites →https://doi.org/10.1002/masy.19950890124openalex-snapshot
Stereospecific metallocene catalysts: Scope and limits of rational catalyst design
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Proposals for structure and effect of methylalumoxane based on mass balances and phase separation experiments
inferredcites →https://doi.org/10.1002/masy.200690041openalex-snapshot
Ansa‐Metallocenes by Intramolecular Ring Closure Reactions – Syntheses and Applications
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New Polyolefin Nanocomposites and Catalyst Supports Based on Organophilic Boehmites
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Neues über Ziegler–Natta–Katalyse
inferredcites →https://doi.org/10.1002/pola.20292openalex-snapshot
The discovery of metallocene catalysts and their present state of the art
inferredcites →https://doi.org/10.1007/bf00265329openalex-snapshot
Halogen-free soluble Ziegler catalysts with methylalumoxan as catalyst
inferredcites →https://doi.org/10.1007/s00396-006-1587-3openalex-snapshot
Polymer dispersions from catalytic polymerization in aqueous systems
inferredcites →https://doi.org/10.1007/s11244-008-9044-9openalex-snapshot
In-situ Polymerization of Olefins on Nanoparticles or Fibers by Metallocene Catalysts
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IUPAC international symposium on macromolecules
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Site selective ligand modification and tactic variation in polypropylene chains produced with metallocene catalysts
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Olefin polymer technologies—History and recent progress at The Dow Chemical Company
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Polymer support of “single-site” catalysts for heterogeneous olefin polymerization
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Mechanistic studies with homogeneous Ziegler-Natta catalysts
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ansa-Metallocene derivatives IV. Synthesis and molecular structures of chiral ansa-titanocene derivatives with bridged tetrahydroindenyl ligands
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Ziegler-Natta Catalysis
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Stereoselective Polymerization with Single-Site Catalysts
inferredcites →https://doi.org/10.1021/ar9501683openalex-snapshot
α-Agostic Interactions and Olefin Insertion in Metallocene Polymerization Catalysts
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Multinuclear Olefin Polymerization Catalysts
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Late-Metal Catalysts for Ethylene Homo- and Copolymerization
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Precise Control of Polyolefin Stereochemistry Using Single-Site Metal Catalysts
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Syndiospecific propylene polymerizations with Group IVB metallocenes
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Mechanisms of stereochemical control in propylene polymerizations with soluble Group 4B metallocene/methylalumoxane catalysts
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Bis-(cyclopentadienyl)-titanium Dichloride-Alkylaluminum Complexes as Soluble Catalysts for the Polymerization of Ethylene1,2
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Kinetics of Ethylene Polymerization Catalyzed by Bis-(cyclopentadienyl)-titanium Dichloride-Dimethylaluminum Chloride1
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CRYSTALLINE HIGH POLYMERS OF α-OLEFINS
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The microstructure of poly(cyclopentene) produced by polymerization of cyclopentene with homogeneous Ziegler-Natta catalysts
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Organometallic compounds of Group III. 52. Active sites for ethylene polymerization with titanium(IV) catalysts in homogeneous media: multinuclear NMR study of ion-pair equilibria and their relation to catalyst activity
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Alumoxanes as Cocatalysts in the Palladium-Catalyzed Copolymerization of Carbon Monoxide and Ethylene: Genesis of a Structure−Activity Relationship
inferredcites →https://doi.org/10.1039/b910542popenalex-snapshot
New application for metallocene catalysts in olefin polymerization
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Metal-catalysed olefin polymerisation into the new millennium: a perspective outlook
inferredcites →https://doi.org/10.1039/c1dt10086fopenalex-snapshot
Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects
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Catalytic Production of Olefin Block Copolymers via Chain Shuttling Polymerization
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Zur Kinetik der Reduktion des Mischkatalysatorsystems Bis-Cyclopentadienyl-Titan(IV)dichlorid/Diäthylaluminiumchlorid
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Chiral Templated Synthesis of Methylalumoxane and its Catalytic Properties in Alkene Oligomerization
inferred← citeshttps://doi.org/10.2139/ssrn.4824729openalex-extracted
Chiral Templated Synthesis of Methylalumoxane and its Catalytic Properties in Alkene Oligomerization
inferred← citeshttps://doi.org/10.1002/0471238961.1305200110011409.a01.pub2openalex-snapshot
Metallocene Catalysts
inferred← citeshttps://doi.org/10.1002/0471238961.1615122508011201.a01.pub2openalex-snapshot
Polybutadiene Rubber
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Mass Spectrometry of Organoaluminum Derivatives
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Polymerization and Selective Oligomerization of Alkenes
inferred← citeshttps://doi.org/10.1002/9781119364757.ch5openalex-snapshot
Chemical Interactions Between Polymer and Plasma
inferred← citeshttps://doi.org/10.1002/9781119390541.ch13openalex-snapshot
Oligomerization and Polymerization
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Aluminum: Organometallic Chemistry
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Aluminum‐Based Catalysis
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Polymerization and Copolymerization
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1,1‐Carbozirconation: Unusual Reaction of an Alkyne with a Methyl Zirconocene Cation and Subsequent Frustrated Lewis Pair Like Reactivity
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Silica‐Grafted Tris(neopentyl)aluminum: A Monomeric Aluminum Solid Co‐catalyst for Efficient Nickel‐Catalyzed Ethene Dimerization
inferred← citeshttps://doi.org/10.1002/ange.202508409openalex-snapshot
Evidence for Methylaluminoxane (MAO) Molecular Structure and Reactivity from Ultrahigh Magnetic Field 27 Al MAS NMR Spectroscopy Combined with DFT Calculations
inferred← citeshttps://doi.org/10.1002/anie.201307493openalex-snapshot
1,1‐Carbozirconation: Unusual Reaction of an Alkyne with a Methyl Zirconocene Cation and Subsequent Frustrated Lewis Pair Like Reactivity
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Silica‐Grafted Tris(neopentyl)aluminum: A Monomeric Aluminum Solid Co‐catalyst for Efficient Nickel‐Catalyzed Ethene Dimerization
inferred← citeshttps://doi.org/10.1002/anie.202508409openalex-snapshot
Evidence for Methylaluminoxane (MAO) Molecular Structure and Reactivity from Ultrahigh Magnetic Field 27 Al MAS NMR Spectroscopy Combined with DFT Calculations
inferred← citeshttps://doi.org/10.1002/app.40151openalex-snapshot
Influence of copolymer fraction composition in ultrahigh molecular weight polyethylene blends with ethylene/1‐hexene copolymers on material physical and tensile properties
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Effect of different additives and their mixtures on thermal stability of polyethylene synthesized using iron and titanocene hybrid catalysts
inferred← citeshttps://doi.org/10.1002/app.52000openalex-snapshot
In‐reactor blends based on ultrahigh molecular weight polyethylene: Effect of microstructure of modifying fraction on the morphology and viscoelastic behavior of blends
inferred← citeshttps://doi.org/10.1002/app.56878openalex-snapshot
Transition and Migration of Ziegler–Natta Catalyst System in Propylene Polymerization. I. Quantitative 1H NMR Analysis of the Extracts From Polypropylene Granules
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Recent Advancement in Ultra‐High Molecular Weight Polymers
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Transition and Migration of Ziegler–Natta Catalyst System in Propylene Polymerization. III . Comprehensive Analysis of the Extracts From Polypropylene Granules With Different Solvent Systems
inferred← citeshttps://doi.org/10.1002/cctc.201600200openalex-snapshot
Real‐time Analysis of a Working Triethylaluminium‐Modified Cr/Ti/SiO2 Ethylene Polymerization Catalyst with In Situ Infrared Spectroscopy
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Activation of Substituted Metallocene Catalysts Using Methylaluminoxane
inferred← citeshttps://doi.org/10.1002/cctc.202200578openalex-snapshot
Cocatalyst Effect in Transition Metal Catalyzed Ethylene Polymerization and Copolymerization
inferred← citeshttps://doi.org/10.1002/cctc.202300221openalex-snapshot
Role of Titanium in Ti/SiO2‐Supported Metallocene‐based Olefin Polymerization Catalysts. Part 1: Genesis of Active Sites and Catalytic Performance
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Water as an Activator for Palladium(II)‐Catalyzed Olefin Polymerization
inferred← citeshttps://doi.org/10.1002/chem.201405319openalex-snapshot
Mass Spectrometric Characterization of Methylaluminoxane‐Activated Metallocene Complexes
inferred← citeshttps://doi.org/10.1002/chem.201602674openalex-snapshot
Insight into Oxide‐Bridged Heterobimetallic Al/Zr Olefin Polymerization Catalysts
inferred← citeshttps://doi.org/10.1002/chem.201705458openalex-snapshot
Oxidation of Methylalumoxane Oligomers
inferred← citeshttps://doi.org/10.1002/chem.201801438openalex-snapshot
A Theoretical Outlook on the Stereoselectivity Origins of Isoselective Zirconocene Propylene Polymerization Catalysts
inferred← citeshttps://doi.org/10.1002/chem.202100271openalex-snapshot
Spectroscopic Studies of Synthetic Methylaluminoxane: Structure of Methylaluminoxane Activators
inferred← citeshttps://doi.org/10.1002/chem.202102463openalex-snapshot
Formation and Structure of Hydrolytic Methylaluminoxane Activators
inferred← citeshttps://doi.org/10.1002/chem.202300913openalex-snapshot
Covalent Organic Framework‐Supported Metallocene for Ethylene Polymerization
inferred← citeshttps://doi.org/10.1002/chem.202404642openalex-snapshot
Methylaluminoxane Reactivities and Anionic Structures: From Small Oligomers to Large Sheets
inferred← citeshttps://doi.org/10.1002/cjce.22773openalex-snapshot
Evaluation of catalyst leaching in silica supported zirconocene alumino hydride catalysts
inferred← citeshttps://doi.org/10.1002/cphc.201402298openalex-snapshot
Formation of Octameric Methylaluminoxanes by Hydrolysis of Trimethylaluminum and the Mechanisms of Catalyst Activation in Single‐Site α‐Olefin Polymerization Catalysis
inferred← citeshttps://doi.org/10.1002/cphc.201700827openalex-snapshot
Formation, Structure, and Composition of Methylaluminoxane
inferred← citeshttps://doi.org/10.1002/cphc.202100268openalex-snapshot
Are Methylaluminoxane Activators Sheets?
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Ionization of Cp 2 ZrMe 2 and Lewis Bases by Methylaluminoxane: Computational Insights
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Cages versus Sheets: A Critical Comparison in the Size Range Expected for Methylaluminoxane (MAO)
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Sheet Models for Methylaluminoxane (MAO) Activators? A Theoretical Case Study involving rac ‐Me 2 Si(η 5 ‐C 9 H 6 ) 2 Zr (SBIZr) Complexes
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Molecular Heterobimetallic Aluminoxanes and Aluminoxane Sulfides Containing Group 4 Metals
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Methylalumoxane – History, Production, Properties, and Applications
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Oxide‐Bridged Heterobimetallic Aluminum/Zirconium Catalysts for Ethylene Polymerization
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Controlling the Microstructure of Isotactic Polypropene by C2‐Symmetric Zirconocene Polymerization Catalysts: Influence of Alkyl Substituents on Regio‐ and Stereocontrol
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Interaction of Neutral Donors with Methylaluminoxane
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On the Nature of the Lewis Acidic Sites in “TMA‐Free” Phenol‐Modified Methylaluminoxane
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Catalytic Behavior of Half‐Metallocene Non‐Cp‐Type Group 4 Metal Complexes (M=Zr, Hf) with a Cyclooctatetraenyl Dianion during Olefin Polymerization
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Understanding Trends in 27 Al Chemical Shifts and Quadrupolar Coupling Constants in Chloroalkyl Aluminum [AlCl x (Me) 3 − x ] n = 1 or 2 Compounds
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Poly(ethylene)‐co‐Poly(norborn‐2‐ene) Prepared by Group IV Bisamido and Half‐Sandwich Amido Complexes with Pendant Aminoborane Groups: Vinyl Insertion vs Ring‐Opening Metathesis Polymerization
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Chemical Composition of Hexene‐Based Linear Low‐Density Polyethylene by Infrared Spectroscopy and Chemometrics
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Determination of Short Chain Branching in LLDPE by Rheology
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Ethylene Polymerization with a Hafnocene Dichloride Catalyst Using Trioctyl Aluminum and Borate: Polymerization Kinetics and Polymer Characterization
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New tethered ansa‐bridged zirconium catalysts: Insights into the “self‐immobilization” mechanism
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Synthesis of polyolefin‐block‐polystyrene through sequential coordination and anionic polymerizations
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{Cyclopentadienyl/Fluorenyl}‐Group 4 ansa ‐Metallocene Catalysts for Production of Tailor‐Made Polyolefins
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Olefin Polymerizations Oriented by Rational Designs of Group‐13 Compounds
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Cationic, Methylene-Bridged, Intramolecular Donor-Acceptor Systems Based on Zirconium and Hafnium and Phosphino-methanides
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Methylaluminoxane: Key Component for New Polymerization Catalysts
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Reaction Engineering of Polyolefins: The Role of Catalyst Supports in Ethylene Polymerization on Metallocene Catalysts
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Polyethylenes and Their Blends
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Effect of immobilization of titanocene catalyst in aralkyl imidazolium chloroaluminate media on performance of biphasic ethylene polymerization and polyethylene properties
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H2 effect in Chevron–Phillips ethylene trimerization catalytic system: an experimental and theoretical investigation
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Supported Single-Site Organometallic Catalysts for the Synthesis of High-Performance Polyolefins
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N-doped Metallocene Catalysts for Synthesis of High Quality Lubricant Base Oils from Fishcher–Tropsch Synthesized α-Olefin
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Porous organic polymer/MMT hybrid supports for efficient metallocene catalysts
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Alkylaluminium/Borate systems for activation of metallocene catalysts in ethylene polymerization: ligand effects and reaction parameter optimization
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Polyolefin-nanocomposites with special properties by in-situ polymerization
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The discovery and evolution of metallocene-based olefin polymerization catalysts
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Modified preparation of HDPE/clay nanocomposite by in situ polymerization using a metallocene catalyst
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In silico approaches for olefin polymerization using transition metal catalyst systems
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Advances in Metallocene Polymerization
inferred← citeshttps://doi.org/10.1016/bs.adomc.2019.08.001openalex-snapshot
Ion pairing in transition metal catalyzed olefin polymerization
inferred← citeshttps://doi.org/10.1016/j.apcata.2018.12.006openalex-snapshot
The catalytic behavior of heterocenes activated by TIBA and MMAO under a low Al/Zr ratios in 1-octene polymerization
inferred← citeshttps://doi.org/10.1016/j.ccr.2020.213515openalex-snapshot
Heterocycle-fused cyclopentadienyl metal complexes: Heterocene synthesis, structure and catalytic applications
inferred← citeshttps://doi.org/10.1016/j.ccr.2023.215122openalex-snapshot
The greener side of polymers in the light of d-block metal complexes as precatalysts
inferred← citeshttps://doi.org/10.1016/j.cej.2021.131750openalex-snapshot
Continuous synthesis of isobutylaluminoxanes in a compact and integrated approach
inferred← citeshttps://doi.org/10.1016/j.cej.2024.158798openalex-snapshot
Advanced stackable membrane microreactor for gas–liquid-solid reactions: Design, operation, and scale-up
inferred← citeshttps://doi.org/10.1016/j.cej.2026.179726openalex-snapshot
Boost the formation of active species in the constrained-geometry catalyst by the intermolecular TiO non-covalent interactions
inferred← citeshttps://doi.org/10.1016/j.cjche.2026.05.018openalex-snapshot
Efficiently Synthesis of Trimethylaluminum(TMA) from Triethylaluminium and Methyl Chloride: RSM Optimization and Mechanisms Insight
inferred← citeshttps://doi.org/10.1016/j.cjche.2026.07.028openalex-snapshot
Design of metallocene catalysts for enhanced ethylene/1-octene copolymerization performance via machine learning and DFT
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2020.110243openalex-snapshot
Dinuclear metallocene complexes for high-performance supported catalysts
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2022.111725openalex-snapshot
Ti-iminocarboxylate catalyzed polymerization of ethylene to highly crystalline, disentangled, ultrahigh molecular weight polyethylene
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2026.114762openalex-snapshot
Steric-bulk directed polymerization of ethylene to disentangled ultra-high molecular weight polyethylene
inferred← citeshttps://doi.org/10.1016/j.ica.2012.09.032openalex-snapshot
Novel titanocene derived from a partially alkylated s-indacene: Synthesis, characterization and comparative study with its zirconium analog
inferred← citeshttps://doi.org/10.1016/j.ica.2015.05.011openalex-snapshot
A new series of zirconium metallocenes derived from partially alkylated s-indacene with potential applications in the polymerization of ethylene
inferred← citeshttps://doi.org/10.1016/j.inoche.2026.117408openalex-snapshot
Fe/Mn-synergistically promoted alkyl exchange of triethylaluminium with chloromethane for trimethylaluminium synthesis
inferred← citeshttps://doi.org/10.1016/j.jcat.2014.02.006openalex-snapshot
Chlorodiethylaluminum supported on silica: A dinuclear aluminum surface species with bridging μ2-Cl-ligand as a highly efficient co-catalyst for the Ni-catalyzed dimerization of ethene
inferred← citeshttps://doi.org/10.1016/j.jcat.2014.06.013openalex-snapshot
Understanding the role of aluminum-based activators in single site iron catalysts for ethylene oligomerization
inferred← citeshttps://doi.org/10.1016/j.jcat.2017.08.016openalex-snapshot
Olefin polymerization on Cr(III)/SiO2: Mechanistic insights from the differences in reactivity between ethene and propene
inferred← citeshttps://doi.org/10.1016/j.jcat.2019.03.036openalex-snapshot
Exploring the benefits beyond the pre-reduction in methane of the Cr/SiO2 Phillips catalyst: The molecular structure of the Cr sites and their role in the catalytic performance
inferred← citeshttps://doi.org/10.1016/j.jmgm.2020.107626openalex-snapshot
The mechanism of the reaction between MAO and TMA: DFT study of the electronic structure and characterization of transition states for [AlOMe]6, [AlOMe]9 and [AlOMe]16 cages
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2012.11.040openalex-snapshot
Synthesis, characterization and styrene polymerization behavior of alkoxysilyl-substituted monocyclopentadienyltitanium(IV) complexes
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2014.09.009openalex-snapshot
Preparation of [bis(amido)-phosphine] and [amido-phosphine sulfide or oxide] hafnium and zirconium complexes for olefin polymerization
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2016.02.024openalex-snapshot
Influence of trimethylaluminum on kinetics of rac-Et(Ind)2ZrCl2/aluminoxane catalyzed ethylene polymerization
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2018.07.024openalex-snapshot
Bidentate and tridentate coordination modes of bis(3-methylindolyl)-2-pyridylmethane in complexes of aluminum and gallium: Structural characterization of bridging N-indolide in a dialuminum complex
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2019.04.027openalex-snapshot
Ansa-zirconocenes bearing 5-NR2-6-alkyl-4-hydrocarbyl-2-methylindenyl moieties: Synthesis, structure, stereoselective polymerization of propylene
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2022.122554openalex-snapshot
Bidentate and tridentate coordination modes of bis(3-methylindolyl)-2-(1-methylimidazolyl)methane in complexes of aluminum and gallium
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123310openalex-snapshot
Chiral templated synthesis of methylalumoxane and its catalytic properties in alkene oligomerization
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2026.124111openalex-snapshot
Sing-site-metallocene catalysts: The chemistry of catalyst activation, deactivation, cocatalyst, and Olefin polymerization
inferred← citeshttps://doi.org/10.1016/j.mcat.2019.110490openalex-snapshot
Effect of supported MAO cocatalysts in ethylene polymerization and ethylene/1-hexene copolymerization using Cp*TiCl2(O-2,6- Pr2C6H3) catalyst
inferred← citeshttps://doi.org/10.1016/j.mcat.2020.110872openalex-snapshot
Group 4 constrained geometry complexes for olefin (co)polymerisation
inferred← citeshttps://doi.org/10.1016/j.mcat.2021.111768openalex-snapshot
Chain and cluster models of methylaluminoxane as activators of zirconocene hydride, alkyl and metallacyclopropane intermediates in alkene transformations
inferred← citeshttps://doi.org/10.1016/j.mencom.2021.07.029openalex-snapshot
Alternative mechanistic interpretation for unconventional catalytic behaviour of triisobutylaluminium-activated heterocenes in ethylene polymerization
inferred← citeshttps://doi.org/10.1016/j.molcata.2015.11.016openalex-snapshot
Quantitative structure–property relationships in propene polymerization by zirconocenes with a rac-SiMe2[Ind]2 based ligand framework
inferred← citeshttps://doi.org/10.1016/j.molstruc.2024.138163openalex-snapshot
Synthesis of the bimetallic zirconium compound derived from unsubstituted as-indacene and its catalytic behavior on ethylene polymerization
inferred← citeshttps://doi.org/10.1016/j.polymer.2025.128394openalex-snapshot
Crystallization behavior and morphology of propylene-ethylene copolymers: tailoring properties by molecular catalysis
inferred← citeshttps://doi.org/10.1016/j.progpolymsci.2020.101290openalex-snapshot
Ultrahigh molecular weight polyethylene: Catalysis, structure, properties, processing and applications
inferred← citeshttps://doi.org/10.1016/j.progpolymsci.2023.101690openalex-snapshot
Control of coordination polymerization behavior by counter-anionic effects
inferred← citeshttps://doi.org/10.1016/j.progpolymsci.2026.102121openalex-snapshot
Organic-supported single-site catalysts for olefin polymerization
inferred← citeshttps://doi.org/10.1016/j.ssnmr.2015.04.002openalex-snapshot
Solid-state NMR studies of Ziegler–Natta and metallocene catalysts
inferred← citeshttps://doi.org/10.1016/j.susc.2016.06.001openalex-snapshot
Synergistic, reconstruction and bonding effects during the adsorption of internal electron donors and TiCl4 on MgCl2 surface: A periodic-DFT investigation
inferred← citeshttps://doi.org/10.1021/acs.accounts.6c00575openalex-snapshot
Methylaluminoxane’s Molecular Cousins : Well-Defined Aluminum-Alkyl Borate Salts as Cocatalysts for Olefin Polymerization
inferred← citeshttps://doi.org/10.1021/acs.iecr.5c01770openalex-snapshot
Impacts of Heat Treatment and Long-Term Storage on Methylaluminoxane Composition, Catalytic Activity, and Polyethylene Properties
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.0c00533openalex-snapshot
Reactivity Trends of Lewis Acidic Sites in Methylaluminoxane and Some of Its Modifications
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c03732openalex-snapshot
Ligand-Assisted Formation of Heterobimetallic Adducts of AlMe 3 and ZnMe 2 with Zr and Hf Salan Catalysts for Olefin Polymerization
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.8b03448openalex-snapshot
Polyanionic Ligand Platforms for Methyl- and Dimethylaluminum Arrays
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.9b00399openalex-snapshot
Selective Activation of CH Bonds in Polar Vinyl Olefins and Coupling of Ethylene to the Activated Carbon Atoms in Pentaruthenium Complexes
inferred← citeshttps://doi.org/10.1021/acs.jpcc.6c02794openalex-snapshot
Aggregation Effects on Methylaluminoxane-Activated Metallocene Catalysts
inferred← citeshttps://doi.org/10.1021/acs.macromol.3c01520openalex-snapshot
Primary Thickening in Nascent Single Crystals of High-Molecular-Weight trans-1,4-Polybutadiene
inferred← citeshttps://doi.org/10.1021/acs.macromol.4c03097openalex-snapshot
Solid-State Processing of In Situ Blended Prepolymer with Z–N Synthesized UHMWPE: Role of the Prepolymer
inferred← citeshttps://doi.org/10.1021/acs.macromol.5b02176openalex-snapshot
Copolymerizations of Norbornene and Tetracyclododecene with α-Olefins by Half-Titanocene Catalysts: Efficient Synthesis of Highly Transparent, Thermal Resistance Polymers
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c00636openalex-snapshot
Propylene–Ethylene Copolymers from Supported Metallocene Catalysts: A Route to Span Properties from Polypropylene to Polyethylene
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c00873openalex-snapshot
Covalent Organic Framework-Oriented Chain Growth for High-Performance Polyolefins
inferred← citeshttps://doi.org/10.1021/acs.macromol.6c00577openalex-snapshot
Composition, Molecular Weight, and Structure of Modified Methylaluminoxane (MMAO): Implications for Selective Ethylene Tetramerization with Cr/PNP Catalysts
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b00933openalex-snapshot
Activation of Cp 2 ZrX 2 (X = Me, Cl) by Methylaluminoxane As Studied by Electrospray Ionization Mass Spectrometry: Relationship to Polymerization Catalysis
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b01003openalex-snapshot
An Alternative Method for the Preparation of Trialkylaluminum-Depleted Modified Methylaluminoxane (dMMAO)
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b01356openalex-snapshot
Reactivity of Difunctional Polar Monomers and Ethylene Copolymerization: A Comprehensive Account
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b00590openalex-snapshot
Judicious Reduction of Supported Ti Catalyst Enables Access to Disentangled Ultrahigh Molecular Weight Polyethylene
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b01028openalex-snapshot
Atypical Multiple Site Behavior of Hafnocene Catalysts in Ethylene/1-Hexene Copolymerization Using Trioctylaluminum and Borate
inferred← citeshttps://doi.org/10.1021/acs.oprd.2c00072openalex-snapshot
Flow Toolkit for Measuring Reaction Enthalpy and Application to Highly Exothermic Synthesis of Alkylaluminoxanes
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00257openalex-snapshot
Synthesis of Cationic, Dimeric α-Diimine Nickel Hydride Complexes and Relevance to the Polymerization of Olefins
inferred← citeshttps://doi.org/10.1021/acs.organomet.1c00282openalex-snapshot
Heterobimetallic [Ti, Al] Complexes: Divergent Synthesis, Redox Properties, and Ethylene Polymerization Catalysis
inferred← citeshttps://doi.org/10.1021/acs.organomet.2c00440openalex-snapshot
Impact of Methylaluminoxane Oxidation on Ethylene Polymerization Using Ni Catalysts
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00303openalex-snapshot
Synthesis of Titanium Complexes Containing an Amine Triphenolate Ligand of the Type [TiX{(O-2,4-R2C6H2)-6-CH2}3N] and the Ti–Al Heterobimetallic Complexes with AlMe3: Effect of a Terminal Donor Ligand in Ethylene Polymerization
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00394openalex-snapshot
Toward Controlling the Metallocene/Methylaluminoxane-Catalyzed Olefin Polymerization Process by a Computational Approach
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00779openalex-snapshot
1,2-Azaborolyl-Ligated Titanium(IV) Half-Metallocenes: Synthesis, Characterization, and Catalytic Activity in Ethylene Polymerization
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00965openalex-snapshot
Discrete Ionic Complexes of Highly Isoselective Zirconocenes. Solution Dynamics, Trimethylaluminum Adducts, and Implications in Propylene Polymerization
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b01027openalex-snapshot
Synthesis and Structural Analysis of Zr–Al Heterobimetallic Complexes, [ZrX{(O-2,4-tBu2C6H2-6-CH2)3(μ2-O-2,4-tBu2-C6H2-6-CH2)}N][R2Al(μ2-OiPr)] [X = Cl, Et, iBu; R = Me, Et, iBu]. Unique Reactivity of the iBu Complex
inferred← citeshttps://doi.org/10.1021/acs.organomet.5c00195openalex-snapshot
Little MAO: Isolation of an {Al 4 } Methylalumoxane Species from the Reaction of Trimethylaluminum with Water
inferred← citeshttps://doi.org/10.1021/acs.organomet.5c00254openalex-snapshot
Correlating the TMA Content with Structural Evolution and Catalytic Behavior of dMAO in Ethylene Polymerization
inferred← citeshttps://doi.org/10.1021/acs.organomet.6b00200openalex-snapshot
Synthesis of (Imido)Vanadium(V) Dichloride Complexes Containing Anionic N-Heterocyclic Carbenes That Contain a Weakly Coordinating Borate Moiety: New MAO-Free Ethylene Polymerization Catalysts
inferred← citeshttps://doi.org/10.1021/acs.organomet.6b00814openalex-snapshot
Ultrarigid Indenyl-based Hafnocene Complexes for the Highly Isoselective Polymerization of Propene: Tunable Polymerization Performance Adopting Various Sterically Demanding 4-Aryl Substituents
inferred← citeshttps://doi.org/10.1021/acs.organomet.7b00641openalex-snapshot
Distinctive Stereochemically Linked Cooperative Effects in Bimetallic Titanium Olefin Polymerization Catalysts
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00220openalex-snapshot
How Close Is Too Close? Polymerization Behavior and Monomer-Dependent Reorganization of a Bimetallic Salphen Organotitanium Catalyst
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00393openalex-snapshot
Catalyst Mileage in Olefin Polymerization: The Peculiar Role of Toluene
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00841openalex-snapshot
Synthesis of Half-Titanocenes Containing Anionic N-Heterocyclic Carbenes That Contain a Weakly Coordinating Borate Moiety, Cp′TiX2(WCA-NHC), and Their Use as Catalysts for Ethylene (Co)polymerization
inferred← citeshttps://doi.org/10.1021/acs.organomet.9b00253openalex-snapshot
Zirconocene-Catalyzed Polymerization of α-Olefins: When Intrinsic Higher Activity Is Flawed by Rapid Deactivation
inferred← citeshttps://doi.org/10.1021/acs.organomet.9b00397openalex-snapshot
Nickel Catalysts Activated by rGO Modified with a Boron Lewis Acid To Produce rGO-Hyperbranched PE Nanocomposites
inferred← citeshttps://doi.org/10.1021/acs.organomet.9b00638openalex-snapshot
Solution XAS Analysis for Exploring Active Species in Syndiospecific Styrene Polymerization and 1-Hexene Polymerization Using Half-Titanocene–MAO Catalysts: Significant Changes in the Oxidation State in the Presence of Styrene
inferred← citeshttps://doi.org/10.1021/acsapm.6c02757openalex-snapshot
Polyolefins Derived from 5-Vinyl-2-norbornene as Platforms for Functional Polymers
inferred← citeshttps://doi.org/10.1021/acscatal.0c05696openalex-snapshot
Methylaluminoxane’s Molecular Cousin: A Well-defined and “Complete” Al-Activator for Molecular Olefin Polymerization Catalysts
inferred← citeshttps://doi.org/10.1021/acscatal.2c01676openalex-snapshot
Alkane-Soluble Bis[tris(alkylphenyl)carbenium] Diborate Cocatalyst for Olefin Polymerizations
inferred← citeshttps://doi.org/10.1021/acscatal.4c01061openalex-snapshot
Ethylene Polymerization over Metal–Organic Framework-Supported Zirconocene Complexes
inferred← citeshttps://doi.org/10.1021/acscatal.5b00788openalex-snapshot
Pyridylamido Bi-Hafnium Olefin Polymerization Catalysis: Conformationally Supported Hf···Hf Enchainment Cooperativity
inferred← citeshttps://doi.org/10.1021/acscatal.5b01697openalex-snapshot
DFT-D Investigation of Active and Dormant Methylaluminoxane (MAO) Species Grafted onto a Magnesium Dichloride Cluster: A Model Study of Supported MAO
inferred← citeshttps://doi.org/10.1021/acscatal.5c05698openalex-snapshot
Mechanism of Action of MAO’s Molecular Cousin
inferred← citeshttps://doi.org/10.1021/acscatal.6b03135openalex-snapshot
C–H Activation and Olefin Insertion as Sources of Multiple Sites in Olefin Polymerization Catalyzed by Cp Alkyl Hf(IV) Complexes
inferred← citeshttps://doi.org/10.1021/acscatal.9b00076openalex-snapshot
BHT-Modified MAO: Cage Size Estimation, Chemical Counting of Strongly Acidic Al Sites, and Activation of a Ti-Phosphinimide Precatalyst
inferred← citeshttps://doi.org/10.1021/acsmacrolett.0c00664openalex-snapshot
100th Anniversary of Macromolecular Science Viewpoint: The Past, Present, and Future of Stereocontrolled Vinyl Polymerization
inferred← citeshttps://doi.org/10.1021/acsmacrolett.5b00562openalex-snapshot
Insertion Copolymerization of Difunctional Polar Vinyl Monomers with Ethylene
inferred← citeshttps://doi.org/10.1021/acsomega.9b00709openalex-snapshot
Neutral Imino-Methyl Benzenesulfonate-Ligated Pd(II) Complexes and Implications in Ethylene Polymerization
inferred← citeshttps://doi.org/10.1021/acsorginorgau.2c00020openalex-snapshot
Effect of Borate Cocatalysts toward Activity and Comonomer Incorporation in Ethylene Copolymerization by Half-Titanocene Catalysts in Methylcyclohexane
inferred← citeshttps://doi.org/10.1021/cs5016436openalex-snapshot
Are Solvent and Dispersion Effects Crucial in Olefin Polymerization DFT Calculations? Some Insights from Propylene Coordination and Insertion Reactions with Group 3 and 4 Metallocenes
inferred← citeshttps://doi.org/10.1021/ic4010054openalex-snapshot
A Synthetic Route to a Molecular Galloxane Dihydroxide and Its Group 4 Heterobimetallic Compounds
inferred← citeshttps://doi.org/10.1021/ja4039505openalex-snapshot
Synthesis, Characterization, and Heterobimetallic Cooperation in a Titanium–Chromium Catalyst for Highly Branched Polyethylenes
inferred← citeshttps://doi.org/10.1021/jacs.1c01725openalex-snapshot
Strongly Polarized Iridiumδ−–Aluminumδ+ Pairs: Unconventional Reactivity Patterns Including CO2 Cooperative Reductive Cleavage
inferred← citeshttps://doi.org/10.1021/jacs.1c10888openalex-snapshot
Controlled Synthesis of Well-Defined Polyaminoboranes on Scale Using a Robust and Efficient Catalyst
inferred← citeshttps://doi.org/10.1021/jacs.8b09039openalex-snapshot
Polyolefin–Polar Block Copolymers from Versatile New Macromonomers
inferred← citeshttps://doi.org/10.1021/ma501892vopenalex-snapshot
The Dynamic Equilibrium Between (AlOMe) n Cages and (AlOMe) n ·(AlMe 3 ) m Nanotubes in Methylaluminoxane (MAO): A First-Principles Investigation
inferred← citeshttps://doi.org/10.1021/om3008635openalex-snapshot
Effect of Terminal Aryloxo Ligands in Ethylene Polymerization Using Titanatranes of the Type, [Ti(OAr){(O-2,4-R2C6H2)-6-CH2}3N]: Synthesis and Structural Analysis of the Heterobimetallic Complexes of Titanatranes with AlMe3
inferred← citeshttps://doi.org/10.1021/om300957kopenalex-snapshot
Old and New C 1 -Symmetric Group 4 Metallocenes {(R 1 R 2 C)-(R 2′ R 3′ R 6′ R 7′ -Flu)(3-R 3 -5-R 4 -C 5 H 2 )}ZrCl 2 : From Highly Isotactic Polypropylenes to Vinyl End-Capped Isotactic-Enriched Oligomers
inferred← citeshttps://doi.org/10.1021/om3010977openalex-snapshot
Characterization of Isobutylaluminoxanes by Electrospray Ionization Mass Spectrometry
inferred← citeshttps://doi.org/10.1021/om400256fopenalex-snapshot
Mass Spectrometric Characterization of Methylaluminoxane
inferred← citeshttps://doi.org/10.1021/om400899gopenalex-snapshot
Preparation of Phosphine-Amido Hafnium and Zirconium Complexes for Olefin Polymerization
inferred← citeshttps://doi.org/10.1038/s41428-020-0325-xopenalex-snapshot
Precise control of coordination polymerization via the modification of methylaluminoxane (MAO)
inferred← citeshttps://doi.org/10.1038/s41428-021-00507-wopenalex-snapshot
Removal of mononuclear alkylaluminum species in aluminoxane using a crosslinked polymer bearing bulky phenoxy groups
inferred← citeshttps://doi.org/10.1039/c3dt00041aopenalex-snapshot
Probing the interactions between all components of the catalytic pool for homogeneous olefin polymerisation by diffusion NMR spectroscopy
inferred← citeshttps://doi.org/10.1039/c3dt51172copenalex-snapshot
Synthesis, structural analysis of the hetero-bimetallic complexes MMe[(O-2,4-tBu2C6H2-6-CH2)2(μ2-O-2,4-tBu2C6H2-6-CH2)N][Me2Al(μ2-OiPr)] [M = Zr, Hf] and their use in catalysis for ethylene polymerisation
inferred← citeshttps://doi.org/10.1039/c3py00319aopenalex-snapshot
Revisiting the long-chain branch formation mechanism in metallocene catalyzed polyethylenes
inferred← citeshttps://doi.org/10.1039/c4dt00997eopenalex-snapshot
Preparation of ansa-metallocenes for production of poly(α-olefin) lubricants
inferred← citeshttps://doi.org/10.1039/c4dt01122hopenalex-snapshot
High temperature ethylene polymerization catalyzed by titanium( iv ) complexes with tetradentate aminophenolate ligands in cis-O, N, N chelating mode
inferred← citeshttps://doi.org/10.1039/c4dt03683bopenalex-snapshot
Preparation of octahydro- and tetrahydro-[1,10]phenanthroline zirconium and hafnium complexes for olefin polymerization
inferred← citeshttps://doi.org/10.1039/c5cp04109kopenalex-snapshot
Grafting trimethylaluminum and its halogen derivatives on silica: general trends for 27 Al SS-NMR response from first principles calculations
inferred← citeshttps://doi.org/10.1039/c5dt01203aopenalex-snapshot
A chromium precursor for the Phillips ethylene trimerization catalyst: (2-ethylhexanoate) 2 CrOH
inferred← citeshttps://doi.org/10.1039/c5dt01367dopenalex-snapshot
Alternative aluminum-based cocatalysts for the iron-catalyzed oligomerization of ethylene
inferred← citeshttps://doi.org/10.1039/c5ra27797copenalex-snapshot
Synthesis of ultrahigh molecular weight polymers by homopolymerisation of higher α-olefins catalysed by aryloxo-modified half-titanocenes
inferred← citeshttps://doi.org/10.1039/c5sc00051copenalex-snapshot
Electrophilic bis-fluorophosphonium dications: Lewis acid catalysts from diphosphines
inferred← citeshttps://doi.org/10.1039/c6cp04260kopenalex-snapshot
Computational prediction and analysis of the 27 Al solid-state NMR spectrum of methylaluminoxane (MAO) at variable temperatures and field strengths
inferred← citeshttps://doi.org/10.1039/c6dt02449aopenalex-snapshot
Aluminum alkoxide, amide and halide complexes supported by a bulky dipyrromethene ligand: synthesis, characterization, and preliminary ε-caprolactone polymerization activity
inferred← citeshttps://doi.org/10.1039/c6ra11501bopenalex-snapshot
Efficient copolymerization of ethylene with norbornene or its derivatives using half-metallocene zirconium( iv ) catalysts
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