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Mechanism of a Chemical Glycosylation Reaction

https://doi.org/10.1021/ar100035r
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Outgoing claims: the papers this work cites, builds on, or argues with.

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Substrate Distortion by a -Mannanase: Snapshots of the Michaelis and Covalent-Intermediate Complexes Suggest a B2,5 Conformation for the Transition State
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Protecting Groups: Effects on Reactivity, Glycosylation Stereoselectivity, and Coupling Efficiency
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Mechanism of 4,6‐O‐Benzylidene‐Directed β‐Mannosylation as Determined by α‐Deuterium Kinetic Isotope Effects
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A Highly Reactive and Stereoselective β‐Mannopyranosylation System: Mannosyl 4‐Pentenoate/PhSeOTf
inferredcites →https://doi.org/10.1002/anie.200802036openalex-snapshot
New Principles for Glycoside‐Bond Formation
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A stable, commercially available sulfenyl chloride for the activation of thioglycosides in conjunction with silver trifluoromethanesulfonate
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Chemoselective glycosylations using sulfonium triflate activator systems
inferredcites →https://doi.org/10.1016/j.tet.2007.03.128openalex-snapshot
β-Selective glucosylation in the absence of neighboring group participation: influence of the 3,4-O-bisacetal protecting system
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Disarming, non-participating 2-O-protecting groups in manno- and rhamnopyranosylation: scope and limitations of sulfonates, vinylogous esters, phosphates, cyanates, and nitrates
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Methanolysis as a model reaction for oligosaccharide synthesis of some 6-substituted 2,3,4-tri-O-benzyl-D-galactopyranosyl derivatives
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Synthesis and 13C-n.m.r. spectra of β-l-rhamnopyranosides
inferredcites →https://doi.org/10.1016/s0008-6215(98)00218-3openalex-snapshot
Capsular polysaccharide of Streptococcus pneumoniae type 19F: synthesis of the repeating unit
inferredcites →https://doi.org/10.1016/s0040-4020(98)00426-8openalex-snapshot
Direct chemical synthesis of β-mannopyranosides and other glycosides via glycosyl triflates
inferredcites →https://doi.org/10.1016/s0040-4039(00)00941-2openalex-snapshot
An unusual example of steric buttressing in glycosylation
inferredcites →https://doi.org/10.1016/s0040-4039(00)01497-0openalex-snapshot
Can preferential β-mannopyranoside formation with 4,6-O-benzylidene protected mannopyranosyl sulfoxides be reached with trichloroacetimidates?
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Chapter 4 Computational Studies of the Role of Glycopyranosyl Oxacarbenium Ions in Glycobiology and Glycochemistry
inferredcites →https://doi.org/10.1016/s0065-3160(06)41005-4openalex-snapshot
Mechanisms for nucleophilic aliphatic substitution at glycosides
inferredcites →https://doi.org/10.1021/ar970172+openalex-snapshot
Glycosidase mechanisms: anatomy of a finely tuned catalyst.
inferredcites →https://doi.org/10.1021/bk-2007-0960.ch005openalex-snapshot
Stereocontrolled Glycosylation: Recent Advances: β- D -Rhamnosides and β- D -Mannans
inferredcites →https://doi.org/10.1021/ja00141a030openalex-snapshot
High-Precision Simultaneous Determination of Multiple Small Kinetic Isotope Effects at Natural Abundance
inferredcites →https://doi.org/10.1021/ja00847a032openalex-snapshot
Halide ion catalyzed glycosidation reactions. Syntheses of .alpha.-linked disaccharides
inferredcites →https://doi.org/10.1021/ja0111481openalex-snapshot
1-Benzenesulfinyl Piperidine/Trifluoromethanesulfonic Anhydride: A Potent Combination of Shelf-Stable Reagents for the Low-Temperature Conversion of Thioglycosides to Glycosyl Triflates and for the Formation of Diverse Glycosidic Linkages
inferredcites →https://doi.org/10.1021/ja011406uopenalex-snapshot
Solid-Phase Synthesis of β-Mannosides
inferredcites →https://doi.org/10.1021/ja0122694openalex-snapshot
Stereoselective Formation of Glycosyl Sulfoxides and Their Subsequent Equilibration: Ring Inversion of an α-Xylopyranosyl Sulfoxide Dependent on the Configuration at Sulfur
inferredcites →https://doi.org/10.1021/ja01583a022openalex-snapshot
Salt Effects and Ion Pairs in Solvolysis and Related Reactions. III.1 Common Ion Rate Depression and Exchange of Anions during Acetolysis2,3
inferredcites →https://doi.org/10.1021/ja015842sopenalex-snapshot
2-(Hydroxycarbonyl)benzyl Glycosides: A Novel Type of Glycosyl Donors for Highly Efficient β-Mannopyranosylation and Oligosaccharide Synthesis by Latent-Active Glycosylation
inferredcites →https://doi.org/10.1021/ja047578jopenalex-snapshot
The Disarming Effect of the 4,6-Acetal Group on Glycoside Reactivity: Torsional or Electronic?
inferredcites →https://doi.org/10.1021/ja048070jopenalex-snapshot
Benzylidene Acetal Fragmentation Route to 6-Deoxy Sugars: Direct Reductive Cleavage in the Presence of Ether Protecting Groups, Permitting the Efficient, Highly Stereocontrolled Synthesis of β- d -Rhamnosides from d -Mannosyl Glycosyl Donors. Total Synthesis of α- d -Gal-(1→3)-α- d -Rha-(1→3)- β-…
inferredcites →https://doi.org/10.1021/ja061594uopenalex-snapshot
Stereocontrolled Synthesis of the d - and l -glycero-β- d -manno-Heptopyranosides and Their 6-Deoxy Analogues. Synthesis of Methyl α- l -Rhamno-pyranosyl-(1→3)- d -glycero-β- d -manno-heptopyranosyl- (1→3)-6-deoxy-glycero-β- d -manno-heptopyranosyl-(1→4)-α- l - rhamno-pyranoside, a Tetrasaccharide…
inferredcites →https://doi.org/10.1021/ja072440xopenalex-snapshot
Electrochemical Generation of Glycosyl Triflate Pools
inferredcites →https://doi.org/10.1021/ja0730258openalex-snapshot
Synthesis and Glycosylation of a Series of 6-Mono-, Di-, and Trifluoro S-Phenyl 2,3,4-Tri-O-benzyl-thiorhamnopyranosides. Effect of the Fluorine Substituents on Glycosylation Stereoselectivity
inferredcites →https://doi.org/10.1021/ja710935zopenalex-snapshot
Stereoselective Direct Glycosylation with Anomeric Hydroxy Sugars by Activation with Phthalic Anhydride and Trifluoromethanesulfonic Anhydride Involving Glycosyl Phthalate Intermediates
inferredcites →https://doi.org/10.1021/ja907252uopenalex-snapshot
β-Directing Effect of Electron-Withdrawing Groups at O-3, O-4, and O-6 Positions and α-Directing Effect by Remote Participation of 3-O-Acyl and 6-O-Acetyl Groups of Donors in Mannopyranosylations
inferredcites →https://doi.org/10.1021/ja971239ropenalex-snapshot
Are Glycosyl Triflates Intermediates in the Sulfoxide Glycosylation Method? A Chemical and 1H, 13C, and 19F NMR Spectroscopic Investigation
inferredcites →https://doi.org/10.1021/ja993595aopenalex-snapshot
Dehydrative Glycosylation with Activated Diphenyl Sulfonium Reagents. Scope, Mode of C(1)-Hemiacetal Activation, and Detection of Reactive Glycosyl Intermediates
inferredcites →https://doi.org/10.1021/jm900819popenalex-snapshot
Carbohydrates: A Frontier in Medicinal Chemistry
inferredcites →https://doi.org/10.1021/jo0349882openalex-snapshot
Influence of the 4,6-O-Benzylidene, 4,6-O-Phenylboronate, and 4,6-O-Polystyrylboronate Protecting Groups on the Stereochemical Outcome of Thioglycoside-Based Glycosylations Mediated by 1-Benzenesulfinyl Piperidine/Triflic Anhydride and N-Iodosuccinimide/Trimethylsilyl Triflate
inferredcites →https://doi.org/10.1021/jo035003jopenalex-snapshot
The 3,4-O-Carbonate Protecting Group as a β-Directing Group in Rhamnopyranosylation in Both Homogeneous and Heterogeneous Glycosylations As Compared to the Chameleon-like 2,3-O-Carbonates
inferredcites →https://doi.org/10.1021/jo0508999openalex-snapshot
Stereocontrolled Formation of β-Glucosides and Related Linkages in the Absence of Neighboring Group Participation: Influence of a trans-Fused 2,3-O-Carbonate Group
inferredcites →https://doi.org/10.1021/jo0526789openalex-snapshot
Enhanced Diastereoselectivity in β-Mannopyranosylation through the Use of Sterically Minimal Propargyl Ether Protecting Groups
inferredcites →https://doi.org/10.1021/jo061417bopenalex-snapshot
On the Influence of the C2−O2 and C3−O3 Bonds in 4,6-O-Benzylidene-Directed β-Mannopyranosylation and α-Glucopyranosylation
inferredcites →https://doi.org/10.1021/jo062294yopenalex-snapshot
4,6-O-Benzylidene-Directed β-Mannopyranosylation and α-Glucopyranosylation: The 2-Deoxy-2-fluoro and 3-Deoxy-3-fluoro Series of Donors and the Importance of the O2−C2−C3−O3 Interaction
inferredcites →https://doi.org/10.1021/jo070473popenalex-snapshot
Direct Stereocontrolled Synthesis of 3-Amino-3-deoxy-β-Mannopyranosides: Importance of the Nitrogen Protecting Group on Stereoselectivity
inferredcites →https://doi.org/10.1021/jo7023398openalex-snapshot
Application of the 4-Trifluoromethylbenzenepropargyl Ether Group as an Unhindered, Electron Deficient Protecting Group for Stereoselective Glycosylation
inferredcites →https://doi.org/10.1021/jo801630mopenalex-snapshot
Does Neighboring Group Participation by Non-Vicinal Esters Play a Role in Glycosylation Reactions? Effective Probes for the Detection of Bridging Intermediates
inferredcites →https://doi.org/10.1021/jo8022439openalex-snapshot
Stereocontrolled Synthesis of d - and l -β-Rhamnopyranosides with 4- O -6- S -α-Cyanobenzylidene-Protected 6-Thiorhamnopyranosyl Thioglycosides
inferredcites →https://doi.org/10.1021/jo902254wopenalex-snapshot
Highly Stereoselective Synthesis of α- d -Mannopyranosyl Phosphosugars
inferredcites →https://doi.org/10.1021/jo9601223openalex-snapshot
A Solvation-Assisted Model for Estimating Anomeric Reactivity. Predicted versus Observed Trends in Hydrolysis of n-Pentenyl Glycosides1
inferredcites →https://doi.org/10.1021/jo9606517openalex-snapshot
Formation of β-Mannopyranosides of Primary Alcohols Using the Sulfoxide Method
inferredcites →https://doi.org/10.1021/jo962345zopenalex-snapshot
Direct Synthesis of β-Mannopyranosides by the Sulfoxide Method
inferredcites →https://doi.org/10.1021/jo990243dopenalex-snapshot
Chemistry of 4,6-O-Benzylidene- d -glycopyranosyl Triflates: Contrasting Behavior between the Gluco and Manno Series
inferredcites →https://doi.org/10.1021/jo9910482openalex-snapshot
Highly Diastereoselective α-Mannopyranosylation in the Absence of Participating Protecting Groups
inferredcites →https://doi.org/10.1021/ol051038popenalex-snapshot
Efficient Installation of β-Mannosides Using a Dehydrative Coupling Strategy
inferredcites →https://doi.org/10.1021/ol061938lopenalex-snapshot
1-Naphthylpropargyl Ether Group: A Readily Cleaved and Sterically Minimal Protecting System for Stereoselective Glycosylation
inferredcites →https://doi.org/10.1021/ol702139uopenalex-snapshot
A New, Powerful Glycosylation Method: Activation of Thioglycosides with Dimethyl Disulfide−Triflic Anhydride
inferredcites →https://doi.org/10.1021/ol8017038openalex-snapshot
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inferredcites →https://doi.org/10.1038/nchembio.278openalex-snapshot
Mechanistic insights into a Ca2+-dependent family of α-mannosidases in a human gut symbiont
inferredcites →https://doi.org/10.1038/nchembio0609-368openalex-snapshot
Chemical glycobiology: why now?
inferredcites →https://doi.org/10.1039/9781847558015openalex-snapshot
Carbohydrate Chemistry and Biochemistry
inferredcites →https://doi.org/10.1039/b803999mopenalex-snapshot
Reagent switchable stereoselective β(1,2) mannoside mannosylation: OH-2 of mannose is a privileged acceptor
inferredcites →https://doi.org/10.1039/jr9600004637openalex-snapshot
896. Mechanisms of reactions in the sugar series. Part II. Nucleophilic substitution in 2,3,4,6-tetra-O-methylglycopyranosyl chlorides
inferredcites →https://doi.org/10.1039/p19760001938openalex-snapshot
Koenigs–Knorr reactions. Part 1. Effects of a 2-O-acetyl substituent, the promoter, and the alcohol concentration on the stereoselectivity of reactions of 1,2-cis-glucopyranosyl bromide
inferredcites →https://doi.org/10.1039/p29760001632openalex-snapshot
Koenigs–Knorr reactions. Part II. A mechanistic study of mercury( II ) cyanide-promoted reactions of 2,3,4,6-tetra-O-methyl-α- D -glucopyranosyl bromide with cyclohexanol in benzene–nitromethane
inferredcites →https://doi.org/10.1039/p29770000795openalex-snapshot
Koenigs–Knorr reactions. Part 3. Mechanistic study of mercury( II ) cyanide promoted reactions of 2-O-acetyl-3,4,6-tri-O-methyl-α- D -glucopyranosyl bromide with cyclohexanol in benzene–nitromethane
inferredcites →https://doi.org/10.1080/07328300802571129openalex-snapshot
Practical Synthesis of a Manβ(1-4)GlcNTroc Fragment via Microfluidic β-Mannosylation
inferredcites →https://doi.org/10.1081/car-200066978openalex-snapshot
Improved Synthesis of 1‐Benzenesulfinyl Piperidine and Analogs for the Activation of Thioglycosides in Conjunction with Trifluoromethanesulfonic Anhydride*
inferredcites →https://doi.org/10.1139/v61-327openalex-snapshot
CONFIGURATION OF GLYCOSIDIC LINKAGES IN OLIGOSACCHARIDES: IX. SYNTHESIS OF α- AND β- D -MANNOPYRANOSYL DISACCHARIDES
inferredcites →https://doi.org/10.3987/com-02-s80openalex-snapshot
Direct and Stereoselective Construction of b-Mannosidic Linkages Capitalizing on 4,6-O-Benzylidene-protected D-Manno- pyranosyl Diethyl Phosphite
inferredcites →https://doi.org/10.3998/ark.5550190.0006.629openalex-snapshot
Approximate OH5 ring conformation of 2,3-O-carbonate protected α- and ß-L-rhamnopyranosides as confirmed by X-ray crystallography

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Incoming claims: where this work appears in other papers’ reference lists and arguments.

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The Glycosylation Mechanisms of 6,3‐Uronic Acid Lactones
inferred← citeshttps://doi.org/10.1002/anie.201907001openalex-snapshot
Structural and Computational Analysis of 2‐Halogeno‐Glycosyl Cations in the Presence of a Superacid: An Expansive Platform
inferred← citeshttps://doi.org/10.1002/anie.202007209openalex-snapshot
Chemical Synthesis Elucidates the Key Antigenic Epitope of the Autism‐Related Bacterium Clostridium bolteae Capsular Octadecasaccharide
inferred← citeshttps://doi.org/10.1002/anie.202010280openalex-snapshot
Reactivity–Stereoselectivity Mapping for the Assembly of Mycobacterium marinum Lipooligosaccharides
inferred← citeshttps://doi.org/10.1002/anie.202115394openalex-snapshot
Stereoselective O ‐Glycosylations by Pyrylium Salt Organocatalysis**
inferred← citeshttps://doi.org/10.1002/anie.202200818openalex-snapshot
Total Synthesis and Stereochemistry Assignment of Nucleoside Antibiotic A‐94964
inferred← citeshttps://doi.org/10.1002/anie.202201510openalex-snapshot
More than a Leaving Group: N ‐Phenyltrifluoroacetimidate as a Remote Directing Group for Highly α‐Selective 1,2‐ cis Glycosylation
inferred← citeshttps://doi.org/10.1002/anie.202206128openalex-snapshot
Direct Synthesis of 2,6‐Dideoxy‐β‐glycosides and β‐Rhamnosides with a Stereodirecting 2‐(Diphenylphosphinoyl)acetyl Group
inferred← citeshttps://doi.org/10.1002/anie.202214167openalex-snapshot
Synthesis of N‐Glycosides by Silver‐Assisted Gold Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202309887openalex-snapshot
Base‐Promoted Glycosylation Allows Protecting Group‐Free and Stereoselective O ‐Glycosylation of Carboxylic Acids**
inferred← citeshttps://doi.org/10.1002/anie.202405297openalex-snapshot
Acceptor‐Reactivity‐Controlled Stereoconvergent Synthesis and Immunological Activity of a Unique Pentasaccharide from the Cell Wall Polysaccharide of Cutibacterium acnes C7
inferred← citeshttps://doi.org/10.1002/anie.202514167openalex-snapshot
Catalytic Strategies for Stereoselective Carbohydrate Synthesis: Emerging Concepts for Accessing Challenging Glycosides
inferred← citeshttps://doi.org/10.1002/asia.201800971openalex-snapshot
Direct Dehydrative Glycosylation of C1‐Alcohols
inferred← citeshttps://doi.org/10.1002/asia.202200896openalex-snapshot
Total Synthesis of Natural Products using Gold Catalysis
inferred← citeshttps://doi.org/10.1002/asia.70928openalex-snapshot
Application of the Hydrogen‐Bond‐Mediated Aglycone Delivery (HAD) Reaction to the Synthesis of α ‐ and β ‐Linked 2‐Azido‐2‐deoxyglucosides
inferred← citeshttps://doi.org/10.1002/cbic.201200582openalex-snapshot
Capture of Uropathogenic E. coli by Using Synthetic Glycan Ligands Specific for the Pap‐Pilus
inferred← citeshttps://doi.org/10.1002/cbic.202200061openalex-snapshot
Synthetic Neoglycoconjugates of Hepta‐ and Nonamannoside Ligands for Eliciting Oligomannose‐Specific HIV‐1‐Neutralizing Antibodies
inferred← citeshttps://doi.org/10.1002/cctc.202000569openalex-snapshot
Substrate‐Controlled Cyclopropanation Reactions of Glycals with Aryl Diazoacetates
inferred← citeshttps://doi.org/10.1002/celc.70240openalex-snapshot
Electroreductive Desulfurization of Thioacetals
inferred← citeshttps://doi.org/10.1002/chem.201001682openalex-snapshot
Synthesis and Biological Properties of the Cytotoxic 14‐Membered Macrolides Aspergillide A and B
inferred← citeshttps://doi.org/10.1002/chem.201003251openalex-snapshot
Direct Experimental Evidence for the High Chemical Reactivity of α‐ and β‐Xylopyranosides Adopting a 2,5B Conformation in Glycosyl Transfer
inferred← citeshttps://doi.org/10.1002/chem.201003721openalex-snapshot
Expanding the Scope of Aminosugars: Synthesis of 2‐Amino Septanosyl Glycoconjugates Using Septanosyl Fluoride Donors
inferred← citeshttps://doi.org/10.1002/chem.201101889openalex-snapshot
Do Glycosyl Sulfonium Ions Engage in Neighbouring‐Group Participation? A Study of Oxathiane Glycosyl Donors and the Basis for their Stereoselectivity
inferred← citeshttps://doi.org/10.1002/chem.201103069openalex-snapshot
Enzymatic Glycosylation of Small Molecules: Challenging Substrates Require Tailored Catalysts
inferred← citeshttps://doi.org/10.1002/chem.201202374openalex-snapshot
NO Bond as a Glycosidic‐Bond Surrogate: Synthetic Studies Toward Polyhydroxylated N‐Alkoxypiperidines
inferred← citeshttps://doi.org/10.1002/chem.201500648openalex-snapshot
Highly Stereoselective β‐Mannopyranosylation via the 1‐α‐Glycosyloxy‐isochromenylium‐4‐gold(I) Intermediates
inferred← citeshttps://doi.org/10.1002/chem.201505019openalex-snapshot
Determination of the Influence of Side‐Chain Conformation on Glycosylation Selectivity using Conformationally Restricted Donors
inferred← citeshttps://doi.org/10.1002/chem.201700908openalex-snapshot
Advances in Stereoselective 1,2‐cis Glycosylation using C‐2 Auxiliaries
inferred← citeshttps://doi.org/10.1002/chem.202003105openalex-snapshot
Statistical Analysis of Glycosylation Reactions
inferred← citeshttps://doi.org/10.1002/chem.202003480openalex-snapshot
Exploratory N‐Protecting Group Manipulation for the Total Synthesis of Zwitterionic Shigella sonnei Oligosaccharides
inferred← citeshttps://doi.org/10.1002/chem.202004158openalex-snapshot
Chemical‐Synthesis‐Based Approach to Glycoprotein Functions in the Endoplasmic Reticulum
inferred← citeshttps://doi.org/10.1002/chem.202005228openalex-snapshot
Systematic Structural Characterization of Chitooligosaccharides Enabled by Automated Glycan Assembly
inferred← citeshttps://doi.org/10.1002/chem.202104002openalex-snapshot
A Stereoselective Glycosylation Approach to the Construction of 1,2‐ trans ‐β‐ d ‐Glycosidic Linkages and Convergent Synthesis of Saponins
inferred← citeshttps://doi.org/10.1002/chem.202203490openalex-snapshot
Origin of Stereoselectivity in SE2′ Reactions of Six‐membered Ring Oxocarbenium Ions
inferred← citeshttps://doi.org/10.1002/chem.202400479openalex-snapshot
Parametric Analysis of Donor Activation for Glycosylation Reactions
inferred← citeshttps://doi.org/10.1002/cjoc.202000484openalex-snapshot
Donor Preactivation‐Based Glycosylation: An Efficient Strategy for Glycan Synthesis
inferred← citeshttps://doi.org/10.1002/cjoc.202100865openalex-snapshot
2‐Diphenylphosphinoyl ‐acetyl as a Remote Directing Group for the Highly Stereoselective Synthesis of β‐Glycosides
inferred← citeshttps://doi.org/10.1002/cjoc.202200595openalex-snapshot
Stereodirecting Effects of 4‐O ‐ortho‐cyanobenzyl Ether on Chemical Glycosylation with Glucopyranosyl Donor
inferred← citeshttps://doi.org/10.1002/cjoc.202200706openalex-snapshot
Exploring the Far Side of Glycosyl Sulfoxide Activation Process
inferred← citeshttps://doi.org/10.1002/cjoc.70429openalex-snapshot
Construction of α‐ GlcN3 Glycosidic Bonds to the Total Synthesis of Acinetobacter baumannii Capsular Polysaccharide K88 Repeating Units
inferred← citeshttps://doi.org/10.1002/cphc.201500139openalex-snapshot
Understanding the Aldo‐Enediolate Tautomerism of Glycolaldehyde in Basic Aqueous Solutions
inferred← citeshttps://doi.org/10.1002/ejoc.201001278openalex-snapshot
N‐Benzyl‐2,3‐trans‐Carbamate‐Bearing Glycosyl Donors for 1,2‐cis‐Selective Glycosylation Reactions
inferred← citeshttps://doi.org/10.1002/ejoc.201100134openalex-snapshot
Gold‐Catalyzed Reactions of 2‐C‐Branched Carbohydrates: Mild Glycosidations and Selective Anomerizations
inferred← citeshttps://doi.org/10.1002/ejoc.201200468openalex-snapshot
Modular Synthesis of Core Fucosylated N‐Glycans
inferred← citeshttps://doi.org/10.1002/ejoc.201200907openalex-snapshot
Halide Effects on Cyclopropenium Cation Promoted Glycosylation with Deoxy Sugars: Highly α‐Selective Glycosylations Using a 3,3‐Dibromo‐1,2‐diphenylcyclopropene Promoter
inferred← citeshttps://doi.org/10.1002/ejoc.201600121openalex-snapshot
C–H Functionalization on Carbohydrates
inferred← citeshttps://doi.org/10.1002/ejoc.201600747openalex-snapshot
Glycosyl ortho‐Methoxybenzoates: Catalytically Activated Glycosyl Donors with an Easily Removable and Recyclable Leaving Group
inferred← citeshttps://doi.org/10.1002/ejoc.201600898openalex-snapshot
A Study on Stereoselective Glycosylations via Sulfonium Ion Intermediates
inferred← citeshttps://doi.org/10.1002/ejoc.201600899openalex-snapshot
On the Gluco/Manno Paradox: Practical α‐Glucosylations by NIS/TfOH Activation of 4,6‐O‐Tethered Thioglucoside Donors
inferred← citeshttps://doi.org/10.1002/ejoc.201700785openalex-snapshot
Recent Advances in Organocatalytic Glycosylations
inferred← citeshttps://doi.org/10.1002/ejoc.201701579openalex-snapshot
Pre‐Activation‐Based Stereoselective Glycosylations
inferred← citeshttps://doi.org/10.1002/ejoc.201800360openalex-snapshot
Efficient Synthesis of α‐Glycosyl Chlorides Using 2‐Chloro‐1,3‐dimethylimidazolinium Chloride: A Convenient Protocol for Quick One‐Pot Glycosylation
inferred← citeshttps://doi.org/10.1002/ejoc.201901033openalex-snapshot
Synthesis and Reactivity of α‐Haloglycine Esters: Hyperconjugation in Action
inferred← citeshttps://doi.org/10.1002/ejoc.201901186openalex-snapshot
Stereodirecting Effect of C3‐Ester Groups on the Glycosylation Stereochemistry of L‐Rhamnopyranose Thioglycoside Donors: Stereoselective Synthesis of α‐ and β‐L‐Rhamnopyranosides
inferred← citeshttps://doi.org/10.1002/ejoc.202100260openalex-snapshot
How do Various Reaction Parameters Influence Anomeric Selectivity in Chemical Glycosylation with Thioglycosides and NIS/TfOH Activation?
inferred← citeshttps://doi.org/10.1002/ejoc.202200320openalex-snapshot
Influence of 3‐Thio Substituents on Benzylidene‐Directed Mannosylation. Isolation of a Bridged Pyridinium Ion and Effects of 3‐O‐Picolyl and 3‐S‐Picolyl Esters
inferred← citeshttps://doi.org/10.1002/ejoc.202400148openalex-snapshot
Recent Advances of 2‐Nitroglycals as Powerful Glycosyl Donors
inferred← citeshttps://doi.org/10.1002/ejoc.202401125openalex-snapshot
Chemical Synthesis of β‐(1,4)‐ d ‐Oligomannurarates with Purported Anti‐Alzheimer Activity
inferred← citeshttps://doi.org/10.1002/ejoc.70599openalex-snapshot
Iron–Carbene Activation Enables Stereocontrolled Glycosylations From Conventional Thioglycosides
inferred← citeshttps://doi.org/10.1002/open.201402010openalex-snapshot
Synthesis and Photochromic Properties of Configurationally Varied Azobenzene Glycosides
inferred← citeshttps://doi.org/10.1002/open.201600043openalex-snapshot
Chemical O‐Glycosylations: An Overview
inferred← citeshttps://doi.org/10.1002/pep2.24124openalex-snapshot
Helical polysaccharides
inferred← citeshttps://doi.org/10.1002/slct.202104152openalex-snapshot
Mechanistic Study of Silyl‐Assist Effect on 1,2‐ cis ‐α‐Glucosylation
inferred← citeshttps://doi.org/10.1002/tcr.202000181openalex-snapshot
Glycosylation and Protecting Group Strategies Towards the Synthesis of Saponins and Bacterial Oligosaccharides: A Personal Account
inferred← citeshttps://doi.org/10.1002/tcr.202100092openalex-snapshot
Self‐Promoted Stereoselective Glycosylations – Past, Present, Future
inferred← citeshttps://doi.org/10.1002/tcr.202100201openalex-snapshot
Recent Advances in Stereocontrolled Mannosylation: Focus on Glycans Comprising Acidic and/or Amino Sugars
inferred← citeshttps://doi.org/10.1007/128_2010_108openalex-snapshot
“Active–Latent” Thioglycosyl Donors and Acceptors in Oligosaccharide Syntheses
inferred← citeshttps://doi.org/10.1007/978-1-61779-373-8_2openalex-snapshot
Chemical Synthesis of Carbohydrates and Their Surface Immobilization: A Brief Introduction
inferred← citeshttps://doi.org/10.1007/978-4-431-54836-2_32-1openalex-snapshot
Glycosylation
inferred← citeshttps://doi.org/10.1007/978-4-431-54841-6_32openalex-snapshot
Glycosylation
inferred← citeshttps://doi.org/10.1007/s10953-020-00977-1openalex-snapshot
Light Scattering in Non-aqueous Solutions of Low-Molecular-Mass Compounds: Application for Supramer Analysis of Reaction Solutions
inferred← citeshttps://doi.org/10.1007/s13361-017-1780-2openalex-snapshot
Influence of Linkage Stereochemistry and Protecting Groups on Glycosidic Bond Stability of Sodium Cationized Glycosyl Phosphates
inferred← citeshttps://doi.org/10.1007/s41061-018-0205-4openalex-snapshot
Glycosyl Sulfoxides in Glycosylation Reactions
inferred← citeshttps://doi.org/10.1016/b978-0-08-097742-3.00602-9openalex-snapshot
6.01 Synthesis of Glycosides
inferred← citeshttps://doi.org/10.1016/b978-0-12-817467-8.00009-8openalex-snapshot
Synthetic polysaccharides
inferred← citeshttps://doi.org/10.1016/b978-0-12-819475-1.00006-7openalex-snapshot
HPLC-Based Automated Oligosaccharide Synthesis
inferred← citeshttps://doi.org/10.1016/b978-0-12-819475-1.00017-1openalex-snapshot
Methods for O-Glycoside Synthesis
inferred← citeshttps://doi.org/10.1016/b978-0-12-819475-1.00074-2openalex-snapshot
The Oxocarbenium Ion Intermediate
inferred← citeshttps://doi.org/10.1016/b978-0-12-819475-1.00075-4openalex-snapshot
Strategies in Oligosaccharide Synthesis
inferred← citeshttps://doi.org/10.1016/b978-0-323-91099-6.00001-3openalex-snapshot
Recent advances of the stereoselective bimodal glycosylations for the synthesis of various glucans
inferred← citeshttps://doi.org/10.1016/b978-0-323-91729-2.00014-8openalex-snapshot
Glycosidic bond formation methodology: challenges and impact in oligosaccharide synthesis
inferred← citeshttps://doi.org/10.1016/b978-0-323-91729-2.00020-3openalex-snapshot
Recent advances in stereoselective intramolecular O-glycosylation
inferred← citeshttps://doi.org/10.1016/b978-0-323-96025-0.00001-6openalex-snapshot
Synthesis of Glycosides
inferred← citeshttps://doi.org/10.1016/bs.accb.2022.10.002openalex-snapshot
Pseudo-glycoconjugates with a C-glycoside linkage
inferred← citeshttps://doi.org/10.1016/bs.accb.2025.10.001openalex-snapshot
Stereoselective 1,2-cis glycosylation via intramolecular aglycone delivery: Opportunities and challenges
inferred← citeshttps://doi.org/10.1016/bs.accb.2025.10.002openalex-snapshot
Late stage O-glycosylation: A strategic gateway to complex therapeutic natural products
inferred← citeshttps://doi.org/10.1016/j.bmc.2024.117615openalex-snapshot
Chemoenzymatic synthesis and immunological evaluation of sialyl-Thomsen-Friedenreich (sTF) antigen conjugate to CRM197
inferred← citeshttps://doi.org/10.1016/j.carres.2011.04.005openalex-snapshot
Influence of the solvent in low temperature glycosylations with O-(2,3,5,6-tetra-O-benzyl-β-d-galactofuranosyl) trichloroacetimidate for 1,2-cis α-d-galactofuranosylation
inferred← citeshttps://doi.org/10.1016/j.carres.2011.07.020openalex-snapshot
Stereoselective glycosylations using oxathiane spiroketal glycosyl donors
inferred← citeshttps://doi.org/10.1016/j.carres.2011.10.004openalex-snapshot
Glycosylation studies on conformationally restricted 3,5-O-(di-tert-butylsilylene)-d-galactofuranosyl trichloroacetimidate donors for 1,2-cis α-d-galactofuranosylation
inferred← citeshttps://doi.org/10.1016/j.carres.2012.02.018openalex-snapshot
Comparison of the conformational properties of carbasugars and glycosides: the role of the endocyclic oxygen
inferred← citeshttps://doi.org/10.1016/j.carres.2012.03.025openalex-snapshot
Structural analysis of methyl 6-O-benzyl-2-deoxy-2-dimethylmaleimido-α-d-allopyranoside by X-ray crystallography, NMR, and QM calculations: hydrogen bonding and comparison of density functionals
inferred← citeshttps://doi.org/10.1016/j.carres.2012.03.040openalex-snapshot
Plausible transition states for glycosylation reactions
inferred← citeshttps://doi.org/10.1016/j.carres.2012.04.020openalex-snapshot
Matched and mismatched acceptor/donor pairs in the glycosylation of a trisaccharide diol free at O-3 of two N-acylated glucosamine residues
inferred← citeshttps://doi.org/10.1016/j.carres.2012.05.025openalex-snapshot
Influence of protecting groups on the anomeric equilibrium; case of the 4,6-O-benzylidene acetal in the mannopyranose series
inferred← citeshttps://doi.org/10.1016/j.carres.2013.02.009openalex-snapshot
Glycosylation of ‘basic’ alcohols: methyl 6-(hydroxymethyl)picolinate as a case study
inferred← citeshttps://doi.org/10.1016/j.carres.2013.08.002openalex-snapshot
Differential O-3/O-4 selectivity in the glycosylation of N-dimethylmaleoyl-protected hexosamine acceptors: effect of a conformationally armed (superarmed) glycosyl donor
inferred← citeshttps://doi.org/10.1016/j.carres.2013.10.017openalex-snapshot
Synthesis and conformational analysis of phosphorylated β-(1→2) linked mannosides
inferred← citeshttps://doi.org/10.1016/j.carres.2013.11.016openalex-snapshot
Is an acyl group at O-3 in glucosyl donors able to control α-stereoselectivity of glycosylation? The role of conformational mobility and the protecting group at O-6
inferred← citeshttps://doi.org/10.1016/j.carres.2014.04.011openalex-snapshot
Total synthesis of the bacillosamine containing α-l-serine linked trisaccharide of Neisseria meningitidis
inferred← citeshttps://doi.org/10.1016/j.carres.2014.06.020openalex-snapshot
A propos of glycosyl cations and the mechanism of chemical glycosylation; the current state of the art
inferred← citeshttps://doi.org/10.1016/j.carres.2014.06.025openalex-snapshot
Glycosyl alkoxythioimidates as building blocks for glycosylation: a reactivity study
inferred← citeshttps://doi.org/10.1016/j.carres.2014.07.004openalex-snapshot
Additive-controlled stereoselective glycosylations of 2,3-oxazolidinone protected glucosamine or galactosamine thioglycoside donors with phenols based on preactivation protocol
inferred← citeshttps://doi.org/10.1016/j.carres.2014.07.024openalex-snapshot
Conformationally restricted 3,5-O-(di-tert-butylsilylene)-d-galactofuranosyl thioglycoside donor for 1,2-cis α-d-galactofuranosylation
inferred← citeshttps://doi.org/10.1016/j.carres.2014.10.013openalex-snapshot
Contact ion pairs and solvent-separated ion pairs from d-mannopyranosyl and d-glucopyranosyl triflates
inferred← citeshttps://doi.org/10.1016/j.carres.2015.03.010openalex-snapshot
Theoretical study on the effects of a 4,6-O-diacetal protecting group on the stability of ion pairs from d-mannopyranosyl and d-glucopyranosyl triflates
inferred← citeshttps://doi.org/10.1016/j.carres.2016.11.009openalex-snapshot
Bimodal concentration-dependent reactivity pattern of a glycosyl donor: Is the solution structure involved?
inferred← citeshttps://doi.org/10.1016/j.carres.2018.09.003openalex-snapshot
Investigation of the H-bond-mediated aglycone delivery reaction in application to the synthesis of β-glucosides
inferred← citeshttps://doi.org/10.1016/j.carres.2018.10.006openalex-snapshot
Recent advances in reagent-controlled stereoselective/stereospecific glycosylation
inferred← citeshttps://doi.org/10.1016/j.carres.2019.107887openalex-snapshot
An eco-friendly N-benzoylglycine/thiourea cooperative catalyzed stereoselective synthesis of β-L-rhamnopyranosides
inferred← citeshttps://doi.org/10.1016/j.carres.2019.107900openalex-snapshot
Synthesis of 2-azido-2-deoxy- and 2-acetamido-2-deoxy-D-manno derivatives as versatile building blocks
inferred← citeshttps://doi.org/10.1016/j.carres.2021.108404openalex-snapshot
Aglycon reactivity as a guiding principle in latent-active approach to chemical glycosylations
inferred← citeshttps://doi.org/10.1016/j.carres.2021.108421openalex-snapshot
2,3-Carbamate mannosamine glycosyl donors in glycosylation reactions of diacetone-d-glucose. An experimental and theoretical study
inferred← citeshttps://doi.org/10.1016/j.carres.2022.108705openalex-snapshot
Protecting group enabled stereocontrolled approach for rare-sugars talose/gulose via dual-ruthenium catalysis
inferred← citeshttps://doi.org/10.1016/j.carres.2023.108859openalex-snapshot
Hydrogen/deuterium exchange for the analysis of carbohydrates
inferred← citeshttps://doi.org/10.1016/j.carres.2024.109033openalex-snapshot
Synthesis of sialyl halides with various acyl protective groups
inferred← citeshttps://doi.org/10.1016/j.carres.2025.109415openalex-snapshot
Recent development on stereoselective intramolecular O-glycosylation methodology
inferred← citeshttps://doi.org/10.1016/j.carres.2025.109458openalex-snapshot
Noncovalent interactions: An emerging focal point in stereoselective catalytic carbohydrate synthesis
inferred← citeshttps://doi.org/10.1016/j.cbpa.2018.04.007openalex-snapshot
Automated glycan assembly as an enabling technology
inferred← citeshttps://doi.org/10.1016/j.cbpa.2023.102418openalex-snapshot
Synthesis and application of bacterial exopolysaccharides
inferred← citeshttps://doi.org/10.1016/j.cclet.2017.09.044openalex-snapshot
Approaches towards the core pentasaccharide in N- linked glycans
inferred← citeshttps://doi.org/10.1016/j.cclet.2025.112235openalex-snapshot
Chemical strategies for the stereoselective construction of 1,2-cis-galacturonic and aminogalacturonic acid glycosides
inferred← citeshttps://doi.org/10.1016/j.checat.2022.10.019openalex-snapshot
Recent advances in transition-metal-catalyzed glycosyl cross-coupling reactions
inferred← citeshttps://doi.org/10.1016/j.chempr.2017.09.007openalex-snapshot
Site-Divergent Delivery of Terminal Propargyls to Carbohydrates by Synergistic Catalysis
inferred← citeshttps://doi.org/10.1016/j.ejmech.2019.04.001openalex-snapshot
Synthesis and immunological studies of β-1,2-mannan-peptide conjugates as antifungal vaccines
inferred← citeshttps://doi.org/10.1016/j.gresc.2024.03.004openalex-snapshot
Unraveling chemical glycosylation: DFT insights into factors imparting stereoselectivity
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2015.06.004openalex-snapshot
Delineating the physical organic profile of the 6-fluoro glycosyl donor
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2020.111259openalex-snapshot
Labelled micelles for the delivery of cytotoxic Cu(II) and Ru(III) compounds in the treatment of aggressive orphan cancers: Design and biological in vitro data
inferred← citeshttps://doi.org/10.1016/j.jscs.2020.11.001openalex-snapshot
Design, synthesis and antimicrobial evaluation of thioglycosides of a novel class of 2-mercaptonicotinonitriles
inferred← citeshttps://doi.org/10.1016/j.molliq.2024.124887openalex-snapshot
Rational screening of ionic liquids as phase transfer catalysts for aromatic O- and S-glycosidations examplified by acetobromo-alpha-D-galactose with phenolic compound
inferred← citeshttps://doi.org/10.1016/j.sbi.2019.11.008openalex-snapshot
Mannosidase mechanism: at the intersection of conformation and catalysis
inferred← citeshttps://doi.org/10.1016/j.tet.2012.04.059openalex-snapshot
A stereocontrolled construction of 2-azido-2-deoxy-1,2-cis-α-galactosidic linkages utilizing 2-azido-4,6-O-benzylidene-2-deoxygalactopyranosyl diphenyl phosphates: stereoselective synthesis of mucin core 5 and core 7 structures
inferred← citeshttps://doi.org/10.1016/j.tet.2013.04.094openalex-snapshot
Improved methods for the stereoselective synthesis of mannoheptosyl donors and their glycosides: toward the synthesis of the trisaccharide repeating unit of the Campylobacter jejuni RM1221 capsular polysaccharide
inferred← citeshttps://doi.org/10.1016/j.tet.2014.07.068openalex-snapshot
N-Iodosuccinimide and acid-washed molecular sieves (NIS/AW-300 MS) as promoters in thioglycoside activation
inferred← citeshttps://doi.org/10.1016/j.tet.2020.131412openalex-snapshot
Concise synthesis of a tetrasaccharide related to the repeating unit of the cell wall O-antigen of Salmonella enterica O60
inferred← citeshttps://doi.org/10.1016/j.tet.2021.132245openalex-snapshot
Synthesis of the pentasaccharide repeating unit of the O-antigenic polysaccharide of enteroaggregative Escherichia coli O44:H18 strain
inferred← citeshttps://doi.org/10.1016/j.tetlet.2010.10.135openalex-snapshot
A green and regioselective acetylation of thioglycoside with ethyl acetate
inferred← citeshttps://doi.org/10.1016/j.tetlet.2011.01.149openalex-snapshot
Preparation of tagged glucose as a key intermediate in the synthesis of branched oligosaccharides
inferred← citeshttps://doi.org/10.1016/j.tetlet.2012.07.059openalex-snapshot
ortho-Alkynylphenyl thioglycosides as a new type of glycosylation donors under the catalysis of Au(I) complexes
inferred← citeshttps://doi.org/10.1016/j.tetlet.2014.03.099openalex-snapshot
Intramolecular aglycon delivery for (1→2)-β-mannosylation: towards the synthesis of phospholipomannan of Candida albicans
inferred← citeshttps://doi.org/10.1016/j.tetlet.2014.05.097openalex-snapshot
β-(Carbonatoxy)alkyl radicals: a new subset of β-(ester)alkyl radical fragmentation during copper(I)-mediated synthesis of 1,1-dichloro-1-alkenes
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