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Radical Formation by Direct Single Electron Transfer between Nitrobenzene and Anionic Organo Bases

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Polymerization of vinyl monomers photoinitiated byp-nitroaniline: Photoinitiation mechanism
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1,1-Di-tert-butyl Peroxide
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Counterion Control oft‐BuO‐Mediated Single Electron Transfer to Nitrostilbenes to ConstructN‐Hydroxyindoles or Oxindoles
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Olefin Dihydroxylation Using Nitroarenes as Photoresponsive Oxidants
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Does Nucleophilic Substitution in Nitroarenes Proceed via Single Electron Transfer (SET)?
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Software update: The ORCA program system—Version 5.0
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A new hybrid exchange–correlation functional using the Coulomb-attenuating method (CAM-B3LYP)
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Determination of the molecular structure of tetrakis(trimethylsilyl)hydrazine, N2(SiMe3)4, in the gas phase by electron diffraction
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Counterattack reagents:hexamethyldisilane and 1,2-dimethyl-1,1,2,2-tetraphenyldisilane in the synthesis of polysilylated hydrazines
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When Light Meets Nitrogen-Centered Radicals: From Reagents to Catalysts
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Nitroreduction: A Critical Metabolic Pathway for Drugs, Environmental Pollutants, and Explosives
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Nitrogen-Centered Radicals in Functionalization of sp 2 Systems: Generation, Reactivity, and Applications in Synthesis
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Insights into Single-Electron-Transfer Processes in Frustrated Lewis Pair Chemistry and Related Donor–Acceptor Systems in Main Group Chemistry
inferredcites →https://doi.org/10.1021/acs.jcim.9b00725openalex-snapshot
New Basis Set Exchange: An Open, Up-to-Date Resource for the Molecular Sciences Community
inferredcites →https://doi.org/10.1021/acs.jmedchem.8b00147openalex-snapshot
Nitro-Group-Containing Drugs
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Photoinduced Nitroarenes as Versatile Anaerobic Oxidants for Accessing Carbonyl and Imine Derivatives
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Merging Photoexcited Nitroarenes with Lewis Acid Catalysis for the Anti-Markovnikov Oxidation of Alkenes
inferredcites →https://doi.org/10.1021/acs.orglett.9b00191openalex-snapshot
Intramolecular Reductive Cyclization of o-Nitroarenes via Biradical Recombination
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Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory
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Basis Set Exchange: A Community Database for Computational Sciences
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Equilibrium studies by electron spin resonance. I. Free nitrobenzene anion radical
inferredcites →https://doi.org/10.1021/j100709a016openalex-snapshot
Radical intermediates. IV. Electron spin resonance studies on the alkali metal nitrobenzenides in nitrilic solvents
inferredcites →https://doi.org/10.1021/j150506a006openalex-snapshot
Paramagnetic Resonance Absorption of Free Radicals
inferredcites →https://doi.org/10.1021/ja00390a015openalex-snapshot
Mechanism of the apparent electron-transfer reaction between tert-butoxide ion and nitrobenzene
inferredcites →https://doi.org/10.1021/ja00530a032openalex-snapshot
Proton-transfer and electron-transfer processes in reaction of p-nitrotoluene with bases. A spectrophotometric study
inferredcites →https://doi.org/10.1021/ja00880a040openalex-snapshot
Spontaneous Formation of Radical-Anions from Nitroaromatics in Basic Solution
inferredcites →https://doi.org/10.1021/ja00880a042openalex-snapshot
The Formation of Radical-Anions by Electron Transfer Between Anions and Their Unsaturated Analogs in Dimethyl Sulfoxide Solution
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Electron Transfer Processes. VI. Disproportionation of o- and p-Nitrotoluenes in Basic Solution
inferredcites →https://doi.org/10.1021/ja01019a026openalex-snapshot
Anion radicals in liquid ammonia
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Electron-Transfer Processes. I. The Scope of the Reaction between Carbanions or Nitranions and Unsaturated Electron Acceptors
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An Electron Spin Resonance Study of Nitro Group-Alkali Metal Interactions in Aromatic Hydrocarbons1
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Electrochemical Generation of Free Radicals and Their Study by Electron Spin Resonance Spectroscopy; the Nitrobenzene Anion Radical
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The Abstraction of Hydrogen Atoms from Liquid Hydrocarbons by t-Butoxy Radicals
inferredcites →https://doi.org/10.1021/ja049856kopenalex-snapshot
Crystallographic Distinction between “Contact” and “Separated” Ion Pairs: Structural Effects on Electronic/ESR Spectra of Alkali-Metal Nitrobenzenides
inferredcites →https://doi.org/10.1021/ja071881dopenalex-snapshot
Triplet (S = 1) Ground State Aminyl Diradical
inferredcites →https://doi.org/10.1021/ja409472fopenalex-snapshot
High-Spin S = 2 Ground State Aminyl Tetraradicals
inferredcites →https://doi.org/10.1021/jacs.0c06035openalex-snapshot
Insight into the Bonding and Aggregation of Alkyllithiums by Experimental Charge Density Studies and Energy Decomposition Analyses
inferredcites →https://doi.org/10.1021/jacs.2c05648openalex-snapshot
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inferredcites →https://doi.org/10.1021/jacs.2c13502openalex-snapshot
Anaerobic Hydroxylation of C(sp 3 )–H Bonds Enabled by the Synergistic Nature of Photoexcited Nitroarenes
inferredcites →https://doi.org/10.1021/jacs.3c07070openalex-snapshot
Frustrated Radical Pairs in Organic Synthesis
inferredcites →https://doi.org/10.1021/jacs.4c03418openalex-snapshot
Potassium Hexamethyldisilazide (KHMDS): Solvent-Dependent Solution Structures
inferredcites →https://doi.org/10.1021/jacs.6b03282openalex-snapshot
KO t Bu: A Privileged Reagent for Electron Transfer Reactions?
inferredcites →https://doi.org/10.1021/jacs.6b12360openalex-snapshot
Nitrogen Lewis Acids
inferredcites →https://doi.org/10.1021/jacs.8b06089openalex-snapshot
Electron Transfer Reactions: KOtBu (but not NaOtBu) Photoreduces Benzophenone under Activation by Visible Light
inferredcites →https://doi.org/10.1021/jo00431a003openalex-snapshot
Reaction of electrogenerated nitrobenzene radical anion with alkyl halides
inferredcites →https://doi.org/10.1021/op000095popenalex-snapshot
New Selective Oxidation Reactions by Nitroarenes in Basic Medium Involving Electron-Transfer Processes
inferredcites →https://doi.org/10.1038/s41586-023-06131-3openalex-snapshot
Regioselective aliphatic C–H functionalization using frustrated radical pairs
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Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy
inferredcites →https://doi.org/10.1039/b810189bopenalex-snapshot
Long-range corrected hybrid density functionals with damped atom–atom dispersion corrections
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Organic super-electron-donors: initiators in transition metal-free haloarene–arene coupling
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Atomic layer deposition of sodium and potassium oxides: evaluation of precursors and deposition of thin films
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The stability of nitrogen-centered radicals
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New amination strategies based on nitrogen-centered radical chemistry
inferredcites →https://doi.org/10.1039/c9ra04242copenalex-snapshot
t BuOK-triggered bond formation reactions
inferredcites →https://doi.org/10.1039/d1qo01141copenalex-snapshot
Copper-catalyzed, N -auxiliary group-controlled switchable transannulation/nitration initiated by nitro radicals: selective synthesis of pyridoquinazolones and 3-nitroindoles
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The quest for organo-alkali metal monomers: unscrambling the structure–reactivity relationship
inferredcites →https://doi.org/10.1039/d4cs00185kopenalex-snapshot
Mechanistic studies on single-electron transfer in frustrated Lewis pairs and its application to main-group chemistry
inferredcites →https://doi.org/10.1039/d4dt00211copenalex-snapshot
Lithium, sodium and potassium enolate aggregates and monomers: syntheses and structures
inferredcites →https://doi.org/10.1039/j19690000109openalex-snapshot
Radical intermediates. Part I. Spectroscopic studies on the alkali-metal nitrobenzenides
inferredcites →https://doi.org/10.1055/s-0042-1751443openalex-snapshot
Photoexcited Nitroarenes as Anaerobic Oxygen Atom Transfer Reagents
inferredcites →https://doi.org/10.1063/1.1383587openalex-snapshot
A long-range correction scheme for generalized-gradient-approximation exchange functionals
inferredcites →https://doi.org/10.1063/1.1712413openalex-snapshot
ESR Studies of Nitrobenzene,o-Dinitrobenzene, andm-Dinitrobenzene Alkali-Metal Salts
inferredcites →https://doi.org/10.1063/1.1734301openalex-snapshot
Analysis of the Electron Spin Resonance Spectra of Aromatic Nitrosubstituted Anion Radicals
inferredcites →https://doi.org/10.1063/1.3382344openalex-snapshot
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
inferredcites →https://doi.org/10.1063/1.433384openalex-snapshot
ESR investigation of the nitrobenzene anion radical in single crystals of benzoate salts
inferredcites →https://doi.org/10.1063/1.456153openalex-snapshot
Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen
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Electron affinities of the first-row atoms revisited. Systematic basis sets and wave functions
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Density-functional thermochemistry. III. The role of exact exchange
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Gaussian basis sets for use in correlated molecular calculations. XI. Pseudopotential-based and all-electron relativistic basis sets for alkali metal (K–Fr) and alkaline earth (Ca–Ra) elements
inferredcites →https://doi.org/10.1103/physreva.38.3098openalex-snapshot
Density-functional exchange-energy approximation with correct asymptotic behavior
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Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
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KOtBu as a Single Electron Donor? Revisiting the Halogenation of Alkanes with CBr4 and CCl4

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inferred← backgroundhttps://doi.org/10.5281/zenodo.20340556zenodo-depositor-declared
Unlocking Nitroaromatic Radicals: Formation & Reactivity
inferred← backgroundhttps://doi.org/10.5281/zenodo.20491615zenodo-depositor-declared
Nitrobenzenide radical formation through single electron transfer: A density functional theory study
inferred← backgroundhttps://doi.org/10.5281/zenodo.22232420zenodo-depositor-declared
inferred← extendshttps://doi.org/10.5281/zenodo.15806911zenodo-depositor-declared
Single Electron Transfer Drives Radical Formation in Nitroaromatics: Characterisation and Applications
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c01470openalex-snapshot
Selective Construction of 1,1-Disubstituted Cyclopropyl Ketones, 2-Arylacetophenones, and 2-Aryl-3,4-dihydronaphthalen-1(2 H )-ones via Palladium-Catalyzed Cross-Coupling of Cyclopropyl Aryl Ketones with Aryl Bromides
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