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Origin of the α‐Effect in SN2 Reactions

https://doi.org/10.1002/anie.202106053
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Outgoing claims: the papers this work cites, builds on, or argues with.

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The α-Effect in SNAr Substitutions − Reaction between Oximate Nucleophiles and 2,4-Dinitrofluorobenzene in Aqueous Solution
inferredcites →https://doi.org/10.1002/ange.201701486openalex-snapshot
Das Distortion/Interaction‐Activation‐Strain‐Modell zur Analyse von Reaktionsgeschwindigkeiten
inferredcites →https://doi.org/10.1002/anie.201701486openalex-snapshot
Analyzing Reaction Rates with the Distortion/Interaction‐Activation Strain Model
inferredcites →https://doi.org/10.1002/anie.202106053openalex-snapshot
Origin of the α‐Effect in SN2 Reactions
inferredcites →https://doi.org/10.1002/chem.200600203openalex-snapshot
G2(+) Investigation on the α‐Effect in the SN2 Reactions at Saturated Carbon
inferredcites →https://doi.org/10.1002/chem.202003831openalex-snapshot
A Unified Framework for Understanding Nucleophilicity and Protophilicity in the SN2/E2 Competition
inferredcites →https://doi.org/10.1002/ejoc.202000590openalex-snapshot
Regioselectivity of Epoxide Ring‐Openings via S N 2 Reactions Under Basic and Acidic Conditions
inferredcites →https://doi.org/10.1002/ijch.198500113openalex-snapshot
The α‐Effect: A Critical Examination of the Phenomenon and Its Origin
inferredcites →https://doi.org/10.1002/jcc.10351openalex-snapshot
Voronoi deformation density (VDD) charges: Assessment of the Mulliken, Bader, Hirshfeld, Weinhold, and VDD methods for charge analysis
inferredcites →https://doi.org/10.1002/jcc.23356openalex-snapshot
The α-effect exhibited in gas-phase S N 2@N and S N 2@C reactions
inferredcites →https://doi.org/10.1002/jcc.23862openalex-snapshot
Probing the reactivity of microhydrated α‐nucleophile in the anionic gas‐phase SN2 reaction
inferredcites →https://doi.org/10.1002/kin.550050102openalex-snapshot
The alpha effect. A review
inferredcites →https://doi.org/10.1007/s0089470030464openalex-snapshot
Reviews in Computational Chemistry, Vol. 8
inferredcites →https://doi.org/10.1007/s13361-013-0781-zopenalex-snapshot
The α-Effect and Competing Mechanisms: The Gas-Phase Reactions of Microsolvated Anions with Methyl Formate
inferredcites →https://doi.org/10.1016/j.bioorg.2003.09.003openalex-snapshot
Predominant role of basicity of leaving group in α-effect for nucleophilic ester cleavage
inferredcites →https://doi.org/10.1016/j.tet.2004.05.006openalex-snapshot
The α-effect and its modulation by solvent
inferredcites →https://doi.org/10.1016/s0040-4020(01)93101-1openalex-snapshot
Supernucleophiles—I
inferredcites →https://doi.org/10.1016/s0040-4039(00)94005-xopenalex-snapshot
Can ground-state destabilization of an α-nucleophile induce an α-effect?
inferredcites →https://doi.org/10.1016/s0040-4039(01)80130-1openalex-snapshot
Enhanced reactivity of an α-nucleophile in water-dimethyl sulfoxide mixtures. A transition state effect.
inferredcites →https://doi.org/10.1021/acs.joc.0c02112openalex-snapshot
SN2 versus E2 Competition of F– and PH2– Revisited
inferredcites →https://doi.org/10.1021/acs.joc.0c02955openalex-snapshot
How Lewis Acids Catalyze Ring-Openings of Cyclohexene Oxide
inferredcites →https://doi.org/10.1021/ct500727copenalex-snapshot
Physical Meaning of Virtual Kohn–Sham Orbitals and Orbital Energies: An Ideal Basis for the Description of Molecular Excitations
inferredcites →https://doi.org/10.1021/ct700214vopenalex-snapshot
Reaction Coordinates and the Transition-Vector Approximation to the IRC
inferredcites →https://doi.org/10.1021/ja00346a066openalex-snapshot
Absence of an .alpha.-effect in the gas-phase nucleophilic reactions of hydroperoxide ion
inferredcites →https://doi.org/10.1021/ja00403a014openalex-snapshot
What happens to molecules as they react? A valence bond approach to reactivity
inferredcites →https://doi.org/10.1021/ja00403a015openalex-snapshot
Reactivity-selectivity relationships. A quantum-mechanical approach to transition-state structure. Application to the SN2 reaction of benzyl derivatives
inferredcites →https://doi.org/10.1021/ja00475a005openalex-snapshot
Quantum mechanical studies of the .alpha. effect
inferredcites →https://doi.org/10.1021/ja00743a034openalex-snapshot
Free energies of hydrolysis of amides and peptides in aqueous solution at 25.deg.
inferredcites →https://doi.org/10.1021/ja00761a043openalex-snapshot
.alpha. Effect. V. Kinetic and thermodynamic nature of the .alpha. effect for amine nucleophiles
inferredcites →https://doi.org/10.1021/ja00860a005openalex-snapshot
The Factors Determining Nucleophilic Reactivities
inferredcites →https://doi.org/10.1021/ja01012a031openalex-snapshot
The mechanism of the aminolysis of methyl formate
inferredcites →https://doi.org/10.1021/ja01093a018openalex-snapshot
Carbon Basicity1a
inferredcites →https://doi.org/10.1021/ja01492a058openalex-snapshot
Reactivity of Nucleophilic Reagents toward Esters
inferredcites →https://doi.org/10.1021/ja205741mopenalex-snapshot
Experimental Validation of the α-Effect in the Gas Phase
inferredcites →https://doi.org/10.1021/ja4066943openalex-snapshot
Investigating the α-Effect in Gas-Phase SN2 Reactions of Microsolvated Anions
inferredcites →https://doi.org/10.1021/ja9012084openalex-snapshot
Reactions of α-Nucleophiles with Alkyl Chlorides: Competition between SN2 and E2 Mechanisms and the Gas-Phase α-Effect
inferredcites →https://doi.org/10.1021/jacs.7b05367openalex-snapshot
Stereoelectronic Interactions as a Probe for the Existence of the Intramolecular α-Effect
inferredcites →https://doi.org/10.1021/jo00139a033openalex-snapshot
The .alpha. effect: on the origin of transition-state stabilization
inferredcites →https://doi.org/10.1021/jo00959a059openalex-snapshot
Aromatic transition states and the .alpha. effect
inferredcites →https://doi.org/10.1021/jo00972a024openalex-snapshot
Nucleophilic reactivity of peroxy anions
inferredcites →https://doi.org/10.1021/jo0156114openalex-snapshot
Solvent Effect on the α-Effect for the Reactions of Aryl Acetates with Butane-2,3-dione Monoximate and p-Chlorophenoxide in MeCN−H2O Mixtures
inferredcites →https://doi.org/10.1021/jo0206263openalex-snapshot
The α-Effect in Methyl Transfers from S-Methyldibenzothiophenium Fluoroborate to Substituted N-Methylbenzohydroxamates
inferredcites →https://doi.org/10.1021/jo050624topenalex-snapshot
The α-Effect in Reactions of sp-Hybridized Carbon Atom: Michael-Type Reactions of 1-Aryl-2-propyn-1-ones with Primary Amines
inferredcites →https://doi.org/10.1021/jo061275lopenalex-snapshot
On Gas Phase α-Effects. 1. The Gas-Phase Manifestation and Potential SET Character
inferredcites →https://doi.org/10.1021/jo070650mopenalex-snapshot
The α-Effect in Gas-Phase SN2 Reactions: Existence and the Origin of the Effect
inferredcites →https://doi.org/10.1021/jo9915776openalex-snapshot
The Origin of the α-Effect: Dissection of Ground-State and Transition-State Contributions
inferredcites →https://doi.org/10.1021/jp407698aopenalex-snapshot
The α-Effect in Gas-Phase SN2 Reactions of Microsolvated Anions: Methanol as a Solvent
inferredcites →https://doi.org/10.1021/ol0526930openalex-snapshot
The α-Effect in Gas-Phase SN2 Reactions Revisited
inferredcites →https://doi.org/10.1038/s41596-019-0265-0openalex-snapshot
Understanding chemical reactivity using the activation strain model
inferredcites →https://doi.org/10.1039/b803734eopenalex-snapshot
Reactions of the hydroperoxide anion with dimethyl methylphosphonate in an ion trap mass spectrometer: evidence for a gas phase α-effect
inferredcites →https://doi.org/10.1039/c4cs00055bopenalex-snapshot
The activation strain model and molecular orbital theory: understanding and designing chemical reactions
inferredcites →https://doi.org/10.1039/c4ob02067gopenalex-snapshot
From α-nucleophiles to functionalized aggregates: exploring the reactivity of hydroxamate ion towards esterolytic reactions in micelles
inferredcites →https://doi.org/10.1039/d1cc02042kopenalex-snapshot
Chemical reactivity from an activation strain perspective
inferredcites →https://doi.org/10.1139/cjc-76-6-678openalex-snapshot
Alpha-Effect nucleophiles and azide ion: effective charge studies of displacement reactions at esters
inferredcites →https://doi.org/10.1515/9783110660074-008openalex-snapshot
8 Energy decomposition analysis in the context of quantitative molecular orbital theory

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