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Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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The Chemistry of Organic Silicon Compounds
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Asymmetric Hydrogenations (Nobel Lecture) Copyright© The Nobel Foundation 2002. We thank the Nobel Foundation, Stockholm, for permission to print this lecture.
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Asymmetric Catalysis: Science and Opportunities (Nobel Lecture) Copyright© The Nobel Foundation 2002. We thank the Nobel Foundation, Stockholm, for permission to print this lecture.
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Searching for New Reactivity (Nobel Lecture) Copyright© The Nobel Foundation 2002. We thank the Nobel Foundation, Stockholm, for permission to print this lecture. Adapted with the permission of the editors from “Coelacanths and Catalysis”: K. B. Sharpless, Tetrahedron 1994, 50, 4235.
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Covalence and the Orbital Reduction Factor, k , in Magnetochemistry
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Applied Homogeneous Catalysis with Organometallic Compounds
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Asymmetric Catalysis: Science and Opportunities (Nobel Lecture 2001)
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Asymmetric Hydrogenations (Nobel Lecture 2001)
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Dinitrogen‐Transition Metal Complexes: Synthesis, Properties, and Significance
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Zwitterionic Relatives to the Classic [(P–P)Rh(solv) 2 ] + Ions: Neutral Catalysts Active for HE Bond Additions to Olefins (E=C, Si, B)
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Catalysis‐Based Total Synthesis of Latrunculin B
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Eisenkomplexe als Modellverbindungen zur homogenen Hydrierung von Kohlenmonoxid
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Diazadienes as Controlling Ligands in Catalysis, 51). Synthesis of Chiral Diazadienes R* – N = CR' – CR' = N – R*
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The Reduction of [Fe(CO)2L2X2] (L = P(OMe)3, P(OiPr)3, PEt3; X = Br, I)—From Iron( II ) to Iron(0) via Stable Iron( I ) Intermediates
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Oligomerisation of Ethylene to Linear α‐Olefins by new Cs‐ and C1‐Symmetric [2,6‐Bis(imino)pyridyl]iron and ‐cobalt Dichloride Complexes
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Chemistry with ADF
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Measurement of magnetic susceptibility and magnetic moment of paramagnetic molecules in solution by high-field fourier transform NMR spectroscopy
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Symmetry and spectroscopy; an introduction to vibrational and electronic spectroscopy
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The crystal and molecular structure of [bis(diphenylphosphino)ethane]tricarbonyliron(0)
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Comprehensive Coordination Chemistry
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Completely selective synthesis of (E)-β-(triethylsilyl) styrenes by Fe3(CO)12-catalyzed reaction of styrenes with triethylsilane
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Übergangsmetall-silyl-komplexe L. darstellung, struktur und reaktivität der Trihydrido-Silyl-und -Stannyl-Komplexe L3FeH3(ER3) (E =Si,
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Asymmetric catalysis in organic synthesis
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Ligand field interpretation of some cases of pentacoordination
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The hydrosilation of olefins catalzed by some rhodium and cobalt complexes
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Addition, substitution, and telomerization reactions of olefins in the presence of metal carbonyls or colloidal iron
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An AB initio treatment of the dependence on amine basicity of the relative energies of neutral orthoamide intermediates in amide hydrolysis.
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NMR studies of rigid bicyclic systems. III. Assignment of chemical shift values in the NMR spectrum of norbornane
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Homogeneous Catalysis of Hydrosilation by Transition Metals
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η2 Coordination of Si–H σ Bonds to Transition Metals
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Bis(dimethylphosphino)methane complexes of iron and ruthenium
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Origins, Current Status, and Future Challenges of Green Chemistry
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On Inventing Reactions for Atom Economy
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Stereochemically nonrigid structures
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Electron-transfer mechanisms for organometallic intermediates in catalytic reactions
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Iridium compounds in catalysis
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Asymmetric Catalysis. A Comparative Study of the Mechanisms of Intramolecular Hydroacylation and Hydrosilation
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Dinitrogen complexes of the transition metals
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Hydrogenation of organic compounds using homogeneous catalysts
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Open-Shell Organometallics as a Bridge between Werner-Type and Low-Valent Organometallic Complexes. The Effect of the Spin State on the Stability, Reactivity, and Structure
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Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal Silyl Compounds
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Structure and stereodynamics of iron carbonyl phosphine or arsine Fe(CO)4L complexes (L = P(o-tolyl)3, As(o-tolyl)3, P(o-tolyl)2CH2Ph, (o-tolyl)2PP(o-tolyl)2)
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Reduction of Dinitrogen to Ammonia and Hydrazine in Iron(0) and Molybdenum(0) Complexes Containing the N(CH2CH2PPh2)3 Ligand. Crystal Structures of [FeH(L)(N(CH2CH2PPh2)3)][BPh4] (L = N2, CO)
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Pentacoordinate iron tricarbonyl complexes of diphosphine ligands with bite angles greater than 120.degree.
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Nuclear magnetic resonance and molecular structural studies of trans-P(OCH2)3PFe(CO)3P(OCH2)3P
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Conformational behavior of ligated tris(dialkylamino)phosphines. X-ray crystal structures of (Me2N)3PFe(CO)4 at 21.degree.C and of [(Me2N)3P]2Fe(CO)3 at -35.degree.C
inferredcites →https://doi.org/10.1021/ja00093a022openalex-snapshot
Pentakis(.eta.1-phosphinine)iron: Synthesis, Structure, and Mode of Formation
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Regioselection and Enantioselection in Organolanthanide-Catalyzed Olefin Hydrosilylation. A Kinetic and Mechanistic Study
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Pentacarbonyliron(0) photocatalyzed hydrogenation and isomerization of olefins
inferredcites →https://doi.org/10.1021/ja00741a070openalex-snapshot
Versatile synthesis of cyclopentenones
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Iron carbonyl catalyzed isomerization of 3-ethyl-1-pentene. Multiple olefin isomerizations via a .pi.-allyl metal hydride intermediate
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Stereochemical rigidity in ML5 complexes. I. Detailed line-shape analysis for pentakis(trimethyl phosphite)rhodium(1+) tetraphenyl borate(1-) and other rhodium(I) complexes
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Intramolecular rearrangements in neutral ML5 species
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Model ligands for square-planar and square-pyramidal complexes
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Formation of an unstable dinitrogen complex of ruthenium(II)
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The Structure of Five-Coordinated High-Spin Complexes of Nickel(II) and Cobalt(II) with N-β-Diethylamineethyl-5-chlorosalicylaldimine1
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Iron-Catalyzed Cross-Coupling Reactions
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Dinitrogen Chemistry from Trigonally Coordinated Iron and Cobalt Platforms
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Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a New Hydrosilylation Mechanism
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Highly Selective Asymmetric Hydrogenation Using a Three Hindered Quadrant Bisphosphine Rhodium Catalyst
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Synthesis and Characterization of Chelating Bis(silane) Complexes [RuH2{(η2-HSiMe2)2X}(PCy3)2] (X = C6H4, O) Containing Two Ru−(η2-Si−H) Bonds
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Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene
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Iron and Cobalt Ethylene Polymerization Catalysts Bearing 2,6-Bis(Imino)Pyridyl Ligands: Synthesis, Structures, and Polymerization Studies
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Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Olefins with a Cationic Zirconocene Catalyst
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Alkyl Rearrangement Processes in Organozirconium Complexes. Observation of Internal Alkyl Complexes during Hydrozirconation
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Selective hydrosilylation of alkenes catalyzed by an organoyttrium complex
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Iron-Catalyzed Cross-Coupling Reactions. A Scalable Synthesis of the Immunosuppressive Agent FTY720
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Selective Iron-Catalyzed Cross-Coupling Reactions of Grignard Reagents with Enol Triflates, Acid Chlorides, and Dichloroarenes
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Iron-Catalyzed Grignard Cross-Coupling with Alkyl Halides Possessing β-Hydrogens
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Selective hydrogenation of 1-alkynes to alkenes catalyzed by an iron(II) cis-hydride .eta.2-dihydrogen complex. A case of intramolecular reaction between .eta.2-H2 and .sigma.-vinyl ligands
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Synthesis and reactivity of bidentate phosphine iron complex [(C2F5)2PCH2CH2P(C2F5)2]Fe(CO)3
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Synthesis, Reactivity, and Solid State Structures of Four-Coordinate Iron(II) and Manganese(II) Alkyl Complexes
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Safe and Convenient Procedure for Solvent Purification
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Synthesis and Structures of Tris[2-(dimethylamino)phenyl]silane and -germane Compounds
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Investigation of the Regioselectivity of Alkene Hydrosilylation Catalyzed by Organolanthanide and Group 3 Metallocene Complexes
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Lewis Acid-Catalyzed Regio- and Stereoselective Hydrosilylation of Alkenes with Trialkylsilanes
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Theoretical Chemistry
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Synthesis, structure and reactions of a dinitrogen complex of iron(0), [Fe(N2)(depe)2] (depe = Et2PCH2CH2PEt2)
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Solvent-free ketone hydrogenations catalyzed by molybdenum complexesElectronic supplementary information (ESI) available: additional spectroscopic data and description of the synthetic procedures. See http://www.rsc.org/suppdata/cc/b4/b401760a/
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A ruthenium(II) dinitrogen complex
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Reaction of bis(cyclo-octa-1,5-diene)iron with trimethyl phosphite, phosphorus trifluoride, t-butyl isocyanide, carbon monoxide, and bis-1,2-(diphenylphosphino)ethane; the synthesis of [Fe(N2)(diphos)2]
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Isolation of a zerovalent iron dinitrogen complex with 1,2-bis(diethylphosphino)ethane ligands
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LV.—Note on a volatile compound of iron with carbonic oxide
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Bis[1,2-bis(dimethylphosphino)ethane]dihydrogenhydridoiron(II) tetraphenylborate as a model for the function of nitrogenases
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Stereochemistry of Aluminum Chloride Catalyzed Hydrosilylation of Methylcyclohexenes
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AN X-RAY STRUCTURAL STUDY OF THE FLUXIONAL MOLECULE [BIS(DIPHENYLPHOSPHINO)METHANE]TRICARBONYLIRON
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Density-functional exchange-energy approximation with correct asymptotic behavior
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Density-functional approximation for the correlation energy of the inhomogeneous electron gas
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Practical Approaches to Green Solvents
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Toward Greener Chemistry
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Accurate spin-dependent electron liquid correlation energies for local spin density calculations: a critical analysis
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Silicon in organic, organometallic, and polymer chemistry

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Anti-Markovnikov Hydrosilylation and Markovnikov Hydroboration of Alkenes by a Phenanthroline-Based Tridentate Manganese(Ii) Catalyst
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Phenylsilane
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Hydrosilylation
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Chemoselective Reduction of Amides and Imides
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inferred← citeshttps://doi.org/10.1002/ange.200804400openalex-snapshot
[FeFe]‐Hydrogenase Models and Hydrogen: Oxidative Addition of Dihydrogen and Silanes
inferred← citeshttps://doi.org/10.1002/ange.200901930openalex-snapshot
Präformierte π‐Allyl‐Eisen‐Komplexe als potente, definierte Katalysatoren für die allylische Substitution
inferred← citeshttps://doi.org/10.1002/ange.200905025openalex-snapshot
Hydrosilane Reduction of Tertiary Carboxamides by Iron Carbonyl Catalysts
inferred← citeshttps://doi.org/10.1002/ange.201003946openalex-snapshot
Exploiting Non‐Innocent Ligands to Prepare Masked Palladium(0) Complexes
inferred← citeshttps://doi.org/10.1002/ange.201007271openalex-snapshot
Neue Trends bei der Katalyse mit definierten niedervalenten Eisenkomplexen
inferred← citeshttps://doi.org/10.1002/ange.201007406openalex-snapshot
Efficient Hydrogenation of Ketones Catalyzed by an Iron Pincer Complex
inferred← citeshttps://doi.org/10.1002/ange.201100145openalex-snapshot
Selektive Reduktion von Carbonsäurederivaten durch katalytische Hydrosilylierung
inferred← citeshttps://doi.org/10.1002/ange.201201360openalex-snapshot
Knölker’s Iron Complex: An Efficient In Situ Generated Catalyst for Reductive Amination of Alkyl Aldehydes and Amines
inferred← citeshttps://doi.org/10.1002/ange.201201787openalex-snapshot
Katalytische selektive Synthese
inferred← citeshttps://doi.org/10.1002/ange.201203362openalex-snapshot
H2 Activation and Hydride Transfer to Olefins by Al(C6F5)3‐Based Frustrated Lewis Pairs
inferred← citeshttps://doi.org/10.1002/ange.201204100openalex-snapshot
Redoxaktive Liganden in der Katalyse
inferred← citeshttps://doi.org/10.1002/ange.201205152openalex-snapshot
Iron‐Catalyzed Polymerization of Isoprene and Other 1,3‐Dienes
inferred← citeshttps://doi.org/10.1002/ange.201206051openalex-snapshot
Mild and Homogeneous Cobalt‐Catalyzed Hydrogenation of CC, CO, and CN Bonds
inferred← citeshttps://doi.org/10.1002/ange.201210347openalex-snapshot
Iron‐Catalyzed, Atom‐Economical, Chemo‐ and Regioselective Alkene Hydroboration with Pinacolborane
inferred← citeshttps://doi.org/10.1002/ange.201306243openalex-snapshot
Silver‐Catalyzed Hydrogenation of Aldehydes in Water
inferred← citeshttps://doi.org/10.1002/ange.201306629openalex-snapshot
Iron Pincer Complex Catalyzed, Environmentally Benign, E‐Selective Semi‐Hydrogenation of Alkynes
inferred← citeshttps://doi.org/10.1002/ange.201308967openalex-snapshot
Heteroatom‐freie Arencobalt‐ und Areneisen‐Katalysatoren für Hydrierungen
inferred← citeshttps://doi.org/10.1002/ange.201309421openalex-snapshot
A Coordination Compound of Ge0 Stabilized by a Diiminopyridine Ligand
inferred← citeshttps://doi.org/10.1002/ange.201311221openalex-snapshot
Unprecedented Iron‐Catalyzed Ester Hydrogenation. Mild, Selective, and Efficient Hydrogenation of Trifluoroacetic Esters to Alcohols Catalyzed by an Iron Pincer Complex
inferred← citeshttps://doi.org/10.1002/ange.201404677openalex-snapshot
(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low‐Coordinate Iron(0) Reagents
inferred← citeshttps://doi.org/10.1002/ange.201405080openalex-snapshot
Discovery of Highly Selective Alkyne Semihydrogenation Catalysts Based on First‐Row Transition‐Metallated Porous Organic Polymers
inferred← citeshttps://doi.org/10.1002/ange.201411884openalex-snapshot
Iron‐Catalyzed Asymmetric Hydrosilylation of 1,1‐Disubstituted Alkenes
inferred← citeshttps://doi.org/10.1002/ange.201502418openalex-snapshot
Cobalt‐Catalyzed Hydrogenation of Esters to Alcohols: Unexpected Reactivity Trend Indicates Ester Enolate Intermediacy
inferred← citeshttps://doi.org/10.1002/ange.201503087openalex-snapshot
Facile Protocol for Catalytic Frustrated Lewis Pair Hydrogenation and Reductive Deoxygenation of Ketones and Aldehydes
inferred← citeshttps://doi.org/10.1002/ange.201507829openalex-snapshot
Chemoselective Alkene Hydrosilylation Catalyzed by Nickel Pincer Complexes
inferred← citeshttps://doi.org/10.1002/ange.201508669openalex-snapshot
Borane‐Catalyzed Reductive α‐Silylation of Conjugated Esters and Amides Leaving Carbonyl Groups Intact
inferred← citeshttps://doi.org/10.1002/ange.201510403openalex-snapshot
Delocalization and Valence Tautomerism in Vanadium Tris(iminosemiquinone) Complexes
inferred← citeshttps://doi.org/10.1002/ange.201601197openalex-snapshot
Base–Metal‐Catalyzed Regiodivergent Alkene Hydrosilylations
inferred← citeshttps://doi.org/10.1002/ange.201605615openalex-snapshot
Cobalt‐Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity
inferred← citeshttps://doi.org/10.1002/ange.201606832openalex-snapshot
An Easily Accessed Nickel Nanoparticle Catalyst for Alkene Hydrosilylation with Tertiary Silanes
inferred← citeshttps://doi.org/10.1002/ange.201608537openalex-snapshot
Iron‐Catalyzed Mild and Selective Hydrogenative Cross‐Coupling of Nitriles and Amines To Form Secondary Aldimines
inferred← citeshttps://doi.org/10.1002/ange.201612460openalex-snapshot
(Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes
inferred← citeshttps://doi.org/10.1002/ange.201612548openalex-snapshot
Alkene Hydrogenations by Soluble Iron Nanocluster Catalysts
inferred← citeshttps://doi.org/10.1002/ange.201705087openalex-snapshot
Iron‐Catalyzed Cyclotrimerization of Terminal Alkynes by Dual Catalyst Activation in the Absence of Reductants
inferred← citeshttps://doi.org/10.1002/ange.201706828openalex-snapshot
Stabilisierung eines niedrigvalenten Eisen(I)‐Ions in einem hochvalenten molekularen Vanadium(V)‐Oxid‐Cluster
inferred← citeshttps://doi.org/10.1002/ange.201805483openalex-snapshot
Manganese‐Catalyzed Hydrofunctionalization of Alkenes
inferred← citeshttps://doi.org/10.1002/ange.201814558openalex-snapshot
Metal‐Catalyzed Sequential Formation of Distant Bonds in Organic Molecules: Palladium‐Catalyzed Hydrosilylation/Cyclization of 1,n‐Dienes by Chain Walking
inferred← citeshttps://doi.org/10.1002/ange.202007930openalex-snapshot
Ligand‐Regulated Regiodivergent Hydrosilylation of Isoprene under Iron Catalysis
inferred← citeshttps://doi.org/10.1002/ange.202100049openalex-snapshot
Experimental and Computational Studies of the Iron‐Catalyzed Selective and Controllable Defluorosilylation of Unactivated Aliphatic gem‐Difluoroalkenes
inferred← citeshttps://doi.org/10.1002/ange.202215029openalex-snapshot
Cobalt‐Catalyzed Regiodivergent Double Hydrosilylation of Arylacetylenes
inferred← citeshttps://doi.org/10.1002/ange.202520739openalex-snapshot
Synthesis and Characterization of Unusual S =1 Fe(0)‐Silyl Complexes Supported by Styrene Ligands
inferred← citeshttps://doi.org/10.1002/ange.5648702openalex-snapshot
Metal–Organic Framework‐Confined Iron Pincer Complex for Highly Efficient and Selective Borylation of Methane and Ethane
inferred← citeshttps://doi.org/10.1002/anie.200502527openalex-snapshot
An η^3-H_2SiR_2 Adduct of [{PhB-(CH_2PiPr_2)_3}Fe^(II)H
inferred← citeshttps://doi.org/10.1002/anie.200703053openalex-snapshot
An Iron Catalyst for Ketone Hydrogenations under Mild Conditions
inferred← citeshttps://doi.org/10.1002/anie.200705115openalex-snapshot
Highly Efficient Catalyst Systems Using Iron Complexes with a Tetradentate PNNP Ligand for the Asymmetric Hydrogenation of Polar Bonds
inferred← citeshttps://doi.org/10.1002/anie.200800012openalex-snapshot
Sustainable Metal Catalysis with Iron: From Rust to a Rising Star?
inferred← citeshttps://doi.org/10.1002/anie.200804400openalex-snapshot
[FeFe]‐Hydrogenase Models and Hydrogen: Oxidative Addition of Dihydrogen and Silanes
inferred← citeshttps://doi.org/10.1002/anie.200901930openalex-snapshot
Preformed π‐Allyl Iron Complexes as Potent, Well‐Defined Catalysts for the Allylic Substitution
inferred← citeshttps://doi.org/10.1002/anie.200905025openalex-snapshot
Hydrosilane Reduction of Tertiary Carboxamides by Iron Carbonyl Catalysts
inferred← citeshttps://doi.org/10.1002/anie.201003946openalex-snapshot
Exploiting Non‐Innocent Ligands to Prepare Masked Palladium(0) Complexes
inferred← citeshttps://doi.org/10.1002/anie.201007271openalex-snapshot
New Trends towards Well‐Defined Low‐Valent Iron Catalysts
inferred← citeshttps://doi.org/10.1002/anie.201007406openalex-snapshot
Efficient Hydrogenation of Ketones Catalyzed by an Iron Pincer Complex
inferred← citeshttps://doi.org/10.1002/anie.201100145openalex-snapshot
Selective Reduction of Carboxylic Acid Derivatives by Catalytic Hydrosilylation
inferred← citeshttps://doi.org/10.1002/anie.201201360openalex-snapshot
Knölker’s Iron Complex: An Efficient In Situ Generated Catalyst for Reductive Amination of Alkyl Aldehydes and Amines
inferred← citeshttps://doi.org/10.1002/anie.201201787openalex-snapshot
Catalytic Selective Synthesis
inferred← citeshttps://doi.org/10.1002/anie.201203362openalex-snapshot
H2 Activation and Hydride Transfer to Olefins by Al(C6F5)3‐Based Frustrated Lewis Pairs
inferred← citeshttps://doi.org/10.1002/anie.201204100openalex-snapshot
Redox‐Active Ligands in Catalysis
inferred← citeshttps://doi.org/10.1002/anie.201205152openalex-snapshot
Iron‐Catalyzed Polymerization of Isoprene and Other 1,3‐Dienes
inferred← citeshttps://doi.org/10.1002/anie.201206051openalex-snapshot
Mild and Homogeneous Cobalt‐Catalyzed Hydrogenation of CC, CO, and CN Bonds
inferred← citeshttps://doi.org/10.1002/anie.201210347openalex-snapshot
Iron‐Catalyzed, Atom‐Economical, Chemo‐ and Regioselective Alkene Hydroboration with Pinacolborane
inferred← citeshttps://doi.org/10.1002/anie.201306243openalex-snapshot
Silver‐Catalyzed Hydrogenation of Aldehydes in Water
inferred← citeshttps://doi.org/10.1002/anie.201306629openalex-snapshot
Iron Pincer Complex Catalyzed, Environmentally Benign, E ‐Selective Semi‐Hydrogenation of Alkynes
inferred← citeshttps://doi.org/10.1002/anie.201308967openalex-snapshot
Heteroatom‐Free Arene‐Cobalt and Arene‐Iron Catalysts for Hydrogenations
inferred← citeshttps://doi.org/10.1002/anie.201309421openalex-snapshot
A Coordination Compound of Ge0 Stabilized by a Diiminopyridine Ligand
inferred← citeshttps://doi.org/10.1002/anie.201311221openalex-snapshot
Unprecedented Iron‐Catalyzed Ester Hydrogenation. Mild, Selective, and Efficient Hydrogenation of Trifluoroacetic Esters to Alcohols Catalyzed by an Iron Pincer Complex
inferred← citeshttps://doi.org/10.1002/anie.201404677openalex-snapshot
(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low‐Coordinate Iron(0) Reagents
inferred← citeshttps://doi.org/10.1002/anie.201405080openalex-snapshot
Discovery of Highly Selective Alkyne Semihydrogenation Catalysts Based on First‐Row Transition‐Metallated Porous Organic Polymers
inferred← citeshttps://doi.org/10.1002/anie.201411884openalex-snapshot
Iron‐Catalyzed Asymmetric Hydrosilylation of 1,1‐Disubstituted Alkenes
inferred← citeshttps://doi.org/10.1002/anie.201502418openalex-snapshot
Cobalt‐Catalyzed Hydrogenation of Esters to Alcohols: Unexpected Reactivity Trend Indicates Ester Enolate Intermediacy
inferred← citeshttps://doi.org/10.1002/anie.201503087openalex-snapshot
Facile Protocol for Catalytic Frustrated Lewis Pair Hydrogenation and Reductive Deoxygenation of Ketones and Aldehydes
inferred← citeshttps://doi.org/10.1002/anie.201507829openalex-snapshot
Chemoselective Alkene Hydrosilylation Catalyzed by Nickel Pincer Complexes
inferred← citeshttps://doi.org/10.1002/anie.201508669openalex-snapshot
Borane‐Catalyzed Reductive α‐Silylation of Conjugated Esters and Amides Leaving Carbonyl Groups Intact
inferred← citeshttps://doi.org/10.1002/anie.201510403openalex-snapshot
Delocalization and Valence Tautomerism in Vanadium Tris(iminosemiquinone) Complexes
inferred← citeshttps://doi.org/10.1002/anie.201601197openalex-snapshot
Base–Metal‐Catalyzed Regiodivergent Alkene Hydrosilylations
inferred← citeshttps://doi.org/10.1002/anie.201605615openalex-snapshot
Cobalt‐Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity
inferred← citeshttps://doi.org/10.1002/anie.201606832openalex-snapshot
An Easily Accessed Nickel Nanoparticle Catalyst for Alkene Hydrosilylation with Tertiary Silanes
inferred← citeshttps://doi.org/10.1002/anie.201608537openalex-snapshot
Iron‐Catalyzed Mild and Selective Hydrogenative Cross‐Coupling of Nitriles and Amines To Form Secondary Aldimines
inferred← citeshttps://doi.org/10.1002/anie.201612460openalex-snapshot
(Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes
inferred← citeshttps://doi.org/10.1002/anie.201612548openalex-snapshot
Alkene Hydrogenations by Soluble Iron Nanocluster Catalysts
inferred← citeshttps://doi.org/10.1002/anie.201705087openalex-snapshot
Iron‐Catalyzed Cyclotrimerization of Terminal Alkynes by Dual Catalyst Activation in the Absence of Reductants
inferred← citeshttps://doi.org/10.1002/anie.201706828openalex-snapshot
Stabilization of Low‐Valent Iron(I) in a High‐Valent Vanadium(V) Oxide Cluster
inferred← citeshttps://doi.org/10.1002/anie.201805483openalex-snapshot
Manganese‐Catalyzed Hydrofunctionalization of Alkenes
inferred← citeshttps://doi.org/10.1002/anie.201814558openalex-snapshot
Metal‐Catalyzed Sequential Formation of Distant Bonds in Organic Molecules: Palladium‐Catalyzed Hydrosilylation/Cyclization of 1,n‐Dienes by Chain Walking
inferred← citeshttps://doi.org/10.1002/anie.202007930openalex-snapshot
Ligand‐Regulated Regiodivergent Hydrosilylation of Isoprene under Iron Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202100049openalex-snapshot
Experimental and Computational Studies of the Iron‐Catalyzed Selective and Controllable Defluorosilylation of Unactivated Aliphatic gem ‐Difluoroalkenes
inferred← citeshttps://doi.org/10.1002/anie.202215029openalex-snapshot
Cobalt‐Catalyzed Regiodivergent Double Hydrosilylation of Arylacetylenes
inferred← citeshttps://doi.org/10.1002/anie.202520739openalex-snapshot
Synthesis and Characterization of Unusual S =1 Fe(0)‐Silyl Complexes Supported by Styrene Ligands
inferred← citeshttps://doi.org/10.1002/anie.5648702openalex-snapshot
Metal–Organic Framework‐Confined Iron Pincer Complex for Highly Efficient and Selective Borylation of Methane and Ethane
inferred← citeshttps://doi.org/10.1002/aoc.1701openalex-snapshot
Iron‐catalyzed hydrosilylation reactions
inferred← citeshttps://doi.org/10.1002/aoc.4573openalex-snapshot
Synthesis of quinazolines over recyclable Fe3O4@SiO2‐PrNH2‐Fe3+ nanoparticles: A green, efficient, and solvent‐free protocol
inferred← citeshttps://doi.org/10.1002/aoc.6315openalex-snapshot
Highly active cobalt complex catalysts used for alkene hydrosilylation
inferred← citeshttps://doi.org/10.1002/aoc.70509openalex-snapshot
Effect of Silylene Ligand on Catalytic Pathway of Alkene Hydrosilylation Catalyzed by Phosphine Cobalt(III) Hydrides
inferred← citeshttps://doi.org/10.1002/aoc.70630openalex-snapshot
Theoretical Studies on Iron‐Catalyzed Enantioselective Hydrogenation of Alkenes
inferred← citeshttps://doi.org/10.1002/asia.200600105openalex-snapshot
An Environmentally Benign Process for the Hydrogenation of Ketones with Homogeneous Iron Catalysts
inferred← citeshttps://doi.org/10.1002/asia.201000064openalex-snapshot
Chemo‐ and Stereoselective Iron‐Catalyzed Hydrosilylation of Ketones
inferred← citeshttps://doi.org/10.1002/asia.201000427openalex-snapshot
Hydrosilylation of Ketones: From Metal–Organic Frameworks to Simple Base Catalysts
inferred← citeshttps://doi.org/10.1002/asia.201000941openalex-snapshot
Highly Selective Iron‐Catalyzed Synthesis of Alkenes by the Reduction of Alkynes
inferred← citeshttps://doi.org/10.1002/asia.201100561openalex-snapshot
Enantioselective Zinc‐Catalyzed Hydrosilylation of Ketones using Pybox or Pybim Ligands
inferred← citeshttps://doi.org/10.1002/asia.201200931openalex-snapshot
Straightforward Iron‐Catalyzed Synthesis of Vinylboronates by the Hydroboration of Alkynes
inferred← citeshttps://doi.org/10.1002/asia.201900577openalex-snapshot
Highly Regio‐ and Stereoselective Hydrosilylation of Alkynes Catalyzed by Tridentate Cobalt Complexes
inferred← citeshttps://doi.org/10.1002/cctc.201000400openalex-snapshot
A Facile and Efficient Iron‐Catalyzed Reduction of Sulfoxides to Sulfides
inferred← citeshttps://doi.org/10.1002/cctc.201000449openalex-snapshot
Electronic Effects in the Catalytic Hydrosilylation with In‐Situ Generated Iron(II)‐Catalysts
inferred← citeshttps://doi.org/10.1002/cctc.201100202openalex-snapshot
Well‐Defined Cyclopentadienyl NHC Iron Complex as the Catalyst for Efficient Hydrosilylation of Amides to Amines and Nitriles
inferred← citeshttps://doi.org/10.1002/cctc.201100347openalex-snapshot
Learning from the Neighbors: Improving Homogeneous Catalysts with Functional Ligands Motivated by Heterogeneous and Biocatalysis
inferred← citeshttps://doi.org/10.1002/cctc.201200592openalex-snapshot
Biorelevant Metals in Sustainable Metal Catalysis—A Survey
inferred← citeshttps://doi.org/10.1002/cctc.201300325openalex-snapshot
Bifunctional Iron Complexes: Efficient Catalysts for CO and CN Reduction in Water
inferred← citeshttps://doi.org/10.1002/cctc.201300338openalex-snapshot
Nickel‐Catalysed Reductive Amination with Hydrosilanes
inferred← citeshttps://doi.org/10.1002/cctc.201402693openalex-snapshot
Iron‐Catalysed Hydrofunctionalisation of Alkenes and Alkynes
inferred← citeshttps://doi.org/10.1002/cctc.201500348openalex-snapshot
An Iron Catalyst for Asymmetric Alkene Hydrosilylation
inferred← citeshttps://doi.org/10.1002/cctc.201700144openalex-snapshot
Synthesis and Catalysis of Redox‐Active Bis(imino)acenaphthene (BIAN) Iron Complexes
inferred← citeshttps://doi.org/10.1002/cctc.201700222openalex-snapshot
Rhodium(III) Catalyzed Solvent‐Free Tandem Isomerization–Hydrosilylation From Internal Alkenes to Linear Silanes
inferred← citeshttps://doi.org/10.1002/cctc.201701722openalex-snapshot
From Ruthenium to Iron and Manganese—A Mechanistic View on Challenges and Design Principles of Base‐Metal Hydrogenation Catalysts
inferred← citeshttps://doi.org/10.1002/cctc.201800159openalex-snapshot
From Remote Alkenes to Linear Silanes or Allylsilanes depending on the Metal Center
inferred← citeshttps://doi.org/10.1002/cctc.201800161openalex-snapshot
Solution Synthesis of N,N‐Dimethylformamide‐Stabilized Iron‐Oxide Nanoparticles as an Efficient and Recyclable Catalyst for Alkene Hydrosilylation
inferred← citeshttps://doi.org/10.1002/cctc.201900530openalex-snapshot
Alkene Hydrosilylation on Oxide‐Supported Pt‐Ligand Single‐Site Catalysts
inferred← citeshttps://doi.org/10.1002/cctc.202000085openalex-snapshot
Bidentate N‐based Ligands for Highly Reusable, Ligand‐coordinated, Supported Pt Hydrosilylation Catalysts
inferred← citeshttps://doi.org/10.1002/cctc.202000662openalex-snapshot
1,3,2‐Diazaphospholenes Catalyze the Conjugate Reduction of Substituted Acrylic Acids
inferred← citeshttps://doi.org/10.1002/cctc.202001699openalex-snapshot
Steric Effects in the Catalytic Tandem Isomerization‐Hydrosilylation Reaction
inferred← citeshttps://doi.org/10.1002/cctc.202100235openalex-snapshot
Precursor Nuclearity and Ligand Effects in Atomically‐Dispersed Heterogeneous Iron Catalysts for Alkyne Semi‐Hydrogenation
inferred← citeshttps://doi.org/10.1002/cctc.202200886openalex-snapshot
Stereoselective Semi‐Hydrogenations of Alkynes by First‐Row (3d) Transition Metal Catalysts
inferred← citeshttps://doi.org/10.1002/cctc.202300004openalex-snapshot
Promising Catalytic Application by Pincer Metal Complexes: Recent Advances in Hydrogenation of Carbon‐Based Molecules
inferred← citeshttps://doi.org/10.1002/cctc.202401398openalex-snapshot
Hydrosilylation of Alkynes Catalyzed by an Iron(II) PCP Pincer Alkyl Complex
inferred← citeshttps://doi.org/10.1002/chem.200802643openalex-snapshot
Iron‐Catalyzed Ligand‐Free Three‐Component Coupling Reactions of Aldehydes, Terminal Alkynes, and Amines
inferred← citeshttps://doi.org/10.1002/chem.200900027openalex-snapshot
Structural and Reactivity Studies of “Pincer” Pyridine Dicarbene Complexes of Fe0: Experimental and Computational Comparison of the Phosphine and NHC Donors
inferred← citeshttps://doi.org/10.1002/chem.201002010openalex-snapshot
Lewis Acid Assisted Stabilization of Side‐On Bonded N2 in [Ru(NCN)]‐Pincer Complexes—Computational Catalyst Design Directed at NH3 Synthesis from N2 and H2
inferred← citeshttps://doi.org/10.1002/chem.201100800openalex-snapshot
Zinc‐Catalyzed Chemoselective Reduction of Esters to Alcohols
inferred← citeshttps://doi.org/10.1002/chem.201103009openalex-snapshot
Fe‐Catalyzed Multicomponent Reactions: The Regioselective Alkoxy Allylation of Activated Olefins and its Application in Sequential Fe Catalysis
inferred← citeshttps://doi.org/10.1002/chem.201200159openalex-snapshot
Iron Borohydride Pincer Complexes for the Efficient Hydrogenation of Ketones under Mild, Base‐Free Conditions: Synthesis and Mechanistic Insight
inferred← citeshttps://doi.org/10.1002/chem.201203450openalex-snapshot
Giant Residual Dipolar 13C–1H Couplings in High‐Spin Organoiron Complexes: Elucidation of Their Structures in Solution by 13C NMR Spectroscopy
inferred← citeshttps://doi.org/10.1002/chem.201300660openalex-snapshot
A Molecularly Defined Iron‐Catalyst for the Selective Hydrogenation of α,β‐Unsaturated Aldehydes
inferred← citeshttps://doi.org/10.1002/chem.201301340openalex-snapshot
The Role of 2,6‐Diaminopyridine Ligands in the Isolation of an Unprecedented, Low‐Valent Tin Complex
inferred← citeshttps://doi.org/10.1002/chem.201301502openalex-snapshot
Cobalt‐Catalyzed Hydrosilation/Hydrogen‐Transfer Cascade Reaction: A New Route to Silyl Enol Ethers
inferred← citeshttps://doi.org/10.1002/chem.201302432openalex-snapshot
Bifunctional (Cyclopentadienone)Iron–Tricarbonyl Complexes: Synthesis, Computational Studies and Application in Reductive Amination
inferred← citeshttps://doi.org/10.1002/chem.201304631openalex-snapshot
Iron Dicarbonyl Complexes Featuring Bipyridine‐Based PNN Pincer Ligands with Short Interpyridine CC Bond Lengths: Innocent or Non‐Innocent Ligand?
inferred← citeshttps://doi.org/10.1002/chem.201403485openalex-snapshot
Characterisation of Alkane σ‐Complexes
inferred← citeshttps://doi.org/10.1002/chem.201404131openalex-snapshot
Methandiide as a Non‐Innocent Ligand in Carbene Complexes: From the Electronic Structure to Bond Activation Reactions and Cooperative Catalysis
inferred← citeshttps://doi.org/10.1002/chem.201406356openalex-snapshot
Hydrosilylation of Ketones, Imines and Nitriles Catalysed by Electrophilic Phosphonium Cations: Functional Group Selectivity and Mechanistic Considerations
inferred← citeshttps://doi.org/10.1002/chem.201504573openalex-snapshot
Computational Study of Formic Acid Dehydrogenation Catalyzed by AlIII–Bis(imino)pyridine
inferred← citeshttps://doi.org/10.1002/chem.201800142openalex-snapshot
Tetrylones: An Intriguing Class of Monoatomic Zero‐valent Group 14 Compounds
inferred← citeshttps://doi.org/10.1002/chem.201803878openalex-snapshot
Pseudo‐tetrahedral Rhodium and Iridium Complexes: Catalytic Synthesis of E‐Enynes
inferred← citeshttps://doi.org/10.1002/chem.201905537openalex-snapshot
Heterogeneous Olefin Hydrogenation Enabled by a Highly‐Reduced Nickel(−II) Catalyst Precursor
inferred← citeshttps://doi.org/10.1002/chem.202000508openalex-snapshot
Light Runs Across Iron Catalysts in Organic Transformations
inferred← citeshttps://doi.org/10.1002/chem.202001019openalex-snapshot
Heterogeneous Olefin Hydrogenation Enabled by a Highly‐Reduced Nickel(−II) Catalyst Precursor
inferred← citeshttps://doi.org/10.1002/chem.202004980openalex-snapshot
Iron Catalyzed Double Bond Isomerization: Evidence for an FeI/FeIII Catalytic Cycle
inferred← citeshttps://doi.org/10.1002/chem.202102070openalex-snapshot
NHC Effects on Reduction Dynamics in Iron‐Catalyzed Organic Transformations**
inferred← citeshttps://doi.org/10.1002/chem.202200596openalex-snapshot
A Single Bioinspired Hexameric Nickel Catechol–Alloxazine Catalyst Combines Metal and Radical Mechanisms for Alkene Hydrosilylation
inferred← citeshttps://doi.org/10.1002/chem.202202172openalex-snapshot
Terminal N2 Dissociation in [(PNN)Fe(N2)]2(μ‐N2) Leads to Local Spin‐State Changes and Augmented Bridging N2 Activation
inferred← citeshttps://doi.org/10.1002/cjoc.201190022openalex-snapshot
FeCl3‐Catalyzed Condensation of 2‐Naphthol and Aldehydes under Solvent‐Free Reaction Conditions: An Efficient and Green Alternative for the Synthesis of 14‐Aryl(Alkyl)‐14‐H‐dibenzo[a, j]xanthenes
inferred← citeshttps://doi.org/10.1002/cjoc.201800314openalex-snapshot
Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis
inferred← citeshttps://doi.org/10.1002/cjoc.202400176openalex-snapshot
Heterometallic Mg‐Ni‐Mg Complex Promoted Hydrosilylation of Alkenes: Catalytic Performance and Intermediates Characterization†
inferred← citeshttps://doi.org/10.1002/cssc.200800071openalex-snapshot
Iron‐Catalyzed Hydrogenation, Hydride Transfer, and Hydrosilylation: An Alternative to Precious‐Metal Complexes?
inferred← citeshttps://doi.org/10.1002/cssc.201100404openalex-snapshot
Benign Catalysis with Iron: Unique Selectivity in Catalytic Isomerization Reactions of Olefins
inferred← citeshttps://doi.org/10.1002/cssc.201200344openalex-snapshot
Iron Complex with Ionic Tag‐Catalyzed Olefin Reduction under Oxidative Conditions—A Different Reaction for Iron
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