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Hydrosilylation and Related Reactions of Silicon Compounds

https://doi.org/10.1002/9783527651733.ch8
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Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products
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Stereochemical Control in Organic Synthesis Using Silicon-Containing Compounds
inferredcites →https://doi.org/10.1021/cr9701086openalex-snapshot
Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal Silyl Compounds
inferredcites →https://doi.org/10.1021/cr970414jopenalex-snapshot
Dendrimers Containing Heteroatoms (Si, P, B, Ge, or Bi)
inferredcites →https://doi.org/10.1021/cs200525eopenalex-snapshot
Transition Metal Nanoparticle Catalysis in Ionic Liquids
inferredcites →https://doi.org/10.1021/cs200571vopenalex-snapshot
Rhodium-Catalyzed Hydrosilylation of Ketones: Catalyst Development and Mechanistic Insights
inferredcites →https://doi.org/10.1021/ja00026a044openalex-snapshot
Catalytic asymmetric synthesis of optically active 2-alkanols via hydrosilylation of 1-alkenes with a chiral monophosphine-palladium catalyst
inferredcites →https://doi.org/10.1021/ja00032a028openalex-snapshot
Asymmetric catalysis. Production of chiral diols by enantioselective catalytic intramolecular hydrosilation of olefins
inferredcites →https://doi.org/10.1021/ja00059a008openalex-snapshot
Mechanism of a cobalt(III)-catalyzed olefin hydrosilation reaction: direct evidence for a silyl migration pathway
inferredcites →https://doi.org/10.1021/ja00105a006openalex-snapshot
Enantioselective Hydrosilylation of Ketones with a Chiral Titanocene Catalyst
inferredcites →https://doi.org/10.1021/ja00178a021openalex-snapshot
Unusual activity and selectivity in alkyne hydrosilylation with an iridium catalyst stabilized by an oxygen-donor ligand
inferredcites →https://doi.org/10.1021/ja00188a074openalex-snapshot
An efficient silylformylation of alkynes catalyzed by tetrarhodium dodecacarbonyl
inferredcites →https://doi.org/10.1021/ja00749a080openalex-snapshot
Asymmetric homogeneous hydrosilylation with platinum(II) complexes of chiral phosphines
inferredcites →https://doi.org/10.1021/ja01079a004openalex-snapshot
Homogeneous Catalysis. II. The Mechanism of the Hydrosilation of Olefins Catalyzed by Group VIII Metal Complexes1
inferredcites →https://doi.org/10.1021/ja011529eopenalex-snapshot
Ligand-Accelerated, Copper-Catalyzed Asymmetric Hydrosilylations of Aryl Ketones
inferredcites →https://doi.org/10.1021/ja01193a508openalex-snapshot
PEROXIDE-CATALYZED ADDITION OF TRICHLOROSILANE TO 1-OCTENE
inferredcites →https://doi.org/10.1021/ja012639oopenalex-snapshot
Application of Chiral Mixed Phosphorus/Sulfur Ligands to Enantioselective Rhodium-Catalyzed Dehydroamino Acid Hydrogenation and Ketone Hydrosilylation Processes
inferredcites →https://doi.org/10.1021/ja01561a054openalex-snapshot
The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts
inferredcites →https://doi.org/10.1021/ja021391fopenalex-snapshot
Asymmetric Hydrosilylation of Aryl Ketones Catalyzed by Copper Hydride Complexed by Nonracemic Biphenyl Bis-phosphine Ligands
inferredcites →https://doi.org/10.1021/ja026457lopenalex-snapshot
A Chemoselective Reduction of Alkynes to (E)-Alkenes
inferredcites →https://doi.org/10.1021/ja029498qopenalex-snapshot
Reversing the Role of the Metal−Oxygen π-Bond. Chemoselective Catalytic Reductions with a Rhenium(V)-Dioxo Complex
inferredcites →https://doi.org/10.1021/ja0351692openalex-snapshot
Catalytic Enantioselective Conjugate Reduction of Lactones and Lactams
inferredcites →https://doi.org/10.1021/ja037620vopenalex-snapshot
Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a New Hydrosilylation Mechanism
inferredcites →https://doi.org/10.1021/ja046753topenalex-snapshot
Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation
inferredcites →https://doi.org/10.1021/ja0528580openalex-snapshot
Alkyne Hydrosilylation Catalyzed by a Cationic Ruthenium Complex: Efficient and General Trans Addition
inferredcites →https://doi.org/10.1021/ja0612293openalex-snapshot
Biphasic Hydrosilylation in Ionic Liquids: A Process Set for Industrial Implementation
inferredcites →https://doi.org/10.1021/ja074477nopenalex-snapshot
Analysis of an Unprecedented Mechanism for the Catalytic Hydrosilylation of Carbonyl Compounds
inferredcites →https://doi.org/10.1021/ja106853yopenalex-snapshot
A Strategy for the Synthesis of Well-Defined Iron Catalysts and Application to Regioselective Diene Hydrosilylation
inferredcites →https://doi.org/10.1021/ja209436sopenalex-snapshot
Selective Dehydrogenative Silylation–Hydrogenation Reaction of Divinyldisiloxane with Hydrosilane Catalyzed by an Iron Complex
inferredcites →https://doi.org/10.1021/ja510924vopenalex-snapshot
Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes
inferredcites →https://doi.org/10.1021/ja960808copenalex-snapshot
Highly Enantioselective Imine Hydrosilylation Using (S,S)-Ethylenebis(η5-tetrahydroindenyl)titanium Difluoride
inferredcites →https://doi.org/10.1021/ja962979nopenalex-snapshot
Mechanistic Studies of Palladium(II)-Catalyzed Hydrosilation and Dehydrogenative Silation Reactions
inferredcites →https://doi.org/10.1021/ja980907lopenalex-snapshot
Silylcarbocyclizations of 1,6-Diynes
inferredcites →https://doi.org/10.1021/ja990450vopenalex-snapshot
Titanocene-Catalyzed Asymmetric Ketone Hydrosilylation: The Effect of Catalyst Activation Protocol and Additives on the Reaction Rate and Enantioselectivity
inferredcites →https://doi.org/10.1021/ja990522iopenalex-snapshot
Enantioselective Reduction of Ketones by Polymethylhydrosiloxane in the Presence of Chiral Zinc Catalysts
inferredcites →https://doi.org/10.1021/ja992366lopenalex-snapshot
Asymmetric Conjugate Reduction of α,β-Unsaturated Esters Using a Chiral Phosphine−Copper Catalyst
inferredcites →https://doi.org/10.1021/jacs.5b01475openalex-snapshot
Interligand Interactions Dictate the Regioselectivity of trans -Hydrometalations and Related Reactions Catalyzed by [Cp*RuCl]. Hydrogen Bonding to a Chloride Ligand as a Steering Principle in Catalysis
inferredcites →https://doi.org/10.1021/jo00115a020openalex-snapshot
A Selective Synthesis of (E)-Vinylsilanes by Cationic Rhodium Complex-Catalyzed Hydrosilylation of 1-Alkynes and Tandem Hydrosilylation/Isomerization Reaction of Propargylic Alcohols to .beta.-Silyl Ketones
inferredcites →https://doi.org/10.1021/jo001614popenalex-snapshot
Asymmetric Hydrosilylation of Styrenes Catalyzed by Palladium−MOP Complexes: Ligand Modification and Mechanistic Studies
inferredcites →https://doi.org/10.1021/jo00417a006openalex-snapshot
A highly stereoselective synthesis of vinyl bromides and chlorides via disubstituted vinylsilanes
inferredcites →https://doi.org/10.1021/jo0163389openalex-snapshot
Metal-Catalyzed Hydrosilylation of Alkenes and Alkynes Using Dimethyl(pyridyl)silane
inferredcites →https://doi.org/10.1021/jo501730nopenalex-snapshot
Ligand-Controlled Reactivity, Selectivity, and Mechanism of Cationic Ruthenium-Catalyzed Hydrosilylations of Alkynes, Ketones, and Nitriles: A Theoretical Study
inferredcites →https://doi.org/10.1021/jo900032xopenalex-snapshot
The Interplay of Invention, Discovery, Development, and Application in Organic Synthetic Methodology: A Case Study
inferredcites →https://doi.org/10.1021/jo980100bopenalex-snapshot
Cyclization of o-Allylstyrene via Hydrosilylation: Mechanistic Aspects of Hydrosilylation of Styrenes Catalyzed by Palladium−Phosphine Complexes
inferredcites →https://doi.org/10.1021/ma00104a011openalex-snapshot
Polymerization by Hydrosilation. 2. Preparation and Characterization of High Molecular Weight Poly[(1,1,3,3-tetramethyldisiloxanyl)ethylene] from 1,3-Dihydridotetramethyldisiloxane and 1,3-Divinyltetramethyldisiloxane
inferredcites →https://doi.org/10.1021/ma201203wopenalex-snapshot
Regioselective Alkyne Polyhydrosilylation: Synthesis and Photonic Properties of Poly(silylenevinylene)s
inferredcites →https://doi.org/10.1021/ma980463dopenalex-snapshot
Synthesis and Polymerization of an Optically Active Bifunctional Disiloxane. 1. Preparation of Optically Active and Highly Stereoregular Poly[{(1S)-1-(1-naphthyl)-1-phenyl-3,3-dimethyldisiloxane-1,3-diyl}ethylene] by Polyaddition via Hydrosilylation
inferredcites →https://doi.org/10.1021/ma9913360openalex-snapshot
Regio- and Stereocontrolled Hydrosilylation Polyaddition Catalyzed by RhI(PPh3)3. Syntheses of Polymers Containing (E)- or (Z)-Alkenylsilane Moieties
inferredcites →https://doi.org/10.1021/ol005583wopenalex-snapshot
A Method for the Asymmetric Hydrosilylation of N-Aryl Imines
inferredcites →https://doi.org/10.1021/ol0059697openalex-snapshot
Highly Stereoselective and Efficient Hydrosilylation of Terminal Alkynes Catalyzed by [RuCl 2 ( p -cymene)] 2
inferredcites →https://doi.org/10.1021/ol0156751openalex-snapshot
Highly Stereoselective Hydrocarbation of Terminal Alkynes via Pt-Catalyzed Hydrosilylation/Pd-Catalyzed Cross-Coupling Reactions
inferredcites →https://doi.org/10.1021/ol300279copenalex-snapshot
Palladium-Catalyzed Regio- and Stereoselective Hydrosilylation of Electron-Deficient Alkynes
inferredcites →https://doi.org/10.1021/ol4001334openalex-snapshot
Regio- and Stereoselective Hydrosilylation of 1,3-Enynes Catalyzed by Palladium
inferredcites →https://doi.org/10.1021/ol502766qopenalex-snapshot
Regioselective Allene Hydroarylation via One-Pot Allene Hydrosilylation/Pd-Catalyzed Cross-Coupling
inferredcites →https://doi.org/10.1021/ol503065aopenalex-snapshot
MIDA–Vinylsilanes: Selective Cross-Couplings and Applications to the Synthesis of Functionalized Stilbenes
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inferred← citeshttps://doi.org/10.2139/ssrn.4673735openalex-extracted
Chlororhodate Ionic Liquids as a New Type of Heterogeneous Catalyst for Hydrosilylation Processes
inferred← citeshttps://doi.org/10.1002/asia.201800726openalex-snapshot
Selective Hydrosilylation of Alkynes with Octaspherosilicate (HSiMe2O)8Si8O12
inferred← citeshttps://doi.org/10.1002/asia.202300968openalex-snapshot
Syntheses of Iminophosphomamido Chlorogermylenes and Their Complexation with a Rhodium(I) Complex
inferred← citeshttps://doi.org/10.1002/cctc.202300781openalex-snapshot
Co‐Catalyzed Hydrosilylation of Ketones under Base‐Free Conditions: A Convenient Route to Silyl Ethers or Secondary Alcohols
inferred← citeshttps://doi.org/10.1002/ciuz.202000038openalex-snapshot
Organofunktionelle Silane als Haftvermittler
inferred← citeshttps://doi.org/10.1002/ejic.202000356openalex-snapshot
A Platinum Molecular Complex Immobilised on the Surface of Graphene as Active Catalyst in Alkyne Hydrosilylation
inferred← citeshttps://doi.org/10.1002/ejic.202300312openalex-snapshot
Base Stabilized σ‐Borane Complex of Group 5 Metals: Synthesis and Structure of [(η5‐C5Me5)Ta(H3BNC5H4) (C5H4NS)(η2‐S2)]
inferred← citeshttps://doi.org/10.1002/marc.202400241openalex-snapshot
Photocatalytic Hydrosilylation over Pt@UiO‐66‐NH2: Enhanced Activity and Polymerization Kinetics
inferred← citeshttps://doi.org/10.1002/tcr.202100083openalex-snapshot
(Z)‐Selective Hydrosilylation and Hydroboration of Terminal Alkynes Enabled by Ruthenium Complexes with an N‐Heterocyclic Carbene Ligand
inferred← citeshttps://doi.org/10.1007/978-1-4020-8172-9_1openalex-snapshot
Hydrosilylation of Alkenes and Their Derivatives
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2022.111191openalex-snapshot
High thermally stable polysiloxanes cross-linked with di(alkenyl)functionalized DDSQs exhibiting swelling abilities
inferred← citeshttps://doi.org/10.1016/j.jcat.2026.116721openalex-snapshot
Mechanistic Insights on the β-(Z) alkyne hydrosilylation by a NHC-based Cp*Rh(III) catalyst: from catalyst design to an alternative model for H-Si activation
inferred← citeshttps://doi.org/10.1016/j.jcat.2026.117229openalex-snapshot
Structure–reactivity relationships in [Cp*Ru(MeCN)3][PF6]-catalyzed anti- and syn-selective hydrosilylation of internal alkynes and 1,3-diynes
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2020.121415openalex-snapshot
Recent progress in the development of catalytic systems for homogenous asymmetric hydrosilylation of ketones
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.1c00309openalex-snapshot
Zinc-Catalyzed Hydroalkoxylation/Cyclization of Alkynyl Alcohols
inferred← citeshttps://doi.org/10.1021/acscatal.0c01582openalex-snapshot
Carboxylate-Assisted β‑( Z ) Stereoselective Hydrosilylation of Terminal Alkynes Catalyzed by a Zwitterionic Bis-NHC Rhodium(III) Complex
inferred← citeshttps://doi.org/10.1021/acssuschemeng.5c09304openalex-snapshot
Synthesis of Silsesquioxane Derivatives via Hydrosilylation of Alkenes and Alkynes Catalyzed by Pt/XAD-4 in Supercritical CO 2
inferred← citeshttps://doi.org/10.1021/jacsau.5c00831openalex-snapshot
Single Photocatalytic Hydrosilylation of Alkenes for the Synthesis of Bis(silyl) and Silaboryl Alkanes
inferred← citeshttps://doi.org/10.1038/s41598-023-37375-8openalex-snapshot
Synthesis of unsymmetrically and symmetrically functionalized disiloxanes via subsequent hydrosilylation of C≡C bonds
inferred← citeshttps://doi.org/10.1038/s41598-023-41461-2openalex-snapshot
Functionalization of octaspherosilicate (HSiMe2O)8Si8O12 with buta-1,3-diynes by hydrosilylation
inferred← citeshttps://doi.org/10.1039/c8ob02298dopenalex-snapshot
Selective alkyl ether cleavage by cationic bis(phosphine)iridium complexes
inferred← citeshttps://doi.org/10.1039/d1dt01946eopenalex-snapshot
Iridium( i ) complexes bearing hemilabile coumarin-functionalised N-heterocyclic carbene ligands with application as alkyne hydrosilylation catalysts
inferred← citeshttps://doi.org/10.1039/d3qi00619kopenalex-snapshot
Coupling agents with 2,4,6,8-tetramethylcyclotetrasiloxane core – synthesis and application in styrene–butadiene rubber production
inferred← citeshttps://doi.org/10.1039/d3qo01777jopenalex-snapshot
Nascent developments in main group element-catalyzed hydrosilylation and dehydrogenative silylation of alkenes and alkynes
inferred← citeshttps://doi.org/10.1039/d3ra01583aopenalex-snapshot
A library of new organofunctional silanes obtained by thiol-(meth)acrylate Michael addition reaction
inferred← citeshttps://doi.org/10.2139/ssrn.5779546openalex-snapshot
Mechanistic Insights on the β-(Z) Alkyne Hydrosilylation by a NHC-based Cp*Rh(III) Catalyst: From Catalyst Design to an Alternative Model for H-Si Activation
inferred← citeshttps://doi.org/10.5937/savteh2601005mopenalex-snapshot
Influence of masterbatch on crosslinking of liquid silicone rubbers
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