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Highly Regio- and Stereoselective Synthesis of Z and E Enol Esters by an Amine-Catalyzed Conjugate Addition–Rearrangement Reaction of Ynals with Carboxylic Acids

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/adsc.201000431openalex-snapshot
Recyclable Solid Ruthenium Catalysts Supported on Metal Oxides for the Addition of Carboxylic Acids to Terminal Alkynes
inferredcites →https://doi.org/10.1002/adsc.201100351openalex-snapshot
Organocatalytic Enantioselective Dipolar [3+2] Cycloadditions of Acetylenic Aldehydes with Nitrones for the Formation of Chiral 4‐Isoxazolines
inferredcites →https://doi.org/10.1002/adsc.201200033openalex-snapshot
Enantioselective Synthesis of 4‐Isoxazolines by 1,3‐Dipolar Cycloadditions of Nitrones to Alkynals Catalyzed by Fluorodiphenylmethylpyrrolidines
inferredcites →https://doi.org/10.1002/adsc.201401176openalex-snapshot
Asymmetric One‐Pot Synthesis of 1,4‐Dihydroquinolines via an Organocatalytic Aza‐Michael/Michael Cascade Strategy
inferredcites →https://doi.org/10.1002/ajoc.201400021openalex-snapshot
Alkynes in Organocatalysis
inferredcites →https://doi.org/10.1002/anie.200501391openalex-snapshot
Metal Vinylidenes and Allenylidenes in Catalysis: Applications in Anti‐Markovnikov Additions to Terminal Alkynes and Alkene Metathesis
inferredcites →https://doi.org/10.1002/anie.200501434openalex-snapshot
Catalytic Asymmetric Couplings of Ketenes with Aldehydes To Generate Enol Esters
inferredcites →https://doi.org/10.1002/anie.200604773openalex-snapshot
Propargylic Esters in Gold Catalysis: Access to Diversity
inferredcites →https://doi.org/10.1002/anie.200906050openalex-snapshot
Iminium–Allenamine Cascade Catalysis: One‐Pot Access to Chiral 4H‐Chromenes by a Highly Enantioselective Michael–Michael Sequence
inferredcites →https://doi.org/10.1002/anie.201202161openalex-snapshot
An Organocatalytic Cascade Approach toward Polysubstituted Quinolines and Chiral 1,4‐Dihydroquinolines–Unanticipated Effect of N‐Protecting Groups
inferredcites →https://doi.org/10.1002/anie.201409450openalex-snapshot
Rhodium(III)/Copper(II)‐Promoted trans‐Selective Heteroaryl Acyloxylation of Alkynes: Stereodefined Access to trans‐Enol Esters
inferredcites →https://doi.org/10.1002/cber.19220550403openalex-snapshot
Umlagerung tertiärer Äthinyl‐carbinole in ungesättigte Ketone
inferredcites →https://doi.org/10.1002/chem.201001293openalex-snapshot
Asymmetric Synthesis of 4‐Amino‐4H‐Chromenes by Organocatalytic Oxa‐Michael/Aza‐Baylis–Hillman Tandem Reactions
inferredcites →https://doi.org/10.1002/chem.201202895openalex-snapshot
A Selective Palladium‐Catalyzed Carbonylative Arylation of Aryl Ketones to Give Vinylbenzoate Compounds
inferredcites →https://doi.org/10.1002/chem.201300160openalex-snapshot
Development of an Improved Rhodium Catalyst for Z‐Selective Anti‐Markovnikov Addition of Carboxylic Acids to Terminal Alkynes
inferredcites →https://doi.org/10.1002/ejoc.200900697openalex-snapshot
Novel, Highly Efficient and Selective Ruthenium Catalysts for the Synthesis of Vinyl Esters from Carboxylic Acids and Alkynes
inferredcites →https://doi.org/10.1016/j.bmcl.2012.12.077openalex-snapshot
Five new phenolic glycosides from Hedyotis scandens
inferredcites →https://doi.org/10.1016/j.ccr.2006.09.002openalex-snapshot
NHC–Ru complexes—Friendly catalytic tools for manifold chemical transformations
inferredcites →https://doi.org/10.1016/j.ccr.2007.09.021openalex-snapshot
Synthesis and application of chiral monodentate phosphines in asymmetric hydrogenation
inferredcites →https://doi.org/10.1016/j.cell.2008.09.002openalex-snapshot
Retinoic Acid Synthesis and Signaling during Early Organogenesis
inferredcites →https://doi.org/10.1016/j.jorganchem.2005.11.061openalex-snapshot
Synthesis and structure of some ruthenium–rhenium heterodinuclear complexes and their catalytic activity in the addition of carboxylic acids to phenylacetylene
inferredcites →https://doi.org/10.1016/j.phytochem.2010.09.008openalex-snapshot
Sebestenoids A–D, BACE1 inhibitors from Cordia sebestena
inferredcites →https://doi.org/10.1016/j.tet.2014.07.023openalex-snapshot
Organocatalytic transformations of alkynals, alkynones, propriolates, and related electron-deficient alkynes
inferredcites →https://doi.org/10.1016/s0040-4039(02)00366-0openalex-snapshot
Ruthenium-catalyzed selective anti-Markovnikov trans addition of carboxylic acids and tail-to-tail dimerization of terminal alkynes
inferredcites →https://doi.org/10.1016/s0190-9622(18)30747-3openalex-snapshot
Rediscovering mycophenolic acid: A review of its mechanism, side effects, and potential uses
inferredcites →https://doi.org/10.1021/acs.joc.5b02293openalex-snapshot
Regioselective Formation of Enol Esters from the Ruthenium-Catalyzed Markovnikov Addition of Carboxylic Acids to Alkynes
inferredcites →https://doi.org/10.1021/cr020049iopenalex-snapshot
New Chiral Phosphorus Ligands for Enantioselective Hydrogenation
inferredcites →https://doi.org/10.1021/cr0201068openalex-snapshot
Transition-Metal-Catalyzed Addition of Heteroatom−Hydrogen Bonds to Alkynes
inferredcites →https://doi.org/10.1021/cr068388popenalex-snapshot
Iminium Catalysis
inferredcites →https://doi.org/10.1021/cr100259topenalex-snapshot
Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds
inferredcites →https://doi.org/10.1021/cs300151xopenalex-snapshot
Active Ruthenium Catalysts Based on Phosphine-Modified Ru/CeO2for the Selective Addition of Carboxylic Acids to Terminal Alkynes
inferredcites →https://doi.org/10.1021/ja034369aopenalex-snapshot
Enol Ester as an Olefinic Partner in Enyne Cyclization. A Novel Tandem Cyclization to Stereodefined Bicyclo[3.3.0]octenes
inferredcites →https://doi.org/10.1021/ja0349554openalex-snapshot
Biscarbene−Ruthenium Complexes in Catalysis: Novel Stereoselective Synthesis of (1 E ,3 E) -1,4-Disubstituted-1,3-dienes via Head-to-Head Coupling of Terminal Alkynes and Addition of Carboxylic Acids
inferredcites →https://doi.org/10.1021/ja1108613openalex-snapshot
Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters
inferredcites →https://doi.org/10.1021/ja803480bopenalex-snapshot
Preparation of Substituted Enol Derivatives From Terminal Alkynes and Their Synthetic Utility
inferredcites →https://doi.org/10.1021/ja901048wopenalex-snapshot
Gold-Catalyzed Homogeneous Oxidative C−O Bond Formation: Efficient Synthesis of 1-Benzoxyvinyl Ketones
inferredcites →https://doi.org/10.1021/ja906472mopenalex-snapshot
Nine-Step Enantioselective Total Synthesis of (+)-Minfiensine
inferredcites →https://doi.org/10.1021/ja982857qopenalex-snapshot
Enantioselective Aldol Reactions Catalyzed by Tin Methoxide and BINAP·Silver(I) Complex
inferredcites →https://doi.org/10.1021/jo00127a033openalex-snapshot
General Synthesis of (Z)-Alk-1-en-1-yl Esters via Ruthenium-Catalyzed anti-Markovnikov trans-Addition of Carboxylic Acids to Terminal Alkynes
inferredcites →https://doi.org/10.1021/jo0606103openalex-snapshot
Highly Stereoselective Oxidative Esterification of Aldehydes with β-Dicarbonyl Compounds
inferredcites →https://doi.org/10.1021/np970576aopenalex-snapshot
Grenadadiene and Grenadamide, Cyclopropyl-Containing Fatty Acid Metabolites from the Marine Cyanobacterium Lyngbya majuscula
inferredcites →https://doi.org/10.1021/ol102096sopenalex-snapshot
“One-Pot” Access to 4H-Chromenes with Formation of a Chiral Quaternary Stereogenic Center by a Highly Enantioselective Iminium-allenamine Involved Oxa-Michael−Aldol Cascade
inferredcites →https://doi.org/10.1021/ol102365eopenalex-snapshot
Rhodium-Catalyzed Selective anti-Markovnikov Addition of Carboxylic Acids to Alkynes
inferredcites →https://doi.org/10.1021/ol201238uopenalex-snapshot
Ruthenium-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Aryl and Trifluoromethyl Group Substituted Unsymmetrical Internal Alkynes
inferredcites →https://doi.org/10.1021/ol301563gopenalex-snapshot
[Pd(μ-Br)(PtBu3)]2 as a Highly Active Isomerization Catalyst: Synthesis of Enol Esters from Allylic Esters
inferredcites →https://doi.org/10.1021/ol3032285openalex-snapshot
One-Pot Formation of Chiral Polysubstituted 3,4-Dihydropyrans via a Novel Organocatalytic Domino Sequence Involving Alkynal Self-Condensation
inferredcites →https://doi.org/10.1021/ol400988eopenalex-snapshot
Synthesis of Benzoxazoles via an Amine-Catalyzed [4 + 1] Annulation
inferredcites →https://doi.org/10.1021/ol4013712openalex-snapshot
Copper-Catalyzed Nondecarboxylative Cross Coupling of Alkenyltrifluoroborate Salts with Carboxylic Acids or Carboxylates: Synthesis of Enol Esters
inferredcites →https://doi.org/10.1021/ol701717zopenalex-snapshot
Enol Esters: Versatile Substrates for Mannich-Type Multicomponent Reactions
inferredcites →https://doi.org/10.1021/om50005a037openalex-snapshot
Addition of carboxylic acids to alkynes catalyzed by ruthenium complexes. Vinyl ester formation
inferredcites →https://doi.org/10.1039/b211277aopenalex-snapshot
Regiocontrolled Ru-catalyzed addition of carboxylic acids to alkynes: practical protocols for the synthesis of vinyl estersWe thank Prof. Dr. M. T. Reetz for generous support and constant encouragement, and gratefully acknowledge the DFG, the FCI, and the BMBF for financial support.
inferredcites →https://doi.org/10.1039/c2cc00129bopenalex-snapshot
Relay catalysis: combined metal catalyzed oxidation and asymmetric iminium catalysis for the synthesis of Bi- and tricyclic chromenes
inferredcites →https://doi.org/10.1039/c2cc38454jopenalex-snapshot
A dinuclear ruthenium catalyst with a confined cavity: selectivity in the addition of aliphatic carboxylic acids to phenylacetylene
inferredcites →https://doi.org/10.1039/c3sc51027aopenalex-snapshot
Asymmetric synthesis of propargylic alcohols via aldol reaction of aldehydes with ynals promoted by prolinol ether–transition metal–Brønsted acid cooperative catalysis
inferredcites →https://doi.org/10.1073/pnas.1508133112openalex-snapshot
Marine and terrestrial herbivores display convergent chemical ecology despite 400 million years of independent evolution
inferredcites →https://doi.org/10.1080/00397911.2011.556298openalex-snapshot
Synthesis of 4-Alkynyl-substituted 3,4-Dihydropyrimidin-2(1H)-ones
inferredcites →https://doi.org/10.1080/10575630008043770openalex-snapshot
Udoteal B, A New Linear Diterpenoid from the Green AlgaUdotea petiolata
inferredcites →https://doi.org/10.1080/10575639708043731openalex-snapshot
A Novel Dietary Sesquiterpene from the marine SacoglossanTridachia Crispata
inferredcites →https://doi.org/10.1152/ajpcell.00227.2008openalex-snapshot
Probenecid, a gout remedy, inhibits pannexin 1 channels
inferredcites →https://doi.org/10.1351/pac200880081725openalex-snapshot
New catalytic transformations of carboxylic acids

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4670490openalex-extracted
Generation and Radical-Radical Cross-Coupling of Alkenyloxy Radical: Ester and Ketone Synthesis
inferred← citeshttps://doi.org/10.1002/asia.201900315openalex-snapshot
1,3‐O‐Transposition or Trisubstituted Z‐Enol Ester? A Comparative Study of Reactions of Ynones
inferred← citeshttps://doi.org/10.1002/ejoc.201900137openalex-snapshot
Enol Ester Intermediate Induced Metal‐Free Oxidative Coupling of Carboxylic Acids and Arylboronic Acids
inferred← citeshttps://doi.org/10.1002/ejoc.202001369openalex-snapshot
A Facile Transition Metal‐Free Ionic Liquid [BMIM]OH Mediated Regio‐ and Stereoselective Hydrocarboxylation of Alkynylnitriles
inferred← citeshttps://doi.org/10.1002/slct.202002728openalex-snapshot
Lewis Acid‐Free Ynoate‐Mediated Chemoselective Reduction of Carboxylic Acids to Primary Alcohols
inferred← citeshttps://doi.org/10.1016/b978-0-443-31482-7.00032-1openalex-snapshot
Aldehydes: α,β-Unsaturated Aldehydes
inferred← citeshttps://doi.org/10.1016/j.gresc.2020.05.001openalex-snapshot
One-pot synthesis of salicylaldehyde containing biaryl frameworks via an aminocatalytic Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones
inferred← citeshttps://doi.org/10.1016/j.tetlet.2018.01.029openalex-snapshot
Cationic ruthenium complex of the formula [RuCl(2,6-diacetylpyridine)(PPh3)2]BArF and its catalytic activity in the formation of enol esters
inferred← citeshttps://doi.org/10.1016/j.tetlet.2025.155907openalex-snapshot
Synthesis of polyfunctionalized carbazole aldehydes by a [4+2] annulation of ethyl 2-(1-alkyl-3-formyl-1H-indol-2-yl)acetate with alkynals
inferred← citeshttps://doi.org/10.1021/acs.joc.6b02712openalex-snapshot
Gold-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Iodoalkynes: Access to (Z)-β-Iodoenol Esters and 1,4-Disubstituted (Z)-Enynyl Esters
inferred← citeshttps://doi.org/10.1021/acs.joc.8b00819openalex-snapshot
Direct Amidation of Carboxylic Acids through an Active α-Acyl Enol Ester Intermediate
inferred← citeshttps://doi.org/10.1021/acs.joc.9b02919openalex-snapshot
Copper Promoted Aerobic Oxidative C(sp3)–C(sp3) Bond Cleavage of N-(2-(Pyridin-2-yl)-ethyl)anilines
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c02027openalex-snapshot
Copper-Catalyzed Regioselective Olefination and Trifluoromethylation of Carboxylic Acids To Give (Z)-Trifluoromethyl Enol Esters
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c00627openalex-snapshot
Generation and Radical–Radical Cross-Coupling of Alkenyloxy Radical
inferred← citeshttps://doi.org/10.1039/c6ob02800dopenalex-snapshot
Gold( i )-catalyzed addition of carboxylic acids to internal alkynes in aqueous medium
inferred← citeshttps://doi.org/10.1039/c8cc02565gopenalex-snapshot
Organocatalytic synthesis of densely functionalized oxa-bridged 2,6-epoxybenzo[ b ][1,5]oxazocine heterocycles
inferred← citeshttps://doi.org/10.1039/c8qo00664dopenalex-snapshot
Cu( i )-Catalyzed stereoselective synthesis of trisubstituted Z -enol esters via interrupting the 1,3- O -transposition reaction
inferred← citeshttps://doi.org/10.1039/c8qo01241eopenalex-snapshot
Organocatalytic atropo- and E / Z -selective Michael addition reaction of ynones with α-amido sulfones as sulfone-type nucleophile
inferred← citeshttps://doi.org/10.1039/d3sc01394dopenalex-snapshot
Atom-economic and stereoselective catalytic synthesis of fully substituted enol esters/carbonates of amides in acyclic systems enabled by boron Lewis acid catalysis
inferred← citeshttps://doi.org/10.1039/d4qo00265bopenalex-snapshot
Blue light-mediated carbene transfer reaction of thioesters with diazoesters: efficient synthesis of tetrasubstituted Z -enol esters
inferred← citeshttps://doi.org/10.24820/ark.5550190.p010.188openalex-snapshot
The intermolecular hydro-oxycarbonylation of internal alkynes: current state of the art
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