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Bidentate ligands by supramolecular chemistry—the future for catalysis?

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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The materials chemistry of porphyrins and metalloporphyrins

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Porphyrin Tessellation by Design: Metal-Mediated Self-Assembly of Large Arrays and Tapes

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Metalloporphyrin Dendrimers with Folding Arms

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Self-Assembled Porphyrin Polymers

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A Modular Approach to Structurally Diverse Bidentate Chelate Ligands for Transition Metal Catalysis

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Highly Enantioselective Rh-Catalyzed Hydrogenation Reactions Based on Chiral Monophosphite Ligands

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Combinatorial and Evolution-Based Methods in the Creation of Enantioselective Catalysts

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Enantioselective Hydrogenation of the Tetrasubstituted C=C Bond of Enamides Catalyzed by a Ruthenium Catalyst Generatedin situ

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Identification of Suitable Ligands for a Transition Metal-Catalyzed Reaction: Screening of a Modular Ligand Library in the Enantioselective Hydroboration of Styrene

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Handbook of Combinatorial Chemistry: Drugs, Catalysts, Materials

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Applied Homogeneous Catalysis with Organometallic Compounds

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Ruthenium‐Catalysed Enantioselective Hydrogenation of Trisubstituted Enamides Derived from 2‐Tetralone and 3‐Chromanone: Influence of Substitution on the Amide Arm and the Aromatic Ring

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Bidentate Ligands by Self‐Assembly through Hydrogen Bonding: A General Room Temperature/Ambient Pressure Regioselective Hydroformylation of Terminal Alkenes

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Synthesis and Structure of the First Stable Germaneselone

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Assembly and Crystal Structure of a Photoactive Array of Five Porphyrins

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New Catalysts and Conditions for a CH Insertion Reaction Identified by High Throughput Catalyst Screening

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Self‐Assembly of an Artificial Light‐Harvesting Antenna: Energy Transfer from a Zinc Chlorin to a Bacteriochlorin in a Supramolecular Aggregate

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Electrospray Ionization Tandem Mass Spectrometry in High‐Throughput Screening of Homogeneous Catalysts

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Multicomponent Porphyrin Assemblies as Functional Bidentate Phosphite Ligands for Regioselective Rhodium‐Catalyzed Hydroformylation

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A New Principle in Combinatorial Asymmetric Transition‐Metal Catalysis: Mixtures of Chiral Monodentate P Ligands

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Self‐Assembly of Bidentate Ligands for Combinatorial Homogeneous Catalysis Based on an A–T Base‐Pair Model

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Mixtures of Configurationally Stable and Fluxional Atropisomeric Monodentate P Ligands in Asymmetric Rh‐Catalyzed Olefin Hydrogenation

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Achiral Ligands Dramatically Enhance Rate and Enantioselectivity in the Rh/Phosphoramidite‐Catalyzed Hydrogenation of α,β‐Disubstituted Unsaturated Acids

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Screening of a Supramolecular Catalyst Library in the Search for Selective Catalysts for the Asymmetric Hydrogenation of a Difficult Enamide Substrate

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Self‐Assembled Bidentate Ligands for Ru‐Catalyzed anti ‐Markovnikov Hydration of Terminal Alkynes

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Cover Picture: Retro‐Cycloaddition Reaction of Pyrrolidinofullerenes (Angew. Chem. Int. Ed. 1/2006)

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Combinatorial Chemistry Approach to Chiral Catalyst Engineering and Screening: Rational Design and Serendipity

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Insights into CO/Styrene Copolymerization by Using PdII Catalysts Containing Modular Pyridine–Imidazoline Ligands

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ZnII–Salphen Complexes as Versatile Building Blocks for the Construction of Supramolecular Box Assemblies

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Rh‐Catalyzed Asymmetric Hydrogenation of Prochiral Olefins with a Dynamic Library of Chiral TROPOS Phosphorus Ligands

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The Power of High‐Throughput Experimentation in Homogeneous Catalysis Research for Fine Chemicals

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The Natural Bite Angle of Chelating Diphosphines

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Recent advances in enantioselective hydroformylation

inferredcites →https://doi.org/10.1016/j.jorganchem.2005.02.026openalex-snapshot

Supraphos: A supramolecular strategy to prepare bidentate ligands

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Combinatorial approach to the asymmetric hydrogenation of β-acylamino acrylates: use of mixtures of chiral monodentate P-ligands

inferredcites →https://doi.org/10.1016/j.tetasy.2004.04.037openalex-snapshot

Chiral monodentate phosphorus ligands for rhodium-catalyzed asymmetric hydrogenation

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Mixtures of chiral monodentate phosphites, phosphonites and phosphines as ligands in Rh-catalyzed hydrogenation of N-acyl enamines: extension of the combinatorial approach

inferredcites →https://doi.org/10.1016/s0010-8545(99)00041-7openalex-snapshot

Supramolecular assemblies of ruthenium complexes and porphyrins

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Rapid derivatization of mesoporous thin-film materials based on Re(I) zinc-porphyrin ‘molecular squares’: selective modification of mesopore size and shape by binding of aromatic nitrogen donor ligands

inferredcites →https://doi.org/10.1016/s0010-8545(99)00207-6openalex-snapshot

Poly- and oligometalloporphyrins associated through coordination

inferredcites →https://doi.org/10.1016/s0010-8545(99)00211-8openalex-snapshot

Self-assembly of metallopyridylporphyrin oligomers

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New general synthetic methods involving π-allylpalladium complexes as intermediates and neutral reaction conditions

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Synthesis and first applications of a new family of chiral monophosphine ligand: 2,5-diphenylphosphospholanes

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Alternative synthesis of the chiral atypical β-adrenergicphenylethanolaminotetraline agonist SR58611A using enantioselective hydrogenation

inferredcites →https://doi.org/10.1016/s0926-860x(01)00886-9openalex-snapshot

Applications of combinatorial methods in catalysis

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Chiral semicorrins and related nitrogen heterocycles as ligands in asymmetric catalysis

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PhosphinooxazolinesA New Class of Versatile, Modular P,N-Ligands for Asymmetric Catalysis

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Photoinduced electron transfer in supramolecular systems for artificial photosynthesis

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Asymmetric Hydroformylation

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Asymmetric Transition-Metal-Catalyzed Allylic Alkylations: Applications in Total Synthesis

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New Chiral Phosphorus Ligands for Enantioselective Hydrogenation

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Combinatorial Libraries of Chiral Ligands for Enantioselective Catalysis

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Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis

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Asymmetric Transition Metal-Catalyzed Allylic Alkylations

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Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation

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Coordination oligomers and a coordination polymer of zinc tetraarylporphyrins

inferredcites →https://doi.org/10.1021/ic051110fopenalex-snapshot

Palladium and Rhodium Ureaphosphine Complexes: Exploring Structural and Catalytic Consequences of Anion Binding

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Dabco-metalloporphyrin binding: ternary complexes, host-guest chemistry and the measurement of .pi.-.pi. interactions

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Thermodynamics of induced-fit binding inside polymacrocyclic porphyrin hosts

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Highly Enantioselective Rhodium-Catalyzed Hydrogenation with Monodentate Ligands

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Electron donor-acceptor properties of phosphorus ligands. Substituent additivity

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A Highly Enantioselective Intramolecular Heck Reaction with a Monodentate Ligand

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Hydrogen Bonding as a Construction Element for Bidentate Donor Ligands in Homogeneous Catalysis: Regioselective Hydroformylation of Terminal Alkenes

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Supraphos: A Supramolecular Strategy To Prepare Bidentate Ligands

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Asymmetric Catalysis Using Self-Assembled Chiral Bidentate P,P-Ligands

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Self-Assembly of Bidentate Ligands for Combinatorial Homogeneous Catalysis: Asymmetric Rhodium-Catalyzed Hydrogenation

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Cooperative Self-Assembly of Double-Strand Conjugated Porphyrin Ladders

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Asymmetric Synthesis of MK-0499

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Rational Syntheses of Cyclic Hexameric Porphyrin Arrays for Studies of Self-Assembling Light-Harvesting Systems

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Modular Approach to Novel Chiral Aryl-Ferrocenyl Phosphines by Suzuki Cross-Coupling

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PipPhos and MorfPhos: Privileged Monodentate Phosphoramidite Ligands for Rhodium-Catalyzed Asymmetric Hydrogenation

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Highly Enantioselective Hydrogenation of Cyclic Enamides Catalyzed by a Rh-PennPhos Catalyst

inferredcites →https://doi.org/10.1021/ol000129dopenalex-snapshot

Self-Assembly of Oligomeric Porphyrin Rings

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An ortho-Substituted BIPHEP Ligand and Its Applications in Rh-Catalyzed Hydrogenation of Cyclic Enamides

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Porphyrin-Containing Molecular Capsules: Metal Mediated Dimerization of a Bis-Porphyrin Cavity

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Catechol-Based Phosphoramidites: A New Class of Chiral Ligands for Rhodium-Catalyzed Asymmetric Hydrogenations

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Supramolecular trans-Coordinating Phosphine Ligands

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2H NMR Investigation of the Rhodium-Catalyzed Deuterioformylation of 1,1-Diphenylethene: Evidence for the Formation of a Tertiary Alkyl−Metal Intermediate

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Combinatorial and rapid screening approaches to homogeneous catalyst discovery and optimization

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Phosphine-substituted porphyrins as supramolecular building blocks

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The metal-directed self-assembly of three-dimensional porphyrin arrays

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Formation of A2B2 supramolecular porphyrin co-polymers

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Improving conversion and enantioselectivity in hydrogenation by combining different monodentate phosphoramidites; a new combinatorial approach in asymmetric catalysisElectronic supplementary information (ESI) available: Experimental details. See http://www.rsc.org/suppdata/ob/b3/b302097e/

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Bidentate ligands formed by self-assemblyElectronic supplementary information (ESI) available: ligand synthesis and detailed experimental data. See http://www.rsc.org/suppdata/cc/b3/b306683e/

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Multivalency in supramolecular chemistry and nanofabrication

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Anion-assisted trans–cis isomerization of palladium( ii ) phosphine complexes containing acetanilide functionalities through hydrogen bonding interactions

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New directions in supramolecular transition metal catalysis

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Encapsulated transition metal catalysts comprising peripheral Zn(ii)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

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Self-assembly of macrocyclic porphyrin oligomers

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Photoinduced electron transfer on a supramolecular scaffold

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Optically Active Amine Derivatives: Ruthenium-Catalyzed Enantioselective Hydrogenation of Enamides

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Combinatorial Methods for the Discovery and Optimisation of Homogeneous Catalysts

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Thermographic Selection of Effective Catalysts from an Encoded Polymer-Bound Library

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Handbook of Chiral Chemicals

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Self-assembly of bidentate ligands for combinatorial homogeneous catalysis based on an A-T base pair model

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Rhodium-catalyzed asymmetric hydrogenation using self-assembled chiral bidentate ligands

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Supramolecular Hybrid Bidentate Ligands in Asymmetric Hydrogenation

inferred← citeshttps://doi.org/10.1002/ejoc.200800499openalex-snapshot

Synthesis of Building Blocks for the Development of the SUPRAPhos Ligand Library and Examples of Their Application in Catalysis

inferred← citeshttps://doi.org/10.1002/ejoc.200900158openalex-snapshot

Combinations of Acidic and Basic Monodentate Binaphtholic Phosphites as Supramolecular Bidentate Ligands for Enantioselective Rh‐Catalyzed Hydrogenations

inferred← citeshttps://doi.org/10.1002/ejoc.201200516openalex-snapshot

SupraBox: Chiral Supramolecular Oxazoline Ligands

inferred← citeshttps://doi.org/10.1002/ijch.201200002openalex-snapshot

Supramolecular Self‐Assembled Ligands in Asymmetric Transition Metal Catalysis

inferred← citeshttps://doi.org/10.1002/ijch.201200080openalex-snapshot

Development of an Enzyme Mimic Using Self‐Selection

inferred← citeshttps://doi.org/10.1002/ijch.201200083openalex-snapshot

Dynamic Combinatorial Chemistry in Chemical Catalysis

inferred← citeshttps://doi.org/10.1007/s10904-011-9596-1openalex-snapshot

A Microporous 1D Heterometallic Coordination Polymer Based on Phosphine–Ag5Cl4 Saddle Unit

inferred← citeshttps://doi.org/10.1016/j.catcom.2014.11.030openalex-snapshot

Cyclodextrins as first and second sphere ligands for Rh(I) complexes of lower-rim PTA derivatives for use as catalysts in aqueous phase hydrogenation

inferred← citeshttps://doi.org/10.1016/j.ccr.2009.12.003openalex-snapshot

Coordination motifs in modern supramolecular chemistry

inferred← citeshttps://doi.org/10.1016/j.ccr.2013.10.024openalex-snapshot

Hybrid diphosphorus ligands in rhodium catalysed asymmetric hydroformylation

inferred← citeshttps://doi.org/10.1016/j.ica.2011.02.076openalex-snapshot

Different coordination behavior of a catechol phosphine and its sulfide: Formation of an unprecedented dinuclear rhodium complex with a non-coordinated P S unit

inferred← citeshttps://doi.org/10.1016/j.poly.2009.06.010openalex-snapshot

A one pot multi-component CuAAC “click” approach to bidentate and tridentate pyridyl-1,2,3-triazole ligands: Synthesis, X-ray structures and copper(II) and silver(I) complexes

inferred← citeshttps://doi.org/10.1016/j.poly.2013.05.008openalex-snapshot

Two in one: Charged tertiary phosphines held together by ionic or covalent interactions as bidentate phosphorus ligands for synthesis of half-sandwich Ru(II)-complexes

inferred← citeshttps://doi.org/10.1016/j.tet.2013.12.040openalex-snapshot

Metathesis for catalyst design: metacatalysis

inferred← citeshttps://doi.org/10.1016/j.tetasy.2008.04.008openalex-snapshot

Assembly of chiral monodentate ligands to chelates by donor–acceptor interactions

inferred← citeshttps://doi.org/10.1016/j.tetasy.2009.04.001openalex-snapshot

Chiral (salen)Co(III)(N-benzyl-l-serine)-derived phosphites: monodentate P-ligands for enantioselective catalytic applications

inferred← citeshttps://doi.org/10.1016/j.tetlet.2007.02.127openalex-snapshot

Improved synthesis of monodentate and bidentate 2- and 3-pyridylphosphines

inferred← citeshttps://doi.org/10.1016/j.tetlet.2007.11.201openalex-snapshot

Highly enantioselective Rh-catalyzed hydrogenations with heterocombinations of pentafluorobenzyl- and methoxybenzyl-derived binaphthyl phosphites

inferred← citeshttps://doi.org/10.1016/j.tetlet.2008.03.039openalex-snapshot

Supramolecular chiral phosphorous ligands based on a [2]pseudorotaxane complex for asymmetric hydrogenation

inferred← citeshttps://doi.org/10.1016/j.tetlet.2025.155955openalex-snapshot

The structure-property correlation in homocoupling reaction; a case study by clamshell and planar palladium complexes

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b01923openalex-snapshot

H-Bonding Assisted Self-Assembly of Anionic and Neutral Ligand on Metal: A Comprehensive Strategy To Mimic Ditopic Ligands in Olefin Polymerization

inferred← citeshttps://doi.org/10.1021/acs.joc.5b00438openalex-snapshot

Enantioselective Synthesis of Tunable Chiral Clickphine P,N-Ligands and Their Application in Ir-Catalyzed Asymmetric Hydrogenation

inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00664openalex-snapshot

Highly Enantioselective Pd-Catalyzed Synthesis of P-Stereogenic Supramolecular Phosphines, Self-Assembly, and Implication

inferred← citeshttps://doi.org/10.1021/acscatal.4c05893openalex-snapshot

Bifunctional Photocatalysts Display Proximity-Enhanced Catalytic Activity in Metallaphotoredox C–O Coupling

inferred← citeshttps://doi.org/10.1021/acscatal.8b00288openalex-snapshot

Supramolecular Approaches To Control Activity and Selectivity in Hydroformylation Catalysis

inferred← citeshttps://doi.org/10.1021/acscatal.9b01809openalex-snapshot

Origin of the Selectivity and Activity in the Rhodium-Catalyzed Asymmetric Hydrogenation Using Supramolecular Ligands

inferred← citeshttps://doi.org/10.1021/acscatal.9b02894openalex-snapshot

Catalysis of Organic Reactions through Halogen Bonding

inferred← citeshttps://doi.org/10.1021/ic200789bopenalex-snapshot

Palladium(II) Complexes of Readily Functionalized Bidentate 2-Pyridyl-1,2,3-triazole “Click” Ligands: A Synthetic, Structural, Spectroscopic, and Computational Study

inferred← citeshttps://doi.org/10.1021/ja208589copenalex-snapshot

“Cofactor”-Controlled Enantioselective Catalysis

inferred← citeshttps://doi.org/10.1021/ja4046235openalex-snapshot

Precise Supramolecular Control of Selectivity in the Rh-Catalyzed Hydroformylation of Terminal and Internal Alkenes

inferred← citeshttps://doi.org/10.1021/om100583popenalex-snapshot

Cyclodextrin-Based Supramolecular P,N Bidentate Ligands and their Platinum and Rhodium Complexes

inferred← citeshttps://doi.org/10.1021/om1006215openalex-snapshot

Assembly of Tunable Supramolecular Organometallic Catalysts with Cyclodextrins

inferred← citeshttps://doi.org/10.1021/om801204aopenalex-snapshot

INDOLPhosphole and INDOLPhos Palladium−Allyl Complexes in Asymmetric Allylic Alkylations

inferred← citeshttps://doi.org/10.1021/om901028zopenalex-snapshot

Phosphinoureas: Cooperative Ligands in Rhodium-Catalyzed Hydroformylation? On the Possibility of a Ligand-Assisted Reductive Elimination of the Aldehyde

inferred← citeshttps://doi.org/10.1039/9781788016490-00168openalex-snapshot

Noncovalent Interactions in Hydrogenation and Hydroformylation

inferred← citeshttps://doi.org/10.1039/b609321copenalex-snapshot

Template-induced formation of heterobidentate ligands and their application in the asymmetric hydroformylation of styrene

inferred← citeshttps://doi.org/10.1039/b614571jopenalex-snapshot

UREAphos: supramolecular bidentate ligands for asymmetric hydrogenation

inferred← citeshttps://doi.org/10.1039/b616102bopenalex-snapshot

Template controlled self-assembly of bidentate phosphine complexes with hemilabile coordination behaviour

inferred← citeshttps://doi.org/10.1039/b700156hopenalex-snapshot

SUPRAphos-based palladium catalysts for the kinetic resolution of racemic cyclohexenyl acetate

inferred← citeshttps://doi.org/10.1039/b702375hopenalex-snapshot

Rigid bis-zinc(ii) salphen building blocks for the formation of template-assisted bidentate ligands and their application in catalysis

inferred← citeshttps://doi.org/10.1039/b702462mopenalex-snapshot

Supramolecular bidentate phosphorus ligands based on bis-zinc(ii) and bis-tin(iv) porphyrin building blocks

inferred← citeshttps://doi.org/10.1039/b708252eopenalex-snapshot

Boron templated catechol phosphines as bidentate ligands in silver complexes

inferred← citeshttps://doi.org/10.1039/b711551bopenalex-snapshot

Solid-state NMR studies of weak interactions in supramolecular systems

inferred← citeshttps://doi.org/10.1039/b716529copenalex-snapshot

Supramolecular PhanePhos-analogous ligands through hydrogen-bonding for asymmetric hydrogenation

inferred← citeshttps://doi.org/10.1039/b818665kopenalex-snapshot

SUPRAPhos ligands for the regioselective rhodium catalyzed hydroformylation of styrene forming the linear aldehyde

inferred← citeshttps://doi.org/10.1039/b911339hopenalex-snapshot

Supramolecular NHC ligands: on the influence of ZnII-templates on the activity of RhI(cod) complexes in ‘carbene polymerization’

inferred← citeshttps://doi.org/10.1039/b926043aopenalex-snapshot

Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions

inferred← citeshttps://doi.org/10.1039/c003352aopenalex-snapshot

Heterotopic silver–NHC complexes: from coordination polymers to supramolecular assemblies

inferred← citeshttps://doi.org/10.1039/c0cy00022aopenalex-snapshot

SPOs as new ligands in Rh(iii) catalyzed enantioselective transfer hydrogenation

inferred← citeshttps://doi.org/10.1039/c0dt01105copenalex-snapshot

Coulombic inter-ligand repulsion effects on the Pt(ii) coordination chemistry of oligocationic, ammonium-functionalized triarylphosphines

inferred← citeshttps://doi.org/10.1039/c0dt01517bopenalex-snapshot

Supramolecular ligand–ligand and ligand–substrate interactions for highly selective transition metal catalysis

inferred← citeshttps://doi.org/10.1039/c0nj00020eopenalex-snapshot

Stoichiometry controlled self-assembly of tri- and octa-nuclear palladium–yttrium complexes

inferred← citeshttps://doi.org/10.1039/c0ob00732copenalex-snapshot

Hybrid bidentate phosphorus ligands in asymmetric catalysis: Privileged ligand approach vs. combinatorial strategies

inferred← citeshttps://doi.org/10.1039/c1cc16326dopenalex-snapshot

Cyclodextrin–phosphane possessing a guest-tunable conformation for aqueous rhodium-catalyzed hydroformylation

inferred← citeshttps://doi.org/10.1039/c1dt10621jopenalex-snapshot

Effects of subtle differences in ligand constitution and conformation in metallo-supramolecular self-assembled polygons

inferred← citeshttps://doi.org/10.1039/c1ob06180aopenalex-snapshot

Rapid, in situ synthesis of bidentate ligands: chromatography-free generation of catalyst libraries

inferred← citeshttps://doi.org/10.1039/c3dt00078hopenalex-snapshot

Supramolecular bulky phosphines comprising 1,3,5-triaza-7-phosphaadamantane and Zn(salphen)s: structural features and application in hydrosilylation catalysis

inferred← citeshttps://doi.org/10.1039/c4sc02555eopenalex-snapshot

Dehydrogenation of formic acid by Ir–bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand

inferred← citeshttps://doi.org/10.1039/c6cc09198aopenalex-snapshot

Supramolecular bidentate phosphine ligand scaffolds from deconstructed Hamilton receptors

inferred← citeshttps://doi.org/10.1039/c6ce01324dopenalex-snapshot

The impact of modular substitution on crystal packing: the tale of two ureas

inferred← citeshttps://doi.org/10.1039/c7cc09537fopenalex-snapshot

Controlling orthogonal self-assembly through cis – trans isomerization of a non-covalent palladium complex dimer

inferred← citeshttps://doi.org/10.1039/c7cs00844aopenalex-snapshot

Ligand libraries for high throughput screening of homogeneous catalysts

inferred← citeshttps://doi.org/10.1039/c7dt02923copenalex-snapshot

Self-assembly of P-chiral supramolecular phosphines on rhodium and direct evidence for Rh-catalyst-substrate interactions

inferred← citeshttps://doi.org/10.1039/c8ob02249fopenalex-snapshot

Aromatic donor–acceptor interaction promoted catalyst assemblies for hydrolytic kinetic resolution of epichlorohydrin

inferred← citeshttps://doi.org/10.1039/c8sc00233aopenalex-snapshot

XBphos-Rh: a halogen-bond assembled supramolecular catalyst

inferred← citeshttps://doi.org/10.1073/pnas.0809666106openalex-snapshot

Self-assembled biomimetic [2Fe2S]-hydrogenase-based photocatalyst for molecular hydrogen evolution

inferred← citeshttps://doi.org/10.1080/00958972.2017.1378812openalex-snapshot

A Pd(II) complex of a β -cyclodextrin-based polydentate ligand: an efficient catalyst for the Suzuki reaction in aqueous media

inferred← citeshttps://doi.org/10.2478/supcat-2012-0001openalex-snapshot

Bidentate ligands templated by a convex trimetallic bis(salphen) platform

inferred← citeshttps://doi.org/10.3390/ijms14012011openalex-snapshot

Catalysis of Transesterification Reactions by a Self-Assembled Nanosystem

inferred← citeshttps://doi.org/10.3390/molecules22122181openalex-snapshot

Novel Chiral Bis-Phosphoramides as Organocatalysts for Tetrachlorosilane-Mediated Reactions

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