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Alkene Hydrosilylation Using Tertiary Silanes with α-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
inferredcites →https://doi.org/10.1002/adsc.201300827openalex-snapshot
Iron‐Catalysed Chemo‐, Regio‐, and Stereoselective Hydrosilylation of Alkenes and Alkynes using a Bench‐Stable Iron(II) Pre‐Catalyst
inferredcites →https://doi.org/10.1002/anie.201304157openalex-snapshot
Method of Continuous Variations: Applications of Job Plots to the Study of Molecular Associations in Organometallic Chemistry
inferredcites →https://doi.org/10.1002/anie.201304596openalex-snapshot
Anchoring of Silyl Donors on a N‐Heterocyclic Carbene through the Cobalt‐Mediated Silylation of Benzylic CH Bonds
inferredcites →https://doi.org/10.1002/anie.201411884openalex-snapshot
Iron‐Catalyzed Asymmetric Hydrosilylation of 1,1‐Disubstituted Alkenes
inferredcites →https://doi.org/10.1002/anie.201507829openalex-snapshot
Chemoselective Alkene Hydrosilylation Catalyzed by Nickel Pincer Complexes
inferredcites →https://doi.org/10.1002/ejic.201200758openalex-snapshot
Alkene Hydrogenation Catalyzed by Nickel Hydride Complexes of an Aliphatic PNP Pincer Ligand
inferredcites →https://doi.org/10.1016/0969-806x(95)00401-iopenalex-snapshot
Photolysis of an arylalkyl-triazenido-platinum-IV complex
inferredcites →https://doi.org/10.1016/j.apcata.2014.08.037openalex-snapshot
Hydrosilylation cross-linking of silicon fluids by a novel class of iron(0) catalysts
inferredcites →https://doi.org/10.1016/j.ccr.2005.02.025openalex-snapshot
Catalysis by transition metal complexes of alkene silylation–recent progress and mechanistic implications
inferredcites →https://doi.org/10.1016/j.ccr.2010.12.025openalex-snapshot
Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view
inferredcites →https://doi.org/10.1016/j.jorganchem.2015.04.051openalex-snapshot
Hydrosilylation vs. dehydrogenative silylation of styrene catalysed by iron(0) carbonyl complexes with multivinylsilicon ligands – Mechanistic implications
inferredcites →https://doi.org/10.1016/j.jpcs.2003.11.015openalex-snapshot
Definition of corresponding orbitals and the diradical character in broken symmetry DFT calculations on spin coupled systems
inferredcites →https://doi.org/10.1016/s0022-328x(00)92207-1openalex-snapshot
Pentacarbonyliron(0) photocatalyzed reactions of trialkylsilanes with alkenes
inferredcites →https://doi.org/10.1016/s0022-328x(99)00685-3openalex-snapshot
Catalysis of hydrosilylation
inferredcites →https://doi.org/10.1016/s1387-7003(00)00089-7openalex-snapshot
Competitive silylation of olefins with vinylsilanes and hydrosilanes photocatalyzed by iron carbonyl complexes
inferredcites →https://doi.org/10.1021/acs.organomet.5b00201openalex-snapshot
Combinatorial Approach to the Catalytic Hydrosilylation of Styrene Derivatives: Catalyst Systems Composed of Organoiron(0) or (II) Precursors and Isocyanides
inferredcites →https://doi.org/10.1021/acs.orglett.5b01135openalex-snapshot
Alkene Isomerization–Hydroboration Promoted by Phosphine-Ligated Cobalt Catalysts
inferredcites →https://doi.org/10.1021/acscatal.5b00072openalex-snapshot
Nickel: The “Spirited Horse” of Transition Metal Catalysis
inferredcites →https://doi.org/10.1021/acscatal.5b02624openalex-snapshot
Platinum Catalysis Revisited—Unraveling Principles of Catalytic Olefin Hydrosilylation
inferredcites →https://doi.org/10.1021/acscatal.6b00304openalex-snapshot
Bench-Stable, Substrate-Activated Cobalt Carboxylate Pre-Catalysts for Alkene Hydrosilylation with Tertiary Silanes
inferredcites →https://doi.org/10.1021/acscatal.6b01091openalex-snapshot
A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes using Tertiary Silanes and Hydrosiloxanes
inferredcites →https://doi.org/10.1021/cs300584bopenalex-snapshot
High-Selectivity Bis(imino)pyridine Iron Catalysts for the Hydrosilylation of 1,2,4-Trivinylcyclohexane
inferredcites →https://doi.org/10.1021/ic301392popenalex-snapshot
Synthesis and Reactivity of Nickel Hydride Complexes of an α-Diimine Ligand
inferredcites →https://doi.org/10.1021/ic50214a058openalex-snapshot
Photochemistry of cobalt carbonyl complexes having a cobalt-silicon bond and its importance in activation of catalysis
inferredcites →https://doi.org/10.1021/ic700407mopenalex-snapshot
Bis(α-diimine)nickel Complexes: Molecular and Electronic Structure of Three Members of the Electron-Transfer Series [Ni(L)2]z (z = 0, 1+, 2+) (L = 2-Phenyl-1,4-bis(isopropyl)-1,4-diazabutadiene). A Combined Experimental and Theoretical Study
inferredcites →https://doi.org/10.1021/ja00059a008openalex-snapshot
Mechanism of a cobalt(III)-catalyzed olefin hydrosilation reaction: direct evidence for a silyl migration pathway
inferredcites →https://doi.org/10.1021/ja00394a060openalex-snapshot
Photogeneration of very active homogeneous catalysts using laser light excitation of iron carbonyl precursors
inferredcites →https://doi.org/10.1021/ja00883a024openalex-snapshot
Redistribution and Reduction Reactions of Alkoxysilanes
inferredcites →https://doi.org/10.1021/ja01083a034openalex-snapshot
Dicobalt Octacarbonyl as a Catalyst for Hydrosilation of Olefins
inferredcites →https://doi.org/10.1021/ja0127335openalex-snapshot
The First Alkene−Platinum−Silyl Complexes: Lifting the Hydrosilation Mechanism Shroud with Long-Lived Precatalytic Intermediates and True Pt Catalysts
inferredcites →https://doi.org/10.1021/ja01561a054openalex-snapshot
The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts
inferredcites →https://doi.org/10.1021/ja021071wopenalex-snapshot
Mechanistic Studies of Nickel(II) Alkyl Agostic Cations and Alkyl Ethylene Complexes: Investigations of Chain Propagation and Isomerization in (α-diimine)Ni(II)-Catalyzed Ethylene Polymerization
inferredcites →https://doi.org/10.1021/ja046753topenalex-snapshot
Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation
inferredcites →https://doi.org/10.1021/ja404963fopenalex-snapshot
Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation
inferredcites →https://doi.org/10.1021/ja5060884openalex-snapshot
Bis(imino)pyridine Cobalt-Catalyzed Dehydrogenative Silylation of Alkenes: Scope, Mechanism, and Origins of Selective Allylsilane Formation
inferredcites →https://doi.org/10.1021/ja510924vopenalex-snapshot
Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes
inferredcites →https://doi.org/10.1021/ja9825377openalex-snapshot
In Situ Determination of the Active Catalyst in Hydrosilylation Reactions Using Highly Reactive Pt(0) Catalyst Precursors
inferredcites →https://doi.org/10.1021/ja991931hopenalex-snapshot
Low-Temperature Spectroscopic Observation of Chain Growth and Migratory Insertion Barriers in (α-Diimine)Ni(II) Olefin Polymerization Catalysts
inferredcites →https://doi.org/10.1021/jacs.5b03092openalex-snapshot
Reversible Substrate Activation and Catalysis at an Intact Metal–Metal Bond Using a Redox-Active Supporting Ligand
inferredcites →https://doi.org/10.1021/jacs.5b08611openalex-snapshot
Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst
inferredcites →https://doi.org/10.1021/jacs.5b11311openalex-snapshot
Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes
inferredcites →https://doi.org/10.1021/jacs.6b02173openalex-snapshot
Mechanism of the Iron(II)-Catalyzed Hydrosilylation of Ketones: Activation of Iron Carboxylate Precatalysts and Reaction Pathways of the Active Catalyst
inferredcites →https://doi.org/10.1021/ol203428copenalex-snapshot
General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes
inferredcites →https://doi.org/10.1021/om000677vopenalex-snapshot
Ruthenium-Catalyzed Silylation of Ethylene by Disilanes
inferredcites →https://doi.org/10.1021/om0494420openalex-snapshot
Influence of SiMe3 Substituents on Structures and Hydrosilylation Activities of ((SiMe3)1 or 2-Indenyl)Ni(PPh3)Cl
inferredcites →https://doi.org/10.1021/om060441copenalex-snapshot
Arene Coordination in Bis(imino)pyridine Iron Complexes: Identification of Catalyst Deactivation Pathways in Iron-Catalyzed Hydrogenation and Hydrosilation
inferredcites →https://doi.org/10.1021/om200937dopenalex-snapshot
R-Allyl Nickel(II) Complexes with Chelating N-Heterocyclic Carbenes: Synthesis, Structural Characterization, and Catalytic Activity
inferredcites →https://doi.org/10.1021/om300279topenalex-snapshot
Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands
inferredcites →https://doi.org/10.1039/c2cc32974copenalex-snapshot
Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(ii) complex
inferredcites →https://doi.org/10.1039/c4ra17281gopenalex-snapshot
Hydrosilylation reaction of olefins: recent advances and perspectives
inferredcites →https://doi.org/10.1039/c5cy00270bopenalex-snapshot
(Salicylaldiminato)Ni( ii )-catalysts for hydrosilylation of olefins
inferredcites →https://doi.org/10.1039/c5dt02333eopenalex-snapshot
α-Diimine nickel complexes of ethylene and related alkenes
inferredcites →https://doi.org/10.1126/science.1214451openalex-snapshot
Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Anti-Markovnikov Hydrosilylation and Markovnikov Hydroboration of Alkenes by a Phenanthroline-Based Tridentate Manganese(Ii) Catalyst
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Dinickel, 1,1(-(1,8-Naphthyridine-2,7-diyl)bis[N-(2,6-diisopropylphenyl)ethan-1-imine](benzene)
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Base Metal‐Catalyzed Addition Reactions Across C C Multiple Bonds
inferred← citeshttps://doi.org/10.1002/9783527804801.ch4openalex-snapshot
Hydrofunctionalization of Carbon–Carbon Double Bonds
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Hydrosilylation Catalyzed by Base Metals
inferred← citeshttps://doi.org/10.1002/ange.201610990openalex-snapshot
Enantioselective NiH/Pmrox‐Catalyzed 1,2‐Reduction of α,β‐Unsaturated Ketones
inferred← citeshttps://doi.org/10.1002/ange.201612460openalex-snapshot
(Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes
inferred← citeshttps://doi.org/10.1002/ange.201702349openalex-snapshot
Iron‐Catalyzed Intermolecular 1,2‐Difunctionalization of Styrenes and Conjugated Alkenes with Silanes and Nucleophiles
inferred← citeshttps://doi.org/10.1002/ange.201712731openalex-snapshot
NiH‐Catalyzed Reductive Relay Hydroalkylation: A Strategy for the Remote C(sp3)−H Alkylation of Alkenes
inferred← citeshttps://doi.org/10.1002/ange.201813222openalex-snapshot
NiH‐Catalyzed Remote Asymmetric Hydroalkylation of Alkenes with Racemic α‐Bromo Amides
inferred← citeshttps://doi.org/10.1002/ange.201907185openalex-snapshot
Rapid Access to Highly Functionalized Alkyl Boronates by NiH‐Catalyzed Remote Hydroarylation of Boron‐Containing Alkenes
inferred← citeshttps://doi.org/10.1002/ange.201915840openalex-snapshot
NiH‐Catalyzed Migratory Defluorinative Olefin Cross‐Coupling: Trifluoromethyl‐Substituted Alkenes as Acceptor Olefins to Form gem‐Difluoroalkenes
inferred← citeshttps://doi.org/10.1002/ange.201916406openalex-snapshot
Mechanistic Studies on the Insertion of Carbonyl Substrates into Cu‐H: Different Rate‐Limiting Steps as a Function of Electrophilicity
inferred← citeshttps://doi.org/10.1002/ange.202001742openalex-snapshot
Ligand‐Enabled Nickel‐Catalyzed Redox‐Relay Migratory Hydroarylation of Alkenes with Arylborons
inferred← citeshttps://doi.org/10.1002/ange.202007930openalex-snapshot
Ligand‐Regulated Regiodivergent Hydrosilylation of Isoprene under Iron Catalysis
inferred← citeshttps://doi.org/10.1002/ange.202008729openalex-snapshot
Recent Advances in Catalytic Hydrosilylations: Developments beyond Traditional Platinum Catalysts
inferred← citeshttps://doi.org/10.1002/ange.202010386openalex-snapshot
Enantio‐ and Regioselective NiH‐Catalyzed Reductive Hydroarylation of Vinylarenes with Aryl Iodides
inferred← citeshttps://doi.org/10.1002/ange.202011342openalex-snapshot
Nickel‐Catalyzed Asymmetric Synthesis of α‐Arylbenzamides
inferred← citeshttps://doi.org/10.1002/ange.202012614openalex-snapshot
Nickel‐Catalyzed, Regio‐ and Enantioselective Benzylic Alkenylation of Olefins with Alkenyl Bromide
inferred← citeshttps://doi.org/10.1002/ange.202015837openalex-snapshot
Ruthenium‐Catalyzed Dehydrogenation Through an Intermolecular Hydrogen Atom Transfer Mechanism
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Facile Synthesis of Chiral Arylamines, Alkylamines and Amides by Enantioselective NiH‐Catalyzed Hydroamination
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Highly Regio‐ and Enantioselective Hydrosilylation of gem‐Difluoroalkenes by Nickel Catalysis
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A General and Efficient Solution to Monofluoroalkylation: Divergent Synthesis of Aliphatic Monofluorides with Modular Synthetic Scaffolds
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Generation and Stabilization of a Dinickel Catalyst in a Metal‐Organic Framework for Selective Hydrogenation Reactions
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Triphasic Hydroxysilylation of Alkenes by Mechanically Piezoelectric Catalysis
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Methoxide‐Enabled Zirconium‐Catalyzed Migratory Alkene Hydrosilylation
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A Homobimetallic Frustrated Lewis Pair Cobalt Catalyst for the Methanolysis of Hydrosilanes
inferred← citeshttps://doi.org/10.1002/ange.3844159openalex-snapshot
Nickel‐Catalyzed Boron‐Mediated Saturative Trifunctionalization of Alkynes
inferred← citeshttps://doi.org/10.1002/anie.201610990openalex-snapshot
Enantioselective NiH/Pmrox‐Catalyzed 1,2‐Reduction of α,β‐Unsaturated Ketones
inferred← citeshttps://doi.org/10.1002/anie.201612460openalex-snapshot
(Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes
inferred← citeshttps://doi.org/10.1002/anie.201702349openalex-snapshot
Iron‐Catalyzed Intermolecular 1,2‐Difunctionalization of Styrenes and Conjugated Alkenes with Silanes and Nucleophiles
inferred← citeshttps://doi.org/10.1002/anie.201712731openalex-snapshot
NiH‐Catalyzed Reductive Relay Hydroalkylation: A Strategy for the Remote C(sp 3 )−H Alkylation of Alkenes
inferred← citeshttps://doi.org/10.1002/anie.201813222openalex-snapshot
NiH‐Catalyzed Remote Asymmetric Hydroalkylation of Alkenes with Racemic α‐Bromo Amides
inferred← citeshttps://doi.org/10.1002/anie.201907185openalex-snapshot
Rapid Access to Highly Functionalized Alkyl Boronates by NiH‐Catalyzed Remote Hydroarylation of Boron‐Containing Alkenes
inferred← citeshttps://doi.org/10.1002/anie.201915840openalex-snapshot
NiH‐Catalyzed Migratory Defluorinative Olefin Cross‐Coupling: Trifluoromethyl‐Substituted Alkenes as Acceptor Olefins to Form gem‐Difluoroalkenes
inferred← citeshttps://doi.org/10.1002/anie.201916406openalex-snapshot
Mechanistic Studies on the Insertion of Carbonyl Substrates into Cu‐H: Different Rate‐Limiting Steps as a Function of Electrophilicity
inferred← citeshttps://doi.org/10.1002/anie.202001742openalex-snapshot
Ligand‐Enabled Nickel‐Catalyzed Redox‐Relay Migratory Hydroarylation of Alkenes with Arylborons
inferred← citeshttps://doi.org/10.1002/anie.202007930openalex-snapshot
Ligand‐Regulated Regiodivergent Hydrosilylation of Isoprene under Iron Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202008729openalex-snapshot
Recent Advances in Catalytic Hydrosilylations: Developments beyond Traditional Platinum Catalysts
inferred← citeshttps://doi.org/10.1002/anie.202010386openalex-snapshot
Enantio‐ and Regioselective NiH‐Catalyzed Reductive Hydroarylation of Vinylarenes with Aryl Iodides
inferred← citeshttps://doi.org/10.1002/anie.202011342openalex-snapshot
Nickel‐Catalyzed Asymmetric Synthesis of α‐Arylbenzamides
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Facile Synthesis of Chiral Arylamines, Alkylamines and Amides by Enantioselective NiH‐Catalyzed Hydroamination
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inferred← citeshttps://doi.org/10.1002/anie.202410334openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202413182openalex-snapshot
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Hydrosilylation of Alkenes Using a Hydrosiloxane as a Surrogate for Me2SiH2 and Catalyzed by a Nickel‐Pincer Complex
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Hydrosilylation of Terminal Alkenes Catalyzed by a Scandium Metalloligand Supported Ni(0) Complex
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Efficient Hydrosilylation Reaction of Olefins Catalyzed by a Dinuclear Ruthenium Complex
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Theoretical prediction of Ni(I)‐catalyst for hydrosilylation of pyridine and quinoline
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Base metal‐catalyzed hydrogen isotope exchange
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Regio‐ and Stereoselective Functionalization Enabled by Bidentate Directing Groups
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Recent Advances of Group 10 Transition Metal Hydrosilylation Catalysts
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Update Hydrometallation Group 4 (Si, Ge and Sn)
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Hydrosilylation reactions with homogeneous catalysts
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Zeolites catalyze selective reactions of large organic molecules
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Recent advances in Ni-catalyzed functionalization of strong C−O and C−H bonds
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Ni(I) complexes relevant to synthetic organic catalysis
inferred← citeshttps://doi.org/10.1016/j.cclet.2023.108293openalex-snapshot
Nickel-catalyzed cooperative B-H bond activation for hydroboration of N‑heteroarenes, ketones and imines
inferred← citeshttps://doi.org/10.1016/j.ccr.2019.213110openalex-snapshot
Earth-abundant metal catalyzed hydrosilylative reduction of various functional groups
inferred← citeshttps://doi.org/10.1016/j.chempr.2017.07.010openalex-snapshot
Ni(I)-Catalyzed Reductive Cyclization of 1,6-Dienes: Mechanism-Controlled trans Selectivity
inferred← citeshttps://doi.org/10.1016/j.chempr.2018.04.008openalex-snapshot
Remote sp3 C–H Amination of Alkenes with Nitroarenes
inferred← citeshttps://doi.org/10.1016/j.chempr.2021.10.015openalex-snapshot
A relay catalysis strategy for enantioselective nickel-catalyzed migratory hydroarylation forming chiral α-aryl alkylboronates
inferred← citeshttps://doi.org/10.1016/j.colsurfa.2019.03.039openalex-snapshot
Preparation and evaluation of a novel and high efficient boronic acid-substituted silica supported Pt catalyst
inferred← citeshttps://doi.org/10.1016/j.isci.2020.100985openalex-snapshot
Iron-Catalyzed Asymmetric Hydrosilylation of Vinylcyclopropanes via Stereospecific C-C Bond Cleavage
inferred← citeshttps://doi.org/10.1016/j.jcat.2023.115197openalex-snapshot
Anti-Markovnikov hydrosilylation and Markovnikov hydroboration of alkenes by a phenanthroline-based tridentate manganese catalyst
inferred← citeshttps://doi.org/10.1016/j.mcat.2022.112238openalex-snapshot
Theoretical study of nickel-catalyzed hydroalkylation of 3-pyrrolines: Origin of ligand-controlled regioselectivity
inferred← citeshttps://doi.org/10.1016/j.mtchem.2026.103845openalex-snapshot
Unveiling coordination structure-performance relationship of platinum single atoms for catalyzing alkene hydrosilylation
inferred← citeshttps://doi.org/10.1016/j.tetlet.2017.03.017openalex-snapshot
(Dicyclopentadiene) platinum(II) dichloride: An efficient catalyst for the hydrosilylation reaction between alkenes and triethoxysilane
inferred← citeshttps://doi.org/10.1016/j.tetlet.2018.05.008openalex-snapshot
Terminal C(sp3) H alkylation of internal alkenes via Ni/H-catalyzed isomerization
inferred← citeshttps://doi.org/10.1016/j.tetlet.2023.154798openalex-snapshot
Recent developments in alkene hydrosilylation utilizing manganese catalysts
inferred← citeshttps://doi.org/10.1021/acs.chemrev.1c00417openalex-snapshot
Inorganometallics (Transition Metal–Metalloid Complexes) and Catalysis
inferred← citeshttps://doi.org/10.1021/acs.chemrev.5c00531openalex-snapshot
Paramagnetic Transition Metal Hydride Complexes
inferred← citeshttps://doi.org/10.1021/acs.chemrev.9b00682openalex-snapshot
Trends in the Usage of Bidentate Phosphines as Ligands in Nickel Catalysis
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.1c02925openalex-snapshot
Extensive Redox Non-Innocence in Iron Bipyridine-Diimine Complexes: a Combined Spectroscopic and Computational Study
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c02094openalex-snapshot
Control over Selectivity in Alkene Hydrosilylation Catalyzed by Cobalt(III) Hydride Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c00521openalex-snapshot
Catalytic Properties of [PSiP] Pincer Cobalt(II) Chlorides Supported by Trimethylphosphine for Alkene Hydrosilylation Reactions
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c04265openalex-snapshot
DFT Calculations Reveal the Origins of Chemo-, Regio-, and Stereoselectivities in Nickel-Catalyzed Synthesis of Chiral Tetrasubstituted Allenes with Simultaneous Construction of Central and Axial Chirality
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6b02862openalex-snapshot
Molecular and Electronic Structures of Ruthenium Complexes Containing an ONS-Coordinated Open-Shell π Radical and an Oxidative Aromatic Ring Cleavage Reaction
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6c00190openalex-snapshot
Regiodivergent Hydrosilylation of Alkenes at Nickel: Tuning the Selectivity by Complex Stoichiometry and Silane Identity
inferred← citeshttps://doi.org/10.1021/acs.joc.0c01439openalex-snapshot
Developing a Highly Active Catalytic System Based on Cobalt Nanoparticles for Terminal and Internal Alkene Hydrosilylation
inferred← citeshttps://doi.org/10.1021/acs.joc.0c01509openalex-snapshot
“Bulky-Yet-Flexible” α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air
inferred← citeshttps://doi.org/10.1021/acs.joc.9b00959openalex-snapshot
Theoretical Study on the Rhodium-Catalyzed Hydrosilylation of C═C and C═O Double Bonds with Tertiary Silane
inferred← citeshttps://doi.org/10.1021/acs.jpca.3c08325openalex-snapshot
DFT Struggles to Predict the Energy Landscape for Iron Pyridine Diimine-Catalyzed [2 + 2] Cycloaddition of Alkenes: Insights into the Problem and Alternative Solutions
inferred← citeshttps://doi.org/10.1021/acs.oprd.2c00279openalex-snapshot
A Cobalt-Containing Polysilane as an Effective Solid-State Catalyst for the Hydrosilylation of Alkenes
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00251openalex-snapshot
[CNC]-Pincer Cobalt Hydride Catalyzed Distinct Selective Hydrosilylation of Aryl Alkene and Alkyl Alkene
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00257openalex-snapshot
Synthesis of Cationic, Dimeric α-Diimine Nickel Hydride Complexes and Relevance to the Polymerization of Olefins
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00551openalex-snapshot
Cationic Nickel(II)-Catalyzed Hydrosilylation of Alkenes: Role of P, N-Type Ligand Scaffold on Selectivity and Reactivity
inferred← citeshttps://doi.org/10.1021/acs.organomet.1c00069openalex-snapshot
Pioneers and Influencers: A Profile of Dr. Kenrick Lewis
inferred← citeshttps://doi.org/10.1021/acs.organomet.1c00613openalex-snapshot
[P, C] Chelate Cobalt(I)-Catalyzed Distinct Selective Hydrosilylation of Alkenes under Mild Conditions
inferred← citeshttps://doi.org/10.1021/acs.organomet.3c00191openalex-snapshot
Hard to Handle: Extremely Labile Hydrido Nickel(II) Complexes of Cyclometalated C∧N∧N and N∧C∧N Ligands
inferred← citeshttps://doi.org/10.1021/acs.organomet.5c00141openalex-snapshot
Silicone Curing Using an Iron PNN Pincer Complex
inferred← citeshttps://doi.org/10.1021/acs.organomet.6b00630openalex-snapshot
Cobalt-Catalyzed C(sp2)–H Borylation with an Air-Stable, Readily Prepared Terpyridine Cobalt(II) Bis(acetate) Precatalyst
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00011openalex-snapshot
Ni(I)-Hydride Catalyst for Hydrosilylation of Carbon Dioxide and Dihydrogen Generation: Theoretical Prediction and Exploration of Full Catalytic Cycle
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00350openalex-snapshot
Synthesis and Reactivity of Reduced α-Diimine Nickel Complexes Relevant to Acrylic Acid Synthesis
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00389openalex-snapshot
Cobalt(0) and Iron(0) Isocyanides as Catalysts for Alkene Hydrosilylation with Hydrosiloxanes
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00416openalex-snapshot
Fe and Co Complexes of Rigidly Planar Phosphino-Quinoline-Pyridine Ligands for Catalytic Hydrosilylation and Dehydrogenative Silylation
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c00111openalex-snapshot
Nickel-Catalyzed Hydrosilylation of Terminal Alkenes with Primary Silanes via Electrophilic Silicon–Hydrogen Bond Activation
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c00858openalex-snapshot
Copper-Catalyzed Highly Selective Hydrosilylation of Silyl or Boryl Alkene: A Method for Preparing Chiral Geminated Disilyl and Borylsilyl Reagents
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c03422openalex-snapshot
Triethoxysilane as a Selective Reagent in Platinum-Catalyzed Hydrosilylation Reactions
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c03797openalex-snapshot
Nickel-Catalyzed Regioselective Markovnikov Hydrosilylation of Vinylarenes via Hydrogen Atom Transfer
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b03064openalex-snapshot
Porous Organic Polymer as a Heterogeneous Ligand for Highly Regio- and Stereoselective Nickel-Catalyzed Hydrosilylation of Alkyne
inferred← citeshttps://doi.org/10.1021/acscatal.0c00393openalex-snapshot
Nickel-Catalyzed Amination of Aryl Thioethers: A Combined Synthetic and Mechanistic Study
inferred← citeshttps://doi.org/10.1021/acscatal.2c02655openalex-snapshot
Ligand-Based Redox: Catalytic Applications and Mechanistic Aspects
inferred← citeshttps://doi.org/10.1021/acscatal.2c03580openalex-snapshot
(NHC)Ni(0)-Catalyzed Branched-Selective Alkene Hydrosilylation with Secondary and Tertiary Silanes
inferred← citeshttps://doi.org/10.1021/acscatal.2c04442openalex-snapshot
Nickel-Catalyzed Ring-Opening of Benzofurans for the Divergent Synthesis of ortho-Functionalized Phenol Derivatives
inferred← citeshttps://doi.org/10.1021/acscatal.3c00238openalex-snapshot
Nickel-Catalyzed Remote C(sp 3 )–N/O Bond Formation of Alkenes with Unactivated Amines and Alcohols
inferred← citeshttps://doi.org/10.1021/acscatal.3c05747openalex-snapshot
Rare-Earth-Catalyzed Regiodivergent Hydrosilylation of Aryl Alkenes
inferred← citeshttps://doi.org/10.1021/acscatal.5c03042openalex-snapshot
Ligand Controlled Regiodivergent Synthesis of α-Tertiary and Quaternary Alkyl-Alkoxysilanes
inferred← citeshttps://doi.org/10.1021/acscatal.6b02990openalex-snapshot
Advances in Base-Metal-Catalyzed Alkene Hydrosilylation
inferred← citeshttps://doi.org/10.1021/acscatal.7b02919openalex-snapshot
Entrances, Traps, and Rate-Controlling Factors for Nickel-Catalyzed C–H Functionalization
inferred← citeshttps://doi.org/10.1021/acscatal.7b03909openalex-snapshot
Air-Stable α-Diimine Nickel Precatalysts for the Hydrogenation of Hindered, Unactivated Alkenes
inferred← citeshttps://doi.org/10.1021/acscatal.8b01972openalex-snapshot
Alkene Isomerization–Hydroboration Catalyzed by First-Row Transition-Metal (Mn, Fe, Co, and Ni) N-Phosphinoamidinate Complexes: Origin of Reactivity and Selectivity
inferred← citeshttps://doi.org/10.1021/acscatal.8b03717openalex-snapshot
Site-Selective Nickel-Catalyzed Hydrogen Isotope Exchange in N-Heterocycles and Its Application to the Tritiation of Pharmaceuticals
inferred← citeshttps://doi.org/10.1021/acscatal.9b00521openalex-snapshot
Migratory Reductive Acylation between Alkyl Halides or Alkenes and Alkyl Carboxylic Acids by Nickel Catalysis
inferred← citeshttps://doi.org/10.1021/acscatal.9b02230openalex-snapshot
An Electrochemically Promoted, Nickel-Catalyzed Mizoroki–Heck Reaction
inferred← citeshttps://doi.org/10.1021/acssuschemeng.2c04444openalex-snapshot
Sustainable Synthesis of Silicon Precursors Coupled with Hydrogen Delivery Based on Circular Economy via Molecular Cobalt-Based Catalysts
inferred← citeshttps://doi.org/10.1021/jacs.0c10333openalex-snapshot
NiH-Catalyzed Proximal-Selective Hydroamination of Unactivated Alkenes
inferred← citeshttps://doi.org/10.1021/jacs.1c01138openalex-snapshot
Merging NiH Catalysis and Inner-Sphere Metal-Nitrenoid Transfer for Hydroamidation of Alkynes
inferred← citeshttps://doi.org/10.1021/jacs.2c02343openalex-snapshot
Nickel-Catalyzed Regio- and Enantioselective Hydroamination of Unactivated Alkenes Using Carbonyl Directing Groups
inferred← citeshttps://doi.org/10.1021/jacs.5c14047openalex-snapshot
Highly Reduced Alkali-Metal Nickelates: Synthesis, Structure, Catalytic Applications, and Alkali-Metal Effects
inferred← citeshttps://doi.org/10.1021/jacs.6b12896openalex-snapshot
Benzyltriboronates: Building Blocks for Diastereoselective Carbon–Carbon Bond Formation
inferred← citeshttps://doi.org/10.1021/jacs.6b12938openalex-snapshot
Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes
inferred← citeshttps://doi.org/10.1021/jacs.6b13029openalex-snapshot
Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles
inferred← citeshttps://doi.org/10.1021/jacs.6b13346openalex-snapshot
C(sp2)–H Borylation of Fluorinated Arenes Using an Air-Stable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic Opportunities
inferred← citeshttps://doi.org/10.1021/jacs.7b08064openalex-snapshot
Remote Migratory Cross-Electrophile Coupling and Olefin Hydroarylation Reactions Enabled by in Situ Generation of NiH
inferred← citeshttps://doi.org/10.1021/jacs.8b06458openalex-snapshot
Mechanistic Interrogation of Co/Ni-Dual Catalyzed Hydroarylation
inferred← citeshttps://doi.org/10.1021/jacs.9b00939openalex-snapshot
Ni(I)–X Complexes Bearing a Bulky α-Diimine Ligand: Synthesis, Structure, and Superior Catalytic Performance in the Hydrogen Isotope Exchange in Pharmaceuticals
inferred← citeshttps://doi.org/10.1038/s41467-017-02472-6openalex-snapshot
Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
inferred← citeshttps://doi.org/10.1038/s41467-019-09783-wopenalex-snapshot
Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols
inferred← citeshttps://doi.org/10.1038/s41467-020-20888-5openalex-snapshot
NiH-catalyzed asymmetric hydroarylation of N-acyl enamines to chiral benzylamines
inferred← citeshttps://doi.org/10.1038/s41467-021-24094-9openalex-snapshot
Nickel-catalysed migratory hydroalkynylation and enantioselective hydroalkynylation of olefins with bromoalkynes
inferred← citeshttps://doi.org/10.1038/s41467-024-50743-wopenalex-snapshot
Nickel-catalyzed regiodivergent hydrosilylation of α-(fluoroalkyl)styrenes without defluorination
inferred← citeshttps://doi.org/10.1038/s41570-018-0001-2openalex-snapshot
Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration
inferred← citeshttps://doi.org/10.1039/c6nj02220kopenalex-snapshot
Coordination of o-benzosemiquinonate, o-iminobenzosemiquinonate, 4,4′-di-tert-butyl-2,2′-bipyridine and 1,10-phenanthroline anion radicals to oxidovanadium( iv )
inferred← citeshttps://doi.org/10.1039/c6nj02903eopenalex-snapshot
Glyoxalbis(2-methylmercaptoanil) complexes of nickel and ruthenium: radical versus non-radical states
inferred← citeshttps://doi.org/10.1039/c7cc01531copenalex-snapshot
Unexpected catalytic activity of simple triethylborohydrides in the hydrosilylation of alkenes
inferred← citeshttps://doi.org/10.1039/c7dt03226aopenalex-snapshot
Allowing the direct interaction of N-aryl α-diimines with a high valent metal chloride: one-pot WCl 6 -promoted formation of quinoxalinium salts
inferred← citeshttps://doi.org/10.1039/c7sc04687aopenalex-snapshot
Tuning the redox non-innocence of a phenalenyl ligand toward efficient nickel-assisted catalytic hydrosilylation
inferred← citeshttps://doi.org/10.1039/c8cc07641copenalex-snapshot
Highly-active, graphene-supported platinum catalyst for the solventless hydrosilylation of olefins
inferred← citeshttps://doi.org/10.1039/c8cy01487fopenalex-snapshot
Alkene hydrosilylation with supported and unsupported Ni nanoparticles: strong influence of the Ni environment on activity and selectivity
inferred← citeshttps://doi.org/10.1039/c8cy02427hopenalex-snapshot
Ni( i )–Ni( iii ) cycle in Buchwald–Hartwig amination of aryl bromide mediated by NHC-ligated Ni( i ) complexes
inferred← citeshttps://doi.org/10.1039/c8dt01857jopenalex-snapshot
Carbonyl and ester C–O bond hydrosilylation using κ 4 -diimine nickel catalysts
inferred← citeshttps://doi.org/10.1039/c8dt04608eopenalex-snapshot
Anti-Markovnikov terminal and gem -olefin hydrosilylation using a κ 4 -diimine nickel catalyst: selectivity for alkene hydrosilylation over ether C–O bond cleavage
inferred← citeshttps://doi.org/10.1039/c8nj00846aopenalex-snapshot
Activation of CN bonds by high-valent group 6 metal chlorides, including the conversion of an α-diimine into a functionalized imidazolium
inferred← citeshttps://doi.org/10.1039/c8sc02768dopenalex-snapshot
A β-diketiminate manganese catalyst for alkene hydrosilylation: substrate scope, silicone preparation, and mechanistic insight
inferred← citeshttps://doi.org/10.1039/c8sc04162hopenalex-snapshot
Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem -difluoroalkenes
inferred← citeshttps://doi.org/10.1039/d0cs00082eopenalex-snapshot
Asymmetric hydrogenation catalyzed by first-row transition metal complexes
inferred← citeshttps://doi.org/10.1039/d0cs00509fopenalex-snapshot
Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts
inferred← citeshttps://doi.org/10.1039/d0sc00997kopenalex-snapshot
Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates
inferred← citeshttps://doi.org/10.1039/d0sc01749copenalex-snapshot
Efficient and selective alkene hydrosilation promoted by weak, double Si–H activation at an iron center
inferred← citeshttps://doi.org/10.1039/d0sc02391dopenalex-snapshot
Cyclic metal(oid) clusters control platinum-catalysed hydrosilylation reactions: from soluble to zeolite and MOF catalysts
inferred← citeshttps://doi.org/10.1039/d1cy00191dopenalex-snapshot
Co 2 (CO) 8 as an efficient catalyst for the synthesis of functionalized polymethylhydrosiloxane oils and unconventional cross-linked materials
inferred← citeshttps://doi.org/10.1039/d1cy00920fopenalex-snapshot
Co 2 (CO) 8 and unsaturated epoxides as unexpected partners in generating functionalized siloxane oils and cross-linked materials
inferred← citeshttps://doi.org/10.1039/d1dt00399bopenalex-snapshot
Oxidation of Pd( ii ) with disilane in a palladium-catalyzed disilylation of aryl halides: a theoretical view
inferred← citeshttps://doi.org/10.1039/d1dt02879kopenalex-snapshot
Phosphorous-substituted redox-active ligands in base metal hydrosilylation catalysis
inferred← citeshttps://doi.org/10.1039/d1nj06133jopenalex-snapshot
Synthesis of aryl cobalt and iron complexes and their catalytic activity on hydrosilylation of alkenes
inferred← citeshttps://doi.org/10.1039/d2cc00377eopenalex-snapshot
Mn 2 (CO) 10 and UV light: a promising combination for regioselective alkene hydrosilylation at low temperature
inferred← citeshttps://doi.org/10.1039/d2cc03917fopenalex-snapshot
Oxime ester-enabled anti-Markovnikov hydrosilylation of alkenes
inferred← citeshttps://doi.org/10.1039/d2dt03471aopenalex-snapshot
Research on inorganic activators of dibromo Co-terpyridine complex precatalyst for hydrosilylation
inferred← citeshttps://doi.org/10.1039/d2qo01266aopenalex-snapshot
Regiodivergent hydrosilylation in the nickel(0)-catalyzed cyclization of 1,6-enynes
inferred← citeshttps://doi.org/10.1039/d3cc05033eopenalex-snapshot
Simply accessible platinum( ii ) complexes enabling alkene hydrosilylation at ppm catalyst loadings
inferred← citeshttps://doi.org/10.1039/d3dt04200fopenalex-snapshot
Preparation of silyl-terminated branched polyethylenes catalyzed by Brookhart's nickel diimine complex activated with hydrosilane/B(C 6 F 5 ) 3
inferred← citeshttps://doi.org/10.1039/d3gc02385kopenalex-snapshot
MnBr(CO) 5 : a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions
inferred← citeshttps://doi.org/10.1039/d3nj03878eopenalex-snapshot
Distinct selective alkene hydrosilylation catalyzed by acylenalato cobalt hydrides
inferred← citeshttps://doi.org/10.1039/d4gc04501gopenalex-snapshot
DIPEA-induced Si–H activation of siloxane for hydrosilylation polymerization via metal-free photocatalysis
inferred← citeshttps://doi.org/10.1039/d4qo01033gopenalex-snapshot
Nickel-catalyzed reductive cross-coupling of monofluoroalkyl triflates with aryl halides for monofluoroalkylated arenes
inferred← citeshttps://doi.org/10.1039/d4qo01579gopenalex-snapshot
Mechanistic insight into Ni( i )-catalyzed regioselective alkene hydroarylation: is it carbonickelation or hydronickelation?
inferred← citeshttps://doi.org/10.1039/d4ra08380fopenalex-snapshot
Recyclable and air-stable colloidal manganese nanoparticles catalyzed hydrosilylation of alkenes with tertiary silane
inferred← citeshttps://doi.org/10.1039/d4sc03364gopenalex-snapshot
Hydrogen atom abstraction as a synthetic route to a square planar Co II complex with a redox-active tetradentate PNNP ligand
inferred← citeshttps://doi.org/10.1039/d5cc03676copenalex-snapshot
Sustainable synthesis of hydrosilanes and alkoxysilanes in a sequential one-pot olefin hydrosilylation and dehydrogenative coupling with alcohol under phenoxyiminato cobalt( ii ) catalysis
inferred← citeshttps://doi.org/10.1039/d5sc02059jopenalex-snapshot
Catalytic alkoxysilylation of C–H bonds with tert -butyl-substituted alkoxysilyldiazenes
inferred← citeshttps://doi.org/10.1039/d6qi00025hopenalex-snapshot
Stable nickel complexes of a siliconoid/silylene hybrid ligand: competent hydrosilylation catalysts for terminal olefins
inferred← citeshttps://doi.org/10.1080/10426507.2018.1493480openalex-snapshot
The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins
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