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A Dft Study on Mechanism and Catalyst Design of Natural Trimethyl Glycine Mediated Ring-Opening Polymerization of Trimethylene Carbonate

https://doi.org/10.2139/ssrn.4873020
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Bioorthogonal Cycloadditions: Computational Analysis with the Distortion/Interaction Model and Predictions of Reactivities
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Aliphatic Polycarbonates from Cyclic Carbonate Monomers and Their Application as Biomaterials
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Nonstrained γ-Butyrolactone to High-Molecular-Weight Poly(γ-butyrolactone): Facile Bulk Polymerization Using Economical Ureas/Alkoxides
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Regioisomeric Preference in Ring-Opening Polymerization of 3′,5′-Cyclic Phosphoesters of Functional Thymidine DNA Analogues
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Fluorescent Polymersomes with Aggregation-Induced Emission
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Trimethyl Glycine as an Environmentally Benign and Biocompatible Organocatalyst for Ring-Opening Polymerization of Cyclic Carbonate
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Organocatalytic Ring Opening Polymerization of Trimethylene Carbonate
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Organocatalysis Paradigm Revisited: Are Metal-Free Catalysts Really Harmless?
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Quantum Mechanical Continuum Solvation Models
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Single-Component Catalyst/Initiators for the Organocatalytic Ring-Opening Polymerization of Lactide
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Thiourea-Based Bifunctional Organocatalysis: Supramolecular Recognition for Living Polymerization
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The Reaction Mechanism for the Organocatalytic Ring-Opening Polymerization of l -Lactide Using a Guanidine-Based Catalyst: Hydrogen-Bonded or Covalently Bound?
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Poly(thioether)s from Closed-System One-Pot Reaction of Carbonyl Sulfide and Epoxides by Organic Bases
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Guanidine and Amidine Organocatalysts for Ring-Opening Polymerization of Cyclic Esters
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Ring-Opening Polymerization of Trimethylene Carbonate Catalyzed by Methanesulfonic Acid: Activated Monomer versus Active Chain End Mechanisms
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Diphenyl Phosphate as an Efficient Acidic Organocatalyst for Controlled/Living Ring-Opening Polymerization of Trimethylene Carbonates Leading to Block, End-Functionalized, and Macrocyclic Polycarbonates
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Organocatalyzed chemoselective ring-opening polymerizations
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N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis
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Hydrogen-bonding organocatalysts for ring-opening polymerization
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4-Dibenzocyclooctynol (DIBO) as an initiator for poly(ε-caprolactone): copper-free clickable polymer and nanofiber-based scaffolds
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