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Supramolecular Approaches To Control Activity and Selectivity in Hydroformylation Catalysis

https://doi.org/10.1021/acscatal.8b00288

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Rapid Access to Diverse Arrays of Chiral 3,4-Diazaphospholanes We thank the Department of Energy, Office of Basic Energy Sciences for financial support of this work. All crystal-structure determinations were performed by Dr. Doug Powell or Dr. Ilyea Guzei. The cone-angle measurements were made…

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Assembly of Encapsulated Transition Metal Catalysts

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Rapid Access to Diverse Arrays of Chiral 3,4-Diazaphospholanes

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Assembly of Encapsulated Transition Metal Catalysts

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Applied Homogeneous Catalysis with Organometallic Compounds

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Bidentate Ligands by Self‐Assembly through Hydrogen Bonding: A General Room Temperature/Ambient Pressure Regioselective Hydroformylation of Terminal Alkenes

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Domino Hydroformylation/Enantioselective Cross‐Aldol Addition

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Supramolecular Encapsulated Rhodium Catalysts for Branched Selective Hydroformylation of Alkenes at High Temperature

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Room Temperature Ambient Pressure (RTAP)‐Hydroformylation in Water Using a Self‐Assembling Ligand

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Branched‐Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group

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An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes

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Tandem Rhodium‐Catalyzed Hydroformylation–Hydrogenation of Alkenes by Employing a Cooperative Ligand System

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β‐Cyclodextrin‐Modified Diphosphanes as Ligands for Supramolecular Rhodium Catalysts

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Multicomponent Porphyrin Assemblies as Functional Bidentate Phosphite Ligands for Regioselective Rhodium‐Catalyzed Hydroformylation

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Self‐Assembly of Bidentate Ligands for Combinatorial Homogeneous Catalysis Based on an A–T Base‐Pair Model

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Supramolecular Approaches to Generate Libraries of Chelating Bidentate Ligands for Homogeneous Catalysis

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A Supramolecular Catalyst for Regioselective Hydroformylation of Unsaturated Carboxylic Acids

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A Supramolecular Catalyst for the Decarboxylative Hydroformylation of α,β‐Unsaturated Carboxylic Acids

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Branched‐Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group

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Functional Molecular Flasks: New Properties and Reactions within Discrete, Self‐Assembled Hosts

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Supramolecular Catalyst for Aldehyde Hydrogenation and Tandem Hydroformylation–Hydrogenation

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Remote Control of Regio‐ and Diastereoselectivity in the Hydroformylation of Bishomoallylic Alcohols with Catalytic Amounts of a Reversibly Bound Directing Group

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Enzyme Mimics Based Upon Supramolecular Coordination Chemistry

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Remote Supramolecular Control of Catalyst Selectivity in the Hydroformylation of Alkenes

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Removable Directing Groups in Organic Synthesis and Catalysis

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Supramolecular Control of Ligand Coordination and Implications in Hydroformylation Reactions

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An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes

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Mechanistic Insights into a Supramolecular Self‐Assembling Catalyst System: Evidence for Hydrogen Bonding during Rhodium‐Catalyzed Hydroformylation

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Supramolecular Control of Selectivity in Hydroformylation of Vinyl Arenes: Easy Access to Valuable β‐Aldehyde Intermediates

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Confining Phosphanes Derived from Cyclodextrins for Efficient Regio‐ and Enantioselective Hydroformylation

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Rhodium‐Catalyzed Hydroformylation of 1,1‐Disubstituted Allenes Employing the Self‐Assembling 6‐DPPon System

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Hydroformylation of Alkenes in a Planetary Ball Mill: From Additive‐Controlled Reactivity to Supramolecular Control of Regioselectivity

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A Comparative In Situ HP‐FTIR Spectroscopic Study of Bi‐ and Monodentate Phosphite‐Modified Hydroformylation

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Hydroformylation in the Realm of Scents

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Comparison of the Full Catalytic Cycle of Hydroformylation Mediated by Mono‐ and Bis‐Ligated Triphenylphosphine–Rhodium Complexes by Using DFT Calculations

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Ligand‐Template Directed Assembly: An Efficient Approach for the Supramolecular Encapsulation of Transition‐Metal Catalysts

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Transition‐State Stabilization by a Secondary Substrate–Ligand Interaction: A New Design Principle for Highly Efficient Transition‐Metal Catalysis

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Formation of Quaternary Carbon Centers by Highly Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group

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Coordination Studies on Supramolecular Chiral Ligands and Application in Asymmetric Hydroformylation

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Exploring Between the Extremes: Conversion‐Dependent Kinetics of Phosphite‐Modified Hydroformylation Catalysis

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Application of Supramolecular Bidentate Hybrid Ligands in Asymmetric Hydroformylation

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Realistic Energy Surfaces for Real‐World Systems: An IMOMO CCSD(T):DFT Scheme for Rhodium‐Catalyzed Hydroformylation with the 6‐DPPon Ligand

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An Operando FTIR Spectroscopic and Kinetic Study of Carbon Monoxide Pressure Influence on Rhodium‐Catalyzed Olefin Hydroformylation

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Tuning the Porphyrin Building Block in Self‐Assembled Cages for Branched‐Selective Hydroformylation of Propene

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ChemInform Abstract: Remote Control of Regio‐ and Diastereoselectivity in the Hydroformylation of Bishomoallylic Alcohols with Catalytic Amounts of a Reversibly Bound Directing Group.

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Synthesis of Building Blocks for the Development of the SUPRAPhos Ligand Library and Examples of Their Application in Catalysis

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Supramolecular Self‐Assembled Ligands in Asymmetric Transition Metal Catalysis

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The structure of the formylation (OXO) products obtained from olefines and watergas

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Catalytic Carbonylation Reactions

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Rhodium-catalysed hydroformylation of branched 1-alkenes; bulky phosphite vs. triphenylphosphine as modifying ligand

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A further breakthrough in biphasic, rhodium-catalyzed hydroformylation: the use of Per(2,6-di-O-methyl)-β-cyclodextrin as inverse phase transfer catalyst

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Rhodium-Catalyzed Hydroformylation

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Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated β-cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives

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New phosphorus self-assembling ligands for the tandem hydroformylation–Wittig olefination reaction of homoallylic alcohols — A key step for stereoselective pyran synthesis

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Rhodium catalyzed hydroformylation assisted by cyclodextrins in biphasic medium: Can sulfonated naphthylphosphanes lead to active, selective and recyclable catalytic species?

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In situ mechanistic studies in rhodium catalyzed hydroformylation of alkenes

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Synthesis and catalytic relevance of P(III) and P(V)-functionalised calixarenes and resorcinarenes

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Chemistry and Catalysis in Functional Cavitands

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Supraphos: A supramolecular strategy to prepare bidentate ligands

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Homogeneous catalysis: understanding the art

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Rhodium catalyzed hydroformylation of water insoluble olefins in the presence of chemically modified β-cyclodextrins: evidence for ligand-cyclodextrin interactions and effect of various parameters on the activity and the aldehydes selectivity

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Rhodium-catalyzed hydroformylation of vinylidenic olefins: the different behaviors of the isomeric alkyl–metal intermediates as the origin of the β-regioselectivity

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Addition reactions of transition metal compounds

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Ligands for Practical Rhodium-Catalyzed Asymmetric Hydroformylation

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Substrate-directable chemical reactions

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Asymmetric Hydroformylation

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Self-Assembled Nanoreactors

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Applied Hydroformylation

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Supramolecular Catalysis in Metal–Ligand Cluster Hosts

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Induced Intramolecularity: An Effective Strategy in Catalysis

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Selective Isomerization–Hydroformylation Sequence: A Strategy to Valuable α-Methyl-Branched Aldehydes from Terminal Olefins

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Isomerization–Hydroformylation Tandem Reactions

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Investigation into the Equilibrium of Iridium Catalysts for the Hydroformylation of Olefins by Combining In Situ High-Pressure FTIR and NMR Spectroscopy

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Template-Assisted Ligand Encapsulation; the Impact of an Unusual Coordination Geometry on a Supramolecular Pyridylphosphine−Zn(II)porphyrin Assembly

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Diphosphines with natural bite angles near 120.degree. increase selectivity for n-aldehyde formation in rhodium-catalyzed hydroformylation

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Highly enantioselective hydroformylation of olefins catalyzed by new phosphine phosphite-rhodium(I) complexes

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(Chelating diphosphine)rhodium-Catalyzed Deuterioformylation of 1-Hexene: Control of Regiochemistry by the Kinetic Ratio of Alkylrhodium Species Formed by Hydride Addition to Complexed Alkene

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Unraveling the Origin of Regioselectivity in Rhodium Diphosphine Catalyzed Hydroformylation. A DFT QM/MM Study

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The Reaction of Cobalt Hydrotetracarbonyl with Olefins

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Hydrogen Bonding as a Construction Element for Bidentate Donor Ligands in Homogeneous Catalysis: Regioselective Hydroformylation of Terminal Alkenes

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Encapsulation of Transition Metal Catalysts by Ligand-Template Directed Assembly

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Supraphos: A Supramolecular Strategy To Prepare Bidentate Ligands

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Highly Active, Regioselective, and Enantioselective Hydroformylation with Rh Catalysts Ligated by Bis-3,4-diazaphospholanes

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A Hybrid Phosphorus Ligand for Highly Enantioselective Asymmetric Hydroformylation

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High-Precision Catalysts: Regioselective Hydroformylation of Internal Alkenes by Encapsulated Rhodium Complexes

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Synthesis of Quaternary Carbon Centers via Hydroformylation

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Application of a Chiral Scaffolding Ligand in Catalytic Enantioselective Hydroformylation

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Ligand Self-Assembling through Complementary Hydrogen-Bonding in the Coordination Sphere of a Transition Metal Center: The 6-Diphenylphosphanylpyridin-2(1 H )-one System

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Self-Assembly of a Confined Rhodium Catalyst for Asymmetric Hydroformylation of Unfunctionalized Internal Alkenes

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Precise Supramolecular Control of Selectivity in the Rh-Catalyzed Hydroformylation of Terminal and Internal Alkenes

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Beyond Classical Reactivity Patterns: Hydroformylation of Vinyl and Allyl Arenes to Valuable β- and γ-Aldehyde Intermediates Using Supramolecular Catalysis

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Distal-Selective Hydroformylation using Scaffolding Catalysis

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Enantioselective Hydroformylation by a Rh-Catalyst Entrapped in a Supramolecular Metallocage

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Catalytic Scaffolding Ligands: An Efficient Strategy for Directing Reactions

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Origin of Pressure Effects on Regioselectivity and Enantioselectivity in the Rhodium-Catalyzed Hydroformylation of Styrene with ( S , S , S )-BisDiazaphos

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Electronic Effect on Rhodium Diphosphine Catalyzed Hydroformylation: The Bite Angle Effect Reconsidered

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Unexpected CO Dependencies, Catalyst Speciation, and Single Turnover Hydrogenolysis Studies of Hydroformylation via High Pressure NMR Spectroscopy

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Understanding a Hydroformylation Catalyst that Produces Branched Aldehydes from Alkyl Alkenes

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Asymmetric Hydroformylation of Heterocyclic Olefins Catalyzed by Chiral Phosphine−Phosphite−Rh(I) Complexes

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Diastereoselective Hydroformylation of 2,5-Cyclohexadienyl-1-carbinols with Catalytic Amounts of a Reversibly Bound Directing Group

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Regioselective Hydroformylation of Sulfonamides using a Scaffolding Ligand

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Rhodium-Catalyzed Hydroformylation and Deuterioformylation with Pyrrolyl-Based Phosphorus Amidite Ligands: Influence of Electronic Ligand Properties

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Online Monitoring of Hydroformylation Intermediates by ESI-MS

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Importance of Long-Range Noncovalent Interactions in the Regioselectivity of Rhodium-Xantphos-Catalyzed Hydroformylation

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Phosphinoureas: Cooperative Ligands in Rhodium-Catalyzed Hydroformylation? On the Possibility of a Ligand-Assisted Reductive Elimination of the Aldehyde

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2H NMR Investigation of the Rhodium-Catalyzed Deuterioformylation of 1,1-Diphenylethene: Evidence for the Formation of a Tertiary Alkyl−Metal Intermediate

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Mechanistic Aspects of Asymmetric Hydroformylation of Olefins Catalyzed by Chiral Phosphine−Phosphite−Rhodium(I) Complexes

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Origin of the Bite Angle Effect on Rhodium Diphosphine Catalyzed Hydroformylation

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A combinatorial approach to the identification of self-assembled ligands for rhodium-catalysed asymmetric hydrogenation

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Capsule-controlled selectivity of a rhodium hydroformylation catalyst

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Scalable and chromatography-free synthesis of 2-(2-formylalkyl)arenecarboxylic acid derivatives through the supramolecularly controlled hydroformylation of vinylarene-2-carboxylic acids

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Bidentate ligands formed by self-assemblyElectronic supplementary information (ESI) available: ligand synthesis and detailed experimental data. See http://www.rsc.org/suppdata/cc/b3/b306683e/

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New directions in supramolecular transition metal catalysis

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Encapsulated transition metal catalysts comprising peripheral Zn(ii)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

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Bidentate ligands by supramolecular chemistry—the future for catalysis?

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Template-induced formation of heterobidentate ligands and their application in the asymmetric hydroformylation of styrene

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Rigid bis-zinc(ii) salphen building blocks for the formation of template-assisted bidentate ligands and their application in catalysis

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Supramolecular bidentate phosphorus ligands based on bis-zinc(ii) and bis-tin(iv) porphyrin building blocks

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SUPRAPhos ligands for the regioselective rhodium catalyzed hydroformylation of styrene forming the linear aldehyde

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Reactivity modulation in container molecules

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Bis-(thiosemicarbazonato) Zn(ii) complexes as building blocks for construction of supramolecular catalysts

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Tandem decarboxylative hydroformylation–hydrogenation reaction of α,β-unsaturated carboxylic acids toward aliphatic alcohols under mild conditions employing a supramolecular catalyst system

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Conformational studies of ligand-template assemblies and the consequences for encapsulation of rhodium complexes and hydroformylation catalysis

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Rhodium-catalyzed hydroformylation of alkynes employing a self-assembling ligand system

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Supramolecular control of selectivity in transition-metal catalysis through substrate preorganization

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Molecular containers in complex chemical systems

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Transition metal catalysis in confined spaces

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Full kinetic analysis of a rhodium-catalyzed hydroformylation: beyond the rate-limiting step picture

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A self-emulsifying catalytic system for the aqueous biphasic hydroformylation of triglycerides

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Harnessing non-covalent interactions to exert control over regioselectivity and site-selectivity in catalytic reactions

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Scaffolding Catalysis: Expanding the Repertoire of Bifunctional Catalysts

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Tandem Regioselective Rhodium-Catalyzed Hydroformylation–Enantioselective Aminocatalytic anti-Mannich Reaction

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Self-assembly of bidentate ligands for combinatorial homogeneous catalysis based on an A-T base pair model

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Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4673734openalex-extracted

Triphenylphosphine-Derived Ligands for Rhodium-Catalyzed High Olefin Hydroformylations: From Traditional Molecules to Modern Cage Ligands

inferred← citeshttps://doi.org/10.1002/9781119870647.ch14openalex-snapshot

Hydroformylation Catalysts for the Synthesis of Fine Chemicals

inferred← citeshttps://doi.org/10.1002/9783527832033openalex-snapshot

Supramolecular Catalysis

inferred← citeshttps://doi.org/10.1002/ajoc.202300244openalex-snapshot

A Highly Active Hydroformylation Catalyst Using a Self‐Assembling Bis‐N‐Pyrrolyl Phosphine Ligand

inferred← citeshttps://doi.org/10.1002/ange.201809073openalex-snapshot

Tandem Regioselective Hydroformylation‐Hydrogenation of Internal Alkynes Using a Supramolecular Catalyst

inferred← citeshttps://doi.org/10.1002/ange.201810902openalex-snapshot

Mechanochemie gasförmiger Reaktanten

inferred← citeshttps://doi.org/10.1002/ange.201812610openalex-snapshot

Cofactor Controlled Encapsulation of a Rhodium Hydroformylation Catalyst

inferred← citeshttps://doi.org/10.1002/ange.201813148openalex-snapshot

Direct Carbohydroxylation of Arylalkenes with Allylic Alcohols: Cooperative Catalysis of Copper, Silver, and a Brønsted Acid

inferred← citeshttps://doi.org/10.1002/ange.201906111openalex-snapshot

Asymmetric Hydrocyanation of Alkenes without HCN

inferred← citeshttps://doi.org/10.1002/ange.201907366openalex-snapshot

Hydrogen Bond Directed ortho‐Selective C−H Borylation of Secondary Aromatic Amides

inferred← citeshttps://doi.org/10.1002/ange.201909865openalex-snapshot

Synergic Interplay Between Halogen Bonding and Hydrogen Bonding in the Activation of a Neutral Substrate in a Nanoconfined Space

inferred← citeshttps://doi.org/10.1002/ange.202000045openalex-snapshot

Supramolecular Strategies for Controlling Reactivity within Confined Nanospaces

inferred← citeshttps://doi.org/10.1002/ange.202211016openalex-snapshot

Sustainable Wacker‐Type Oxidations

inferred← citeshttps://doi.org/10.1002/ange.202411086openalex-snapshot

Metal–Organic Framework‐Induced Rh Monocoodination on Diphosphine Ligand Enables Catalytic Hydroformylation of Aliphatic Olefins at Room Temperature and Pressure

inferred← citeshttps://doi.org/10.1002/ange.202509042openalex-snapshot

Self‐Assembly of a Customizable Library of Nickel Trifluoromethylation Catalysts via Selective C─F and C─O Bond Cleavage

inferred← citeshttps://doi.org/10.1002/anie.201809073openalex-snapshot

Tandem Regioselective Hydroformylation‐Hydrogenation of Internal Alkynes Using a Supramolecular Catalyst

inferred← citeshttps://doi.org/10.1002/anie.201810902openalex-snapshot

Mechanochemistry of Gaseous Reactants

inferred← citeshttps://doi.org/10.1002/anie.201812610openalex-snapshot

Cofactor Controlled Encapsulation of a Rhodium Hydroformylation Catalyst

inferred← citeshttps://doi.org/10.1002/anie.201813148openalex-snapshot

Direct Carbohydroxylation of Arylalkenes with Allylic Alcohols: Cooperative Catalysis of Copper, Silver, and a Brønsted Acid

inferred← citeshttps://doi.org/10.1002/anie.201906111openalex-snapshot

Asymmetric Hydrocyanation of Alkenes without HCN

inferred← citeshttps://doi.org/10.1002/anie.201907366openalex-snapshot

Hydrogen Bond Directed ortho‐Selective C−H Borylation of Secondary Aromatic Amides

inferred← citeshttps://doi.org/10.1002/anie.201909865openalex-snapshot

Synergic Interplay Between Halogen Bonding and Hydrogen Bonding in the Activation of a Neutral Substrate in a Nanoconfined Space

inferred← citeshttps://doi.org/10.1002/anie.202000045openalex-snapshot

Supramolecular Strategies for Controlling Reactivity within Confined Nanospaces

inferred← citeshttps://doi.org/10.1002/anie.202211016openalex-snapshot

Sustainable Wacker‐Type Oxidations

inferred← citeshttps://doi.org/10.1002/anie.202411086openalex-snapshot

Metal–Organic Framework‐Induced Rh Monocoodination on Diphosphine Ligand Enables Catalytic Hydroformylation of Aliphatic Olefins at Room Temperature and Pressure

inferred← citeshttps://doi.org/10.1002/anie.202509042openalex-snapshot

Self‐Assembly of a Customizable Library of Nickel Trifluoromethylation Catalysts via Selective C─F and C─O Bond Cleavage

inferred← citeshttps://doi.org/10.1002/asia.201801302openalex-snapshot

Hydrogen‐Bonding‐Assisted Supramolecular Metal Catalysis

inferred← citeshttps://doi.org/10.1002/asia.202300935openalex-snapshot

Macrocyclic Sulfur Ligand Stabilized Trans‐Palladium Dichloride Complex: Syntheses, Structure, Chlorine Rotation, and Application in α‐Olefination of Nitriles by Primary Alcohols

inferred← citeshttps://doi.org/10.1002/cctc.201801551openalex-snapshot

Pillar5arenes as Supramolecular Hosts in Aqueous Biphasic Rhodium‐Catalyzed Hydroformylation of Long Alkyl‐chain Alkenes

inferred← citeshttps://doi.org/10.1002/cctc.201900089openalex-snapshot

Gold‐catalyzed Cycloisomerization Reactions within Guanidinium M12L24 Nanospheres: the Effect of Local Concentrations

inferred← citeshttps://doi.org/10.1002/cctc.201900487openalex-snapshot

Rational Redesign of a Regioselective Hydroformylation Catalyst for 3‐Butenoic Acid by Supramolecular Substrate Orientation

inferred← citeshttps://doi.org/10.1002/cctc.202001431openalex-snapshot

Molecularly Controlled Catalysis – Targeting Synergies Between Local and Non‐local Environments

inferred← citeshttps://doi.org/10.1002/cctc.202001610openalex-snapshot

Synthetic Application of Cyclodextrins in Combination with Metal Ions, Complexes, and Metal Particles

inferred← citeshttps://doi.org/10.1002/cctc.202101727openalex-snapshot

Caged Iridium Catalyst for Hydrosilylation of Alkynes with High Site Selectivity

inferred← citeshttps://doi.org/10.1002/cctc.202200541openalex-snapshot

Unraveling the Origin of the Regioselectivity of a Supramolecular Hydroformylation Catalyst

inferred← citeshttps://doi.org/10.1002/cctc.202201204openalex-snapshot

Understanding Rh‐catalysed Hydroformylation with Phosphite Ligands through Catalyst Speciation Analysis by Operando FlowNMR Spectroscopy

inferred← citeshttps://doi.org/10.1002/cctc.202201394openalex-snapshot

Iron‐Catalyzed Magnesium‐Mediated Formal Hydroformylation of Alkynes and Alkenes

inferred← citeshttps://doi.org/10.1002/cctc.202500979openalex-snapshot

Rh‐Catalyzed Asymmetric Hydroformylation: The Case of Substituted and Heterocyclic Olefins

inferred← citeshttps://doi.org/10.1002/cctc.202501023openalex-snapshot

Catalytic Hydrocyanation of Alkynes with HCN Surrogates: Advances and Challenges

inferred← citeshttps://doi.org/10.1002/chem.201805206openalex-snapshot

The Hexameric Resorcinarene Capsule at Work: Supramolecular Catalysis in Confined Spaces

inferred← citeshttps://doi.org/10.1002/chem.202000620openalex-snapshot

Regioselective Hydroformylation of Internal and Terminal Alkenes via Remote Supramolecular Control

inferred← citeshttps://doi.org/10.1002/chem.202203861openalex-snapshot

Control of Selectivity in Homogeneous Catalysis through Noncovalent Interactions

inferred← citeshttps://doi.org/10.1002/ejic.201801486openalex-snapshot

Bifunctional Pincer Catalysts for Chemoselective Transfer Hydrogenation and Related Reactions

inferred← citeshttps://doi.org/10.1002/ejic.201900974openalex-snapshot

Styrene Hydroformylation with Cavity‐Shaped Ligands

inferred← citeshttps://doi.org/10.1002/ejic.202100032openalex-snapshot

Reusable Catalysts for Hydroformylation‐Based Reactions

inferred← citeshttps://doi.org/10.1002/ejoc.201801309openalex-snapshot

Accelerated and Enantioselective Synthesis of a Library of P‐Stereogenic Urea Phosphines

inferred← citeshttps://doi.org/10.1002/ejoc.202300398openalex-snapshot

Modular Synthesis of Phosphite and Phosphoramidite Ligands for Rh‐Catalyzed Hydroformylation

inferred← citeshttps://doi.org/10.1002/ejoc.70722openalex-snapshot

Hydroformylation of Olefins With Paraformaldehyde Catalyzed by a Rhodium(I)/Diphosphine/Diphosphoramidite System

inferred← citeshttps://doi.org/10.1002/tcr.202100007openalex-snapshot

Phosphorus Ligands in Hydroformylation and Hydrogenation: A Personal Account

inferred← citeshttps://doi.org/10.1002/tcr.202300063openalex-snapshot

Recent Advances On Direct Formylation Reactions

inferred← citeshttps://doi.org/10.1007/s10562-019-02933-1openalex-snapshot

Chirally-Modified Graphite Oxide as Chirality Inducing Support for Asymmetric Epoxidation of Olefins with Grafted Manganese Porphyrin

inferred← citeshttps://doi.org/10.1007/s10562-025-05110-9openalex-snapshot

Phosphorylated Imidazole-Functionalized Chloromethylated Polystyrene-Supported Rhodium Catalyst for Hydroformylation of Dihydrofurans

inferred← citeshttps://doi.org/10.1007/s10847-019-00964-0openalex-snapshot

Coordination cages in catalysis

inferred← citeshttps://doi.org/10.1007/s12039-026-02479-xopenalex-snapshot

Exploring bisphenol-A derived bisphosphine ligands in Rh-catalysed hydroformylation of terminal alkenes

inferred← citeshttps://doi.org/10.1016/j.apcata.2020.117950openalex-snapshot

Hydroformylation of olefins using redox-active rhodium(I) alpha-diimine-cored aryl ether metallodendrimers

inferred← citeshttps://doi.org/10.1016/j.apcatb.2025.125952openalex-snapshot

Metal-organic framework-supported palladium(II) single-site as a solid catalyst for the hydroformylation and hydroxycarbonylation of styrene with formic acid

inferred← citeshttps://doi.org/10.1016/j.catcom.2018.09.020openalex-snapshot

Chiral calixarene and resorcinarene derivatives. Conical cavities substituted at their upper rim by two phosphito units and their use as ligands in Rh-catalysed hydroformylation

inferred← citeshttps://doi.org/10.1016/j.cattod.2024.115052openalex-snapshot

Low-nuclearity single-atom and supported metal cluster catalysts in ethylene and propylene hydroformylation

inferred← citeshttps://doi.org/10.1016/j.ccr.2025.216990openalex-snapshot

Hydroformylation of specific substrates as a perspective route to monomers and valuable bifunctional compounds

inferred← citeshttps://doi.org/10.1016/j.cej.2026.181569openalex-snapshot

Construction of a porous-ionic-polymer encapsulated Rh-TPPTS catalyst for regioselective hydroformylation

inferred← citeshttps://doi.org/10.1016/j.chempr.2021.12.012openalex-snapshot

Weak bonding strategies for achieving regio- and site-selective transformations

inferred← citeshttps://doi.org/10.1016/j.fuel.2026.141127openalex-snapshot

Co@C nanoparticles supported on interparticle porosity-dominated MFI zeolites with adjustable surface Lewis acidity for efficient and selective styrene hydroformylation

inferred← citeshttps://doi.org/10.1016/j.gresc.2021.04.008openalex-snapshot

Transition metal-catalyzed branch-selective hydroformylation of olefins in organic synthesis

inferred← citeshttps://doi.org/10.1016/j.isci.2023.106183openalex-snapshot

Single-atom catalysts for hydroformylation of olefins

inferred← citeshttps://doi.org/10.1016/j.jcat.2020.03.032openalex-snapshot

Enhancing regioselectivity via tuning the microenvironment in heterogeneous hydroformylation of olefins

inferred← citeshttps://doi.org/10.1016/j.jcat.2021.04.021openalex-snapshot

Mechanistic insight into formaldehyde hydroformylation catalyzed by rhodium complexes: A theoretical and experimental study

inferred← citeshttps://doi.org/10.1016/j.jcat.2022.03.030openalex-snapshot

Flexible homogeneous hydroformylation: on-demand tuning of aldehyde branching with a cyclic fluorophosphite ligand

inferred← citeshttps://doi.org/10.1016/j.jcat.2024.115394openalex-snapshot

Enhanced regioselectivity in propylene hydroformylation using Xantphos-modified single-atom Rh/CeO2 catalyst

inferred← citeshttps://doi.org/10.1016/j.jcat.2025.116382openalex-snapshot

Highly selective rhodium-catalyzed bis-hydroformylation of 1,7-octadiene to decanedial

inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2026.113409openalex-snapshot

A review on sulfonamides and their coordination compounds: Fighting diseases and catalytic applications

inferred← citeshttps://doi.org/10.1016/j.jorganchem.2020.121417openalex-snapshot

Sequential catalytic carbonylation reactions for sustainable synthesis of biologically relevant entities

inferred← citeshttps://doi.org/10.1016/j.jscs.2021.101260openalex-snapshot

Regio- and stereoselective functionalization of alkenes with emphasis on mechanistic insight and sustainability concerns

inferred← citeshttps://doi.org/10.1016/j.molstruc.2019.127491openalex-snapshot

Structures of ten organic salts from 2-aminothiazole/2-aminobenzothiazole and acidic compounds

inferred← citeshttps://doi.org/10.1016/j.molstruc.2021.132208openalex-snapshot

Non-covalent bonded 1D-3D supramolecular salts from tert‑butylamine and organic acids

inferred← citeshttps://doi.org/10.1016/j.xcrp.2024.101983openalex-snapshot

Ligand-induced suppression of undesirable pathways in cobalt-catalyzed hydroformylation

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c03365openalex-snapshot

Linear Free Energy Relationships Associated with Hydride Transfer From [(6,6′-R2-bpy)Re(CO)3H]: A Cautionary Tale in Identifying Hydrogen Bonding Effects in the Secondary Coordination Sphere

inferred← citeshttps://doi.org/10.1021/acs.joc.1c00884openalex-snapshot

Base-Catalyzed, Solvent-Free Synthesis of Rigid V-Shaped Epoxydibenzo[b,f][1,5]diazocines

inferred← citeshttps://doi.org/10.1021/acs.organomet.2c00442openalex-snapshot

Synergistic Ligand Effect in Rhodium(I)-Catalyzed Regio-Controlled Propene Hydroformylation

inferred← citeshttps://doi.org/10.1021/acs.organomet.3c00333openalex-snapshot

Carbon Dioxide Insertion into Rhenium Hydrides as a Probe for the Impact of Solvent on Linear Free Energy Relationships between Thermodynamic and Kinetic Hydricity

inferred← citeshttps://doi.org/10.1021/acs.orglett.2c03091openalex-snapshot

Regulation of Chiral Phosphoric Acid Catalyzed Asymmetric Reaction through Crown Ether Based Host–Guest Chemistry

inferred← citeshttps://doi.org/10.1021/acsami.4c08030openalex-snapshot

A Host–Guest Approach to Engineering Oxidase-Mimetic Assembly with Substrate Selectivity and Dynamic Catalysis

inferred← citeshttps://doi.org/10.1021/acscatal.4c03510openalex-snapshot

A Resorcin[4]arene-Based Phosphite-Phosphine Ligand for the Branched-Selective Hydroformylation of Alkyl Alkenes

inferred← citeshttps://doi.org/10.1021/acscatal.5c06595openalex-snapshot

Bayesian Optimization for Resource-Efficient Hydroformylation

inferred← citeshttps://doi.org/10.1021/acssuschemeng.3c07517openalex-snapshot

Composite Catalyst of Rh/POP-BINAPa&PPh3@ZSM-35(10) for the Heterogeneous Tandem Hydroformylation–Acetalization of Olefins

inferred← citeshttps://doi.org/10.1021/acssuschemeng.4c01883openalex-snapshot

Heterogeneous Bisphosphine Ligand-Encapsulated Rh Catalysts for Heterogeneous Hydroformylation of Alkenes with CO2

inferred← citeshttps://doi.org/10.1021/jacs.0c01563openalex-snapshot

Chiral Metallacycles as Catalysts for Asymmetric Conjugate Addition of Styrylboronic Acids to α,β-Enones

inferred← citeshttps://doi.org/10.1021/jacs.0c06942openalex-snapshot

Unraveling the Importance of Noncovalent Interactions in Asymmetric Hydroformylation Reactions

inferred← citeshttps://doi.org/10.1021/jacs.0c11601openalex-snapshot

Selecting Double Bond Positions with a Single Cation-Responsive Iridium Olefin Isomerization Catalyst

inferred← citeshttps://doi.org/10.1021/jacs.1c04924openalex-snapshot

Just Add Water: Modulating the Structure-Derived Acidity of Catalytic Hexameric Resorcinarene Capsules

inferred← citeshttps://doi.org/10.1021/jacs.2c04182openalex-snapshot

Impact of Host Flexibility on Selectivity in a Supramolecular Host-Catalyzed Enantioselective aza-Darzens Reaction

inferred← citeshttps://doi.org/10.1021/jacs.2c07192openalex-snapshot

Correlating Thermodynamic and Kinetic Hydricities of Rhenium Hydrides

inferred← citeshttps://doi.org/10.1021/jacs.5c07415openalex-snapshot

Thiophenol-Catalyzed Radical Hydroformylation of Unactivated Sterically Hindered Alkenes

inferred← citeshttps://doi.org/10.1021/jacs.5c08248openalex-snapshot

Elucidation of Marcus Relationships for Hydride Transfer Reactions Involving Transition Metal Hydrides

inferred← citeshttps://doi.org/10.1021/jacs.9b05604openalex-snapshot

A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length

inferred← citeshttps://doi.org/10.1038/s41467-019-11080-5openalex-snapshot

Bio-inspired creation of heterogeneous reaction vessels via polymerization of supramolecular ion pair

inferred← citeshttps://doi.org/10.1038/s41467-019-12770-wopenalex-snapshot

A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis

inferred← citeshttps://doi.org/10.1038/s41467-021-25061-0openalex-snapshot

Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins

inferred← citeshttps://doi.org/10.1038/s41929-020-00528-3openalex-snapshot

Advances in supramolecular host-mediated reactivity

inferred← citeshttps://doi.org/10.1038/s41929-022-00843-xopenalex-snapshot

Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis

inferred← citeshttps://doi.org/10.1039/c9qo00224copenalex-snapshot

A hexameric resorcinarene capsule as a hydrogen bonding catalyst in the conjugate addition of pyrroles and indoles to nitroalkenes

inferred← citeshttps://doi.org/10.1039/c9sc02558hopenalex-snapshot

Effector responsive hydroformylation catalysis

inferred← citeshttps://doi.org/10.1039/d1cs00175bopenalex-snapshot

New horizons for catalysis disclosed by supramolecular chemistry

inferred← citeshttps://doi.org/10.1039/d1cy00737hopenalex-snapshot

Recent developments in asymmetric hydroformylation

inferred← citeshttps://doi.org/10.1039/d1cy01754copenalex-snapshot

Valorisation of mixtures of linear alkenes using cobalt-mediated isomerisation and hydroformylation chemistries

inferred← citeshttps://doi.org/10.1039/d1dt02131aopenalex-snapshot

Supramolecular catalysis: the role of H-bonding interactions in substrate orientation and activation

inferred← citeshttps://doi.org/10.1039/d2gc04195bopenalex-snapshot

Coordination assembly enables highly selective catalytic hydroaminomethylation of olefins

inferred← citeshttps://doi.org/10.1039/d3dt00375bopenalex-snapshot

A palladium complex of a macrocyclic selenium ligand: catalyst for the dehydroxymethylation of dihydroxy compounds

inferred← citeshttps://doi.org/10.1039/d3fd00023kopenalex-snapshot

A substrate descriptor based approach for the prediction and understanding of the regioselectivity in caged catalyzed hydroformylation

inferred← citeshttps://doi.org/10.1039/d3py00311fopenalex-snapshot

Palladium-catalyzed polar solvent empowered synthesis of hyper-branched ethylene oligomers and their applications

inferred← citeshttps://doi.org/10.1039/d3sc02151copenalex-snapshot

Structural and dimensional control of porphyrin capsules using Group 15 tris(3-pyridyl) linkers

inferred← citeshttps://doi.org/10.1039/d4cp00011kopenalex-snapshot

Spectroscopic characterization of carbon monoxide activation by neutral chromium carbides

inferred← citeshttps://doi.org/10.1039/d4cy00051jopenalex-snapshot

Substrate scope driven optimization of an encapsulated hydroformylation catalyst

inferred← citeshttps://doi.org/10.1039/d4cy00516copenalex-snapshot

Penta- versus hexa-coordinated iridium catalysts control the reactivity of the direct reductive amination between aliphatic amines and aliphatic ketones: a DFT-guided mechanism

inferred← citeshttps://doi.org/10.1039/d4dt02519aopenalex-snapshot

Supramolecular bidentate rhodium( i ) or iridium( i ) phosphine and oxazoline amino acid bioconjugates as selective catalysts for enantioselective reactions

inferred← citeshttps://doi.org/10.1039/d4dt02627fopenalex-snapshot

Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications

inferred← citeshttps://doi.org/10.1039/d4ob00714jopenalex-snapshot

Highly (regio)selective hydroformylation of olefins using self-assembling phosphines

inferred← citeshttps://doi.org/10.1039/d4ob00886copenalex-snapshot

A macrocycle-based new organometallic nano-vessel towards sustainable C2-selective arylation of free indole in water

inferred← citeshttps://doi.org/10.1039/d4su00662copenalex-snapshot

Hydroformylation, hydroaminomethylation and related tandem reactions of bio-derived renewable olefins: a step closer to sustainability

inferred← citeshttps://doi.org/10.1039/d5cy01127bopenalex-snapshot

Efficient synthesis of π-acidic phosphorus-containing porous polymer supported catalysts for hydroformylation of olefins

inferred← citeshttps://doi.org/10.1039/d5cy01398dopenalex-snapshot

Mechanism-informed machine learning for rational catalyst design: application to regioselectivity of allyl acetate hydroformylation

inferred← citeshttps://doi.org/10.1039/d5qi02352aopenalex-snapshot

Solvatochrony: solvatochronic photocatalysts and their applications in intermolecular [2 + 2] cycloaddition reactions of unactivated styrenes

inferred← citeshttps://doi.org/10.1055/a-2012-4754openalex-snapshot

Iodide-Assisted Pd Catalysis as an Attractive Alternative to Rh Catalysis for the Industrially Relevant Isoselective Hydroformylation of Simple Aliphatic Alkenes

inferred← citeshttps://doi.org/10.1070/rcr5011openalex-snapshot

Functional supramolecular systems: design and applications

inferred← citeshttps://doi.org/10.2533/chimia.2020.561openalex-snapshot

Molecular Capsule Catalysis: Ready to Address Current Challenges in Synthetic Organic Chemistry?

inferred← citeshttps://doi.org/10.26599/nr.2026.94908341openalex-snapshot

Silanol nest-assisted Rh nanoparticles inducing homogeneous-like kinetics in heterogeneous hydroformylation

inferred← citeshttps://doi.org/10.31635/ccschem.021.202101286openalex-snapshot

Whither Second-Sphere Coordination?

inferred← citeshttps://doi.org/10.3390/ma18122691openalex-snapshot

Boosting Hydroformylation via Reactant Enrichment in Covalent Triazine Frameworks with Atomically Dispersed Rh

inferred← citeshttps://doi.org/10.3390/molecules29092039openalex-snapshot

P(V)-Promoted Rh-Catalyzed Highly Regioselective Hydroformylation of Styrenes under Mild Conditions

inferred← citeshttps://doi.org/10.34133/research.0466openalex-snapshot

Monomeric, Oligomeric, Polymeric, and Supramolecular Cyclodextrins as Catalysts for Green Chemistry

inferred← citeshttps://doi.org/10.4995/thesis/10251/203121openalex-snapshot

Catalizadores heterogéneos de rodio y cobalto para la hidroformilación de olefinas y la reacción de evolución del hidrógeno

inferred← citeshttps://doi.org/10.6023/cjoc202405034openalex-snapshot

Progress in Heterogeneous Catalyzed Tandem Reactions Based on Hydroformylation

inferred← citeshttps://doi.org/10.6023/cjoc202412013openalex-snapshot

Synthesis of Phosphine Ligands via a Coordination Assembly Strategy and Their Applications in Hydroformylation

inferred← citeshttps://doi.org/10.70675/9a82da04zb70bz4054zaf48z83a07717baafopenalex-snapshot

Synthesis of Carboxylic Acids from Oxygenated Substrates, CO2 and H2

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