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A new model for dioxygen binding in hemocyanin. Synthesis, characterization, and molecular structure of the .mu.-.eta.2:.eta.2 peroxo dinuclear copper(II) complexes, [Cu(HB(3,5-R2pz)3)]2(O2) (R = isopropyl and Ph)
Dioxygen-copper reactivity. Models for hemocyanin: Reversible O2 and CO binding to structurally characterized dicopper(I) complexes containing hydrocarbon-linked bis[2-(2-pyridyl)ethyl]amine units
Crystal Structure and Reversible O2-Binding of a Room Temperature Stable μ-η2:η2-Peroxodicopper(II) Complex of a Sterically Hindered Hexapyridine Dinucleating Ligand
Novel tert-Butyl Migration in Copper-Mediated Phenol Ortho-Oxygenation Implicates a Mechanism Involving Conversion of a 6-Hydroperoxy-2,4-cyclohexadienone Directly to an o-Quinone
Hydroxylation of a methyl group: synthesis of [Cu2(btmmO)2I]+ and of [Cu2(btmmO)2]2+ containing the novel ligand {bis(trimethylmethoxy)guanidino}propane (btmmO) by copper-assisted oxygen activation
Spectrophotometric determination of formation constants for the Cu–ethylenediamine–halogen (chloride and bromide) system and their catalytic effect on the oxidative coupling of 2,6-di-tert-butyl-phenol
Spectrophotometric determination of the formation constants of the cupric halogen complexes with 1,3-propanediamine and 1,4-butanediamine in methanol solution and their activity on the oxidative coupling of the 2,6-di-tert-butylphenol
A comparative study of the speciation in methanol solution and activity in the oxidative coupling of 2,6-di-tert-butylphenol presented by the complexes: Copper(II)-N,N′-di-tert-butylethylenediamine-halogen and some copper(II)-diamine-halogen complexes
Copper(II)-assisted hydrolysis of cyclic ureas: Transformation of 1-(pyridin-2-yl)-2,3,7,8-tetrahydro-1H-imidazo[2,1-b][1,3,5]triazepin-5(6H)-ones into N1-[1-(pyridin-2-yl)imidazolidin-2-ylidene]-ethane-1,2-diamine ligands
Ligand Effect on Reversible Conversion between Copper(I) and Bis(μ-oxo)dicopper(III) Complex with a Sterically Hindered Tetradentate Tripodal Ligand and Monooxygenase Activity of Bis(μ-oxo)dicopper(III) Complex
Bis(μ-oxo)dicopper(III) Complexes of a Homologous Series of Simple Peralkylated 1,2-Diamines: Steric Modulation of Structure, Stability, and Reactivity
Resonance Raman Investigation of Equatorial Ligand Donor Effects on the Cu 2 O 2 2+ Core in End-On and Side-On μ-Peroxo-Dicopper(II) and Bis-μ-oxo-Dicopper(III) Complexes
Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediateElectronic supplementary information (ESI) available: Experimental, crystallographic and computational details. See http://www.rsc.org/suppdata/cc/b4/b405358c/
Reaction with dioxygen of a Cu(i) complex of 1-benzyl-[3-(2′-pyridyl)]pyrazole triggers ethyl acetate hydrolysis: acetato-/pyrazolato-, dihydroxo- and diacetato-bridged Cu(ii) complexes
Unique Functions of Metal Complexes Inspired by Control of Coordination Environment around Metal Ions
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