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Organocatalysis Paradigm Revisited: Are Metal-Free Catalysts Really Harmless?

https://doi.org/10.1021/bm5015443
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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New Paradigms for Organic Catalysts: The First Organocatalytic Living Polymerization
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Handbook of Ring‐Opening Polymerization
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Methods for the evaluation of biocompatibility of soluble synthetic polymers which have potential for biomedical use: 1 ? Use of the tetrazolium-based colorimetric assay (MTT) as a preliminary screen for evaluation ofin vitro cytotoxicity
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Acute oral toxicity and repellency of 933 chemicals to house and deer mice
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In vitro evaluation of cell/biomaterial interaction by MTT assay
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In vitro biocompatibility of bioresorbable polymers: poly(L, DL-lactide) and poly(L-lactide-co-glycolide)
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Wheat sprout extract-induced apoptosis in human cancer cells by proteasomes modulation
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The reliability and limits of the MTT reduction assay for carbon nanotubes–cell interaction
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The human hepatoma HepaRG cells: A highly differentiated model for studies of liver metabolism and toxicity of xenobiotics
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Recent advances in the controlled preparation of poly(α-hydroxy acids): Metal-free catalysts and new monomers
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Neuronal damage and changes in the expression of muscarinic acetylcholine receptor subtypes in the neonatal rat cerebral cortical upon exposure to sparteine, a quinolizidine alkaloid
inferredcites →https://doi.org/10.1016/j.progpolymsci.2014.02.003openalex-snapshot
Implementation of metal-free ring-opening polymerization in the preparation of aliphatic polycarbonate materials
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Cartilage tissue engineering for auricular reconstruction: In vitro evaluation of potential genotoxic and cytotoxic effects of scaffold materials
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Cytotoxicity of a series of mono- and di-substituted thiourea in freshly isolated rat hepatocytes: a preliminary structure-toxicity relationship study
inferredcites →https://doi.org/10.1021/bm060795nopenalex-snapshot
Organocatalytic Ring Opening Polymerization of Trimethylene Carbonate
inferredcites →https://doi.org/10.1021/cr050947popenalex-snapshot
“Green” Atom Transfer Radical Polymerization: From Process Design to Preparation of Well-Defined Environmentally Friendly Polymeric Materials
inferredcites →https://doi.org/10.1021/cr068415bopenalex-snapshot
Organocatalytic Ring-Opening Polymerization
inferredcites →https://doi.org/10.1021/ja0543346openalex-snapshot
Thiourea-Based Bifunctional Organocatalysis: Supramolecular Recognition for Living Polymerization
inferredcites →https://doi.org/10.1021/ja060662+openalex-snapshot
Triazabicyclodecene: A Simple Bifunctional Organocatalyst for Acyl Transfer and Ring-Opening Polymerization of Cyclic Esters
inferredcites →https://doi.org/10.1021/jf901503aopenalex-snapshot
Differential Effects of Falcarinol and Related Aliphatic C17-Polyacetylenes on Intestinal Cell Proliferation
inferredcites →https://doi.org/10.1021/ma061607oopenalex-snapshot
Exploration, Optimization, and Application of Supramolecular Thiourea−Amine Catalysts for the Synthesis of Lactide (Co)polymers
inferredcites →https://doi.org/10.1021/ma0619381openalex-snapshot
Guanidine and Amidine Organocatalysts for Ring-Opening Polymerization of Cyclic Esters
inferredcites →https://doi.org/10.1021/ma9025948openalex-snapshot
Organocatalysis: Opportunities and Challenges for Polymer Synthesis
inferredcites →https://doi.org/10.1021/mz3005956openalex-snapshot
Organic Catalysis for Ring-Opening Polymerization
inferredcites →https://doi.org/10.1021/ol102539xopenalex-snapshot
Bifunctional Organocatalyst for Activation of Carbon Dioxide and Epoxide To Produce Cyclic Carbonate: Betaine as a New Catalytic Motif
inferredcites →https://doi.org/10.1021/tx00022a013openalex-snapshot
Rat hepatic microsomal metabolism of ethylenethiourea. Contributions of the flavin-containing monooxygenase and cytochrome P-450 isozymes
inferredcites →https://doi.org/10.1039/b511333dopenalex-snapshot
Assessing the factors responsible for ionic liquid toxicity to aquatic organisms via quantitative structure–property relationship modeling
inferredcites →https://doi.org/10.1039/b713925jopenalex-snapshot
Tagging alcohols with cyclic carbonate: a versatile equivalent of (meth)acrylate for ring-opening polymerization
inferredcites →https://doi.org/10.1039/c2cc37061aopenalex-snapshot
An imidazole-based organocatalyst designed for bulk polymerization of lactide isomers: inspiration from Nature
inferredcites →https://doi.org/10.1039/c2sc00590eopenalex-snapshot
Synthesis of poly( l -lactide) and gradient copolymers from a l -lactide/trimethylene carbonate eutectic melt
inferredcites →https://doi.org/10.1039/c3py00563aopenalex-snapshot
Microstructure analysis of biocompatible phosphoester copolymers
inferredcites →https://doi.org/10.1039/c3py01380dopenalex-snapshot
One-step synthesis of polylactide macrocycles from sparteine-initiated ROP
inferredcites →https://doi.org/10.1039/c4cc03347gopenalex-snapshot
Ammonium betaines: efficient ionic nucleophilic catalysts for the ring-opening polymerization of l -lactide and cyclic carbonates
inferredcites →https://doi.org/10.1055/s-0033-1360273openalex-snapshot
Methods Applied to the In Vitro Primary Toxicology Testing of Natural Products: State of the Art, Strengths, and Limits
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Gut health immunomodulatory and anti-inflammatory functions of gut enzyme digested high protein micro-nutrient dietary supplement-Enprocal
inferredcites →https://doi.org/10.1186/1748-717x-2-1openalex-snapshot
Radiosensitization by 2-benzoyl-3-phenyl-6,7-dichloroquinoxaline 1,4-dioxide under oxia and hypoxia in human colon cancer cells
inferredcites →https://doi.org/10.3892/or.17.6.1517openalex-snapshot
Onopordum cynarocephalum induces apoptosis and protects against 1,2 dimethylhydrazine-induced colon cancer

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Opportunities for organocatalysis in polymer synthesis via step-growth methods
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Evolution of design approaches in asymmetric organocatalysis over the last decade
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Preliminary insight into the potential antiplasmodial activity and cytotoxicity of Bufo bufo and Incilius alvarius poison
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Stereoretention in the Bulk ROP of l -Lactide Guided by a Thermally Stable Organocatalyst
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trans- and cis-DACH-Based Bifunctional Squaramides Catalyzed Ring-Opening Polymerizations of Asymmetric Substituted Glycolides
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Simple In-Based Dual Catalyst Enables Significant Progress in ε-Decalactone Ring-Opening (Co)polymerization
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Benzoic Acid as an Efficient Organocatalyst for the Statistical Ring-Opening Copolymerization of ε-Caprolactone and L -Lactide: A Computational Investigation
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inferred← citeshttps://doi.org/10.1021/acsmacrolett.9b00481openalex-snapshot
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inferred← citeshttps://doi.org/10.1021/acssuschemeng.2c05552openalex-snapshot
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inferred← citeshttps://doi.org/10.1021/acssuschemeng.9b00884openalex-snapshot
Trimethyl Glycine as an Environmentally Benign and Biocompatible Organocatalyst for Ring-Opening Polymerization of Cyclic Carbonate
inferred← citeshttps://doi.org/10.1021/jacs.1c09263openalex-snapshot
Metal-Free Hydrosilylation Polymerization by Merging Photoredox and Hydrogen Atom Transfer Catalysis
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Biodegradable functional biomaterials exploiting substituted trimethylene carbonates and organocatalytic transesterification
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Amino acid complexes with tin as a new class of catalysts with high reactivity and low toxicity towards biocompatible aliphatic polyesters
inferred← citeshttps://doi.org/10.1039/9781788015738-00121openalex-snapshot
Base Catalysts for Organopolymerization
inferred← citeshttps://doi.org/10.1039/c5ob01452bopenalex-snapshot
Thiourea-based spacers in potent divalent inhibitors of Pseudomonas aeruginosa virulence lectin LecA
inferred← citeshttps://doi.org/10.1039/c5py00831jopenalex-snapshot
Polyhydroxyalkanoate-based amphiphilic diblock copolymers as original biocompatible nanovectors
inferred← citeshttps://doi.org/10.1039/c5py01913copenalex-snapshot
Poly(2-ethyl-2-oxazoline)-block-polycarbonate block copolymers: from improved end-group control in poly(2-oxazoline)s to chain extension with aliphatic polycarbonate through a fully metal-free ring-opening polymerisation process
inferred← citeshttps://doi.org/10.1039/c6py00314aopenalex-snapshot
One-pot synthesis of well-defined polyether/polyester block copolymers and terpolymers by a highly efficient catalyst switch approach
inferred← citeshttps://doi.org/10.1039/c6py01107aopenalex-snapshot
Traceless switch organocatalysis enables multiblock ring-opening copolymerizations of lactones, carbonates, and lactides: by a one plus one approach in one pot
inferred← citeshttps://doi.org/10.1039/c6py01248eopenalex-snapshot
Triethylamine-based catalysts for the melt polymerization of carbonate monomers
inferred← citeshttps://doi.org/10.1039/c7gc03261gopenalex-snapshot
Lewis pairs for ring-opening alternating copolymerization of cyclic anhydrides and epoxides
inferred← citeshttps://doi.org/10.1039/c7py01472dopenalex-snapshot
Controlled ring-opening polymerisation of cyclic phosphates, phosphonates and phosphoramidates catalysed by heteroleptic BHT-alkoxy magnesium complexes
inferred← citeshttps://doi.org/10.1039/c7ra12843fopenalex-snapshot
Amphiphilic diblock copolymer of hydrophilic-functionalized lactone and lactide via switchable organocatalytic polymerization
inferred← citeshttps://doi.org/10.1039/c8cc01913dopenalex-snapshot
Photoinduced ring-opening polymerisation of l -lactide via a photocaged superbase
inferred← citeshttps://doi.org/10.1039/c8gc00482jopenalex-snapshot
The Green ChemisTREE: 20 years after taking root with the 12 principles
inferred← citeshttps://doi.org/10.1039/c8gc03096kopenalex-snapshot
Benzoic acid-organocatalyzed ring-opening (co)polymerization (ORO(c)P) of l -lactide and ε-caprolactone under solvent-free conditions: from simplicity to recyclability
inferred← citeshttps://doi.org/10.1039/c8ob03174fopenalex-snapshot
The mechanistic duality of (thio)urea organocatalysts for ring-opening polymerization
inferred← citeshttps://doi.org/10.1039/c9py00111eopenalex-snapshot
Heterogeneous catalysts based on built-in N-heterocyclic carbenes with high removability, recoverability and reusability for ring-opening polymerization of cyclic esters
inferred← citeshttps://doi.org/10.1039/c9py01472aopenalex-snapshot
Polymer-supported metal catalysts for the heterogeneous polymerisation of lactones
inferred← citeshttps://doi.org/10.1039/d0gc02660copenalex-snapshot
Crosslinking diene rubbers by using an inverse vulcanised co-polymer
inferred← citeshttps://doi.org/10.1039/d1cs00356aopenalex-snapshot
Controlling polymer stereochemistry in ring-opening polymerization: a decade of advances shaping the future of biodegradable polyesters
inferred← citeshttps://doi.org/10.1039/d1cy00756dopenalex-snapshot
Accelerating effect of crown ethers on the lactide polymerization catalysed by potassium acetate
inferred← citeshttps://doi.org/10.1039/d2gc03451dopenalex-snapshot
A recyclable process between a monomer and polyester with a natural catalyst
inferred← citeshttps://doi.org/10.1039/d2py00092jopenalex-snapshot
Syntheses of polylactides by means of tin catalysts
inferred← citeshttps://doi.org/10.1039/d3py00890hopenalex-snapshot
Novel epoxide-promoted polymerization of lactides mediated by a zinc guanidine complex: a potential strategy for the tin-free PLA industry
inferred← citeshttps://doi.org/10.1039/d5qo01075fopenalex-snapshot
The photocatalytic synthesis and closed-loop recycling of poly(semi-aromatic 1,2-ethanediol)s
inferred← citeshttps://doi.org/10.1039/d6cc00971aopenalex-snapshot
Readily available systems for the cycloaddition of CO 2 to epoxides through a water-enhanced application of alkaloid organocatalysts
inferred← citeshttps://doi.org/10.1126/science.adr7175openalex-snapshot
Stereomicrostructure-regulated biodegradable adhesives
inferred← citeshttps://doi.org/10.1134/s1560090417050074openalex-snapshot
Green chemistry of polyurethanes: The catalytic n-butylaminolysis of ethylene carbonate as a model chain-growth reaction in the formation of nonisocyanate polyurethanes
inferred← citeshttps://doi.org/10.11606/d.97.2019.tde-12072019-121420openalex-snapshot
Modificação química de resinas à base de estireno através do processo de sulfonação: estudo experimental e modelagem matemática
inferred← citeshttps://doi.org/10.1515/9783111618906-002openalex-snapshot
21Chapter 2 Methods for synthesizing green materials
inferred← citeshttps://doi.org/10.1515/psr-2018-0087openalex-snapshot
Chiral imidazolidinones: A class of priviliged organocatalysts in stereoselective organic synthesis
inferred← citeshttps://doi.org/10.2174/1385272822666181026115752openalex-snapshot
Recent Application of Polystyrene-supported Triphenylphosphine in Solid-Phase Organic Synthesis
inferred← citeshttps://doi.org/10.23860/diss-dharmaratne-nayanthara-2020openalex-snapshot
DEVELOPMENT OF NOVEL (THIO)UREA ORGANOCATALYSTS FOR RING OPENING POLYMERIZATION OF CYCLIC LACTONES
inferred← citeshttps://doi.org/10.23860/diss-pothupitiya-jinal-2019openalex-snapshot
ORGANOCATALYTIC RING-OPENING POLYMERIZATION OF CYCLIC LACTONES: DEVELOPMENT OF NEW CATALYSTS GUIDED BY MECHANISM
inferred← citeshttps://doi.org/10.33581/2520-257x-2019-2-40-50openalex-snapshot
Synthesis of functionalized polyisobutylene and its block copolymers with D,L-lactide
inferred← citeshttps://doi.org/10.3389/fchem.2021.647245openalex-snapshot
Recent Developments in Ring-Opening Copolymerization of Epoxides With CO2 and Cyclic Anhydrides for Biomedical Applications
inferred← citeshttps://doi.org/10.3390/chemosensors9100278openalex-snapshot
Thiourea Organocatalysts as Emerging Chiral Pollutants: En Route to Porphyrin-Based (Chir)Optical Sensing
inferred← citeshttps://doi.org/10.3390/molecules24224117openalex-snapshot
Coordination Ring-Opening Polymerization of Cyclic Esters: A Critical Overview of DFT Modeling and Visualization of the Reaction Mechanisms
inferred← citeshttps://doi.org/10.3390/nano9091208openalex-snapshot
Poly(Cyclohexene Phthalate) Nanoparticles for Controlled Dasatinib Delivery in Breast Cancer Therapy
inferred← citeshttps://doi.org/10.3390/pharmaceutics10040209openalex-snapshot
Complex Polymeric Architectures Self-Assembling in Unimolecular Micelles: Preparation, Characterization and Drug Nanoencapsulation
inferred← citeshttps://doi.org/10.3390/polym11121987openalex-snapshot
Reactive Extrusion and Magnesium (II) N-Heterocyclic Carbene Catalyst in Continuous PLA Production
inferred← citeshttps://doi.org/10.3390/polym11122078openalex-snapshot
DFT Modeling of Organocatalytic Ring-Opening Polymerization of Cyclic Esters: A Crucial Role of Proton Exchange and Hydrogen Bonding
inferred← citeshttps://doi.org/10.70675/34759a3azc801z4ab2z8ce6z59605e4274cbopenalex-snapshot
Elaboration de nanoparticules fonctionnelles à base de dérivés du poly(acide diméthylmalique) pour la vectorisation ciblée de principes actifs
inferred← citeshttps://doi.org/10.70675/41cff6acz59ffz4187z9806zf0a27353aad8openalex-snapshot
Etude de la polymérisation enzymatique de la malolactonates en présence de lipases
inferred← citeshttps://doi.org/10.70675/5a7a9963ze6baz4cf0zb5eczfcdc079758d5openalex-snapshot
Synthesis of functionalized lactones by thiol-ene reaction and their application to the preparation of tunable biodegradable polymers
inferred← citeshttps://doi.org/10.70675/b3eae817z9ef5z4b85z8b71z4af37be33182openalex-snapshot
A nature « copy-paste » approach for an efficient metal-free polymerization route
inferred← citeshttps://doi.org/10.70675/b75ffe81z010bz41fdz8234z767f7353746fopenalex-snapshot
New challenges in the synthesis of non-isocyanate polyurethanes
inferred← citeshttps://doi.org/10.70675/c81bffdfz2e37z444az80e3z81f702776b78openalex-snapshot
New poly(hydroxyalkanoate)-based copolymers : from synthesis to tunable self-assembled systems
inferred← citeshttps://doi.org/10.70675/fb02d936zd560z40b0zade1z5c8b7f7cb2d6openalex-snapshot
Exploring the potential of ring-opening polymerization of biobased lactones as a substitute for non-biodegradable polymers
inferred← citeshttps://doi.org/10.7868/s2308113917050072openalex-snapshot
Зеленая химия полиуретанов: каталитический н-бутиламинолиз этиленкарбоната как модельная реакция роста цепи при образовании неизоцианатных полиуретанов, "Высокомолекулярные соединения. Серия Б"
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