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Redox‐Active Tetraruthenium Macrocycles Built from 1,4‐Divinylphenylene‐Bridged Diruthenium Complexes

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2‐[p‐(N‐tert‐butyl‐N‐oxyamino)phenyl]‐4,4,5,5‐tetramethyl‐4,5‐dihydroimidazol‐3‐oxid‐1‐oxyl, ein stabiles Diradikal mit einem Triplett‐Grundzustand
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Nitrogen Analogues of Thiele’s Hydrocarbon
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Electronically Strongly Coupled Divinylheterocyclic‐Bridged Diruthenium Complexes
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The influence of polarization functions on molecular orbital hydrogenation energies
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Energy-adjustedab initio pseudopotentials for the second and third row transition elements
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Effect of configuration and conformation on the spin multiplicity in xylylene type biradicals
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Mixed-valence molecules: Electronic delocalization and stabilization
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Reactions of Ru(HCCHR)Cl(CO)(PPh3)2 with functionalized carboxylates. Crystal structure of Ru(HCCHPh)(O2CCHCHCHCHCH3)(CO)(PPh3)2
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Simple construction of an infrared optically transparent thin-layer electrochemical cell
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Five- and six-coordinate hydrido(carbonyl)-ruthenium(II) and -osmium(II) complexes containing triisopropylphosphine as ligand
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Reactions of Ru(CO)Cl(RCCHR′)(PPh3)2 with carboxylates. The crystal structure of Ru(O2CMe)(CO)(HCCHPh)(PPh3)2
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Quantum chemical interpretation of redox properties of ruthenium complexes with vinyl and TCNX type non-innocent ligands
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Concepts for metal complex chromophores absorbing in the near infrared
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Self-assembled M2L4 coordination cages: Synthesis and potential applications
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Vinyl-ruthenium entities as markers for intramolecular electron transfer processes
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Electron delocalization in vinyl ruthenium substituted cyclophanes: Assessment of the through-space and the through-bond pathways
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Encapsulation of inorganic and organic guest molecules into an organometallic hexacationic arene osmium metalla-prism: Synthesis, characterisation and anticancer activity
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Synthesis, spectroelectrochemistry and electronic structure calculations of 4-(2-ferrocenylvinyl)-[2.2]-paracyclophane and 4,12-di-(2-ferrocenylvinyl)-[2.2]-paracyclophane
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Lack of electronic coupling despite half-wave potential splittings in ferrocenylvinyl-substituted [2.2]-paracyclophanes
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Homo- and heterobimetallic 1,4-divinylphenylene- and naphthalene-1,8-divinyl-bridged diruthenium, diosmium and ruthenium osmium complexes
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Insertion reactions of acetylenes with hydridocarbonyl-chlorotris(triphenylphosphine)ruthenium(II). X-ray structure of carbonylchloro(cis-1,2-diphenylethenyl)bis(triphenylphosphine)ruthenium(II)
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Mixed Valence Chemistry-A Survey and Classification
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Reaction of Ru(CO)Cl(RCCHR′)(PPh3)2 with the 3,3-dimethylacrylate anion. The molecular structure of Ru(O2CCHCMe2)(CO)(C(CO2Me)CH(CO2Me))(PPh3)2
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Synthesis, structure and magnetic properties of bis(hexafluoroacetylacetonato)Mn(II) complex with a novel triplet organic radical, 4-N-tert-butylaminoxyl-4′-nitronylnitroxylbiphenyl
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Ruthenium Styryl Complexes with Ligands Derived from 2-Hydroxy- and 2-Mercaptopyridine and 2-Hydroxy- and 2-Mercaptoquinoline
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Coordination Assemblies from a Pd(II)-Cornered Square Complex
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Biomedical and Biochemical Applications of Self-Assembled Metallacycles and Metallacages
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Heteroligated Supramolecular Coordination Complexes Formed via the Halide-Induced Ligand Rearrangement Reaction
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Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles
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Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
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Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials
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Diradicals
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Reversible and Site-Specific Reduction of the Ligand Sides in a Molecular Rectangle with up to Eight Electrons
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Metalla-Supramolecular Rectangles as Electron Reservoirs for Multielectron Reduction and Oxidation
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Self-Assembly of Heterobimetallic Neutral Macrocycles Incorporating Ferrocene Spacer Groups: Spectroelectrochemical Analysis of the Double Two-Electron Oxidation of a Molecular Rectangle
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Borderline Class II/III Ligand-Centered Mixed Valency in a Porphyrinic Molecular Rectangle
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Temperature-Dependent Coordination of Phosphine to Five-Coordinate Alkenylruthenium Complexes
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3,5-Bis(ethynyl)pyridine and 2,6-Bis(ethynyl)pyridine Spanning Two Fe(Cp*)(dppe) Units: Role of the Nitrogen Atom on the Electronic and Magnetic Couplings
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Self-Assembly of Metallamacrocycles Using a Dinuclear Organometallic Acceptor: Synthesis, Characterization, and Sensing Study
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Fully Delocalized (Ethynyl)(vinyl)phenylene Bridged Triruthenium Complexes in up to Five Different Oxidation States
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Multimetallic Complexes and Functionalized Nanoparticles Based on Oxygen- and Nitrogen-Donor Combinations
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Single Two-Electron Transfers vs Successive One-Electron Transfers in Polyconjugated Systems Illustrated by the Electrochemical Oxidation and Reduction of Carotenoids
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Use of Medium Effects to Tune the ΔE1/2Values of Bimetallic and Oligometallic Compounds
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Sequence-Selective Recognition of Peptides within the Single Binding Pocket of a Self-Assembled Coordination Cage
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Tetra-Rhenium Molecular Rectangles as Organizational Motifs for the Investigation of Ligand-Centered Mixed Valency: Three Examples of Full Delocalization
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Rhenium-Based Molecular Rectangles as Frameworks for Ligand-Centered Mixed Valency and Optical Electron Transfer
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Use of Weakly Coordinating Anions to Develop an Integrated Approach to the Tuning of Δ E 1/2 Values by Medium Effects
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A New Class of Mixed-Valence Systems with Orbitally Degenerate Organic Redox Centers. Examples Based on Hexa-Rhenium Molecular Prisms
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Unusual [2+4] and [2+2] Cycloadditions of Arenes in the Confined Cavity of Self-Assembled Cages
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Ruthenium Complexes with Vinyl, Styryl, and Vinylpyrenyl Ligands: A Case of Non-innocence in Organometallic Chemistry
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A Stable Non-Kekulé Singlet Biradicaloid from meso -Free 5,10,20,25-Tetrakis(Pentafluorophenyl)-Substituted [26]Hexaphyrin(1.1.1.1.1.1)
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Kinetically Blocked Stable Heptazethrene and Octazethrene: Closed-Shell or Open-Shell in the Ground State?
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Ruthenium Stilbenyl and Diruthenium Distyrylethene Complexes: Aspects of Electron Delocalization and Electrocatalyzed Isomerization of the Z-Isomer
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10,10‘-(m- and p-Phenylene)diphenothiazine Dications: Violation of a Topology Rule in Heterocyclic High-Spin π-Systems
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Disproportionation and Structural Changes of Tetraarylethylene Donors upon Successive Oxidation to Cation Radicals and to Dications
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14-Electron Four-Coordinate Ru(II) Carbyl Complexes and Their Five-Coordinate Precursors: Synthesis, Double Agostic Interactions, and Reactivity
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Transannular Effects in Dicobalta−Superphane Complexes on the Mixed-Valence Class II/Class III Interface: Distinguishing between Spin and Charge Delocalization by Electrochemistry, Spectroscopy, and ab Initio Calculations
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Push–Pull Type Oligo( N -annulated perylene)quinodimethanes: Chain Length and Solvent-Dependent Ground States and Physical Properties
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On the Causes of Potential Inversion in 1,2,4,5-Tetrakis(amino)benzenes
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A Microelectrode Study of the Reduction of Phenyl-Substituted Ethenes in Toluene/Dimethylformamide Mixtures
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Study of the Effects of Ion Pairing and Activity Coefficients on the Separation in Standard Potentials for Two-Step Reduction of Dinitroaromatics
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Intramolecular Charge Transfer Effects on the Diradical Character and Second Hyperpolarizabilities of Open-Shell Singlet X−π–X (X = Donor/Acceptor) Systems
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Divinylphenylene-Bridged Diruthenium Complexes Bearing Ru(CO)Cl(PiPr3)2Entities
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Coordination-Driven Self-Assembly of Metallamacrocycles via a New PtII2 Organometallic Building Block with 90° Geometry and Optical Sensing of Anions
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Fully Delocalized (Ethynyl)(vinyl)phenylene-Bridged Diruthenium Radical Complexes
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Synthesis, Characterization, and Electrochemical Properties of Diruthenium Complexes Bridged by Anthraquinones
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Spectroscopic and Computational Studies of the Ligand Redox Non-Innocence in Mono- and Binuclear Ruthenium Vinyl Complexes
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Spectroscopic Evidence for Redox Isomerism in the 1,4-Diethynylbenzene-Bridged Heterobimetallic Cation [{Fe(dppe)Cp*}(μ-C≡CC6H4C≡C){Mo(dppe)(η-C7H7)}]PF6
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Synthesis and Characterization of Dithia[3.3]paracyclophane-Bridged Binuclear Ruthenium Vinyl and Alkynyl Complexes
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Divinylphenylene- and Ethynylvinylphenylene-Bridged Mono-, Di-, and Triruthenium Complexes for Covalent Binding to Gold Electrodes
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Charge and Spin Confinement to the Amine Site in 3-Connected Triarylamine Vinyl Ruthenium Conjugates
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Dinuclear Quinonoid-Bridged d8Metal Complexes with Redox-Active Azobenzene Stoppers: Electrochemical Properties and Electrochromic Behavior
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Strategy to Optimize the Biological Activity of Arene Ruthenium Metalla-Assemblies
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Ligand-Centered Oxidations and Electron Delocalization in a Tetranuclear Complex of a Tetradonor-Substituted Olefin
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Mechanisms of C−Si and C−H Bond Formation on the Reactions of Alkenylruthenium(II) Complexes with Hydrosilanes
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Key multi(ferrocenyl) complexes in the interplay between electronic coupling and electrostatic interaction
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Energy-adjusted a b i n i t i o pseudopotentials for the rare earth elements
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Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Supramolecular Approaches to Improve the Performance of Ruthenium‐Based Water Oxidation Catalysts
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inferred← citeshttps://doi.org/10.1002/ejic.202000387openalex-snapshot
Structural Versatility and Supramolecular Isomerism in Redox‐Active Tetra‐ and Hexaruthenium Macrocycles
inferred← citeshttps://doi.org/10.1002/slct.202402469openalex-snapshot
Electronically Weakly Coupled 4,4′‐Divinylazoarylenes‐Bridged Diruthenium Complexes Featuring Two Ru(CO)Cl(P i Pr 3 ) 2 Entities
inferred← citeshttps://doi.org/10.1007/s11243-025-00639-5openalex-snapshot
1,4-Divinylphenylene-bridged diruthenium complexes terminated with deprotonated 2-mercaptopyridine or 2- or 8-mercaptoquinoline co-ligands
inferred← citeshttps://doi.org/10.1016/b978-0-08-102688-5.00049-0openalex-snapshot
Metal-Carbon Bonds of Heavier Group 7 and 8 Metals (Tc, Re, Ru, Os): Mononuclear Tc/Re/Ru/Os Complexes With Metal-Carbon Bonds
inferred← citeshttps://doi.org/10.1016/j.ccr.2018.05.017openalex-snapshot
Electrostatic interactions within mixed-valent compounds
inferred← citeshttps://doi.org/10.1016/j.ccr.2026.218021openalex-snapshot
Redox-active metal-organic macrocycles and nanocages: From functionality to function
inferred← citeshttps://doi.org/10.1016/j.coelec.2017.11.011openalex-snapshot
The molecular electrochemistry of metal–organic metallamacrocycles
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2017.05.010openalex-snapshot
Polyelectrochromism and electronic coupling in vinylruthenium-modified carbazoles
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123185openalex-snapshot
The influence of phosphine ligands on the redox properties of 1,4-divinylanthrylene-bridged diruthenium complexes and a derived macrocyclic analog
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123368openalex-snapshot
Controlling quantum interference patterns in redox-active rings
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.0c02695openalex-snapshot
Redox-Induced Hydrogen Bond Reorientation Mimicking Electronic Coupling in Mixed-Valent Diruthenium and Macrocyclic Tetraruthenium Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c01608openalex-snapshot
Reversible Multielectron Release from Redox-Active Three-Dimensional Molecular Barrels with Ruthenium-Alkenyl Moieties
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b01297openalex-snapshot
Near-Infrared and Two-Wavelength Electrochromism Based on Nanocrystalline TiO2 Films Functionalized with Ruthenium-Amine Conjugated Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b02186openalex-snapshot
Manipulation and Assessment of Charge and Spin Delocalization in Mixed-Valent Triarylamine–Vinylruthenium Conjugates
inferred← citeshttps://doi.org/10.1021/acs.joc.7b02437openalex-snapshot
Tetraaza[14]- and Octaaza[18]paracyclophane: Synthesis and Characterization of Their Neutral and Cationic States
inferred← citeshttps://doi.org/10.1021/acs.jpcc.9b02478openalex-snapshot
Delocalization-to-Localization Charge Transition in Divinylthiophene-Bridged Biruthenium Complexes as a Function of Length of the Bridging Chain by Both IR Spectroscopy and Theoretical Investigations
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00116openalex-snapshot
Self-Assembled Redox-Active Tetraruthenium Macrocycles with Large Intracyclic Cavities
inferred← citeshttps://doi.org/10.1021/acs.organomet.1c00619openalex-snapshot
Charge and Spin Delocalization in Mixed-Valent Vinylruthenium–Triarylamine-Conjugates with Planarized Triarylamines
inferred← citeshttps://doi.org/10.1021/acs.organomet.3c00337openalex-snapshot
Diruthenium Complexes with π-Extended Bridging Bis(alkenyl)arylene Ligands, A Derived Metallamacrocycle, and Their Oxidized Forms
inferred← citeshttps://doi.org/10.1021/acs.organomet.6c00111openalex-snapshot
Molecular Conductances of Styryl Ruthenium and Divinylphenylene-Bridged Diruthenium Complexes with Thioanisyl Anchor Groups
inferred← citeshttps://doi.org/10.1021/acs.organomet.7b00194openalex-snapshot
Polyelectrochromic Vinyl Ruthenium-Modified Tritylium Dyes
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00057openalex-snapshot
Constitutional Isomers of Macrocyclic Tetraruthenium Complexes with Vastly Different Spectroscopic and Electrochemical Properties
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00255openalex-snapshot
Electrochemical and Spectroscopic Studies on σ-Phenyl Ruthenium Complexes Ru(CO)Cl(C6H4R-4)(PiPr3)2
inferred← citeshttps://doi.org/10.1021/acs.organomet.9b00318openalex-snapshot
Influence of Quinoidal Distortion on the Electronic Properties of Oxidized Divinylarylene-Bridged Diruthenium Complexes
inferred← citeshttps://doi.org/10.1021/acs.organomet.9b00332openalex-snapshot
Tetrakis[3,5-bis(pentafluorosulfanyl)phenyl]borate: A Weakly Coordinating Anion Probed in Polymerization Catalysis
inferred← citeshttps://doi.org/10.1039/c7dt03509hopenalex-snapshot
Non-innocence and mixed valency in tri- and tetranuclear ruthenium complexes of a heteroquinone bridging ligand
inferred← citeshttps://doi.org/10.1039/c8dt04968hopenalex-snapshot
Nanocrystalline Sb-doped SnO 2 films modified with cyclometalated ruthenium complexes for two-step electrochromism
inferred← citeshttps://doi.org/10.1039/c9cc09307aopenalex-snapshot
Ring size matters: supramolecular isomerism in self-assembled redox-active tetra- and hexaruthenium macrocycles
inferred← citeshttps://doi.org/10.21203/rs.3.rs-4458964/v1openalex-snapshot
RETRACTED: Electronically Weakly Coupled 4,4'-Divinylazoarylenes-Bridged Diruthenium Complexes Featuring Two Ru(PiPr3)2Cl(CO) Entities
inferred← citeshttps://doi.org/10.3390/inorganics10060082openalex-snapshot
Tetraruthenium Macrocycles with Laterally Extended Bis(alkenyl)quinoxaline Ligands and Their F4TCNQ•− Salts
inferred← citeshttps://doi.org/10.3390/inorganics6030073openalex-snapshot
Tetraruthenium Metallamacrocycles with Potentially Coordinating Appended Functionalities
inferred← citeshttps://doi.org/10.3390/molecules26175232openalex-snapshot
A “Pretender” Croconate-Bridged Macrocyclic Tetraruthenium Complex: Sizable Redox Potential Splittings despite Electronically Insulated Divinylphenylene Diruthenium Entities
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