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.alpha. Effect. V. Kinetic and thermodynamic nature of the .alpha. effect for amine nucleophiles
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Pitfalls in the determination of the α-effect by a two-point analysis. The effect of solvent on the α-effect.
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Aggregation effects in the reactions of 2,4-dinitrochlorobenzene with aniline in aprotic solvents
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Nucleophilic substitution of acyl chlorides by electrogenerated polysulfide ions in N,N-dimethylacetamide
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Reactivity of electrogenerated polysulfide ions towards acyl thioanhydrides and anhydrides in N,N-dimethylacetamide
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Nucleophilic substitution of S-phenyl thiol esters by electrogenerated polysulfide ions in N,N-dimethylacetamide
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The effect of solvent on the α-effect: CO, PO and SO2 centers
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Catalyst-free, aza-Michael polymerization of hydrazides: polymerizability, kinetics, and mechanistic origin of an α-effect
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Medium effect on the α-effect for nucleophilic substitution reactions of p-nitrophenyl acetate with benzohydroxamates and m-chlorophenoxide in DMSO–H2O mixtures as contrasts with MeCN–H2O mixtures: comparing two very different polar aprotic solvent components
inferred← citeshttps://doi.org/10.1139/cjc-2018-0290openalex-snapshot
Hydrazinolysis of aryl cinnamates and related esters: the α-effect arises from stabilization of five-membered cyclic transition state
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Alpha-Effect nucleophiles and azide ion: effective charge studies of displacement reactions at esters
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An unusual ground-state stabilization effect and origins of the alpha-effect in aminolyses of Y-substituted phenyl X-substituted benzoates
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Effect of modification of the electrophilic center on the α effect
inferred← citeshttps://doi.org/10.3184/030823407x240926openalex-snapshot
Reaction of 4-Chloro-3,5-Dinitrobenzotrifluoride with Aniline Derivatives. Substituent Effects
inferred← citeshttps://doi.org/10.3389/fchem.2021.740161openalex-snapshot
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inferred← citeshttps://doi.org/10.5012/bkcs.2002.23.9.1263openalex-snapshot
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inferred← citeshttps://doi.org/10.5012/bkcs.2013.34.8.2251openalex-snapshot
The α-Effect in Nucleophilic Substitution Reactions of Y-Substituted-Phenyl Diphenylphosphinates with HOO-and OH-
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In vitro reconstitution of vertebrate Sonic Hedgehog protein cholesterolysis
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