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A Stabilized μ-η2:η2 Peroxodicopper(II) Complex with a Secondary Diamine Ligand and Its Tyrosinase-like Reactivity

https://doi.org/10.1021/ja026905p
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Reversible Dioxygen Binding and Phenol Oxygenation in a Tyrosinase Model System
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Is the Bis(-oxo)dicopper Core Capable of Hydroxylating an Arene?
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Reactivity of Copper(I) Complexes Towards Dioxygen
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Copper-Dioxygen and Copper-Oxo Species Relevant to Copper Oxygenases and Oxidases
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Biomimetic modeling of copper oxidase reactivity
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A New Cu(II) Side-on Peroxo Model Clarifies the Assignment of the Oxyhemocyanin Raman Spectrum
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Experimental Studies of the Interconversion of μ-η2:η2-Peroxo- and Bis(μ-oxo)dicopper Complexes
inferredcites →https://doi.org/10.1021/ja00030a025openalex-snapshot
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inferredcites →https://doi.org/10.1021/ja00212a031openalex-snapshot
Dioxygen-copper reactivity. Models for hemocyanin: Reversible O2 and CO binding to structurally characterized dicopper(I) complexes containing hydrocarbon-linked bis[2-(2-pyridyl)ethyl]amine units
inferredcites →https://doi.org/10.1021/ja002527hopenalex-snapshot
Differential Reactivity between Interconvertible Side-On Peroxo and Bis-μ-oxodicopper Isomers Using Peralkylated Diamine Ligands
inferredcites →https://doi.org/10.1021/ja0125265openalex-snapshot
Contrasting Copper−Dioxygen Chemistry Arising from Alike Tridentate Alkyltriamine Copper(I) Complexes
inferredcites →https://doi.org/10.1021/ja015702iopenalex-snapshot
Oxygenation of Phenols to Catechols by A (μ-η2:η2-Peroxo)dicopper(II) Complex: Mechanistic Insight into the Phenolase Activity of Tyrosinase
inferredcites →https://doi.org/10.1021/ja026047xopenalex-snapshot
Fine-Tuning of Copper(I)-Dioxygen Reactivity by 2-(2-Pyridyl)ethylamine Bidentate Ligands
inferredcites →https://doi.org/10.1021/ja972946nopenalex-snapshot
Irreversible Reduction of Dioxygen by Simple Peralkylated Diamine−Copper(I) Complexes: Characterization and Thermal Stability of a [Cu2(μ-O)2]2+ Core
inferredcites →https://doi.org/10.1021/ja980687bopenalex-snapshot
Investigation of the Reactive Oxygen Intermediate in an Arene Hydroxylation Reaction Performed by Xylyl-Bridged Binuclear Copper Complexes
inferredcites →https://doi.org/10.1021/ja981283mopenalex-snapshot
Highly Regioselective Oxidative Polymerization of 4-Phenoxyphenol to Poly(1,4-phenylene oxide) Catalyzed by Tyrosinase Model Complexes
inferredcites →https://doi.org/10.1021/ja981878hopenalex-snapshot
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inferredcites →https://doi.org/10.1021/ja983635vopenalex-snapshot
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inferredcites →https://doi.org/10.1021/ja9918425openalex-snapshot
Spectroscopic and Electronic Structural Studies of the Cu(III)2Bis-μ-oxo Core and Its Relation to the Side-On Peroxo-Bridged Dimer
inferredcites →https://doi.org/10.1021/ja992017ropenalex-snapshot
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inferredcites →https://doi.org/10.1021/ja992295qopenalex-snapshot
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A Trinuclear Intermediate in the Copper-Mediated Reduction of O 2 : Four Electrons from Three Coppers

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Orbital Analysis Of Oxo And Peroxo Dicopper Complexes Via Quantum Chemical Workflows In Mosgrid
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Structure, Spectroscopy, and Function of Tyrosinase; Comparison with Hemocyanin and Catechol Oxidase
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Organic Synthetic Methods Using Copper Oxygen Chemistry
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Developing Molecular Copper Complexes for Water Oxidation
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Structure, Spectroscopy, and Function of Tyrosinase; Comparison with Hemocyanin and Catechol Oxidase
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O 2 Reactivity at Model Copper Systems: Mimicking Tyrosinase Activity
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Katalytische Phenolhydroxylierung mit Sauerstoff: Substratvielfalt jenseits der Proteinmatrix von Tyrosinase
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Selective Ortho‐Hydroxylation–Defluorination of 2‐Fluorophenolates with a Bis(μ‐oxo)dicopper(III) Species
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Imidazolate‐Stabilized Cu(III): Dioxygen to Oxides at Type 3 Copper Sites
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Catalytic Phenol Hydroxylation with Dioxygen: Extension of the Tyrosinase Mechanism beyond the Protein Matrix
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Selective Ortho‐Hydroxylation–Defluorination of 2‐Fluorophenolates with a Bis(μ‐oxo)dicopper(III) Species
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Imidazolate‐Stabilized Cu(III): Dioxygen to Oxides at Type 3 Copper Sites
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Oxidative coupling of 2,6‐dimethylphenol catalyzed by copper(II) complexes in aqueous solution
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Quantitative Evaluation of d–π Interaction in Copper( i) Complexes and Control of Copper( i) –Dioxygen Reactivity
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Theoretical Study of the Oxidation of Phenolates by the [Cu 2 O 2 ( N , N ′‐di‐ tert ‐butylethylenediamine) 2 ] 2+ Complex
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Bioinspired Copper(I) Complexes that Exhibit Monooxygenase and Catechol Dioxygenase Activity
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Structure, Bonding, and Tyrosinase‐Like Reactivity of Copper Complexes Coordinated by Mononucleating Tridentate N−O−N Type Ligands
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Tuning of Copper( I )–Dioxygen Reactivity by Bis(guanidine) Ligands
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BOX Ligands in Biomimetic Copper‐Mediated Dioxygen Activation: A Hemocyanin Model
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Formation of Hybrid Guanidine‐Stabilized Bis(μ‐oxo)dicopper Cores in Solution: Electronic and Steric Perturbations
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Reactivity of Copper Complexes with Bis(piperidinyl)methane and Bis(quinolinyl)methane Ligands
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Anorganische Chemie 2002
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Organische Chemie 2002
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Dioxygen-Binding in Metalloproteins and Corresponding Models
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Kinetic characterization of a bioinspired, heterogeneously active macromolecular catalyst for phenol oxidation and coupling reactions
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Hydroxylation of p-substituted phenols by tyrosinase: Further insight into the mechanism of tyrosinase activity
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The complexes of multiimidazole with copper(I) display tyrosinase activity
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Hydroxylation of a methyl group: synthesis of [Cu2(btmmO)2I]+ and of [Cu2(btmmO)2]2+ containing the novel ligand {bis(trimethylmethoxy)guanidino}propane (btmmO) by copper-assisted oxygen activation
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Spectrophotometric determination of formation constants for the Cu–ethylenediamine–halogen (chloride and bromide) system and their catalytic effect on the oxidative coupling of 2,6-di-tert-butyl-phenol
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Spectrophotometric determination of the formation constants of the cupric halogen complexes with 1,3-propanediamine and 1,4-butanediamine in methanol solution and their activity on the oxidative coupling of the 2,6-di-tert-butylphenol
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A comparative study of the speciation in methanol solution and activity in the oxidative coupling of 2,6-di-tert-butylphenol presented by the complexes: Copper(II)-N,N′-di-tert-butylethylenediamine-halogen and some copper(II)-diamine-halogen complexes
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Copper(II)-assisted hydrolysis of cyclic ureas: Transformation of 1-(pyridin-2-yl)-2,3,7,8-tetrahydro-1H-imidazo[2,1-b][1,3,5]triazepin-5(6H)-ones into N1-[1-(pyridin-2-yl)imidazolidin-2-ylidene]-ethane-1,2-diamine ligands
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Cu-ZSM-5: A biomimetic inorganic model for methane oxidation
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A room temperature catalyst for toluene aliphatic C–H bond oxidation: Tripodal tridentate copper complex immobilized in mesoporous silica
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Synthesis and reactivity of (μ-η2:η2-peroxo)dicopper(II) complexes with dinucleating ligands: Hydroxylation of xylyl linker with a NIH shift
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Mechanism studies of oxidation and hydrolysis of Cu(I)–NHC and Ag–NHC in solution under air
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Structural and spectroscopic studies of three-coordinate copper(I) supported by bis(phosphino)borate ligands
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Steric-influenced fluxionality in monomeric two and three coordinate copper(I) complexes with a trans-chelating bis-pyrazole ligand
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Adenine supported hydroxyl-bridged dicopper core as a catalytically competent unit for phenol oxidation
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Ligand Influences in Copper-Dioxygen Complex-Formation and Substrate Oxidations
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A Biomimetic Mechanism for the Copper-Catalyzed Aerobic Oxygenation of 4-tert-Butylphenol
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Parallel Screening of Homogeneous Copper Catalysts for the Oxidation of Benzylic Alcohols with Molecular Oxygen in Aqueous Solutions
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Reactivity of Dioxygen−Copper Systems
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Aerobic Copper-Catalyzed Organic Reactions
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Ligand Effect on Reversible Conversion between Copper(I) and Bis(μ-oxo)dicopper(III) Complex with a Sterically Hindered Tetradentate Tripodal Ligand and Monooxygenase Activity of Bis(μ-oxo)dicopper(III) Complex
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Structures and Redox Reactivities of Copper Complexes of (2-Pyridyl)alkylamine Ligands. Effects of the Alkyl Linker Chain Length
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Bis(μ-oxo)dicopper(III) Complexes of a Homologous Series of Simple Peralkylated 1,2-Diamines: Steric Modulation of Structure, Stability, and Reactivity
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Copper−Dioxygen Adducts and the Side-on Peroxo Dicopper(II)/Bis(μ-oxo) Dicopper(III) Equilibrium: Significant Ligand Electronic Effects
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Bis(μ-oxo) Dicopper(III) Species of the Simplest Peralkylated Diamine: Enhanced Reactivity toward Exogenous Substrates
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Characterization of Two Distinct Adducts in the Reaction of a Nonheme Diiron(II) Complex with O2
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Resonance Raman Investigation of Equatorial Ligand Donor Effects on the Cu 2 O 2 2+ Core in End-On and Side-On μ-Peroxo-Dicopper(II) and Bis-μ-oxo-Dicopper(III) Complexes
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Tuning Copper−Dioxygen Reactivity and Exogenous Substrate Oxidations via Alterations in Ligand Electronics
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Oxidation Mechanism of Phenols by Dicopper−Dioxygen (Cu2/O2) Complexes
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Kinetic Evaluation of Phenolase Activity of Tyrosinase Using Simplified Catalytic Reaction System
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Synthesis of the Azaphilones Using Copper-Mediated Enantioselective Oxidative Dearomatization
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inferred← citeshttps://doi.org/10.1021/ja058117gopenalex-snapshot
Intramolecular Arene Hydroxylation versus Intermolecular Olefin Epoxidation by (μ-η2:η2-Peroxo)dicopper(II) Complex Supported by Dinucleating Ligand
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Controlling the Catalytic Aerobic Oxidation of Phenols
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Primary Amine Stabilization of a Dicopper(III) Bis(μ-oxo) Species: Modeling the Ligation in pMMO
inferred← citeshttps://doi.org/10.1021/ja807081dopenalex-snapshot
Toluene and Ethylbenzene Aliphatic C−H Bond Oxidations Initiated by a Dicopper(II)-μ-1,2-Peroxo Complex
inferred← citeshttps://doi.org/10.1021/ja807898hopenalex-snapshot
Reaction Coordinate of a Functional Model of Tyrosinase: Spectroscopic and Computational Characterization
inferred← citeshttps://doi.org/10.1021/ja809822copenalex-snapshot
Aliphatic C−H Bond Activation Initiated by a (μ-η 2 :η 2 -Peroxo)dicopper(II) Complex in Comparison with Cumylperoxyl Radical
inferred← citeshttps://doi.org/10.1021/om7012748openalex-snapshot
New Diimine−Copper Complexes: An Efficient and Simple Catalyst System for Buchwald N-Arylation of Indole
inferred← citeshttps://doi.org/10.1039/b210307aopenalex-snapshot
Theoretical study of phenol and 2-aminophenol docking at a model of the tyrosinase active site
inferred← citeshttps://doi.org/10.1039/b211517bopenalex-snapshot
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Complexity with simplicity: a steric continuum of chelating diamines with copper( i ) and dioxygen
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Alkane hydroperoxidation with peroxides catalysed by copper complexes
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Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediateElectronic supplementary information (ESI) available: Experimental, crystallographic and computational details. See http://www.rsc.org/suppdata/cc/b4/b405358c/
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Spectroscopic characterization of the oxo-transfer reaction from a bis(μ-oxo)dicopper( iii ) complex to triphenylphosphine
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Reaction with dioxygen of a Cu(i) complex of 1-benzyl-[3-(2′-pyridyl)]pyrazole triggers ethyl acetate hydrolysis: acetato-/pyrazolato-, dihydroxo- and diacetato-bridged Cu(ii) complexes
inferred← citeshttps://doi.org/10.1039/b802095gopenalex-snapshot
The first stereochemically nonrigid monomeric two-coordinate copper(i) complexes with homoleptic and heteroleptic “N2” donor set
inferred← citeshttps://doi.org/10.1039/c1dt11065aopenalex-snapshot
Efficient oxidative coupling of 2,6-disubstituted phenol catalyzed by a dicopper( ii ) complex
inferred← citeshttps://doi.org/10.1039/d1fd00071copenalex-snapshot
Phenolate-bonded bis(μ-oxido)-bis-copper( iii ) intermediates: hydroxylation and dehalogenation reactivities
inferred← citeshttps://doi.org/10.1055/s-0037-1609635openalex-snapshot
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inferred← citeshttps://doi.org/10.1055/sos-sd-218-00197openalex-snapshot
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inferred← citeshttps://doi.org/10.1080/02603590701572940openalex-snapshot
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inferred← citeshttps://doi.org/10.1126/science.1112081openalex-snapshot
Tyrosinase Reactivity in a Model Complex: An Alternative Hydroxylation Mechanism
inferred← citeshttps://doi.org/10.1134/s0022476614080150openalex-snapshot
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inferred← citeshttps://doi.org/10.1134/s2079978016010027openalex-snapshot
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