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Use of Medium Effects to Tune the ΔE1/2Values of Bimetallic and Oligometallic Compounds
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Outgoing claims: the papers this work cites, builds on, or argues with.
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Thermodynamics of successive electron transfers
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Medium Effects on Charge Transfer in Metal Complexes
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Two-Electron Reactions in Organic and Organometallic Electrochemistry.
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inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123185openalex-snapshot
The influence of phosphine ligands on the redox properties of 1,4-divinylanthrylene-bridged diruthenium complexes and a derived macrocyclic analog
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2025.123539openalex-snapshot
Overview of organometallic electrochemistry
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2025.123622openalex-snapshot
NIR absorbing ferrocenyl phenothiazine based push–pull chromophores
inferred← citeshttps://doi.org/10.1016/j.molstruc.2015.11.020openalex-snapshot
Unusual coordination modes of ligand 2-chloro-5-nitrobenzene sulfonate: Synthesis, spectroscopic characterization, thermal and X-ray structural studies of metal 2-chloro-5-nitrobenzene sulfonate complexes, metal = Tl(I), Cu(II), Ag(I) and Pb(II)
inferred← citeshttps://doi.org/10.1016/j.poly.2010.02.009openalex-snapshot
Chemical and electrochemical oxidation and reduction of dithizone
inferred← citeshttps://doi.org/10.1016/j.poly.2012.03.028openalex-snapshot
Oxidation resilient dithizones – Synthesis, cyclic voltammetry and DFT perspectives
inferred← citeshttps://doi.org/10.1016/j.poly.2013.02.059openalex-snapshot
Intramolecular electronic communication in ferrocene-based β-diketonato copper(II) complexes as observed by an electrochemical study
inferred← citeshttps://doi.org/10.1016/j.poly.2014.04.035openalex-snapshot
Synthesis and redox properties of mono-, di- and tri-metallic platinum-ethynyl complexes based on the trans-Pt(C6H4N{C6H4OCH3-4}2)(C CR)(PPh3)2 motif
inferred← citeshttps://doi.org/10.1016/j.poly.2018.06.038openalex-snapshot
Ferrocenylmethyl-functionalized 5-membered heterocycles: Synthesis, solid-state structure and electrochemical investigations
inferred← citeshttps://doi.org/10.1016/s0022-0728(03)00143-8openalex-snapshot
Strong ion-pairing effects in a room temperature ionic liquid
inferred← citeshttps://doi.org/10.1016/s1452-3981(23)14744-4openalex-snapshot
Electrochemically-Induced CO-Substitution Reactions of CoCp(CO)2: Manipulating the [CoCp(CO)2]+/CoCp(CO)2 Radical/Substrate Coupling with PR3 Nucleophiles (R = Ph or OMe)†
inferred← citeshttps://doi.org/10.1021/acs.chemmater.2c01040openalex-snapshot
Double Doping of a Low-Ionization-Energy Polythiophene with a Molybdenum Dithiolene Complex
inferred← citeshttps://doi.org/10.1021/acs.chemrev.4c00295openalex-snapshot
Multi-Ferrocene-Based Ligands: From Design to Applications
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.0c00276openalex-snapshot
(Electrochemical) Properties and Computational Investigations of Ferrocenyl-substituted Fe3(μ3-PFc)2(CO)9and Co4(μ4-PFc)2(CO)9Clusters and Their Reduced Species
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.0c00491openalex-snapshot
Photoconducting Devices with Response in the Visible–Near-Infrared Region Based on Neutral Ni Complexes of Aryl-1,2-dithiolene Ligands
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.0c02696openalex-snapshot
Diradical Character of Neutral Heteroleptic Bis(1,2-dithiolene) Metal Complexes: Case Study of [Pd(Me2timdt)(mnt)] (Me2timdt = 1,3-Dimethyl-2,4,5-trithioxoimidazolidine; mnt2– = 1,2-Dicyano-1,2-ethylenedithiolate)
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c04481openalex-snapshot
Intervalence Charge Transfer in an Osmium(IV) Tetra(ferrocenylaryl) Complex
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b00397openalex-snapshot
Tuning Electron-Transfer Properties in 5,10,15,20-Tetra(1′-hexanoylferrocenyl)porphyrins as Prospective Systems for Quantum Cellular Automata and Platforms for Four-Bit Information Storage
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.8b03253openalex-snapshot
Mixed-Valent Ruthenocene–Vinylruthenium Conjugates: Valence Delocalization Despite Chemically Different Redox Sites
inferred← citeshttps://doi.org/10.1021/acs.joc.7b00030openalex-snapshot
Reactivity of Ferrocenyl Phosphates Bearing (Hetero-)Aromatics and [3]Ferrocenophanes toward Anionic Phospho-Fries Rearrangements
inferred← citeshttps://doi.org/10.1021/acs.joc.9b00541openalex-snapshot
Redox-Driven Folding, Unfolding, and Refolding of Bis(tetrathiafulvalene) Molecular Switch
inferred← citeshttps://doi.org/10.1021/acs.jpcb.6c00294openalex-snapshot
Thermodynamic and Kinetic Effects of Ion Pairing in Class II/III Mixed-Valent Systems
inferred← citeshttps://doi.org/10.1021/acs.macromol.5b01683openalex-snapshot
Ferrocene and Silicon-Containing Oxathiacrown Macrocycles and Linear Oligo-Oxathioethers Obtained via Thiol–Ene Chemistry of a Redox-Active Bifunctional Vinyldisiloxane
inferred← citeshttps://doi.org/10.1021/acs.nanolett.6b02471openalex-snapshot
Building Diatomic and Triatomic Superatom Molecules
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00681openalex-snapshot
Iron Versus Ruthenium: Evidence for the Distinct Differences in the Electronic Structures of Hexa-1,3,5-triyn-1,6-diyl-bridged Complexes [Cp*(dppe)M}{μ-(C≡C)3}{M(dppe)Cp*}]+ (M = Fe, Ru)
inferred← citeshttps://doi.org/10.1021/acs.organomet.3c00337openalex-snapshot
Diruthenium Complexes with π-Extended Bridging Bis(alkenyl)arylene Ligands, A Derived Metallamacrocycle, and Their Oxidized Forms
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00327openalex-snapshot
Dimers of Nineteen-Electron Sandwich Compounds: An Electrochemical Study of the Kinetics of Their Formation
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00450openalex-snapshot
Ferrocenes Bridged by Ethylenediamino Thiophene: Varying Charge Transfer Properties in a Series of 3,4-Di-N-substituted 2,5-Diferrocenyl Thiophenes
inferred← citeshttps://doi.org/10.1021/acs.organomet.5c00168openalex-snapshot
Localized Class-II Mixed Valency in Zwitterionic Diiron Complexes Containing [Cp*(dppe)Fe] n + Units and an Internal Carboxylate: Experimental Validation and Theoretical Insights into Solvent-Stabilized Charge Trapping
inferred← citeshttps://doi.org/10.1021/acs.organomet.6b00559openalex-snapshot
Multi-Ferrocene-Containing Silanols as Redox-Active Anion Receptors
inferred← citeshttps://doi.org/10.1021/acs.organomet.6c00055openalex-snapshot
NIR-Absorbing TCBD and Expanded TCBD-Functionalized Ferrocene–Phenothiazine Conjugates
inferred← citeshttps://doi.org/10.1021/acs.organomet.7b00686openalex-snapshot
Diferrocenes Bridged by a Geminal Diethynylethene Scaffold with Varying Pendant Substituents: Electronic Interactions in Cross-Conjugated System
inferred← citeshttps://doi.org/10.1021/acs.organomet.9b00318openalex-snapshot
Influence of Quinoidal Distortion on the Electronic Properties of Oxidized Divinylarylene-Bridged Diruthenium Complexes
inferred← citeshttps://doi.org/10.1021/acs.organomet.9b00818openalex-snapshot
Is Indenyl a Stronger or Weaker Electron Donor Ligand than Cyclopentadienyl? Opposing Effects of Indenyl Electron Density and Ring Slipping on Electrochemical Potentials
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b00522openalex-snapshot
A Star-Shaped Molecule with Low-Lying Lowest Unoccupied Molecular Orbital Level, n-Type Panchromatic Electrochromism, and Long-Term Stability
inferred← citeshttps://doi.org/10.1021/acsomega.4c04917openalex-snapshot
Light Activated Release of Nitrile Ligands from trans-Ru(L)(PPh3)2(nitrile) Complexes
inferred← citeshttps://doi.org/10.1021/acsorginorgau.2c00005openalex-snapshot
Estimation of Electron Distribution over Dinuclear Organometallic Molecular Wires by “IR Tag” Analysis of Ancillary Acyl-Cp Ligands
inferred← citeshttps://doi.org/10.1021/ar068100iopenalex-snapshot
Studies of Electronic Coupling and Mixed Valency in Metal−Metal Quadruply Bonded Complexes Linked by Dicarboxylate and Closely Related Ligands
inferred← citeshttps://doi.org/10.1021/ar1000023openalex-snapshot
Organometallic Electrochemistry Based on Electrolytes Containing Weakly-Coordinating Fluoroarylborate Anions
inferred← citeshttps://doi.org/10.1021/cr050010oopenalex-snapshot
Intervalence Charge Transfer (IVCT) in Trinuclear and Tetranuclear Complexes of Iron, Ruthenium, and Osmium
inferred← citeshttps://doi.org/10.1021/cr9003852openalex-snapshot
Electronic Communication through Unsaturated Hydrocarbon Bridges in Homobimetallic Organometallic Complexes
inferred← citeshttps://doi.org/10.1021/ic0205132openalex-snapshot
Heterodimetallic Compounds Assembled from Ferrocenedicarboxylato and Ferrocenecarboxylato Ligands
inferred← citeshttps://doi.org/10.1021/ic030079jopenalex-snapshot
Sterically Encumbered Diphosphaalkenes and a Bis(diphosphene) as Potential Multiredox-Active Molecular Switches: EPR and DFT Investigations
inferred← citeshttps://doi.org/10.1021/ic030216copenalex-snapshot
Synthesis, Characterization, and Detailed Electrochemistry of Binuclear Ruthenium(III) Complexes Bridged by Bisacetylacetonate. Crystal and Molecular Structures of [{Ru(acac)2}2(tae)] (acac = 2,4-Pentanedionate Ion, tae = 1,1,2,2-Tetraacetylethanate Dianion)
inferred← citeshttps://doi.org/10.1021/ic0349454openalex-snapshot
Outer Sphere Perturbation of Delocalized Mixed-Valence Complexes
inferred← citeshttps://doi.org/10.1021/ic040090zopenalex-snapshot
Di([5]trovacenyl)ethyne, Di([5]trovacenyl)butadiyne, and Di-1,4-([5]trovacenylethynyl)benzene: Electrocommunication and Magnetocommunication Mediated by C⋮C, C⋮CC⋮C and C⋮CC6H4C⋮C Spacers
inferred← citeshttps://doi.org/10.1021/ic060956wopenalex-snapshot
Concerning the Electronic Coupling of MoMo Quadruple Bonds Linked by 4,4‘-Azodibenzoate and Comparison with t2g6-Ru(II) Centers by 4,4‘-Azodiphenylcyanamido Ligands
inferred← citeshttps://doi.org/10.1021/ic061803bopenalex-snapshot
Electroactive Thiazole Derivatives Capped with Ferrocenyl Units Showing Charge-Transfer Transition and Selective Ion-Sensing Properties: A Combined Experimental and Theoretical Study
inferred← citeshttps://doi.org/10.1021/ic0702973openalex-snapshot
Control of Electronic and Magnetic Coupling via Bridging Ligand Geometry in a Bimetallic Ytterbocene Complex
inferred← citeshttps://doi.org/10.1021/ic101415copenalex-snapshot
How Do Nitriles Compare with Isoelectronic Alkynyl Groups in the Electronic Communication between Iron Centers Bridged by Phenylenebis- and -tris(nitrile) Ligands? An Electronic and Crystal-Structure Study
inferred← citeshttps://doi.org/10.1021/ic201012mopenalex-snapshot
Interaction of Ferrocene Moieties Across a Square Pt4 Unit: Synthesis, Characterization, and Electrochemical Properties of Carboxylate-Bridged Bimetallic Pt4Fen (n = 2, 3, and 4) Complexes
inferred← citeshttps://doi.org/10.1021/ic201521wopenalex-snapshot
Electronic Structure of the Water Oxidation Catalyst cis , cis -[(bpy) 2 (H 2 O)Ru III ORu III (OH 2 )(bpy) 2 ] 4+ , The Blue Dimer
inferred← citeshttps://doi.org/10.1021/ic201849uopenalex-snapshot
Electrochemical Illumination of Intramolecular Communication in Ferrocene-Containingtris-β-Diketonato Aluminum(III) Complexes; Cytotoxicity of Al(FcCOCHCOCF3)3
inferred← citeshttps://doi.org/10.1021/ic301777yopenalex-snapshot
[1.1]Ferrocenophanes and Bis(ferrocenyl) Species with Aluminum and Gallium as Bridging Elements: Synthesis, Characterization, and Electrochemical Studies
inferred← citeshttps://doi.org/10.1021/ic302535hopenalex-snapshot
Phenylcyanamidoruthenium Scorpionate Complexes
inferred← citeshttps://doi.org/10.1021/ic302730vopenalex-snapshot
Electrochemical Evidence of Intramolecular Electronic Communication in Zr and Hf Phthalocyanines Bearing Ferrocene-Containing β-Diketonato Axial Ligands: Structure of [PcHf(FcCOCHCOC6H5)2]
inferred← citeshttps://doi.org/10.1021/ic401555gopenalex-snapshot
Hydrogen Bonding and Electron Transfer between Dimetal Paddlewheel Compounds Containing Pendant 2-Pyridone Functional Groups
inferred← citeshttps://doi.org/10.1021/ic402202wopenalex-snapshot
Metal–Metal Interaction in Fischer Carbene Complexes: A Study of Ferrocenyl and Biferrocenyl Tungsten Alkylidene Complexes
inferred← citeshttps://doi.org/10.1021/ic402538eopenalex-snapshot
A Combined Computational and Spectroelectrochemical Study of Platinum-Bridged Bis-Triarylamine Systems
inferred← citeshttps://doi.org/10.1021/ic900100wopenalex-snapshot
Anthracene-Bridged Binuclear Ruthenium Complexes: Electrochemical and Spectroscopic Evidence of Electronic Communication Through the π System
inferred← citeshttps://doi.org/10.1021/ic901676eopenalex-snapshot
Synthesis, Substitution Kinetics, and Electrochemistry of the First Tetrathiafulvalene-Containing β-Diketonato Complexes of Rhodium(I)
inferred← citeshttps://doi.org/10.1021/ic9018458openalex-snapshot
Efficient Transfer of Either One or Two Dithiolene Ligands from Nickel to Ruthenium: Synthesis and Crystal Structures of [Ru(SCR═CPhS)2(PPh3)] and [RuCl2(SCR═CPhS)(PPh3)2] (R = Ph, H)
inferred← citeshttps://doi.org/10.1021/ic902378hopenalex-snapshot
Fc-Fc Electronic Interaction through Equatorial Pathways of a Diruthenium Core
inferred← citeshttps://doi.org/10.1021/ja012641fopenalex-snapshot
Characterization and Reactions of Previously Elusive 17-Electron Cations: Electrochemical Oxidations of (C6H6)Cr(CO)3and (C5H5)Co(CO)2in the Presence of [B(C6F5)4]-
inferred← citeshttps://doi.org/10.1021/ja027705gopenalex-snapshot
Pentalene Complexes of Group 7 Metal Carbonyls: An Organometallic Mixed-Valence System with Very Large Metal−Metal Electronic Coupling
inferred← citeshttps://doi.org/10.1021/ja030362hopenalex-snapshot
Microwave Spectroscopy Measurements of Rotational Spectra and DFT Calculations for Two Distinct Structural Isomers of 1,1‘-Dimethylferrocene
inferred← citeshttps://doi.org/10.1021/ja035434jopenalex-snapshot
Polyyn-diyls Capped by Diruthenium Termini: A New Family of Carbon-Rich Organometallic Compounds and Distance-Dependent Electronic Coupling Therein
inferred← citeshttps://doi.org/10.1021/ja036600qopenalex-snapshot
Synthesis, Cyclic Voltammetric Studies, and Electrogenerated Chemiluminescence of a New Phenylquinoline-Biphenothiazine Donor−Acceptor Molecule
inferred← citeshttps://doi.org/10.1021/ja036920+openalex-snapshot
Fully Localized Mixed-Valence Oxidation Products of Molecules Containing Two Linked Dimolybdenum Units: An Effective Structural Criterion
inferred← citeshttps://doi.org/10.1021/ja049915uopenalex-snapshot
trans-Bis(alkynyl) Diruthenium(III) Tetra(amidinate): An Effective Facilitator of Electronic Delocalization
inferred← citeshttps://doi.org/10.1021/ja054136eopenalex-snapshot
Intervalence Transitions in the Mixed-Valence Monocations of Bis(triarylamines) Linked with Vinylene and Phenylene−Vinylene Bridges
inferred← citeshttps://doi.org/10.1021/ja0550982openalex-snapshot
Electronically Coupled MM Quadruply-Bonded Complexes (M = Mo or W) Employing Functionalized Terephthalate Bridges: Toward Molecular Rheostats and Switches
inferred← citeshttps://doi.org/10.1021/ja058171xopenalex-snapshot
Use of Weakly Coordinating Anions to Develop an Integrated Approach to the Tuning of Δ E 1/2 Values by Medium Effects
inferred← citeshttps://doi.org/10.1021/ja058667eopenalex-snapshot
Ytterbocene Charge-Transfer Molecular Wire Complexes
inferred← citeshttps://doi.org/10.1021/ja0603453openalex-snapshot
C7and C9Carbon-Rich Bridges in Diruthenium Systems: Synthesis, Spectroscopic, and Theoretical Investigations of Different Oxidation States
inferred← citeshttps://doi.org/10.1021/ja060386zopenalex-snapshot
Efficient Electronic Communication between Two Identical Ferrocene Centers in a Hydrogen-Bonded Dimer
inferred← citeshttps://doi.org/10.1021/ja064701topenalex-snapshot
Ion Permeability of SAMs on Nanoparticle Surfaces
inferred← citeshttps://doi.org/10.1021/ja075933aopenalex-snapshot
Assessment of Water-Soluble π-Extended Squaraines as One- and Two-Photon Singlet Oxygen Photosensitizers: Design, Synthesis, and Characterization
inferred← citeshttps://doi.org/10.1021/ja0779755openalex-snapshot
Ruthenium Complexes ofC,C‘-Bis(ethynyl)carboranes: An Investigation of Electronic Interactions Mediated by Spherical Pseudo-aromatic Spacers
inferred← citeshttps://doi.org/10.1021/ja101585zopenalex-snapshot
Diferrocenyl Molecular Wires. The Role of Heteroatom Linkers
inferred← citeshttps://doi.org/10.1021/ja109380uopenalex-snapshot
Ferrocenyl-Terminated Redox Stars: Synthesis and Electrostatic Effects in Mixed-Valence Stabilization
inferred← citeshttps://doi.org/10.1021/ja204813hopenalex-snapshot
Modulation of Electronic Couplings within Ru2–Polyyne Frameworks
inferred← citeshttps://doi.org/10.1021/ja3059606openalex-snapshot
Ruthenium Stilbenyl and Diruthenium Distyrylethene Complexes: Aspects of Electron Delocalization and Electrocatalyzed Isomerization of the Z-Isomer
inferred← citeshttps://doi.org/10.1021/ja312176xopenalex-snapshot
Mixed Valency in Hydrogen Bonded ‘Dimers of Dimers’
inferred← citeshttps://doi.org/10.1021/ja507107topenalex-snapshot
Diruthenium–Polyyn-diyl–Diruthenium Wires: Electronic Coupling in the Long Distance Regime
inferred← citeshttps://doi.org/10.1021/ja904928copenalex-snapshot
Redox-Active Metallomacrocycles and Cyclic Metallopolymers: Photocontrolled Ring-Opening Oligomerization and Polymerization of Silicon-Bridged [1]Ferrocenophanes Using Substitutionally-Labile Lewis Bases as Initiators
inferred← citeshttps://doi.org/10.1021/ja908948gopenalex-snapshot
“Chain-Like” Trimetallic Ruthenium Complexes with C7Carbon-Rich Bridges: Experimental and Theoretical Investigations of Electronic Communication Tuning in Five Distinct Oxidation States
inferred← citeshttps://doi.org/10.1021/jacs.5b06453openalex-snapshot
Ligand Field Strength Mediates Electron Delocalization in Octahedral [( H L) 2 Fe 6 (L′) m ] n + Clusters
inferred← citeshttps://doi.org/10.1021/jacs.5b12181openalex-snapshot
Maximizing Electron Exchange in a [Fe3] Cluster
inferred← citeshttps://doi.org/10.1021/jacs.6b02404openalex-snapshot
Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy
inferred← citeshttps://doi.org/10.1021/jacsau.5c00484openalex-snapshot
Arrested Cooperative Electron Transfer by Stabilization of a Long-Lived Confined Unpaired Electron
inferred← citeshttps://doi.org/10.1021/jo051196uopenalex-snapshot
Bis(phosphine Imide)s: Easily Tunable Organic Electron Donors
inferred← citeshttps://doi.org/10.1021/jo071066gopenalex-snapshot
Synthesis, Electrochemical, and Optical Properties of Linear Homo- and Heterometallocene Triads
inferred← citeshttps://doi.org/10.1021/jo401263zopenalex-snapshot
Anodic Oxidation of Disulfides: Detection and Reactions of Disulfide Radical Cations
inferred← citeshttps://doi.org/10.1021/jo401921fopenalex-snapshot
Oxidation Products of Doubly Trimethylene-Bridged Tetrabenzylp-Phenylenediamine Paracyclophane
inferred← citeshttps://doi.org/10.1021/jp0666129openalex-snapshot
Rapid-Scan Time-Resolved FT-IR Spectroelectrochemistry Studies on the Electrochemical Redox Process
inferred← citeshttps://doi.org/10.1021/jp303989topenalex-snapshot
Charge Delocalization in a Homologous Series of α,α′-Bis(dianisylamino)-Substituted Thiophene Monocations
inferred← citeshttps://doi.org/10.1021/jp7096185openalex-snapshot
Roles of Ion Pairing on Electroreduction of Dioxygen in Imidazolium-Cation-Based Room-Temperature Ionic Liquid
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