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Mechanistic Studies of Nickel(II) Alkyl Agostic Cations and Alkyl Ethylene Complexes: Investigations of Chain Propagation and Isomerization in (α-diimine)Ni(II)-Catalyzed Ethylene Polymerization
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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Gesetzliche Temperatur – gesetzliche Wärmemenge
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2,3‐Dilithio‐1,3‐butadiene durch Addition von Lithium an Butatriene
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Novel Nickel‐ and Palladium‐Complexes with Aminobis(imino)phosphorane Ligands for the Polymerization of Ethylene
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Synthesis of Multielectron Ligands for Transition Metals via Spiro[cyclopropane‐1,1′‐indene]
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Novel Polymerization of α‐Olefins with the Catalyst System Nickel/Aminobis(imino)phosphorane
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The Synthesis of Porphyrins Doubly Linked to Quinones by Hydrocarbon Chains
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Synthesis and characterization of rigid bidentate nitrogen ligands and some examples of coordination to divalent palladium. X‐ray crystal structures of bis (p‐tolylimino) acenaphthene and methylchloro [bis(o,o′‐diisopropylphenyl‐imino) acenaphthene] palladium (II)
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Chemical kinetics and reaction mechanisms
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Nickel catalysis for ethylene homo- and co-polymerization
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Diazadien-nickel-alkyle
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Late-Metal Catalysts for Ethylene Homo- and Copolymerization
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Mechanistic Studies of Pd(II)−α-Diimine-Catalyzed Olefin Polymerizations 1
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Living Polymerization of α-Olefins Using NiII−α-Diimine Catalysts. Synthesis of New Block Polymers Based on α-Olefins
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A Density Functional Study of the Mechanism of the Diimine−Nickel-Catalyzed Ethylene Polymerization Reaction
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Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate
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Low-Temperature Spectroscopic Observation of Chain Growth and Migratory Insertion Barriers in (α-Diimine)Ni(II) Olefin Polymerization Catalysts
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Dichlorofluoromethane-d: a versatile solvent for VT-NMR experiments
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Novel Branching Topology in Polyethylenes As Revealed by Light Scattering and 13C NMR
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Cobalt(III)-Catalyzed Living Polymerization of Ethylene: Routes to End-Capped Polyethylene with a Narrow Molar Mass Distribution
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13C and 2D NMR Analysis of Propylene Polymers Made with α-Diimine Late Metal Catalysts
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Living Polymerization of Ethylene Using Pd(II) α-Diimine Catalysts
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Ni(II)-Catalyzed Polymerization of trans-2-Butene
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Addition Polymerization of Cyclopentene with Nickel and Palladium Catalysts
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Polymerization of Propylene by a New Generation of Iron Catalysts: Mechanisms of Chain Initiation, Propagation, and Termination
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Synthesis of Branched Polyethylene Using (α-Diimine)nickel(II) Catalysts: Influence of Temperature, Ethylene Pressure, and Ligand Structure on Polymer Properties
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Control of intramolecular .beta.-hydrogen migration in coordinatively unsaturated (diphosphine)platinum ethyl cations
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Gas-phase synthesis of metallocyclotriynes
inferredcites →https://doi.org/10.1021/om010211sopenalex-snapshot
A Highly Active Anilinotropone-Based Neutral Nickel(II) Catalyst for Ethylene Polymerization
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Safe and Convenient Procedure for Solvent Purification
inferredcites →https://doi.org/10.1021/om960697qopenalex-snapshot
α-Olefin Polymerization with Ether-Coordinated Chromium(III) Alkyls
inferredcites →https://doi.org/10.1021/om961057qopenalex-snapshot
Preparation of Linear α-Olefins Using Cationic Nickel(II) α-Diimine Catalysts
inferredcites →https://doi.org/10.1021/om971137+openalex-snapshot
The Dynamics of the β-Agostic Isopropyl Complex (ArNC(R)−C(R)NAr)Pd(CH(CH2-μ-H)(CH3))+BAr4‘-(Ar = 2,6-C6H3(i-Pr)2): Evidence for In-Place Rotation versus Dissociation of the Agostic Methyl Group
inferredcites →https://doi.org/10.1021/om980736topenalex-snapshot
Ethylene Oligomerization and Propylene Dimerization Using Cationic (α-Diimine)nickel(II) Catalysts
inferredcites →https://doi.org/10.1126/science.287.5452.460openalex-snapshot
Neutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms
inferredcites →https://doi.org/10.5771/9781475873191-360openalex-snapshot
University of North Carolina at Chapel Hill
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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A Rapid and Simple Method for Estimating the Density of Branched Polyethylene by Differential Scanning Calorimetry
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Olefin Polymerization Using Homogeneous Group IV Metallocenes
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Oxidative Addition of Phenylacetylene through CH Bond Cleavage To Form the Mg II –dpp‐bian Complex: Molecular Structure of [Mg{dpp‐bian(H)}(CCPh)(thf)2] and Its Diphenylketone Insertion Product [Mg(dpp‐bian).−{OC(Ph2)CCPh}(thf)]
inferred← citeshttps://doi.org/10.1002/anie.200502532openalex-snapshot
Ethylene Oligomerization at Coordinatively and Electronically Unsaturated Low‐Valent Nickel
inferred← citeshttps://doi.org/10.1002/anie.200701188openalex-snapshot
Terminal FeIN2 and FeII⋅⋅⋅HC Interactions Supported by Tris(phosphino)silyl Ligands
inferred← citeshttps://doi.org/10.1002/anie.200804661openalex-snapshot
Nickel α‐Keto‐β‐Diimine Initiators for Olefin Polymerization
inferred← citeshttps://doi.org/10.1002/anie.201003125openalex-snapshot
Well‐Defined Cationic Methallyl α‐Keto‐β‐Diimine Complexes of Nickel
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Structure and Isotope Effects of the β‐H Agostic (α‐Diimine)Nickel Cation as a Polymerization Intermediate
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Phenoxythiazoline (FTz)‐Cobalt(II) Precatalysts Enable C(sp2)–C(sp3) Bond‐Formation for Key Intermediates in the Synthesis of Toll‐like Receptor 7/8 Antagonists**
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Unsymmetrical Strategy Makes Significant Differences in α‐Diimine Nickel and Palladium Catalyzed Ethylene (Co)Polymerizations
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Iminopyridine‐Nickel Precatalysts for Low Molecular Weight Branched Macro‐Olefin: Dominant β‐Elimination Following Isomerization
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Addition of Nitriles to Alkaline Earth Metal Complexes of 1,2‐Bis[(phenyl)imino]acenaphthenes
inferred← citeshttps://doi.org/10.1002/chem.201101152openalex-snapshot
Neutral Nickel Oligo‐ and Polymerization Catalysts: The Importance of Alkyl Phosphine Intermediates in Chain Termination
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Ligand Steric and Fluoroalkyl Substituent Effects on Enchainment Cooperativity and Stability in Bimetallic Nickel(II) Polymerization Catalysts
inferred← citeshttps://doi.org/10.1002/chem.201300890openalex-snapshot
Water as an Activator for Palladium(II)‐Catalyzed Olefin Polymerization
inferred← citeshttps://doi.org/10.1002/chem.201301037openalex-snapshot
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Neutral Nickel Ethylene Oligo‐ and Polymerization Catalysts: Towards Computational Catalyst Prediction and Design
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Fluorinated α‐Diimine Nickel Mediated Ethylene (Co)Polymerization
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Addition of Enolisable Ketones to (dpp‐bian)Mg(THF)3 [dpp‐bian =1,2‐Bis{(2,6‐diisopropylphenyl)imino}acenaphthene]
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Reductive Isopropyl Radical Elimination from (dpp‐bian)Mg‐iPr(Et2O)
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Functionalized semi‐crystalline polyethylene with polar groups at branch end enabled by bulky cationic palladium catalysts
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Ethylene polymerization by sterically and electronically modulated Ni(II) α‐diimine complexes
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Poly(1‐hexene) with long methylene sequences and controlled branches obtained by a thermostable α‐diimine nickel catalyst with bulky camphyl backbone
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Polymerization of ethylene using a series of binuclear and a mononuclear Ni (II)‐based catalysts
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Highly branched and high‐molecular‐weight polyethylenes produced by 1‐[2,6‐bis(bis(4‐fluorophenyl)methyl)‐4‐MeOC6H2N]‐2‐aryliminoacenaphthylnickel(II) halides
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A Rapid and Simple Method for Estimating the Density of Branched Polyethylene Using the Melt Enthalpy Measured by Differential Scanning Calorimetry
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Monomeric Magnesium and Calcium Complexes containing the Rigid, Dianionic 1, 2‐Bis[(2, 5‐di‐tert‐butylphenyl)imino]acenaphthene (dtb‐BIAN) and 1, 2‐Bis[(2‐biphenyl)imino]acenaphthene (bph‐BIAN) Ligands
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Hydrosilylation of Dihydrosilylium Ion Stabilized by Coordination of a σ‐Donating Ni(0) Ligand
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Polymerization of Polar Monomers
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DFT studies on isomerization reactions in the copolymerization of ethylene and methyl acrylate catalyzed by Ni-diimine and Pd-diimine complexes
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Ethylene dimerization catalyzed by mixed phosphine–iminophosphorane nickel(II) complexes: a DFT investigation
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One-pot synthesis of symmetrical and unsymmetrical α-diimine Nickel complexes in comparison with two-pot synthesis method for ethylene polymerization
inferred← citeshttps://doi.org/10.1007/s11164-017-3207-xopenalex-snapshot
Influence of a diimine ligand and an activator on the processes taking place in Brookhart-type nickel catalytic systems
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Magnesium and calcium complexes with two diimine radical-anion ligands. Molecular structure of the Ca complex with 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene
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Protonation of magnesium and sodium complexes containing dianionic diimine ligands. Molecular structures of 1,2-bis{(2,6-diisopropylphenyl)imino}acenaphthene (dpp-BIAN), [(dph-BIAN)H2(Et2O)], and [(dpp-BIAN)HNa(Et2O)]
inferred← citeshttps://doi.org/10.1007/s11172-005-0186-7openalex-snapshot
Reactions of (dpp-BIAN)Mg(thf)3 complex (dpp-BIAN is 1,2-bis{(2,6-diisopropylphenyl)imino}acenaphthene) with halogen-containing reagents
inferred← citeshttps://doi.org/10.1007/s11172-006-0273-4openalex-snapshot
Aluminum complexes with mono-and dianionic diimine ligands
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Synthesis and structure of novel chiral amido-imine complexes of aluminum, gallium, and indium
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inferred← citeshttps://doi.org/10.1007/s11172-014-0523-9openalex-snapshot
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inferred← citeshttps://doi.org/10.1007/s11172-019-2383-9openalex-snapshot
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Mechanistic Aspects of Olefin-polymerization Catalysis
inferred← citeshttps://doi.org/10.1016/b0-08-045047-4/00017-0openalex-snapshot
Dynamic NMR Spectroscopy in Organometallic Chemistry
inferred← citeshttps://doi.org/10.1016/b0-08-045047-4/00100-xopenalex-snapshot
Nickel–Carbon σ-Bonded Complexes
inferred← citeshttps://doi.org/10.1016/b978-0-443-15680-9.00006-5openalex-snapshot
An overview of homogeneous catalysts for oligomerization
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Recent advances in Ni-catalyzed functionalization of strong C−O and C−H bonds
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Acrylates from Alkenes and CO2, the Stuff That Dreams Are Made of
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A tale of two metals: The Mizoroki-Heck reaction as a guide to compare the chemical characters of nickel and palladium in catalysis
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Determination and tracing of active and dormant propagation chains in 1-hexene polymerization with supported Ziegler-Natta catalyst
inferred← citeshttps://doi.org/10.1016/j.catcom.2008.08.015openalex-snapshot
Heterogeneous catalysts immobilizing α-diimine nickel complexes into fluorotetrasilicic mica interlayers to prepare branched polyethylene from only ethylene
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Trinuclear Fe(II)/Ni(II) complexes as catalysts for ethylene polymerizations
inferred← citeshttps://doi.org/10.1016/j.cattod.2017.04.029openalex-snapshot
Ethene oligomerization on nickel microporous and mesoporous-supported catalysts: Investigation of the active sites
inferred← citeshttps://doi.org/10.1016/j.ccr.2005.12.018openalex-snapshot
Ethylene oligomerization, homopolymerization and copolymerization by iron and cobalt catalysts with 2,6-(bis-organylimino)pyridyl ligands
inferred← citeshttps://doi.org/10.1016/j.ccr.2007.12.025openalex-snapshot
Transition metal-dialkyl compounds (LxMR2; R=alkyl; M=metals of groups VI–X)—Synthesis, structure, reactivity and applications
inferred← citeshttps://doi.org/10.1016/j.ccr.2009.02.014openalex-snapshot
Mechanism of stereospecific polymerization of α-olefins by late-transition metal and octahedral group 4 metal catalysts
inferred← citeshttps://doi.org/10.1016/j.ccr.2017.06.003openalex-snapshot
Recent advances in Ni-mediated ethylene chain growth: Nimine-donor ligand effects on catalytic activity, thermal stability and oligo-/polymer structure
inferred← citeshttps://doi.org/10.1016/j.ccr.2020.213401openalex-snapshot
A theoretical perspective of the agostic effect in early transition metal compounds
inferred← citeshttps://doi.org/10.1016/j.ccr.2022.214844openalex-snapshot
Recent advances on α-diimine Ni and Pd complexes for catalyzed ethylene (Co)polymerization: A comprehensive review
inferred← citeshttps://doi.org/10.1016/j.ccr.2025.216833openalex-snapshot
Recent advances in nickel Catalysis for thermoplastic polyethylene elastomers: Synthesis strategies, properties, and future perspectives
inferred← citeshttps://doi.org/10.1016/j.ccr.2025.217373openalex-snapshot
A review of the recent coordination chemistry and catalytic applications of pyrazole and pyrazolyl transition metal complexes
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2005.07.009openalex-snapshot
Polymerization of acrylate monomers with MAO activated iron(II) and cobalt(II) complexes bearing tri- and tetradentate nitrogen ligands
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2019.05.015openalex-snapshot
Access to polyethylene elastomers via ethylene homo-polymerization using N,N′-nickel(II) catalysts appended with electron withdrawing difluorobenzhydryl group
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2019.109339openalex-snapshot
Recent progress in preparation of branched polyethylene with nickel, titanium, vanadium and chromium catalytic systems and EPR study of related catalytic systems
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2022.111105openalex-snapshot
Synthesis of thermoplastic polyethylene elastomers and ethylene–methyl acrylate copolymers using methylene-bridged binuclear bulky dibenzhydryl α-diimine Ni(II) and Pd(II) catalysts
inferred← citeshttps://doi.org/10.1016/j.ica.2011.06.007openalex-snapshot
Novel halogen-bridged bisphosphine nickel(II) complexes
inferred← citeshttps://doi.org/10.1016/j.ica.2015.12.008openalex-snapshot
Tailoring polyethylenes through constraining geometry of nickel complex: Synthesis, characterization and ethylene polymerization of 8-(2-benzhydrylnaphthylimino)-5,6,7-trihydroquinolylnickel halides
inferred← citeshttps://doi.org/10.1016/j.ica.2017.05.005openalex-snapshot
Synthesis of polyethylene and PE/MWCNT composite using a spherical bulky α-diimine Pd(II) catalyst
inferred← citeshttps://doi.org/10.1016/j.ica.2021.120780openalex-snapshot
Synthesis, structural, DNA/protein binding and cytotoxic studies of copper(I) ∝-diimine hydrazone complexes
inferred← citeshttps://doi.org/10.1016/j.ica.2022.120900openalex-snapshot
Effect of alkylaluminum structure and aggregation state on the micro-kinetics of ethylene polymerization catalyzed by α-diimine nickel complex
inferred← citeshttps://doi.org/10.1016/j.ica.2024.122120openalex-snapshot
Preparation of polyethylene elastomers with increased high molecular weight and nearly perfect strain recovery by steric control of asymmetric α-diimine nickel catalyst
inferred← citeshttps://doi.org/10.1016/j.inoche.2006.03.011openalex-snapshot
Synthesis, characterization and crystal structure of diamagnetic tetracoordinated chromium (II) complexes supported by α-diimine ligands
inferred← citeshttps://doi.org/10.1016/j.inoche.2018.04.004openalex-snapshot
Reactions of [(dpp-Bian)Ln(dme)2] (Ln = Eu, Yb) with some oxidants
inferred← citeshttps://doi.org/10.1016/j.jcat.2020.02.022openalex-snapshot
Thermally robust α-diimine nickel and palladium catalysts with constrained space for ethylene (co)polymerizations
inferred← citeshttps://doi.org/10.1016/j.jcat.2020.07.017openalex-snapshot
A concerted double-layer steric strategy enables an ultra-highly active nickel catalyst to access ultrahigh molecular weight polyethylenes
inferred← citeshttps://doi.org/10.1016/j.jcat.2022.06.044openalex-snapshot
Combining 1,2-diketopyracene with bulky benzhydryl-substituted anilines to obtain highly active α-diimine nickel catalysts at elevated temperature
inferred← citeshttps://doi.org/10.1016/j.jcat.2024.115632openalex-snapshot
Study on the micro-mechanism for the thermal stability of α-diimine nickel catalysts and active centers
inferred← citeshttps://doi.org/10.1016/j.jcat.2026.116816openalex-snapshot
Unexpected discovery in developing α-diimine nickel catalysts with enhanced N-aryl bond rotation and synthesis of block polyethylene elastomer
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2003.08.016openalex-snapshot
Preparation and characterization of molybdenum and tungsten compounds with diazabutadiene ligands constructed from amino esters and glyoxal
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2004.07.018openalex-snapshot
Mechanism in homogeneous catalysis; NMR as a prime mover
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2009.08.010openalex-snapshot
Conversion of imine ligands in allyl–nickel(II) complexes
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2011.07.022openalex-snapshot
Intramolecular rearrangement of the imine–amide ligand within the nickel coordination sphere affected by carbon monoxide
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2011.07.023openalex-snapshot
Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 – (2,6-diisopropylphenyl)diazabutadiene system
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2011.08.017openalex-snapshot
Vinyl addition polymerization of norbornene catalyzed by β-iminoamine Ni(II) complexes/methylaluminoxane systems
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2013.08.021openalex-snapshot
Recent progress on nickel-based systems for ethylene oligo-/polymerization catalysis
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2017.08.020openalex-snapshot
Vanadium olefin polymerization catalysts: NMR spectroscopic characterization of V(III) intermediates
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2018.11.021openalex-snapshot
EPR spectroscopic study of Ni(I) species in the catalyst system for ethylene polymerization based on α-diimine Ni(II) complex activated by MMAO
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2019.121063openalex-snapshot
The nature of nickel species formed upon the activation of α-diimine nickel(II) pre-catalyst with alkylaluminum sesquichlorides
inferred← citeshttps://doi.org/10.1016/j.mencom.2020.05.013openalex-snapshot
Electrochemical and catalytic properties of nickel(II) complexes with bis(imino)acenaphthene and diazadiphosphacyclooctane ligands
inferred← citeshttps://doi.org/10.1016/j.molcata.2004.10.013openalex-snapshot
New bi-nuclear and multi-nuclear α-diimine/nickel catalysts for ethylene polymerization
inferred← citeshttps://doi.org/10.1016/j.molcata.2004.12.024openalex-snapshot
Investigation of 1-hexene isomerization and oligomerization catalyzed with β-diketiminato Ni(II) bromide complexes/methylaluminoxane system
inferred← citeshttps://doi.org/10.1016/j.molcata.2005.12.027openalex-snapshot
Ethylene polymerization and oligomerization catalyzed by bulky β-diketiminato Ni(II) and β-diimine Ni(II) complexes/methylaluminoxane systems
inferred← citeshttps://doi.org/10.1016/j.molcata.2010.03.023openalex-snapshot
On the nature of the active site in ruthenium olefin coordination–insertion polymerization catalysts☆
inferred← citeshttps://doi.org/10.1016/j.molcata.2011.03.025openalex-snapshot
On the regioselectivity of the insertion step in nickel complex catalyzed dimerization of butene: A density-functional study
inferred← citeshttps://doi.org/10.1016/j.molstruc.2025.141892openalex-snapshot
Thermostable polyhalogen-substituted α-diimine nickel precatalysts towards high performance polyethylene elastomer
inferred← citeshttps://doi.org/10.1016/j.poly.2005.10.032openalex-snapshot
Electrochemical synthesis of the σ-aryl complex [NiBr(Mes)(bpy)] and its use as catalyst precursor for the oligomerization of ethylene (Mes=2,4,6-trimethylphenyl, bpy=2,2′-bipyridine)
inferred← citeshttps://doi.org/10.1016/j.poly.2020.114469openalex-snapshot
Nickel catalyzed oligomerization of internal olefins: Towards lubricant basestocks and high cetane diesel fuels
inferred← citeshttps://doi.org/10.1016/j.polymer.2010.11.008openalex-snapshot
Polymerization of 4-methyl-1-pentene catalyzed by α-diimine nickel catalysts: Living/controlled behavior, branch structure, and mechanism
inferred← citeshttps://doi.org/10.1016/j.polymer.2018.08.056openalex-snapshot
Finely tuned nickel complexes as highly active catalysts affording branched polyethylene of high molecular weight: 1-(2,6-Dibenzhydryl-4- methoxyphenylimino)-2-(arylimino)acenaphthylenenickel halides
inferred← citeshttps://doi.org/10.1016/j.polymer.2024.126690openalex-snapshot
Synergistic influence of methoxy and benzhydryl groups in α-diimine nickel precatalysts for facile synthesizing UHMW PE elastomers
inferred← citeshttps://doi.org/10.1016/j.trechm.2019.08.004openalex-snapshot
Mechanisms of Nickel-Catalyzed Cross-Coupling Reactions
inferred← citeshttps://doi.org/10.1021/acs.accounts.0c00032openalex-snapshot
Mechanisms of Nickel-Catalyzed Coupling Reactions and Applications in Alkene Functionalization
inferred← citeshttps://doi.org/10.1021/acs.accounts.8b00225openalex-snapshot
Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts
inferred← citeshttps://doi.org/10.1021/acs.chemrev.0c00076openalex-snapshot
Nickel Catalyzed Olefin Oligomerization and Dimerization
inferred← citeshttps://doi.org/10.1021/acs.chemrev.4c00524openalex-snapshot
Cross-Electrophile Coupling: Principles, Methods, and Applications in Synthesis
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c04255openalex-snapshot
Intramolecular Agostic Interactions and Dynamics of a Methyl Group at a Preorganized Dinickel(II) Site
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b00539openalex-snapshot
Synthesis and the Optical and Electrochemical Properties of Indium(III) Bis(arylimino)acenaphthene Complexes
inferred← citeshttps://doi.org/10.1021/acs.joc.2c02256openalex-snapshot
Observing the Agostic Hydrogen in Pd(II)-Catalyzed Aromatic C–H Activation
inferred← citeshttps://doi.org/10.1021/acs.joc.4c01739openalex-snapshot
Factors Affecting the Formation and Transformation of the Intermediates in Pd(II)-Catalyzed Aromatic C–H Activation: A Comprehensive Study with the Pd(II)/LA Platform
inferred← citeshttps://doi.org/10.1021/acs.macromol.1c00174openalex-snapshot
Polar Additive Triggered Branching Switch and Block Polyolefin Topology in Living Ethylene Polymerization
inferred← citeshttps://doi.org/10.1021/acs.macromol.2c00360openalex-snapshot
Unprecedented Square-Planar α-Diimine Dibromonickel Complexes and Their Ethylene Polymerizations Modulated by Ni–Phenyl Interactions
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b01150openalex-snapshot
Understanding the Insertion Pathways and Chain Walking Mechanisms of α-Diimine Nickel Catalysts for α-Olefin Polymerization: A 13 C NMR Spectroscopic Investigation
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00257openalex-snapshot
Synthesis of Cationic, Dimeric α-Diimine Nickel Hydride Complexes and Relevance to the Polymerization of Olefins
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00395openalex-snapshot
Activation of an α-Diimine Ni(II) Precatalyst with AlMe3 and AliBu3: Catalytic and NMR and EPR Spectroscopy Studies
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00696openalex-snapshot
Cationic α-Diimine Nickel and Palladium Complexes Incorporating Phenanthrene Substituents: Highly Active Ethylene Polymerization Catalysts and Mechanistic Studies of syn / anti Isomerization
inferred← citeshttps://doi.org/10.1021/acs.organomet.1c00015openalex-snapshot
Nature of Heterobinuclear Ni(I) Complexes Formed upon the Activation of the α-Diimine Complex LNiIIBr2 with AlMe3 and MMAO
inferred← citeshttps://doi.org/10.1021/acs.organomet.2c00065openalex-snapshot
Ni(I) Intermediates Formed upon Activation of a Ni(II) α-Diimine Ethylene Polymerization Precatalyst with AlR3 (R = Me, Et, and iBu), AlR2Cl (R = Me, Et), and MMAO: A Comparative Study
inferred← citeshttps://doi.org/10.1021/acs.organomet.2c00241openalex-snapshot
Phosphine-Phenoxide Nickel Catalysts for Ethylene/Acrylate Copolymerization: Olefin Coordination and Complex Isomerization Studies Relevant to the Mechanism of Catalysis
inferred← citeshttps://doi.org/10.1021/acs.organomet.2c00267openalex-snapshot
Comparative Investigation of η6-Arene Tethered Ru(II) Complexes with Different Tethered Heteroatoms for Ethylene Polymerization Catalysis: Experimental and DFT Studies
inferred← citeshttps://doi.org/10.1021/acs.organomet.2c00415openalex-snapshot
Maurice Brookhart: A Legacy to Organometallic Chemistry
inferred← citeshttps://doi.org/10.1021/acs.organomet.2c00505openalex-snapshot
Rigid Triptycene-Based Di- and Trinuclear Salicylaldiminato Nickel Cooperative Polymerization Catalysts
inferred← citeshttps://doi.org/10.1021/acs.organomet.4c00227openalex-snapshot
Formation of Ni(I) Species upon Activation of 5,6,7-Trihydroquinolin-8-imine Nickel(II) Dihalides with MAO and MMAO
inferred← citeshttps://doi.org/10.1021/acs.organomet.4c00512openalex-snapshot
2,4,6-Triphenylpyridinium-Substituted Neutral Nickel Catalysts: Ethylene Polymerization, Influence of Activator, Catalyst Decomposition, and End-Group Analysis
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00263openalex-snapshot
NMR and EPR Spectroscopic Identification of Intermediates Formed upon Activation of 8-Mesitylimino-5,6,7-trihydroquinolylnickel Dichloride with AlR2Cl (R = Me, Et)
inferred← citeshttps://doi.org/10.1021/acs.organomet.5c00477openalex-snapshot
Synthesis, Structural Diversity, and Ethylene Polymerization Reactivity of Nickel(0)/(II) and Palladium(II) Complexes Supported by {PN(H)P}- and {PN(H)P(O)}-Type (Pro)Ligands
inferred← citeshttps://doi.org/10.1021/acs.organomet.6b00036openalex-snapshot
Agostic versus Terminal Ethyl Rhodium Complexes: A Combined Experimental and Theoretical Study
inferred← citeshttps://doi.org/10.1021/acs.organomet.6b00165openalex-snapshot
Synthesis of Branched Polyethylene with “Half-Sandwich” Pyridine-Imine Nickel Complexes
inferred← citeshttps://doi.org/10.1021/acs.organomet.6c00138openalex-snapshot
“Coordinatively Open” Binuclear α-Diiminonickel Complexes: Polyethylene Branch Control via Cocatalyst
inferred← citeshttps://doi.org/10.1021/acs.organomet.7b00666openalex-snapshot
Structural Characterization of β-Agostic Bonds in Pd-Catalyzed Polymerization
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00379openalex-snapshot
[(dmpe)2MnH(C2H4)] as a Source of a Low-Coordinate Ethyl Manganese(I) Species: Reactions with Primary Silanes, H2, and Isonitriles
inferred← citeshttps://doi.org/10.1021/acs.organomet.9b00649openalex-snapshot
Ethylene Polymerization with Ni(II) Diimine Complexes Generated from 8-Halo-1-naphthylamines: The Role of Equilibrating Syn / Anti Diastereomers in Determining Polymer Properties
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c02893openalex-snapshot
Nickel-Catalyzed Reductive Csp2–Csp3 Cross Coupling Using Phosphonium Salts
inferred← citeshttps://doi.org/10.1021/acscatal.0c02115openalex-snapshot
Nickel-Catalyzed Dicarbofunctionalization of Alkenes
inferred← citeshttps://doi.org/10.1021/acscatal.5b01957openalex-snapshot
Ethene Oligomerization in Ni-Containing Zeolites: Theoretical Discrimination of Reaction Mechanisms
inferred← citeshttps://doi.org/10.1021/acscatal.5b02003openalex-snapshot
Lewis Acid Enhanced Ethene Dimerization and Alkene Isomerization—ESI-MS Identification of the Catalytically Active Pyridyldimethoxybenzimidazole Nickel(II) Hydride Species
inferred← citeshttps://doi.org/10.1021/acscatal.5b02216openalex-snapshot
A Career in Catalysis: Maurice Brookhart
inferred← citeshttps://doi.org/10.1021/acscatal.5c02037openalex-snapshot
Overcoming Conformational Complexity to Elucidate Selective Ethylene Tetramerization Behavior
inferred← citeshttps://doi.org/10.1021/acscatal.6b01134openalex-snapshot
Alkene Hydrosilylation Using Tertiary Silanes with α-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts
inferred← citeshttps://doi.org/10.1021/acscatal.7b02919openalex-snapshot
Entrances, Traps, and Rate-Controlling Factors for Nickel-Catalyzed C–H Functionalization
inferred← citeshttps://doi.org/10.1021/acsomega.1c05418openalex-snapshot
Fluorinated Sterically Bulky Mononuclear and Binuclear 2-Iminopyridylnickel Halides for Ethylene Polymerization: Effects of Ligand Frameworks and Remote Substituents
inferred← citeshttps://doi.org/10.1021/cr500370fopenalex-snapshot
Neutral Nickel Catalysts for Olefin Homo- and Copolymerization: Relationships between Catalyst Structures and Catalytic Properties
inferred← citeshttps://doi.org/10.1021/cr900079ropenalex-snapshot
Coordination−Insertion Copolymerization of Fundamental Polar Monomers
inferred← citeshttps://doi.org/10.1021/cs5016029openalex-snapshot
Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using “Sandwich” Diimine Palladium Catalysts
inferred← citeshttps://doi.org/10.1021/ic048801gopenalex-snapshot
Divalent Germanium Compound with a Radical-Anionic Ligand: Molecular Structures of (dpp-BIAN)•-GeCl and Its Hydrochloration Products [(dpp-BIAN)(H)2]•+[GeCl3]- and [{(dpp-BIAN)(H)2•+}2(Cl-)]+[GeCl3]- (dpp-BIAN = 1,2-Bis{(2,6-diisopropylphenyl)imino}acenaphthene)
inferred← citeshttps://doi.org/10.1021/ic061162kopenalex-snapshot
Coordination of Fluoro Ligands toward Sodium Ions Makes the Difference: Aqua Sodium Ions Act as Brønsted Acids in Polymerization of Vinyl Ethers and Styrenes
inferred← citeshttps://doi.org/10.1021/ic500259kopenalex-snapshot
Digallane with Redox-Active Diimine Ligand: Dualism of Electron-Transfer Reactions
inferred← citeshttps://doi.org/10.1021/ic902439xopenalex-snapshot
One- and Two-Electron-Transfer Reactions of (dpp-Bian)Sm(dme)3
inferred← citeshttps://doi.org/10.1021/ie040197uopenalex-snapshot
Kinetic Modeling and Prediction of Polymer Properties for Ethylene Polymerization over Nickel Diimine Catalysts
inferred← citeshttps://doi.org/10.1021/ja030634gopenalex-snapshot
A Mechanistic Investigation of the Polymerization of Ethylene Catalyzed by Neutral Ni(II) Complexes Derived from Bulky Anilinotropone Ligands
inferred← citeshttps://doi.org/10.1021/ja0477221openalex-snapshot
Structure and Dynamics of Neutral β-H Agostic Nickel Alkyls: A Combined Experimental and Theoretical Study
inferred← citeshttps://doi.org/10.1021/ja068118oopenalex-snapshot
Mechanistic Studies of Platinum(II)-Catalyzed Ethylene Dimerization: Determination of Barriers to Migratory Insertion in Diimine Pt(II) Hydrido Ethylene and Ethyl Ethylene Intermediates
inferred← citeshttps://doi.org/10.1021/ja100491yopenalex-snapshot
Cationic Polymerization and Insertion Chemistry in the Reactions of Vinyl Ethers with (α-Diimine)PdMe + Species
inferred← citeshttps://doi.org/10.1021/ja108426fopenalex-snapshot
Three-Coordinate NiII: Tracing the Origin of an Unusual, Facile Si−C(sp3) Bond Cleavage in [(tBu2PCH2SiMe2)2N]Ni+
inferred← citeshttps://doi.org/10.1021/ja8017847openalex-snapshot
Axial Donating Ligands: A New Strategy for Late Transition Metal Olefin Polymerization Catalysis
inferred← citeshttps://doi.org/10.1021/ja808855vopenalex-snapshot
Deactivation Pathways of Neutral Ni(II) Polymerization Catalysts
inferred← citeshttps://doi.org/10.1021/jacs.3c01513openalex-snapshot
Deciphering the Olefin Isomerization-Polymerization Paradox of Palladium(II) Diimine Catalysts: Discovery of Simultaneous and Independent Pathways of Olefin Isomerization and Living Polymerization
inferred← citeshttps://doi.org/10.1021/jacs.3c10800openalex-snapshot
Acrylate-Induced β-H Elimination in Coordination Insertion Copolymerizaton Catalyzed by Nickel
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