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Advances in C–CN Bond Formation via C–H Bond Activation

https://doi.org/10.1021/acscatal.6b01632

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Organometallic alkane CH activation

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Cyanation of indoles with benzyl cyanide as the cyanide anion surrogate

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Pd(OAc)2-catalyzed C–H activation of indoles: a facile synthesis of 3-cyanoindoles

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Direct oxidative cyanation of tertiary amines promoted by in situ generated hypervalent iodine(III)-CN intermediate

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Tetrahedron report number 163

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Radical reactions of arenediazonium ions: An easy entry into the chemistry of the aryl radical

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Tropylium Ion Mediated α-Cyanation of Amines

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Iron catalyzed oxidative cyanation of tertiary amines

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Gold-complexes catalyzed oxidative α-cyanation of tertiary amines

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inferred← citeshttps://doi.org/10.1002/anie.201713109openalex-snapshot

Mechanochemical Activation of Iron Cyano Complexes: A Prebiotic Impact Scenario for the Synthesis of α‐Amino Acid Derivatives

inferred← citeshttps://doi.org/10.1002/anie.201807455openalex-snapshot

Site‐Selective Remote Radical C−H Functionalization of Unactivated C−H Bonds in Amides Using Sulfone Reagents

inferred← citeshttps://doi.org/10.1002/anie.201807735openalex-snapshot

Straightforward α‐Amino Nitrile Synthesis Through Mo(CO)6‐Catalyzed Reductive Functionalization of Carboxamides

inferred← citeshttps://doi.org/10.1002/anie.201809411openalex-snapshot

Catalytic Promiscuity of Galactose Oxidase: A Mild Synthesis of Nitriles from Alcohols, Air, and Ammonia

inferred← citeshttps://doi.org/10.1002/anie.202010735openalex-snapshot

Synthesis of Nitrile Bearing Acyclic Quaternary Centers through Co(III)‐Catalyzed Sequential C−H Bond Addition to Dienes and N‐Cyanosuccinimide

inferred← citeshttps://doi.org/10.1002/anie.202108352openalex-snapshot

Electrochemical Synthesis of Glycine from Oxalic Acid and Nitrate

inferred← citeshttps://doi.org/10.1002/anie.202412552openalex-snapshot

6‐Hydroxy Picolinohydrazides Promoted Cu(I)‐Catalyzed Hydroxylation Reaction in Water: Machine‐Learning Accelerated Ligands Design and Reaction Optimization

inferred← citeshttps://doi.org/10.1002/anie.202414689openalex-snapshot

Nickel‐Catalyzed Reductive Hydrolysis of Nitriles to Alcohols

inferred← citeshttps://doi.org/10.1002/aoc.4107openalex-snapshot

Immobilization of nickel ions onto the magnetic nanocomposite based on cross‐linked melamine groups: Effective heterogeneous catalyst for N ‐Arylation of Arylboronic acids

inferred← citeshttps://doi.org/10.1002/aoc.6340openalex-snapshot

Recent advances in the rhodium‐catalyzed cyanation reactions

inferred← citeshttps://doi.org/10.1002/asia.202001219openalex-snapshot

Co(III), Rh(III) & Ir(III)‐Catalyzed Direct C−H Alkylation/Alkenylation/Arylation with Carbene Precursors

inferred← citeshttps://doi.org/10.1002/asia.70176openalex-snapshot

Recent Advances in the Synthesis of Nitrile Compounds Utilizing K 4 [Fe(CN) 6 ]: Mechanistic Studies and Applications

inferred← citeshttps://doi.org/10.1002/asia.71005openalex-snapshot

Precise Introduction of Small Functional Group (NH 2 , OH, CH 3 , CN, F, CF 3 ) in Organic Molecules via Direct C–H Activation

inferred← citeshttps://doi.org/10.1002/cctc.70947openalex-snapshot

Manganese‐Catalyzed Selective Hydration of Nitriles to Primary Amides: Experimental and Theoretical Studies

inferred← citeshttps://doi.org/10.1002/chem.201604621openalex-snapshot

Synergistic Heterobimetallic Manifold for Expedient Manganese(I)‐Catalyzed C−H Cyanation

inferred← citeshttps://doi.org/10.1002/chem.201703931openalex-snapshot

C−H Cyanation of 6‐Ring N‐Containing Heteroaromatics

inferred← citeshttps://doi.org/10.1002/chem.201704178openalex-snapshot

Pd‐Catalyzed Cyanation of (Hetero)Aryl Halides by Using Biphosphine Ligands

inferred← citeshttps://doi.org/10.1002/chem.201801746openalex-snapshot

C(sp 3 )−H Cyanation Promoted by Visible‐Light Photoredox/Phosphate Hybrid Catalysis

inferred← citeshttps://doi.org/10.1002/chem.202001368openalex-snapshot

Para ‐Selective Cyanation of Arenes by H‐Bonded Template

inferred← citeshttps://doi.org/10.1002/chem.202300217openalex-snapshot

Iron‐Catalyzed Deoxynitrogenation of Carboxylic Acids with Cyanamides to Access Nitriles

inferred← citeshttps://doi.org/10.1002/chem.202302620openalex-snapshot

Late‐Stage C−H Activation of Drug (Derivative) Molecules with Pd(ll) Catalysis

inferred← citeshttps://doi.org/10.1002/chem.202502629openalex-snapshot

Efficient, Functional Group‐Tolerant, and Catalyst‐Free Nitrile Formation from Aldehydes

inferred← citeshttps://doi.org/10.1002/chin.201645215openalex-snapshot

ChemInform Abstract: Advances in C—CN Bond Formation via C—H Bond Activation

inferred← citeshttps://doi.org/10.1002/cjoc.201800334openalex-snapshot

Copper‐Mediated Cyanation of Aryl C—H Bond with Removable Bidenate Auxiliary Using Acetonitrile as the Cyano Source

inferred← citeshttps://doi.org/10.1002/ejoc.201700383openalex-snapshot

SeO2‐Mediated One‐Pot Synthesis of 3‐Cyanofurans from 3‐Oxo‐3‐arylpropanenitriles and Substituted Acetaldehydes

inferred← citeshttps://doi.org/10.1002/ejoc.201700546openalex-snapshot

Amides as Weak Coordinating Groups in Proximal C–H Bond Activation

inferred← citeshttps://doi.org/10.1002/ejoc.201701476openalex-snapshot

Rhodium‐Catalyzed ortho‐Cyanation of 2‐Aryl‐1,2,3‐triazole: An Alternative Approach to Suvorexant

inferred← citeshttps://doi.org/10.1002/ejoc.201900909openalex-snapshot

An Insight into Nitromethane as an Organic Nitrile Alternative Source towards the Synthesis of Aryl Nitriles

inferred← citeshttps://doi.org/10.1002/ejoc.201901364openalex-snapshot

Decyanative Cross‐Coupling of Cyanopyrimidines with O‐, S‐, and N‐Nucleophiles: A Route to Alkoxylpyrimidines, Aminopyrimidines and Alkylthiopyrimidines

inferred← citeshttps://doi.org/10.1002/ejoc.202100348openalex-snapshot

Electrochemical Oxidative C−H Cyanation of Quinoxalin‐2(1H)‐ones with TMSCN

inferred← citeshttps://doi.org/10.1002/ejoc.202301135openalex-snapshot

Three‐Component Reactions of 2,2,2‐Trifluoroethyl Ketones, Aryl Azides and Aqueous Ammonia for the Synthesis of 4‐Cyano‐1,2,3‐triazoles

inferred← citeshttps://doi.org/10.1002/jlcr.3630openalex-snapshot

New trends and applications in cyanation isotope chemistry

inferred← citeshttps://doi.org/10.1002/slct.202500936openalex-snapshot

NiFeB Hydroxide with Modulated Active Sites for Electrocatalytic Benzylamine Oxidation

inferred← citeshttps://doi.org/10.1002/smll.202411523openalex-snapshot

Unlocking Efficient Electrosynthesis of α‐Amino Acids: Adsorption Geometry Modulation and Electronic Structure Reconstruction in the Ag/Cu Bimetallic System

inferred← citeshttps://doi.org/10.1002/smll.73507openalex-snapshot

Synergistic Defect and Hole Engineering in K–Doped Cyano–Rich Porous Graphitic Carbon Nitride to Boost Photocatalytic Hydrogen Peroxide Production

inferred← citeshttps://doi.org/10.1002/tcr.202000066openalex-snapshot

‐Aminonitriles: From Sustainable Preparation to Applications in Natural Product Synthesis

inferred← citeshttps://doi.org/10.1002/tcr.202200228openalex-snapshot

1,3‐Diynes: A Versatile Precursor in Transition‐Metal Catalyzed (Mediated) C−H Functionalizations

inferred← citeshttps://doi.org/10.1007/s10562-021-03779-2openalex-snapshot

Zinc Oxide/Graphene Oxide as a Robust Active Catalyst for Direct Oxidative Synthesis of Nitriles from Alcohols in Water

inferred← citeshttps://doi.org/10.1007/s11426-023-1653-3openalex-snapshot

Dual ligands relay-promoted transformation of unstrained ketones to polyfluoroarenes and nitriles

inferred← citeshttps://doi.org/10.1016/j.cclet.2021.04.018openalex-snapshot

Transition-metal-switchable divergent synthesis of nitrile-containing pyrazolo[1,5-a]pyridines and indolizines

inferred← citeshttps://doi.org/10.1016/j.chempr.2018.09.027openalex-snapshot

Palladium-Catalyzed Late-Stage Direct Arene Cyanation

inferred← citeshttps://doi.org/10.1016/j.jcat.2021.01.003openalex-snapshot

Iron-catalyzed reductive strecker reaction

inferred← citeshttps://doi.org/10.1016/j.jechem.2022.02.054openalex-snapshot

Recent developments in electrosynthesis of nitriles and electrocatalytic cyanations

inferred← citeshttps://doi.org/10.1016/j.mcat.2020.111313openalex-snapshot

Facile dehydration of primary amides to nitriles catalyzed by lead salts: The anionic ligand matters

inferred← citeshttps://doi.org/10.1016/j.mcat.2022.112576openalex-snapshot

Hemin-catalyzed controlled oxidative cyanation of secondary amine for the synthesis of α-aminonitriles and α-iminonitriles

inferred← citeshttps://doi.org/10.1016/j.molliq.2019.112157openalex-snapshot

Metal-based surface active ionic liquids: Self-assembling characteristics and C C bond functionalization of tertiary amines with TMSCN in aqueous micellar solutions

inferred← citeshttps://doi.org/10.1016/j.tet.2018.01.005openalex-snapshot

Strecker reaction and α-amino nitriles: Recent advances in their chemistry, synthesis, and biological properties

inferred← citeshttps://doi.org/10.1016/j.tet.2020.131388openalex-snapshot

RETRACTED: Metal-catalyzed cyanation of aromatic hydrocarbon with less toxic nitriles as a cyano source

inferred← citeshttps://doi.org/10.1016/j.tet.2021.132313openalex-snapshot

Primary amides: Sustainable weakly coordinating groups in transition metal-catalyzed C–H bond functionalization reactions

inferred← citeshttps://doi.org/10.1016/j.tetlet.2018.07.030openalex-snapshot

Redox-neutral C–H cyanation of tetrahydroisoquinolines under photoredox catalysis

inferred← citeshttps://doi.org/10.1016/j.tetlet.2021.153062openalex-snapshot

KSeCN as an efficient cyanide source for the one-step synthesis of imino-1-oxoisoindolines via copper-promoted C–H activation

inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00507openalex-snapshot

3d Transition Metals for C–H Activation

inferred← citeshttps://doi.org/10.1021/acs.jcim.4c02136openalex-snapshot

Mechanisms of C(sp3)-H Functionalization of Acetonitrile or Acetone with Alkynes: A DFT Investigation

inferred← citeshttps://doi.org/10.1021/acs.joc.0c01386openalex-snapshot

Rh(III)-Catalyzed C–H Cyanation of 2H-Indazole with N-Cyano-N-phenyl-p-toluenesulfonamide

inferred← citeshttps://doi.org/10.1021/acs.joc.0c02642openalex-snapshot

Iron-Catalyzed α-C–H Cyanation of Simple and Complex Tertiary Amines

inferred← citeshttps://doi.org/10.1021/acs.joc.0c03026openalex-snapshot

Electrochemical Oxidative Regioselective C–H Cyanation of Imidazo[1,2- a ]pyridines

inferred← citeshttps://doi.org/10.1021/acs.joc.1c01631openalex-snapshot

Construction of CF3-Functionalized Fully Substituted Benzonitriles through Rauhut–Currier Reaction Initiated [3 + 3] Benzannulation

inferred← citeshttps://doi.org/10.1021/acs.joc.1c02498openalex-snapshot

Synthesis of Unsymmetrical Diarylfumaronitriles via Tandem Michael Addition and Oxidation under K3Fe(CN)6/O2 System

inferred← citeshttps://doi.org/10.1021/acs.joc.1c02835openalex-snapshot

KOtBu-Mediated Reductive Cyanation of Tertiary Amides for Synthesis of α-Aminonitriles

inferred← citeshttps://doi.org/10.1021/acs.joc.2c01703openalex-snapshot

Intermolecular C–H Aminocyanation of Indoles via Copper–iodine Cocatalyzed Tandem C–N/C–C Bond Formation

inferred← citeshttps://doi.org/10.1021/acs.joc.2c02050openalex-snapshot

Chemoselective α-Alkylation and α-Olefination of Arylacetonitriles with Alcohols via Iron-Catalyzed Borrowing Hydrogen and Dehydrogenative Coupling

inferred← citeshttps://doi.org/10.1021/acs.joc.3c01431openalex-snapshot

Palladium-Catalyzed Direct C(sp2)–H Cyanomethylation of Arylamides using Chloroacetonitrile

inferred← citeshttps://doi.org/10.1021/acs.joc.3c02085openalex-snapshot

Visible Light-Enhanced [3 + 2] Cycloaddition of N,N-Disubstituted Hydrazines with Organo-Cyanamides: Access to Polysubstituted 1,2,4-Triazol-3-amines

inferred← citeshttps://doi.org/10.1021/acs.joc.4c00281openalex-snapshot

Metal-Free Cyanation of gem-Difluoroalkenes via Azide-Mediated C–C Double Bond Fragmentation

inferred← citeshttps://doi.org/10.1021/acs.joc.4c02945openalex-snapshot

An Acetic Acid-Promoted Strecker Type Reaction of N,N-Disubstituted Aminomalononitriles: An Efficient Way for the Construction of α-Aminonitriles

inferred← citeshttps://doi.org/10.1021/acs.joc.6b02731openalex-snapshot

Palladium-Catalyzed, ortho-Selective C–H Halogenation of Benzyl Nitriles, Aryl Weinreb Amides, and Anilides

inferred← citeshttps://doi.org/10.1021/acs.joc.6b03036openalex-snapshot

Rhodium-Catalyzed Direct Bis-cyanation of Arylimidazo[1,2-α]pyridine via Double C–H Activation

inferred← citeshttps://doi.org/10.1021/acs.joc.6c00578openalex-snapshot

Pd-Catalyzed Cyclization and Cyanation of Alkynone O -Methyloximes with tert -Butyl Isocyanide

inferred← citeshttps://doi.org/10.1021/acs.joc.6c01169openalex-snapshot

Photoinduced Nickel-Catalyzed Cascade Cyclization and Cyanation of Functionalized Alkynes

inferred← citeshttps://doi.org/10.1021/acs.joc.7b02021openalex-snapshot

Metal-Free Aerobic Oxidative Cyanation of Tertiary Amines: Azobis(isobutyronitrile) (AIBN) as a Sole Cyanide Source

inferred← citeshttps://doi.org/10.1021/acs.joc.7b02133openalex-snapshot

Access to Cyano-Containing Isoxazolines via Copper-Catalyzed Domino Cyclization/Cyanation of Alkenyl Oximes

inferred← citeshttps://doi.org/10.1021/acs.joc.8b01763openalex-snapshot

Nickel-Catalyzed Cyanation of Benzylic and Allylic Pivalate Esters

inferred← citeshttps://doi.org/10.1021/acs.joc.8b02191openalex-snapshot

Metal-Free Regioselective Monocyanation of Hydroxy-, Alkoxy-, and Benzyloxyarenes by Potassium Thiocyanate and Silica Sulfuric Acid as a Cyanating Agent

inferred← citeshttps://doi.org/10.1021/acs.joc.9b01194openalex-snapshot

Synthesis of 2-Arylbenzothiazole and 2-Arylthiazole Derivatives via a Ru-Catalyzed meta-Selective C–H Nitration Reaction

inferred← citeshttps://doi.org/10.1021/acs.jpcc.9b02529openalex-snapshot

Mechanistic Investigations of Aluminum Nitrite Assisted Aryl Nitrile Synthesis through C(sp3)–C(sp2) Bond Cleavage of Aryl Ketones

inferred← citeshttps://doi.org/10.1021/acs.oprd.7b00285openalex-snapshot

Copper-Mediated C–X Functionalization of Aryl Halides

inferred← citeshttps://doi.org/10.1021/acs.orglett.0c03138openalex-snapshot

Combined Cyanoborylation, C–H Activation Strategy for Styrene Functionalization

inferred← citeshttps://doi.org/10.1021/acs.orglett.1c00468openalex-snapshot

Ni-Catalyzed C–H Cyanation of (Hetero)arenes with 2-Cyanoisothiazolidine 1,1-Dioxide as a Cyanation Reagent

inferred← citeshttps://doi.org/10.1021/acs.orglett.2c01867openalex-snapshot

Synthesis of Diverse γ-Lactams via Rh-Catalyzed C(sp 2 )–H Addition to Aliphatic Nitriles

inferred← citeshttps://doi.org/10.1021/acs.orglett.2c01897openalex-snapshot

Paired Electrolysis for Decarboxylative Cyanation: 4-CN-Pyridine, a Versatile Nitrile Source

inferred← citeshttps://doi.org/10.1021/acs.orglett.2c04185openalex-snapshot

Fe-Catalyzed Direct Synthesis of Nitriles from Carboxylic Acids with Electron-Deficient N -Cyano- N -aryl–arylsulfonamide

inferred← citeshttps://doi.org/10.1021/acs.orglett.3c02256openalex-snapshot

Ag-Catalyzed Cyanomethylation of Amines Using Nitromethane as a C1 Source

inferred← citeshttps://doi.org/10.1021/acs.orglett.4c00429openalex-snapshot

Palladium-Catalyzed Directed Carbon–Carbon Bond Activation of Aryl Nitriles for Cyano Transfer

inferred← citeshttps://doi.org/10.1021/acs.orglett.4c02552openalex-snapshot

Electrochemically Driven Denitrative Cyanation of Nitroarenes

inferred← citeshttps://doi.org/10.1021/acs.orglett.4c03901openalex-snapshot

Formal 1,1-Hydrocyanation Reaction of Alkynyl Halides with Isocyanides Enabled by Dual Nickel/Base Catalysis Relay

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c02286openalex-snapshot

Rh(III)-Catalyzed Atroposelective C–H Cyanation of 1-Aryl benzo[ h ]isoquinolines

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c04508openalex-snapshot

Co(III)-Catalyzed Three-Component Cascade for the Synthesis of α-Quaternary Acyclic Nitriles via C–H Bond Activation

inferred← citeshttps://doi.org/10.1021/acs.orglett.6c00892openalex-snapshot

Chemodivergent C–H Activation and C–C Coupling between Indoles and Alkyne-Tethered N -Cyanosulfonamides via Substrate-Controlled Group Migration

inferred← citeshttps://doi.org/10.1021/acs.orglett.6c02869openalex-snapshot

Electrochemical One- or Two-Electron Oxidation Enables Chemoselective α-Amino C(sp3)–H Arylation and Cyanation

inferred← citeshttps://doi.org/10.1021/acs.orglett.7b00826openalex-snapshot

Iminoxyl Radical-Promoted Oxycyanation and Aminocyanation of Unactivated Alkenes: Synthesis of Cyano-Featured Isoxazolines and Cyclic Nitrones

inferred← citeshttps://doi.org/10.1021/acs.orglett.7b01199openalex-snapshot

Decarbonylative Cyanation of Amides by Palladium Catalysis

inferred← citeshttps://doi.org/10.1021/acs.orglett.7b01710openalex-snapshot

Deoxycyanamidation of Alcohols with N -Cyano- N -phenyl- p -methylbenzenesulfonamide (NCTS)

inferred← citeshttps://doi.org/10.1021/acs.orglett.7b01756openalex-snapshot

Catalytic Asymmetric Electrophilic Cyanation of 3-Substituted Oxindoles

inferred← citeshttps://doi.org/10.1021/acs.orglett.7b03858openalex-snapshot

Oxycyanation of Vinyl Ethers with 2,2,6,6-Tetramethyl-N-oxopiperidinium Enabled by Electron Donor–Acceptor Complex

inferred← citeshttps://doi.org/10.1021/acs.orglett.8b02225openalex-snapshot

Synthesis and Reactivity of N -Allenyl Cyanamides

inferred← citeshttps://doi.org/10.1021/acscatal.1c00733openalex-snapshot

A Molecular Iron-Based System for Divergent Bond Activation: Controlling the Reactivity of Aldehydes

inferred← citeshttps://doi.org/10.1021/acscatal.2c01029openalex-snapshot

Nickel-Catalyzed Synthesis of an Aryl Nitrile via Aryl Exchange between an Aromatic Amide and a Simple Nitrile

inferred← citeshttps://doi.org/10.1021/acscatal.5c03331openalex-snapshot

Pd-Catalyzed Late-Stage Installation of Nitrile and Carbamoyl Groups via a Cross-Coupling Approach of Thianthrenium Salts with Isonitriles

inferred← citeshttps://doi.org/10.1021/acscatal.7b03583openalex-snapshot

Advances in Direct Metal-Catalyzed Functionalization of Azobenzenes

inferred← citeshttps://doi.org/10.1021/acscatal.8b00021openalex-snapshot

Direct Synthesis of N,N-Dimethylated and β-Methyl N,N-Dimethylated Amines from Nitriles Using Methanol: Experimental and Computational Studies

inferred← citeshttps://doi.org/10.1021/acscatal.8b05111openalex-snapshot

Ni-Mediated Generation of “CN” Unit from Formamide and Its Catalysis in the Cyanation Reactions

inferred← citeshttps://doi.org/10.1021/acscatal.9b03916openalex-snapshot

Atom-Economical and Tandem Conversion of Nitriles to N -Methylated Amides Using Methanol and Water

inferred← citeshttps://doi.org/10.1021/acscatal.9b04586openalex-snapshot

Nickel-Catalyzed Cyanation of Aryl Halides and Hydrocyanation of Alkynes via C–CN Bond Cleavage and Cyano Transfer

inferred← citeshttps://doi.org/10.1021/jacs.4c00885openalex-snapshot

Highly Stable 72-Nuclearity Nanocages for Efficient Synthesis of Aryl Nitriles via Ni/Cu Synergistic Catalysis

inferred← citeshttps://doi.org/10.1021/jacs.5c11876openalex-snapshot

Electrophilic Cyanation with Carbon Isotopes: A Versatile Access to 13 C, 14 C, and 11 C Aryl Nitriles from Labeled NCTS

inferred← citeshttps://doi.org/10.1021/jacs.8b00643openalex-snapshot

Mechanistic Insight Facilitates Discovery of a Mild and Efficient Copper-Catalyzed Dehydration of Primary Amides to Nitriles Using Hydrosilanes

inferred← citeshttps://doi.org/10.1021/jacs.8b01330openalex-snapshot

Palladium and Lewis-Acid-Catalyzed Intramolecular Aminocyanation of Alkenes: Scope, Mechanism, and Stereoselective Alkene Difunctionalizations

inferred← citeshttps://doi.org/10.1021/jacsau.2c00030openalex-snapshot

Late-Stage Carbon-14 Labeling and Isotope Exchange: Emerging Opportunities and Future Challenges

inferred← citeshttps://doi.org/10.1021/jacsau.5c00633openalex-snapshot

Enantioselective Radical Hydrocyanoalkylation of Alkenes via Photoenzymatic Catalysis

inferred← citeshttps://doi.org/10.1039/c6cc08601bopenalex-snapshot

CuI-Catalyzed intramolecular aminocyanation of terminal alkynes in N-(2-ethynylphenyl)-N-sulfonylcyanamides via Cu–vinylidene intermediates

inferred← citeshttps://doi.org/10.1039/c6sc04907aopenalex-snapshot

Room temperature decarboxylative cyanation of carboxylic acids using photoredox catalysis and cyanobenziodoxolones: a divergent mechanism compared to alkynylation

inferred← citeshttps://doi.org/10.1039/c7ra02574bopenalex-snapshot

Palladium( ii )-catalyzed ortho-C–H olefination of phenylalanine and phenylethylamine derivatives directed by removable picolinamide group

inferred← citeshttps://doi.org/10.1039/c8cc08930bopenalex-snapshot

Rhodium( iii )-catalyzed aromatic C–H cyanation with dimethylmalononitrile as a cyanating agent

inferred← citeshttps://doi.org/10.1039/c8ob01770kopenalex-snapshot

Recent developments and applications of cyanamides in electrophilic cyanation

inferred← citeshttps://doi.org/10.1039/c8ob02140fopenalex-snapshot

Non-toxic cyanide sources and cyanating agents

inferred← citeshttps://doi.org/10.1039/c8ob02186dopenalex-snapshot

A facile tandem decyanation/cyanation reaction of α-iminonitriles toward cyano-substituted amides

inferred← citeshttps://doi.org/10.1039/c8qo01143eopenalex-snapshot

Cyanofluorination of vinyl ethers enabled by electron donor–acceptor complexes

inferred← citeshttps://doi.org/10.1039/c9cy01170fopenalex-snapshot

Application of metal oxide semiconductors in light-driven organic transformations

inferred← citeshttps://doi.org/10.1039/c9gc00720bopenalex-snapshot

Strecker reactions with hexacyanoferrates as non-toxic cyanide sources

inferred← citeshttps://doi.org/10.1039/c9nj00776hopenalex-snapshot

Cu(OAc) 2 -Mediated benzimidazole-directed C–H cyanation using 2-(4-methylpiperazin-1-yl)acetonitrile as the cyano source

inferred← citeshttps://doi.org/10.1039/c9ob02760bopenalex-snapshot

Tandem transformations and multicomponent reactions utilizing alcohols following dehydrogenation strategy

inferred← citeshttps://doi.org/10.1039/c9qo00235aopenalex-snapshot

Copper-catalysed C(sp 3 )–N coupling initiated by selective C–C bond cleavage of cyclobutanone oxime esters

inferred← citeshttps://doi.org/10.1039/c9qo01055fopenalex-snapshot

Transition-metal-free direct C-3 cyanation of quinoxalin-2(1 H )-ones with ammonium thiocyanate as the “CN” source

inferred← citeshttps://doi.org/10.1039/c9ra02979fopenalex-snapshot

One-pot regioselective C–H activation iodination–cyanation of 2,4-diarylquinazolines using malononitrile as a cyano source

inferred← citeshttps://doi.org/10.1039/c9ra06120gopenalex-snapshot

Oxidative cyanation of N -aryltetrahydroisoquinoline induced by visible light for the synthesis of α-aminonitrile using potassium thiocyanate as a “CN” agent

inferred← citeshttps://doi.org/10.1039/d0cc08126dopenalex-snapshot

Cyanation of glycine derivatives

inferred← citeshttps://doi.org/10.1039/d0cs00535eopenalex-snapshot

Beyond classical sulfone chemistry: metal- and photocatalytic approaches for C–S bond functionalization of sulfones

inferred← citeshttps://doi.org/10.1039/d0cy02087gopenalex-snapshot

Recent advances and perspectives in manganese-catalyzed C–H activation

inferred← citeshttps://doi.org/10.1039/d0gc00608dopenalex-snapshot

Base-mediated benzannulation of α-cyanocrotonates with ynones: facile synthesis of benzonitriles and fluorenes

inferred← citeshttps://doi.org/10.1039/d0nj01996hopenalex-snapshot

Recent advances in C–CN and C–H bond activation of green nitrile (MeCN) for organo-complexation, cyanation and cyanomethylation

inferred← citeshttps://doi.org/10.1039/d0ob00485eopenalex-snapshot

The palladium-catalyzed direct C3-cyanation of indoles using acetonitrile as the cyanide source

inferred← citeshttps://doi.org/10.1039/d0ob01928copenalex-snapshot

An aerobic and green C–H cyanation of terminal alkynes

inferred← citeshttps://doi.org/10.1039/d0ob02309dopenalex-snapshot

Recent advances in Rh( iii )/Ir( iii )-catalyzed C–H functionalization/annulation via carbene migratory insertion

inferred← citeshttps://doi.org/10.1039/d0qo00282hopenalex-snapshot

Access to cyano-substituted pyrazolines through copper-catalyzed cascade cyanation/cyclization of unactivated olefins

inferred← citeshttps://doi.org/10.1039/d0qo01182gopenalex-snapshot

Visible light-mediated applications of methylene blue in organic synthesis

inferred← citeshttps://doi.org/10.1039/d0ra01286fopenalex-snapshot

Direct cyanation, hydrocyanation, dicyanation and cyanofunctionalization of alkynes

inferred← citeshttps://doi.org/10.1039/d1cy00241dopenalex-snapshot

Directing group strategies in catalytic sp 2 C–H cyanations: scope, mechanism and limitations

inferred← citeshttps://doi.org/10.1039/d1ob00192bopenalex-snapshot

Cyanoalkylation/alkynylation of allylic alcohol through intramolecular radical 1,2-alkynyl migration

inferred← citeshttps://doi.org/10.1039/d1ob00675dopenalex-snapshot

Recent developments in decarboxylative C(aryl)–X bond formation from (hetero)aryl carboxylic acids

inferred← citeshttps://doi.org/10.1039/d1ob01086gopenalex-snapshot

An expedient route to tricyanovinylindoles and indolylmaleimides from o -alkynylanilines utilising DMSO as a one-carbon synthon

inferred← citeshttps://doi.org/10.1039/d1ob02143eopenalex-snapshot

Metal-free three-component cyanoalkylation of quinoxalin-2(1 H )-ones with vinylarenes and azobis(alkylcarbonitrile)s

inferred← citeshttps://doi.org/10.1039/d1qo01858bopenalex-snapshot

Cyanation and cyanomethylation of trimethylammonium salts via electrochemical cleavage of C–N bonds

inferred← citeshttps://doi.org/10.1039/d2cc00342bopenalex-snapshot

Palladium-catalyzed synthesis of nitriles from N -phthaloyl hydrazones

inferred← citeshttps://doi.org/10.1039/d2cc05826jopenalex-snapshot

Organo-cyanamides: convenient reagents for catalytic amidation of carboxylic acids

inferred← citeshttps://doi.org/10.1039/d2cs00012aopenalex-snapshot

C–H bond activation and sequential addition to two different coupling partners: a versatile approach to molecular complexity

inferred← citeshttps://doi.org/10.1039/d2nj06338gopenalex-snapshot

Metal-free synthesis of ketonitriles via C–F bond cleavage

inferred← citeshttps://doi.org/10.1039/d2ob01199aopenalex-snapshot

Iron( iii )-catalyzed α-cyanation and carbonylation with 2-pyridylacetonitrile: divergent synthesis of α-amino nitriles and tetrahydroisoquinolinones

inferred← citeshttps://doi.org/10.1039/d2ob01644copenalex-snapshot

Iodonium ylides: an emerging and alternative carbene precursor for C–H functionalizations

inferred← citeshttps://doi.org/10.1039/d2qo00486kopenalex-snapshot

Copper-catalyzed regioselective 1,4-sulfonylcyanation of 1,3-enynes with sulfonyl chlorides and TMSCN

inferred← citeshttps://doi.org/10.1039/d3cc03075jopenalex-snapshot

Weakly coordinating tert -amide assisted Rh( iii )-catalyzed C4-cyanation of indoles: application in photophysical studies

inferred← citeshttps://doi.org/10.1039/d3cc05880hopenalex-snapshot

Cyanation with isocyanides: recent advances and perspectives

inferred← citeshttps://doi.org/10.1039/d3ob01528aopenalex-snapshot

tert -Butylhydroperoxide mediated radical cyanoalkylation/cyanoalkenylation of 2-anilino-1,4-naphthoquinones with vinylarenes/arylalkynes and azobis(alkylcarbonitrile)s

inferred← citeshttps://doi.org/10.1039/d4cc04539dopenalex-snapshot

Deacetylative cyanation: a cyanide-free route to thiocyanates and cyanamides

inferred← citeshttps://doi.org/10.1039/d4ce00950aopenalex-snapshot

Bridging linker installation strategy in the engineering of copper( ii ) complexes: activation of nitriles, efficient catalysts for the cyanosilylation of aldehydes

inferred← citeshttps://doi.org/10.1039/d4ob01849dopenalex-snapshot

TFA-catalyzed solvent-free dearomative cyanidation of isoquinoline using (Boc) 2 O as an acylation agent

inferred← citeshttps://doi.org/10.1039/d5ob00012bopenalex-snapshot

Catalyst and transition-metal free 1,6-conjugate addition of azobisisobutyronitrile: access to isobutyronitrile containing diarylmethanes

inferred← citeshttps://doi.org/10.1039/d5qo01254fopenalex-snapshot

Copper-catalyzed radical aminocyanation of allenes

inferred← citeshttps://doi.org/10.1039/d6cc00754fopenalex-snapshot

Desulfonylcyanamidation of α,β-unsaturated sulfones with N -tosyl N -aryl cyanamides (NCTS): access to N -cyanoenaminones

inferred← citeshttps://doi.org/10.1055/a-1704-4822openalex-snapshot

Synthesis of C3-Cyanomethylated Imidazo[1,2-a]pyridines via Ultrasound-Promoted Three-Component Reaction under Catalyst- and Oxidant-Free Conditions

inferred← citeshttps://doi.org/10.1055/a-1965-3028openalex-snapshot

Recent Advances on Radical-Mediated Cyanoalkylation/Cyanation using AIBN and Analogues as the Radical Sources

inferred← citeshttps://doi.org/10.1055/a-2053-1750openalex-snapshot

Silver-Catalyzed Synthesis of Nitriles from Carboxylic Acids and Cyanamides

inferred← citeshttps://doi.org/10.1055/s-0037-1610795openalex-snapshot

Copper-Mediated Direct Aromatic ortho-C–H Cyanation by AIBN

inferred← citeshttps://doi.org/10.1080/00268976.2022.2105271openalex-snapshot

DFT investigates the mechanisms of cross-dehydrogenative coupling between heterocycles and acetonitrile

inferred← citeshttps://doi.org/10.1080/00397911.2019.1655765openalex-snapshot

Cp*Co(III) catalyzed annulation of N-Cbz hydrazones for the redox-neutral synthesis of isoquinolines via C–H/N–N bond activation

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