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Theoretical Investigation of Solvent Effects on Glycosylation Reactions: Stereoselectivity Controlled by Preferential Conformations of the Intermediate Oxacarbenium-Counterion Complex

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A biomolecular force field based on the free enthalpy of hydration and solvation: The GROMOS force‐field parameter sets 53A5 and 53A6
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The GROMOS software for biomolecular simulation: GROMOS05
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Using the local elevation method to construct optimized umbrella sampling potentials: Calculation of the relative free energies and interconversion barriers of glucopyranose ring conformers in water
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Formation and stability of oxocarbenium ions from glycosides
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Conformation of carbohydrates
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Validation of the 53A6 GROMOS force field
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Conformational analysis of nitrilium intermediates in glycosylation reactions
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Numerical integration of the cartesian equations of motion of a system with constraints: molecular dynamics of n-alkanes
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The two-conformer hypothesis: 2,3,4,6-tetra-O-methyl-mannopyranosyl and -glucopyranosyl oxacarbenium ions
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NMR evidence for the participation of triflated ionic liquids in glycosylation reaction mechanisms
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Investigations into the role of oxacarbenium ions in glycosylation reactions by ab initio molecular dynamics
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DFT studies of the role of C-2–O-2 bond rotation in neighboring-group glycosylation reactions
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Conformation, dynamics, solvation and relative stabilities of selected β-hexopyranoses in water: a molecular dynamics study with the gromos 45A4 force field
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DFT studies of the ionization of alpha and beta glycopyranosyl donors
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A stable, commercially available sulfenyl chloride for the activation of thioglycosides in conjunction with silver trifluoromethanesulfonate
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Rapid oligosaccharide synthesis on a fluorous support
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Can the stereochemical outcome of glycosylation reactions be controlled by the conformational preferences of the glycosyl donor?
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Quantitative description of six-membered ring conformations following the IUPAC conformational nomenclature
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Reaction d'imidates de glucopyranosyle avec l'acetonitrile. Applications synthetiques
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Stereoselective glycosidations of uronic acids
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Glycosylation using glucopyranosyl fluorides and silicon-based catalysts. Solvent dependency of the stereoselection
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Chapter 4 Computational Studies of the Role of Glycopyranosyl Oxacarbenium Ions in Glycobiology and Glycochemistry
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Mechanisms for nucleophilic aliphatic substitution at glycosides
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Stereoelectronic Substituent Effects
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Two Unexpected Effects Found with 2,3,4,6-Tetra-O-methyl-D-Gluco- and Mannopyranosyl Oxacarbenium Ions
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Quantum Mechanical Continuum Solvation Models
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Ab Initio Calculation of Vibrational Absorption and Circular Dichroism Spectra Using Density Functional Force Fields
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An ab initio study (6-31G*) of transition states in glycoside hydrolysis based on axial and equatorial 2-methoxytetrahydropyrans
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Molecular mechanical investigations of the properties of oxocarbenium ions. 2. Application to glycoside hydrolysis
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The Conformational Origin of the Barrier to the Formation of Neighboring Group Assistance in Glycosylation Reactions: A Dynamical Density Functional Theory Study
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Tag-Reporter Strategy for Facile Oligosaccharide Synthesis on Polymer Support
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Halide ion catalyzed glycosidation reactions. Syntheses of .alpha.-linked disaccharides
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On-Resin Real-Time Reaction Monitoring of Solid-Phase Oligosaccharide Synthesis
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Glycosidic Bond Formation in Aqueous Solution: On the Oxocarbenium Intermediate
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Stereochemistry of Nucleophilic Substitution Reactions Depending upon Substituent: Evidence for Electrostatic Stabilization of Pseudoaxial Conformers of Oxocarbenium Ions by Heteroatom Substituents
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Hydrophobically Assisted Switching Phase Synthesis: The Flexible Combination of Solid-Phase and Solution-Phase Reactions Employed for Oligosaccharide Preparation
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The Conformational Free Energy Landscape of β- d -Glucopyranose. Implications for Substrate Preactivation in β-Glucoside Hydrolases
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Electrochemical Generation of Glycosyl Triflate Pools
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Equatorial Anomeric Triflates from Mannuronic Acid Esters
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Carbohydrates: A Frontier in Medicinal Chemistry
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Continuum of Mechanisms for Nucleophilic Substitutions of Cyclic Acetals
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Chemical glycobiology: why now?
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Electrostatic interactions in cations and their importance in biology and chemistry
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Neighbouring group participation vs. addition to oxacarbenium ions: studies on the synthesis of mycobacterial oligosaccharides
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Solvent and Other Effects on the Stereoselectivity of Thioglycoside Glycosidations
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Solvent Effect in Glycosylation Reaction on Polymer Support
inferredcites →https://doi.org/10.1055/s-2005-872269openalex-snapshot
Oligosaccharide Synthesis by Affinity Separation Based on Molecular Recognition between Podand Ether and Ammonium Ion
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Molecular dynamics with coupling to an external bath
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Density-functional thermochemistry. III. The role of exact exchange
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CHEMISTRY OF GLYCOSYL TRIFLATES: SYNTHESIS OFβ-MANNOPYRANOSIDES
inferredcites →https://doi.org/10.1139/v04-059openalex-snapshot
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The azidonitration of tri-O-acetyl- D -galactal
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The Dielectric Constant of 1,4-Dioxane
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ENAMINES. VII(1). THE REACTION OF ENAMINES WITH SCHIFF BASES. A POSSIBLE CYCLOADDITION PATHWAY
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Conformational and Dynamical Properties of Disaccharides in Water: a Molecular Dynamics Study
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inferred← citeshttps://doi.org/10.1002/jcc.21675openalex-snapshot
A reoptimized GROMOS force field for hexopyranose‐based carbohydrates accounting for the relative free energies of ring conformers, anomers, epimers, hydroxymethyl rotamers, and glycosidic linkage conformers
inferred← citeshttps://doi.org/10.1002/jcc.23898openalex-snapshot
Solvents effects on the mechanism of cellulose hydrolysis: A QM/MM study
inferred← citeshttps://doi.org/10.1002/qua.24422openalex-snapshot
Bimolecular nature of boron trifluoride catalyzed glycosylation of a galactosyl donor: The role of the acceptor
inferred← citeshttps://doi.org/10.1002/slct.202200963openalex-snapshot
Stereoselective Synthesis of α ‐ʟ‐Rhamnopyranosides from ʟ‐Rhamnal Employing Ruthenium‐Catalysis
inferred← citeshttps://doi.org/10.1002/tcr.201402004openalex-snapshot
Pyranosides with 2,3‐trans Carbamate Groups: Exocyclic or Endocyclic Cleavage Reaction?
inferred← citeshttps://doi.org/10.1002/tcr.201500245openalex-snapshot
Design of α-Selective Glycopyranosyl Donors Relying on Remote Anchimeric Assistance
inferred← citeshttps://doi.org/10.1007/10_2020_150openalex-snapshot
Advances in the Chemical Synthesis of Carbohydrates and Glycoconjugates
inferred← citeshttps://doi.org/10.1007/s10719-016-9687-xopenalex-snapshot
Expedient synthesis of the pentasaccharide repeating unit of the O-antigen of Escherichia coli O86 and its conformational analysis
inferred← citeshttps://doi.org/10.1007/s11172-022-3625-9openalex-snapshot
The first example of unpromoted sialylation of a secondary alcohol
inferred← citeshttps://doi.org/10.1007/s11172-023-3842-6openalex-snapshot
Glycosylation with derivatives of phenyl 2-azido-2-deoxy-1-seleno-α-d-gluco- and -α-d-mannopyranosides
inferred← citeshttps://doi.org/10.1016/b978-0-08-097742-3.00602-9openalex-snapshot
6.01 Synthesis of Glycosides
inferred← citeshttps://doi.org/10.1016/b978-0-12-819475-1.00074-2openalex-snapshot
The Oxocarbenium Ion Intermediate
inferred← citeshttps://doi.org/10.1016/b978-0-443-44921-5.00012-2openalex-snapshot
Solvent-structured effects on homogeneous organic reactions
inferred← citeshttps://doi.org/10.1016/j.carres.2012.03.040openalex-snapshot
Plausible transition states for glycosylation reactions
inferred← citeshttps://doi.org/10.1016/j.carres.2014.05.021openalex-snapshot
In a glycosylation reaction how does a hydroxylic nucleophile find the activated anomeric carbon?
inferred← citeshttps://doi.org/10.1016/j.carres.2014.06.020openalex-snapshot
A propos of glycosyl cations and the mechanism of chemical glycosylation; the current state of the art
inferred← citeshttps://doi.org/10.1016/j.carres.2014.10.013openalex-snapshot
Contact ion pairs and solvent-separated ion pairs from d-mannopyranosyl and d-glucopyranosyl triflates
inferred← citeshttps://doi.org/10.1016/j.carres.2015.12.009openalex-snapshot
Synthesis of 5-O-oligoglucosyl extended α-(2→4)-Kdo disaccharides corresponding to inner core fragments of Moraxellaceae lipopolysaccharides
inferred← citeshttps://doi.org/10.1016/j.carres.2019.107748openalex-snapshot
Chemical synthesis of diglucosyl diacylglycerols utilizing glycosyl donors with stereodirecting cyclic silyl protective groups
inferred← citeshttps://doi.org/10.1016/j.carres.2023.109010openalex-snapshot
On the influence of solvent on the stereoselectivity of glycosylation reactions
inferred← citeshttps://doi.org/10.1016/j.carres.2024.109227openalex-snapshot
Role of ion pairs in model glycosylation reactions of permethylated glucosyl and xylosyl triflates
inferred← citeshttps://doi.org/10.1016/j.carres.2025.109527openalex-snapshot
Bi(OTf)3-promoted direct activation of formidable per-O-acetylated ʟ-rhamnose Donor: Stereoselective access to α-ʟ-rhamnopyranosides
inferred← citeshttps://doi.org/10.1016/j.carres.2025.109617openalex-snapshot
The influence of protective groups in sialyl halides on their reactivity and selectivity in glycosylation reactions: implications for the mechanism of sialylation
inferred← citeshttps://doi.org/10.1016/j.carres.2026.109994openalex-snapshot
Facile synthesis of the pentasaccharide corresponding to the O-antigen of Shigella boydii type 13 strain using linear and one-pot iterative glycosylations
inferred← citeshttps://doi.org/10.1016/j.gresc.2024.03.004openalex-snapshot
Unraveling chemical glycosylation: DFT insights into factors imparting stereoselectivity
inferred← citeshttps://doi.org/10.1016/j.jelechem.2010.09.022openalex-snapshot
The dielectric continuum solvent model adapted for treating preferential solvation effects
inferred← citeshttps://doi.org/10.1016/j.tet.2012.04.059openalex-snapshot
A stereocontrolled construction of 2-azido-2-deoxy-1,2-cis-α-galactosidic linkages utilizing 2-azido-4,6-O-benzylidene-2-deoxygalactopyranosyl diphenyl phosphates: stereoselective synthesis of mucin core 5 and core 7 structures
inferred← citeshttps://doi.org/10.1016/j.tetlet.2016.01.013openalex-snapshot
Phenyl 2-azido-2-deoxy-1-selenogalactosides: a single type of glycosyl donor for the highly stereoselective synthesis of α- and β-2-azido-2-deoxy-d-galactopyranosides
inferred← citeshttps://doi.org/10.1016/j.tetlet.2017.12.077openalex-snapshot
Recent topics in β-stereoselective mannosylation
inferred← citeshttps://doi.org/10.1021/acs.accounts.7b00449openalex-snapshot
Venturing beyond Donor-Controlled Glycosylation: New Perspectives toward Anomeric Selectivity
inferred← citeshttps://doi.org/10.1021/acs.chemrev.2c00029openalex-snapshot
Synthesis and Glycosidation of Anomeric Halides: Evolution from Early Studies to Modern Methods of the 21st Century
inferred← citeshttps://doi.org/10.1021/acs.chemrev.7b00731openalex-snapshot
Methods for 2-Deoxyglycoside Synthesis
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00051openalex-snapshot
Automated Chemical Oligosaccharide Synthesis: Novel Approach to Traditional Challenges
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00083openalex-snapshot
The Experimental Evidence in Support of Glycosylation Mechanisms at the SN1–SN2 Interface
inferred← citeshttps://doi.org/10.1021/acs.jcim.5c01613openalex-snapshot
CSMILES: A Compact, Human-Readable SMILES Extension for Conformations
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02207openalex-snapshot
Rationalizing the Stereoelectronic Influence of Interglycosidic Bond Conformations on the Reactivity of 1,4-O-Linked Disaccharide Donors
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02650openalex-snapshot
4,5-Dioxo-imidazolinium Cation-Promoted α-Selective Dehydrative Glycosylation of 2-Deoxy- and 2,6-Dideoxy Sugars
inferred← citeshttps://doi.org/10.1021/acs.joc.4c02956openalex-snapshot
The Stereochemical Outcome of Galactosylations Is Influenced by Both the Position and Electron-Withdrawing Power of Distal Acyl Protecting Groups
inferred← citeshttps://doi.org/10.1021/acs.joc.4c03128openalex-snapshot
Influence of Halogen Atoms and the Reactivity of Nucleophiles on Reactions of Tetrahydropyran and Tetrahydrofuran Acetals with C-Nucleophiles: Hyperconjugation and Inductive Effects
inferred← citeshttps://doi.org/10.1021/acs.joc.7b01167openalex-snapshot
1,3-syn-Diaxial Repulsion of Typical Protecting Groups Used in Carbohydrate Chemistry in 3-O-Substituted Derivatives of Isopropyl d -Idopyranosides
inferred← citeshttps://doi.org/10.1021/acs.joc.8b02422openalex-snapshot
Gold(III)-Catalyzed Glycosylation using Phenylpropiolate Glycosides: Phenylpropiolic Acid, An Easily Separable and Reusable Leaving Group
inferred← citeshttps://doi.org/10.1021/acs.jpca.0c05738openalex-snapshot
The Effect of Solvent–Substrate Noncovalent Interactions on the Diastereoselectivity in the Intramolecular Carbonyl-Ene and the Staudinger [2 + 2] Cycloaddition Reactions
inferred← citeshttps://doi.org/10.1021/acs.jpca.7b06602openalex-snapshot
Theoretical Studies of the Glycosidation of 2-O-Substituted 5-Fluorouracil: N-Regioselective Synthesis with the Phase-Transfer-Catalysis Method
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b03282openalex-snapshot
Aryl(trifluoroethyl)iodonium Triflimide and Nitrile Solvent Systems: A Combination for the Stereoselective Synthesis of Armed 1,2- trans -β-Glycosides at Noncryogenic Temperatures
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c03974openalex-snapshot
Chemical Synthesis of Conjugation-Ready Oligosaccharide Haptens of Pseudomonas aeruginasa O11 and Staphylococcus aureus Type 5
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b00976openalex-snapshot
Combined Effect of the Picoloyl Protecting Group and Triflic Acid in Sialylation
inferred← citeshttps://doi.org/10.1021/acscatal.4c04293openalex-snapshot
Gold(I)-Catalyzed Access to 1-Alkynyl C-Glycosides from 1-Silylated Alkynes: An Alternative Paradigm for the Direct and α-Stereoselective Alkynylation of Glycosides
inferred← citeshttps://doi.org/10.1021/acscatal.5c06507openalex-snapshot
Stereoselective Synthesis of 2-Deoxy-α-O-glycosides Enabled by Cobalt-Catalyzed Hydrogen Atom Transfer and Radical-Polar Crossover
inferred← citeshttps://doi.org/10.1021/acsomega.4c10086openalex-snapshot
Modeling of the Carbohydrate Oxacarbenium Ionic Intermediates of Glycosylation Reactions with Explicit Account for Protective Group Effects
inferred← citeshttps://doi.org/10.1021/cr500434xopenalex-snapshot
Mechanisms of Glycosylation Reactions Studied by Low-Temperature Nuclear Magnetic Resonance
inferred← citeshttps://doi.org/10.1021/ja307266nopenalex-snapshot
Cation Clock Permits Distinction Between the Mechanisms of α- and β-O- and β-C-Glycosylation in the Mannopyranose Series: Evidence for the Existence of a Mannopyranosyl Oxocarbenium Ion
inferred← citeshttps://doi.org/10.1021/jacs.0c12096openalex-snapshot
Ab Initio Molecular Dynamics Simulations of the S N 1/S N 2 Mechanistic Continuum in Glycosylation Reactions
inferred← citeshttps://doi.org/10.1021/jacs.1c02188openalex-snapshot
Automated Assembly of Starch and Glycogen Polysaccharides
inferred← citeshttps://doi.org/10.1021/jacs.3c02792openalex-snapshot
Directed S N 2 Glycosylation Employing an Amide-Functionalized 1-Naphthoate Platform Featuring a Selectivity-Safeguarding Mechanism
inferred← citeshttps://doi.org/10.1021/jacs.3c08709openalex-snapshot
Detection and Characterization of Rapidly Equilibrating Glycosylation Reaction Intermediates Using Exchange NMR
inferred← citeshttps://doi.org/10.1021/jacs.5c03519openalex-snapshot
Elucidating the Curtin–Hammett Principle in Glycosylation Reactions: The Decisive Role of Equatorial Glycosyl Triflates
inferred← citeshttps://doi.org/10.1021/jacs.5c20878openalex-snapshot
Ab Initio Molecular Dynamics Simulations for Organic Chemists─It is About Time!
inferred← citeshttps://doi.org/10.1021/jacs.6b08874openalex-snapshot
β-Stereoselective Mannosylation Using 2,6-Lactones
inferred← citeshttps://doi.org/10.1021/jacs.6c00007openalex-snapshot
Stereo-Switchable Electrochemical Glycosylation
inferred← citeshttps://doi.org/10.1021/jacs.8b04525openalex-snapshot
An Empirical Understanding of the Glycosylation Reaction
inferred← citeshttps://doi.org/10.1021/jacs.9b08875openalex-snapshot
Synthesis of Cage-Shaped Aluminum Aryloxides: Efficient Lewis Acid Catalyst for Stereoselective Glycosylation Driven by Flexible Shift of Four- to Five-Coordination
inferred← citeshttps://doi.org/10.1021/jacsau.4c01113openalex-snapshot
Why Are 5-Thioglycopyranosyl Donors More Axially Selective than their Glycopyranosyl Counterparts? A Low and Variable Temperature NMR Spectroscopy and Computational Study
inferred← citeshttps://doi.org/10.1021/jo101779vopenalex-snapshot
Mannosazide Methyl Uronate Donors. Glycosylating Properties and Use in the Construction of β-ManNAcA-Containing Oligosaccharides
inferred← citeshttps://doi.org/10.1021/jo1025157openalex-snapshot
Study of the Stereoselectivity of 2-Azido-2-deoxygalactosyl Donors: Remote Protecting Group Effects and Temperature Dependency
inferred← citeshttps://doi.org/10.1021/jo2017026openalex-snapshot
Methodology Development and Physical Organic Chemistry: A Powerful Combination for the Advancement of Glycochemistry
inferred← citeshttps://doi.org/10.1021/jo202563fopenalex-snapshot
Could Diastereoselectivity in the Presence of O-2 Chiral Nonparticipating Groups Be an Indicator of Glycopyranosyl Oxacarbenium Ions in Glycosylation Reactions?
inferred← citeshttps://doi.org/10.1021/jo202639gopenalex-snapshot
C2 Hydroxyl Group Governs the Difference in Hydrolysis Rates of Methyl-α- d -glycero- d -guloseptanoside and Methyl-β- d -glycero- d -guloseptanoside
inferred← citeshttps://doi.org/10.1021/jo302455dopenalex-snapshot
Influence of O6 in Mannosylations Using Benzylidene Protected Donors: Stereoelectronic or Conformational Effects?
inferred← citeshttps://doi.org/10.1021/jo400020qopenalex-snapshot
Exploring the Native Chemical Ligation Concept for Highly Stereospecific Glycosylation Reactions
inferred← citeshttps://doi.org/10.1021/jo400282xopenalex-snapshot
Hafnium(IV) Tetratriflate as a Glycosyl Fluoride Activation Reagent
inferred← citeshttps://doi.org/10.1021/jo4012464openalex-snapshot
Conformationally Armed 3,6-Tethered Glycosyl Donors: Synthesis, Conformation, Reactivity, and Selectivity
inferred← citeshttps://doi.org/10.1021/jo501012sopenalex-snapshot
Theoretical Foundation for the Presence of Oxacarbenium Ions in Chemical Glycoside Synthesis
inferred← citeshttps://doi.org/10.1021/la5049216openalex-snapshot
Sodium Triflate Decreases Interaggregate Repulsion and Induces Phase Separation in Cationic Micelles
inferred← citeshttps://doi.org/10.1021/ol302941qopenalex-snapshot
Visible Light Mediated Activation and O-Glycosylation of Thioglycosides
inferred← citeshttps://doi.org/10.1021/ol401095kopenalex-snapshot
Selective Synthesis of 1,2-cis-α-Glycosides without Directing Groups. Application to Iterative Oligosaccharide Synthesis
inferred← citeshttps://doi.org/10.1021/ol403722fopenalex-snapshot
β-Selective Mannosylation with a 4,6-Silylene-Tethered Thiomannosyl Donor
inferred← citeshttps://doi.org/10.1021/ol501471copenalex-snapshot
Solvent Effects in the Nucleophilic Substitutions of Tetrahydropyran Acetals Promoted by Trimethylsilyl Trifluoromethanesulfonate: Trichloroethylene as Solvent for Stereoselective C - and O -Glycosylations
inferred← citeshttps://doi.org/10.1038/nchem.1404openalex-snapshot
Dissecting the mechanisms of a class of chemical glycosylation using primary 13C kinetic isotope effects
inferred← citeshttps://doi.org/10.1038/ncomms6051openalex-snapshot
The intriguing dual-directing effect of 2-cyanobenzyl ether for a highly stereospecific glycosylation reaction
inferred← citeshttps://doi.org/10.1038/s41467-026-69820-3openalex-snapshot
Detecting glycosyl-oxonium and glycosyl-nitrilium ions using exchange NMR to investigate solvent effects in glycosylation reactions
inferred← citeshttps://doi.org/10.1039/c2ob06696copenalex-snapshot
On a so-called “kinetic anomeric effect” in chemical glycosylation
inferred← citeshttps://doi.org/10.1039/c3cs35457aopenalex-snapshot
Design of chemical glycosyl donors: does changing ring conformation influence selectivity/reactivity?
inferred← citeshttps://doi.org/10.1039/c3ob41747fopenalex-snapshot
Chair interconversion and reactivity of mannuronic acid esters
inferred← citeshttps://doi.org/10.1039/c3ob42073fopenalex-snapshot
An unusual glycosylation product from a partially protected fucosyl donor under silver triflate activation conditions
inferred← citeshttps://doi.org/10.1039/c3ob42129eopenalex-snapshot
Modulating glycosylation with exogenous nucleophiles: an overview
inferred← citeshttps://doi.org/10.1039/c5cc04716aopenalex-snapshot
β-Mannosylation with 4,6-benzylidene protected mannosyl donors without preactivation
inferred← citeshttps://doi.org/10.1039/c5np00033eopenalex-snapshot
O-Glycosylation methods in the total synthesis of complex natural glycosides
inferred← citeshttps://doi.org/10.1039/c5ob00177copenalex-snapshot
Chemical synthesis of the outer core oligosaccharide of Escherichia coli R3 and immunological evaluation
inferred← citeshttps://doi.org/10.1039/c5sc00280jopenalex-snapshot
Stereocontrolled 1,2-cis glycosylation as the driving force of progress in synthetic carbohydrate chemistry
inferred← citeshttps://doi.org/10.1039/c6cc10076gopenalex-snapshot
Catalytic stereospecific O -glycosylation
inferred← citeshttps://doi.org/10.1039/c7ob00947jopenalex-snapshot
A sialosyl sulfonate as a potent inhibitor of influenza virus replication
inferred← citeshttps://doi.org/10.1039/c7ob03035eopenalex-snapshot
Synthesis of branched and linear 1,4-linked galactan oligosaccharides
inferred← citeshttps://doi.org/10.1039/c9ob02700aopenalex-snapshot
C-2 auxiliaries for stereoselective glycosylation based on common additive functional groups
inferred← citeshttps://doi.org/10.1039/c9sc00768gopenalex-snapshot
Automated glycan assembly of Lewis type I and II oligosaccharide antigens
inferred← citeshttps://doi.org/10.1039/d0cp05090copenalex-snapshot
The keto–enol tautomerization of ethyl acetoacetate in choline ionic liquids: the role of cation and anion in switching the tautomeric equilibrium
inferred← citeshttps://doi.org/10.1039/d0ob01128bopenalex-snapshot
Indirect synthetic route to α- l -fucosides via highly stereoselective construction of α- l -galactosides followed by C6-deoxygenation
inferred← citeshttps://doi.org/10.1039/d0ob02373fopenalex-snapshot
Computational evidence of glycosyl cations
inferred← citeshttps://doi.org/10.1039/d0sc04595kopenalex-snapshot
Chemical synthesis and immunological evaluation of entirely carbohydrate conjugate Globo H-PS A1
inferred← citeshttps://doi.org/10.1039/d0sc06222gopenalex-snapshot
Predicting glycosylation stereoselectivity using machine learning
inferred← citeshttps://doi.org/10.1039/d1ob02001copenalex-snapshot
Deoxy sugars. General methods for carbohydrate deoxygenation and glycosidation
inferred← citeshttps://doi.org/10.1039/d1ob02139gopenalex-snapshot
Computational discoveries of reaction mechanisms: recent highlights and emerging challenges
inferred← citeshttps://doi.org/10.1039/d3cp03326kopenalex-snapshot
Selective reactivity of glycosyl cation stereoisomers: the role of intramolecular hydrogen bonding
inferred← citeshttps://doi.org/10.1039/d4cc04877fopenalex-snapshot
Recent advancements in synthesis of cyclic oligosaccharides
inferred← citeshttps://doi.org/10.1039/d4gc04572fopenalex-snapshot
1,2- trans and regioselective glycosylation of multihydroxy sugars via a simple yet synergistic combination of BF 3 ·Et 2 O in THF
inferred← citeshttps://doi.org/10.1039/d4ob01978dopenalex-snapshot
Stereoselective 1,1′-glycosylation via reactivity tuning with protecting groups
inferred← citeshttps://doi.org/10.1055/a-1938-2293openalex-snapshot
Recent Developments in Solid-Phase Glycan Synthesis
inferred← citeshttps://doi.org/10.1055/a-2193-4615openalex-snapshot
Activation of Stable and Recyclable Phenylpropiolate Glycoside (PPG) Donors by Iron Catalysis
inferred← citeshttps://doi.org/10.1055/s-0042-1751541openalex-snapshot
Acetal Substitution Reactions: Stereoelectronic Effects, Conformational Analysis, Reactivity vs Selectivity, and Neighboring-Group Participation
inferred← citeshttps://doi.org/10.1063/5.0289569openalex-snapshot
Semi-empirical metadynamics simulations for chemical glycosylation reactions
inferred← citeshttps://doi.org/10.1071/ch16429openalex-snapshot
Sweet Poisons: Synthetic Strategies towards Tutin Glycosides
inferred← citeshttps://doi.org/10.1080/00268976.2011.598136openalex-snapshot
Molecular dynamics study of reaction kinetics in viscous media
inferred← citeshttps://doi.org/10.1080/07328303.2017.1365369openalex-snapshot
Proton transfer and hydrogen bonding in glycosylation reactions
inferred← citeshttps://doi.org/10.1139/cjc-2016-0417openalex-snapshot
Controlling the stereoselectivity of glycosylation via solvent effects
inferred← citeshttps://doi.org/10.1246/bcsj.20200258openalex-snapshot
G-RMSD: Root Mean Square Deviation Based Method for Three-Dimensional Molecular Similarity Determination
inferred← citeshttps://doi.org/10.2174/1570193x20666230223144523openalex-snapshot
Organocatalyzed Stereoselective Glycosylation: An Overview of the Last Decade
inferred← citeshttps://doi.org/10.2174/9789815322798125010005openalex-snapshot
Recent Advances in the Synthesis of O- and S-Glycosides from Glycals
inferred← citeshttps://doi.org/10.26686/wgtn.17148029openalex-snapshot
The Synthesis of Carbohydrate Probes for the Diagnosis of Multiple Sclerosis
inferred← citeshttps://doi.org/10.31390/gradschool_dissertations.5396openalex-snapshot
Methods for 1,2-Cis-Selective O-Glycosylation and Synthesis of an A. baumannii Lipooligosaccharide Core Disaccharide
inferred← citeshttps://doi.org/10.3390/molecules31183145openalex-snapshot
The Computational Study of the Mechanism of the Acid-Promoted Pyranoside-into-Furanoside Rearrangement
inferred← citeshttps://doi.org/10.3762/bjoc.12.164openalex-snapshot
TMSBr-mediated solvent- and work-up-free synthesis of α-2-deoxyglycosides from glycals
inferred← citeshttps://doi.org/10.3762/bjoc.21.131openalex-snapshot
Structural analysis of stereoselective galactose pyruvylation toward the synthesis of bacterial capsular polysaccharides
inferred← citeshttps://doi.org/10.3987/rev-20-933openalex-snapshot
Recent Development of Stereoselective Glycosylation Reactions
inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.71.616openalex-snapshot
Unique Reactivity of Pyranosides with 2,3-trans Carbamate Group; Renaissance of Endocyclic Cleavage Reaction
inferred← citeshttps://doi.org/10.57709/7008260openalex-snapshot
Chemical Synthesis of Outer Core Oligosaccharide of Escherichia Coli R3 and Convergent Synthesis of O-glycan Library
inferred← citeshttps://doi.org/10.58837/chula.the.2018.104openalex-snapshot
Glycosylation of Thioglycosides with Bromodiethylsulfonium bromopentachloroantimonate as novel activator
inferred← citeshttps://doi.org/10.66617/001c.1125openalex-snapshot
The counter ion: expanding excipient functionality
inferred← citeshttps://doi.org/10.70675/4ac4273fz8c40z4ab0zb723z741101d10d1copenalex-snapshot
Dérivés de l'exopolysaccharide d’Alteromonas infernus, mimétiques de glycosaminoglycanes, et développement d'une stratégie pour leur analyse structurale
inferred← citeshttps://doi.org/10.70675/6aeb1162zd647z45dfz9caezc47a127b8923openalex-snapshot
Groupements protecteurs et contrôle de la stéréosélectivité de réactions de glycosylation en série 2-azido-2-déoxy-D-glucose
inferred← citeshttps://doi.org/10.70675/90e72228z707fz4f01z88d6z19cef2e17425openalex-snapshot
Exploiter des superacides pour générer et caractériser des espèces ioniques clés dans le domaine des glycosciences
inferred← citeshttps://doi.org/10.70675/a989942bzba69z4952z9e2bz9990449769e9openalex-snapshot
Utilisation de conditions superacides pour la mise en évidence d'intermédiaires réactionnels glycosidiques inédits
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