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Spectroscopic and Electronic Structural Studies of the Cu(III)2Bis-μ-oxo Core and Its Relation to the Side-On Peroxo-Bridged Dimer
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Outgoing claims: the papers this work cites, builds on, or argues with.
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Reactivity of Dioxygen−Copper Systems
inferred← citeshttps://doi.org/10.1021/cr9900275openalex-snapshot
Geometric and Electronic Structure/Function Correlations in Non-Heme Iron Enzymes
inferred← citeshttps://doi.org/10.1021/ic000248popenalex-snapshot
Ligand Macrocycle Structural Effects on Copper−Dioxygen Reactivity
inferred← citeshttps://doi.org/10.1021/ic010348aopenalex-snapshot
Geometric and Electronic Structure Contributions to Function in Bioinorganic Chemistry: Active Sites in Non-Heme Iron Enzymes
inferred← citeshttps://doi.org/10.1021/ic015539sopenalex-snapshot
A New Cu(II) Side-on Peroxo Model Clarifies the Assignment of the Oxyhemocyanin Raman Spectrum
inferred← citeshttps://doi.org/10.1021/ic020369kopenalex-snapshot
Copper Chemistry of β-Diketiminate Ligands: Monomer/Dimer Equilibria and a New Class of Bis(μ-oxo)dicopper Compounds
inferred← citeshttps://doi.org/10.1021/ic0345166openalex-snapshot
Ligand Effect on Reversible Conversion between Copper(I) and Bis(μ-oxo)dicopper(III) Complex with a Sterically Hindered Tetradentate Tripodal Ligand and Monooxygenase Activity of Bis(μ-oxo)dicopper(III) Complex
inferred← citeshttps://doi.org/10.1021/ic048584jopenalex-snapshot
Spectroscopic and Computational Studies on the Trans-μ-1,2-Peroxo-Bridged Dinickel(II) Species [{Ni(tmc)}2(O2)](OTf)2: Nature of End-On Peroxo−Nickel(II) Bonding and Comparison with Peroxo−Copper(II) Bonding
inferred← citeshttps://doi.org/10.1021/ic0498283openalex-snapshot
Solvent Effects on the Conversion of Dicopper(II) μ-η2:η2-Peroxo to Bis-μ-oxo Dicopper(III) Complexes: Direct Probing of the Solvent Interaction
inferred← citeshttps://doi.org/10.1021/ic050331iopenalex-snapshot
Bis(μ-oxo)dicopper(III) Complexes of a Homologous Series of Simple Peralkylated 1,2-Diamines: Steric Modulation of Structure, Stability, and Reactivity
inferred← citeshttps://doi.org/10.1021/ic0514243openalex-snapshot
Sequential Reaction Intermediates in Aliphatic C−H Bond Functionalization Initiated by a Bis(μ-oxo)dinickel(III) Complex
inferred← citeshttps://doi.org/10.1021/ic051800jopenalex-snapshot
Copper(II) Hexaaza Macrocyclic Binuclear Complexes Obtained from the Reaction of Their Copper(I) Derivates and Molecular Dioxygen
inferred← citeshttps://doi.org/10.1021/ic052185mopenalex-snapshot
Copper−Dioxygen Adducts and the Side-on Peroxo Dicopper(II)/Bis(μ-oxo) Dicopper(III) Equilibrium: Significant Ligand Electronic Effects
inferred← citeshttps://doi.org/10.1021/ic060050qopenalex-snapshot
Heterobimetallic Activation of Dioxygen: Characterization and Reactivity of Novel Cu(I)−Ge(II) Complexes
inferred← citeshttps://doi.org/10.1021/ic062206sopenalex-snapshot
Syntheses, Characterization, and Dioxygen Reactivities of Cu(I) Complexes with cis,cis-1,3,5-Triaminocyclohexane Derivatives: A Cu(III)2O2 Intermediate Exhibiting Higher C−H Activation
inferred← citeshttps://doi.org/10.1021/ic101515gopenalex-snapshot
Bis(μ-oxo) Dicopper(III) Species of the Simplest Peralkylated Diamine: Enhanced Reactivity toward Exogenous Substrates
inferred← citeshttps://doi.org/10.1021/ic701803gopenalex-snapshot
On the Performance of Ligand Field Molecular Mechanics for Model Complexes Containing the Peroxido-Bridged [Cu2O2]2+Center
inferred← citeshttps://doi.org/10.1021/ic702437copenalex-snapshot
Copper Dioxygen Adducts: Formation of Bis(μ-oxo)dicopper(III) versus (μ-1,2)Peroxodicopper(II) Complexes with Small Changes in One Pyridyl-Ligand Substituent
inferred← citeshttps://doi.org/10.1021/ic801568gopenalex-snapshot
H2O2-Reactivity of Copper(II) Complexes Supported by Tris[(pyridin-2-yl)methyl]amine Ligands with 6-Phenyl Substituents
inferred← citeshttps://doi.org/10.1021/ic9002466openalex-snapshot
Effects of Electron-Deficient β-Diketiminate and Formazan Supporting Ligands on Copper(I)-Mediated Dioxygen Activation
inferred← citeshttps://doi.org/10.1021/ja001591wopenalex-snapshot
Spectroscopic and Electronic Structural Studies of Blue Copper Model Complexes. 1. Perturbation of the Thiolate−Cu Bond
inferred← citeshttps://doi.org/10.1021/ja001592oopenalex-snapshot
Spectroscopic and Electronic Structural Studies of Blue Copper Model Complexes. 2. Comparison of Three- and Four-Coordinate Cu(II)−Thiolate Complexes and Fungal Laccase
inferred← citeshttps://doi.org/10.1021/ja002527hopenalex-snapshot
Differential Reactivity between Interconvertible Side-On Peroxo and Bis-μ-oxodicopper Isomers Using Peralkylated Diamine Ligands
inferred← citeshttps://doi.org/10.1021/ja004166bopenalex-snapshot
Dioxygen Binding to Deoxyhemocyanin: Electronic Structure and Mechanism of the Spin-Forbidden Two-Electron Reduction of O 2
inferred← citeshttps://doi.org/10.1021/ja0104094openalex-snapshot
Formation, Characterization, and Reactivity of Bis(μ-oxo)dinickel(III) Complexes Supported by A Series of Bis[2-(2-pyridyl)ethyl]amine Ligands
inferred← citeshttps://doi.org/10.1021/ja0125265openalex-snapshot
Contrasting Copper−Dioxygen Chemistry Arising from Alike Tridentate Alkyltriamine Copper(I) Complexes
inferred← citeshttps://doi.org/10.1021/ja015721sopenalex-snapshot
C−H Bond Activation of External Substrates with a Bis(μ-oxo)dicopper(III) Complex
inferred← citeshttps://doi.org/10.1021/ja016209+openalex-snapshot
Dioxygen Activation by a Nickel Thioether Complex: Characterization of a NiIII2(μ-O)2 Core
inferred← citeshttps://doi.org/10.1021/ja017204fopenalex-snapshot
A Synthetic Model for the Putative FeIV2O2 Diamond Core of Methane Monooxygenase Intermediate Q
inferred← citeshttps://doi.org/10.1021/ja017820bopenalex-snapshot
β-Diketiminate Ligand Backbone Structural Effects on Cu(I)/O2 Reactivity: Unique Copper−Superoxo and Bis(μ-oxo) Complexes
inferred← citeshttps://doi.org/10.1021/ja021137nopenalex-snapshot
Spectroscopic Study of [Fe2O2(5-Et3-TPA)2]3+: Nature of the Fe2O2 Diamond Core and Its Possible Relevance to High-Valent Binuclear Non-Heme Enzyme Intermediates
inferred← citeshttps://doi.org/10.1021/ja026047xopenalex-snapshot
Fine-Tuning of Copper(I)-Dioxygen Reactivity by 2-(2-Pyridyl)ethylamine Bidentate Ligands
inferred← citeshttps://doi.org/10.1021/ja026905popenalex-snapshot
A Stabilized μ-η2:η2 Peroxodicopper(II) Complex with a Secondary Diamine Ligand and Its Tyrosinase-like Reactivity
inferred← citeshttps://doi.org/10.1021/ja027049kopenalex-snapshot
Spectroscopic and Computational Studies on [(PhTttBu)2Ni2(μ-O)2]: Nature of the Bis-μ-oxo (Ni3+)2 “Diamond” Core
inferred← citeshttps://doi.org/10.1021/ja027164vopenalex-snapshot
Snapshots of Dioxygen Activation by Copper: The Structure of a 1:1 Cu/O2 Adduct and Its Use in Syntheses of Asymmetric Bis(μ-oxo) Complexes
inferred← citeshttps://doi.org/10.1021/ja0276366openalex-snapshot
Resonance Raman Investigation of Equatorial Ligand Donor Effects on the Cu 2 O 2 2+ Core in End-On and Side-On μ-Peroxo-Dicopper(II) and Bis-μ-oxo-Dicopper(III) Complexes
inferred← citeshttps://doi.org/10.1021/ja045191aopenalex-snapshot
Substrate Oxidation by Copper−Dioxygen Adducts: Mechanistic Considerations
inferred← citeshttps://doi.org/10.1021/ja047158uopenalex-snapshot
Selective Oxidation of Methane by the Bis(μ-oxo)dicopper Core Stabilized on ZSM-5 and Mordenite Zeolites
inferred← citeshttps://doi.org/10.1021/ja049106aopenalex-snapshot
Nature of the Peroxo Intermediate of the W48F/D84E Ribonucleotide Reductase Variant: Implications for O 2 Activation by Binuclear Non-Heme Iron Enzymes
inferred← citeshttps://doi.org/10.1021/ja050865iopenalex-snapshot
Reactions of the Peroxo Intermediate of Soluble Methane Monooxygenase Hydroxylase with Ethers
inferred← citeshttps://doi.org/10.1021/ja056740vopenalex-snapshot
μ-η2:η2-Peroxodicopper(II) Complex with a Secondary Diamine Ligand: A Functional Model of Tyrosinase
inferred← citeshttps://doi.org/10.1021/ja057745vopenalex-snapshot
Effects of Thioether Substituents on the O2 Reactivity of β-Diketiminate−Cu(I) Complexes: Probing the Role of the Methionine Ligand in Copper Monooxygenases
inferred← citeshttps://doi.org/10.1021/ja071744gopenalex-snapshot
Heterobimetallic Dioxygen Activation: Synthesis and Reactivity of Mixed Cu−Pd and Cu−Pt Bis(μ-oxo) Complexes
inferred← citeshttps://doi.org/10.1021/ja4048762openalex-snapshot
Precursor Transformation during Molecular Oxidation Catalysis with Organometallic Iridium Complexes
inferred← citeshttps://doi.org/10.1021/ja406721aopenalex-snapshot
Access to a Cu II –O–Cu II Motif: Spectroscopic Properties, Solution Structure, and Reactivity
inferred← citeshttps://doi.org/10.1021/ja4078717openalex-snapshot
L-Edge X-ray Absorption Spectroscopy and DFT Calculations on Cu2O2 Species: Direct Electrophilic Aromatic Attack by Side-on Peroxo Bridged Dicopper(II) Complexes
inferred← citeshttps://doi.org/10.1021/ja508630dopenalex-snapshot
Primary Amine Stabilization of a Dicopper(III) Bis(μ-oxo) Species: Modeling the Ligation in pMMO
inferred← citeshttps://doi.org/10.1021/ja804339mopenalex-snapshot
Defining the Electronic and Geometric Structure of One-Electron Oxidized Copper−Bis-phenoxide Complexes
inferred← citeshttps://doi.org/10.1021/ja807809xopenalex-snapshot
Phenolate Hydroxylation in a Bis(μ-oxo)dicopper(III) Complex: Lessons from the Guanidine/Amine Series
inferred← citeshttps://doi.org/10.1021/ja807898hopenalex-snapshot
Reaction Coordinate of a Functional Model of Tyrosinase: Spectroscopic and Computational Characterization
inferred← citeshttps://doi.org/10.1021/ja994406ropenalex-snapshot
Spectroscopic and Electronic Structure Description of the Reduced Binuclear Non-Heme Iron Active Site in Ribonucleotide Reductase fromE.coli: Comparison to Reduced Δ9Desaturase and Electronic Structure Contributions to Differences in O2Reactivity
inferred← citeshttps://doi.org/10.1021/jacs.1c12799openalex-snapshot
Controlling the Direction of S-Nitrosation versus Denitrosation: Reversible Cleavage and Formation of an S–N Bond within a Dicopper Center
inferred← citeshttps://doi.org/10.1021/jacs.3c13649openalex-snapshot
Divergent Bimetallic Mechanisms in Copper(II)-Mediated C–C, N–N, and O–O Oxidative Coupling Reactions
inferred← citeshttps://doi.org/10.1021/jacs.5c01897openalex-snapshot
Iodine-Induced Redirection of Active Sources in Cu-Based Catalysts during Efficient and Stable Water Oxidation
inferred← citeshttps://doi.org/10.1021/jacs.6b12990openalex-snapshot
Substrate and Lewis Acid Coordination Promote O–O Bond Cleavage of an Unreactive L2CuII2(O22–) Species to Form L2CuIII2(O)2 Cores with Enhanced Oxidative Reactivity
inferred← citeshttps://doi.org/10.1021/jacs.7b00210openalex-snapshot
Determination of the Cu(III)–OH Bond Distance by Resonance Raman Spectroscopy Using a Normalized Version of Badger’s Rule
inferred← citeshttps://doi.org/10.1021/jacs.7b06472openalex-snapshot
Methane to Methanol: Structure–Activity Relationships for Cu-CHA
inferred← citeshttps://doi.org/10.1021/jacs.9b03710openalex-snapshot
Unraveling Oxygen Evolution in Li-Rich Oxides: A Unified Modeling of the Intermediate Peroxo/Superoxo-like Dimers
inferred← citeshttps://doi.org/10.1021/jacsau.2c00014openalex-snapshot
DFT Mechanistic Insights into Aldehyde Deformylations with Biomimetic Metal–Dioxygen Complexes: Distinct Mechanisms and Reaction Rules
inferred← citeshttps://doi.org/10.1021/jp056791eopenalex-snapshot
Theoretical Models on the Cu2O2 Torture Track: Mechanistic Implications for Oxytyrosinase and Small-Molecule Analogues
inferred← citeshttps://doi.org/10.1021/jp9040716openalex-snapshot
Oxidation of Copper(I) Hexaaza Macrocyclic Dinuclear Complexes
inferred← citeshttps://doi.org/10.1038/nchem.1284openalex-snapshot
Self-assembly of the oxy-tyrosinase core and the fundamental components of phenolic hydroxylation
inferred← citeshttps://doi.org/10.1038/s41467-023-42646-zopenalex-snapshot
Active oxygen species mediate the iron-promoting electrocatalysis of oxygen evolution reaction on metal oxyhydroxides
inferred← citeshttps://doi.org/10.1039/b003776lopenalex-snapshot
26 Mechanisms of reactions in solution
inferred← citeshttps://doi.org/10.1039/b105244fopenalex-snapshot
Dioxygen activation by a neutral β-diketiminato copper(i) ethylene complex
inferred← citeshttps://doi.org/10.1039/b210193aopenalex-snapshot
The chemistry and biochemistry of the copper–radical interaction
inferred← citeshttps://doi.org/10.1039/b300201mopenalex-snapshot
Complexity with simplicity: a steric continuum of chelating diamines with copper( i ) and dioxygen
inferred← citeshttps://doi.org/10.1039/b404640dopenalex-snapshot
Mixed metal bis(μ-oxo) complexes with [CuM(μ-O) 2 ] n+ (M = Ni( iii ) or Pd( ii )) cores
inferred← citeshttps://doi.org/10.1039/b406692hopenalex-snapshot
Spectroscopic characterization of the oxo-transfer reaction from a bis(μ-oxo)dicopper( iii ) complex to triphenylphosphine
inferred← citeshttps://doi.org/10.1039/b418856jopenalex-snapshot
Vibrational and electronic structure of the dinuclear bis(µ-nitrido) vanadium( v ) complex [V(N{N″} 2 )(µ-N)] 2 : spectroscopic properties of the M 2 (µ-N) 2 diamond core
inferred← citeshttps://doi.org/10.1039/b603285kopenalex-snapshot
Spectroscopic and kinetic studies of the reaction of [CuI(6-PhTPA)]+ with O2
inferred← citeshttps://doi.org/10.1039/b715590eopenalex-snapshot
Synthesis and reactivity of copper( i ) complexes with an ethylene-bridged bis(imidazolin-2-imine) ligand
inferred← citeshttps://doi.org/10.1039/c005500jopenalex-snapshot
Copper dioxygen (bio)inorganic chemistry
inferred← citeshttps://doi.org/10.1039/c6sc04820jopenalex-snapshot
Acid/base triggered interconversion of μ-η 2 :η 2 -peroxido and bis(μ-oxido) dicopper intermediates capped by proton-responsive ligands
inferred← citeshttps://doi.org/10.1039/c7cp00241fopenalex-snapshot
Corrosion inhibition of copper in aqueous chloride solution by 1H-1,2,3-triazole and 1,2,4-triazole and their combinations: electrochemical, Raman and theoretical studies
inferred← citeshttps://doi.org/10.1039/c8cy02414fopenalex-snapshot
Methane selective oxidation to methanol by metal-exchanged zeolites: a review of active sites and their reactivity
inferred← citeshttps://doi.org/10.1039/c8sc01410hopenalex-snapshot
CuCl/TMEDA/nor-AZADO-catalyzed aerobic oxidative acylation of amides with alcohols to produce imides
inferred← citeshttps://doi.org/10.1039/c9cc02982fopenalex-snapshot
Exclusive imidazole ligation to CuIII2O 2 and Cu III CuII2O 2 cores
inferred← citeshttps://doi.org/10.1039/c9cy01471copenalex-snapshot
One step phenol synthesis from benzene catalysed by nickel( ii ) complexes
inferred← citeshttps://doi.org/10.1039/d0dt01001dopenalex-snapshot
Theoretical rationalization for the equilibrium between (μ–η 2 :η 2 -peroxido)Cu II Cu II and bis(μ-oxido)Cu III Cu III complexes: perturbational effects from ligand frameworks
inferred← citeshttps://doi.org/10.1039/d1fd00071copenalex-snapshot
Phenolate-bonded bis(μ-oxido)-bis-copper( iii ) intermediates: hydroxylation and dehalogenation reactivities
inferred← citeshttps://doi.org/10.1039/d4cp01309copenalex-snapshot
Towards reliable and efficient modeling of [Cu 2 O 2 ] 2+ -based compound electronic structures with the partially fixed reference space protocols
inferred← citeshttps://doi.org/10.1039/d5cs00544bopenalex-snapshot
Mechanism of oxidative stress and neurotoxicity associated with heme and copper–Aβ relevant to Alzheimer's disease
inferred← citeshttps://doi.org/10.1039/d5ra03248bopenalex-snapshot
Increased functional unit flexibility and solvent accessibility favours oxygen capture in molluscan hemocyanin
inferred← citeshttps://doi.org/10.1055/s-0037-1609635openalex-snapshot
Cu(III)-Mediated Aerobic Oxidations
inferred← citeshttps://doi.org/10.1063/1.2123388openalex-snapshot
Coordination-complex polymer as an organic conductor for organic light-emitting diodes
inferred← citeshttps://doi.org/10.1073/pnas.0737180100openalex-snapshot
Superoxo, μ-peroxo, and μ-oxo complexes from heme/O 2 and heme-Cu/O 2 reactivity: Copper ligand influences in cytochrome c oxidase models
inferred← citeshttps://doi.org/10.1073/pnas.0910461106openalex-snapshot
A [Cu 2 O] 2+ core in Cu-ZSM-5, the active site in the oxidation of methane to methanol
inferred← citeshttps://doi.org/10.1088/1742-6596/190/1/012201openalex-snapshot
Characterization of the optically excited state of a bis (μ-oxo)-dicopper(III) species mimicking the hemocyanin and tyrosinase active sites
inferred← citeshttps://doi.org/10.1126/science.1112081openalex-snapshot
Tyrosinase Reactivity in a Model Complex: An Alternative Hydroxylation Mechanism
inferred← citeshttps://doi.org/10.1246/bcsj.20100124openalex-snapshot
Resonance Raman Spectra of β-Diketiminatocopper(II) Complexes
inferred← citeshttps://doi.org/10.1246/bcsj.75.1657openalex-snapshot
Inorganic Chemistry Based on Tp Ligands —From Dioxygen Complexes to Organometallic Systems—
inferred← citeshttps://doi.org/10.1246/bcsj.75.2081openalex-snapshot
Dioxygen Activation by Copper Complexes. Mechanistic Insights into Copper Monooxygenases and Copper Oxidases
inferred← citeshttps://doi.org/10.1246/cl.2000.1172openalex-snapshot
Tetrahedral Distortion in Copper(II) Complexes of (−)-Sparteine and Its Effect on the Oxygen Adduct Formation
inferred← citeshttps://doi.org/10.1246/cl.2002.416openalex-snapshot
Modulation of the Copper-Dioxygen Reactivity by Stereochemical Effect of Tetradentate Tripodal Ligands
inferred← citeshttps://doi.org/10.1515/irm-2012-0004openalex-snapshot
Metal-oxo-mediated O-O bond formation reactions in chemistry and biology
inferred← citeshttps://doi.org/10.3390/inorganics6040114openalex-snapshot
Fluorescent Bis(guanidine) Copper Complexes as Precursors for Hydroxylation Catalysis
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