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Rearrangement of Pyridine to Its 2-Carbene Tautomer Mediated by Iridium

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/anie.200603224openalex-snapshot
The σ‐CAM Mechanism: σ Complexes as the Basis of σ‐Bond Metathesis at Late‐Transition‐Metal Centers
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Characterization of mono(carbene) and bis(carbene) complexes of gold(I) derived from lithiated pyridine
inferredcites →https://doi.org/10.1016/c2009-0-15932-9openalex-snapshot
Comprehensive Heterocyclic Chemistry
inferredcites →https://doi.org/10.1016/s1387-3806(98)14053-8openalex-snapshot
Generation of neutral and cationic hydrogen shift isomers of pyridine: a combined experimental and computational investigation
inferredcites →https://doi.org/10.1021/ic00011a009openalex-snapshot
Pyridine and related adducts, (silox)3ML (M = scandium, titanium, vanadium, tantalum): .eta.1-pyridine-N vs .eta.2-pyridine-N,C ligation
inferredcites →https://doi.org/10.1021/ic010714qopenalex-snapshot
Preferential C-Binding versus N-Binding in Imidazole Depends on the Metal Fragment Involved
inferredcites →https://doi.org/10.1021/ic0511367openalex-snapshot
Coupling of an Aldehyde or Ketone to Pyridine Mediated by a Tungsten Imido Complex
inferredcites →https://doi.org/10.1021/ja00089a054openalex-snapshot
Stereoselective Olefin Insertion Reactions of Chiral (EBI)Zr(.eta.2-pyrid-2-yl)+ and (EBTHI)Zr(.eta.2-pyrid-2-yl)+ Complexes
inferredcites →https://doi.org/10.1021/ja00174a017openalex-snapshot
Acylation of pyridine rings mediated by Group 4 metal aryl oxide compounds: high yield formation of .alpha.,.alpha.'-disubstituted-2,6-pyridinedimethoxide ligands
inferredcites →https://doi.org/10.1021/ja00184a081openalex-snapshot
Zirconium-catalyzed coupling of propene and .alpha.-picoline
inferredcites →https://doi.org/10.1021/ja00235a031openalex-snapshot
.sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds
inferredcites →https://doi.org/10.1021/ja028512wopenalex-snapshot
The Reactivity of Mo(PMe3)6 towards Heterocyclic Nitrogen Compounds: Transformations Relevant to Hydrodenitrogenation
inferredcites →https://doi.org/10.1021/ja029829zopenalex-snapshot
Ruthenium-Mediated Regio- and Stereoselective Alkenylation of Pyridine
inferredcites →https://doi.org/10.1021/ja0576684openalex-snapshot
Experimental and Computational Studies on the Mechanism ofN-Heterocycle C−H Activation by Rh(I)
inferredcites →https://doi.org/10.1021/ja0646592openalex-snapshot
Iridium(III)-Induced Isomerization of 2-Substituted Pyridines to N-Heterocyclic Carbenes
inferredcites →https://doi.org/10.1021/ja064979lopenalex-snapshot
Stabilization of NH Tautomers of Quinolines by Osmium and Ruthenium
inferredcites →https://doi.org/10.1021/ja070388zopenalex-snapshot
Rh(I)-Catalyzed Alkylation of Quinolines and Pyridines via C−H Bond Activation
inferredcites →https://doi.org/10.1021/ja961954lopenalex-snapshot
Observation of the Hammick Intermediate: Reduction of the Pyridine-2-ylid Ion in the Gas Phase
inferredcites →https://doi.org/10.1021/om00029a016openalex-snapshot
Reactions of iridium complex [Ir(COD)(PMe3)3]Cl with benzene, pyridine, furan, and thiophene: carbon-hydrogen cleavage vs. ring opening
inferredcites →https://doi.org/10.1021/om00099a018openalex-snapshot
Photolysis of cyclotrigermane. Synthesis and chemistry of digermiranes and digermetanes containing sulfur and selenium
inferredcites →https://doi.org/10.1039/b608293aopenalex-snapshot
Unusual fragmentation of CH 2 Cl 2 by an Ir( iii ) centre bonded to a doubly metalated Tp Ms Ligand (Tp Ms = hydrotris(3-mesitylpyrazol-1-yl)borate)
inferredcites →https://doi.org/10.1039/jr9370001724openalex-snapshot
362. Experiments on the mechanism of decarboxylation. Part I. Decomposition of quinaldinic and isoquinaldinic acids in the presence of compounds containing carbonyl groups

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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A Study Toward Synthesis of Triaryl(Fluorinated)-Gallium, Their Rollover and Classic Cyclometallated Species and Aryl-Ga Clusters
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C H Activation Coupling Reactions
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Monodentate, N‐Heterocyclic Carbene‐Type Coordination of 2,2′‐Bipyridine and 1,10‐Phenanthroline to Iridium
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A Simple Preparation of Pyridine‐Derived N‐Heterocyclic Carbenes and Their Transformation into Bridging Ligands by Orthometalation
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Anion‐Exchange‐Triggered 1,3‐Shift of an NH Proton to Iridium in Protic N‐Heterocyclic Carbenes: Hydrogen‐Bonding and Ion‐Pairing Effects
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Metallacyclic Pyridylidene Structures from Reactions of Terminal Pyridylidenes with Alkenes and Acetylene
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Monodentate, N‐Heterocyclic Carbene‐Type Coordination of 2,2′‐Bipyridine and 1,10‐Phenanthroline to Iridium
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A Simple Preparation of Pyridine‐Derived N‐Heterocyclic Carbenes and Their Transformation into Bridging Ligands by Orthometalation
inferred← citeshttps://doi.org/10.1002/anie.200905691openalex-snapshot
Anion‐Exchange‐Triggered 1,3‐Shift of an NH Proton to Iridium in Protic N‐Heterocyclic Carbenes: Hydrogen‐Bonding and Ion‐Pairing Effects
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Metallacyclic Pyridylidene Structures from Reactions of Terminal Pyridylidenes with Alkenes and Acetylene
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Cationic Heterocycles as Ligands: Synthesis and Reactivity with Anionic Nucleophiles of Cationic Triruthenium Clusters Containing C‐Metalated N‐Methylquinoxalinium or N‐Methylpyrazinium Ligands
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Effect of the Nature of the Substituent in N‐Alkylimidazole Ligands on the Outcome of Deprotonation: Ring Opening versus the Formation of N‐Heterocyclic Carbene Complexes
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β‐Protic Pyrazole and N‐Heterocyclic Carbene Complexes: Synthesis, Properties, and Metal–Ligand Cooperative Bifunctional Catalysis
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CN Bond Formation by O2‐Mediated Dehydrogenative Coupling of Phenyl and NH‐pyridylidene Ligands on TpIrIII Complexes
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Tautomerisation of 2‐Substituted Pyridines to N‐Heterocyclic Carbene Ligands Induced by the 16 e− Unsaturated [TpMe2IrIII(C6H5)2] Moiety
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Reactivity Studies of Iridium Pyridylidenes [TpMe2Ir(C6H5)2(C(CH)3C(R)NH] (R=H, Me, Ph)
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Computational Study of the C‐ and N‐Bound Tautomers of [Ru(Cl)(H)(CO)‐(PPh3)2(IiPrMe2)] (IiPrMe2 = 3‐Isopropyl‐4,5‐dimethylimidazol‐2‐ylidene)
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Substituted Hammick carbenes: The effects of fused rings and hetero atoms through DFT calculations
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Reaching for two new stable ambiphilic quinoline-derivedN-heterocyclic carbenes at DFT level
inferred← citeshttps://doi.org/10.1007/s13361-015-1165-3openalex-snapshot
Activation of Methane by the Pyridine Radical Cation and its Substituted Forms in the Gas Phase
inferred← citeshttps://doi.org/10.1016/b978-0-12-800976-5.00002-3openalex-snapshot
Normal and Abnormal N-Heterocyclic Carbene Ligands
inferred← citeshttps://doi.org/10.1016/b978-0-12-818655-8.00068-8openalex-snapshot
Pyridines and Their Benzo Derivatives: Structure
inferred← citeshttps://doi.org/10.1016/b978-008044992-0.00601-5openalex-snapshot
Pyridines and their Benzo Derivatives: Structure
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Dearomatization of Transition Metal-Coordinated N-Heterocyclic Ligands and Related Chemistry
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The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the Year 2007
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Rhodium and iridium olefin complexes with bulky cyclopentadienyl and hydrotris(pyrazolyl)borate ligands
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Different coordination modes of an aryl-substituted hydrotris(pyrazolyl)borate ligand in rhodium and iridium complexes
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Six- and seven-membered ring carbenes: Rational synthesis of amidinium salts, generation of carbenes, synthesis of Ag(I) and Cu(I) complexes
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Theoretical studies of iridium-mediated tautomerization of substituted pyridines
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Diaryl(fluorinated)-mercury species as potential precursors of triaryl(fluorinated)-gallium to be used in the synthesis of cyclometallated Ga compounds and unexpected formation of aryl-Ga clusters
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A DFT study on pyridine-derived N-heterocyclic carbenes
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Mesoionic and Related Less Heteroatom-Stabilized N-Heterocyclic Carbene Complexes: Synthesis, Catalysis, and Other Applications
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Activation of Small Molecules by the Metal–Amido Bond of Rhodium(III) and Iridium(III) (η5-C5Me5)M-Aminopyridinate Complexes
inferred← citeshttps://doi.org/10.1021/acs.joc.3c02274openalex-snapshot
PPM Ir-f-phamidol-Catalyzed Asymmetric Hydrogenation of γ-Amino Ketones Followed by Stereoselective Cyclization for Construction of Chiral 2-Aryl-pyrrolidine Pharmacophores
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00156openalex-snapshot
Osmium- and Iridium-Promoted C–H Bond Activation of 2,2′-Bipyridines and Related Heterocycles: Kinetic and Thermodynamic Preferences
inferred← citeshttps://doi.org/10.1021/acs.organomet.7b00906openalex-snapshot
Osmium Catalysts for Acceptorless and Base-Free Dehydrogenation of Alcohols and Amines: Unusual Coordination Modes of a BPI Anion
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c00044openalex-snapshot
Manganese-Catalyzed Asymmetric Hydrogenation of Pyridyl Cyclic N-Alkyl Imines: A Direct Route to S-Nicotine and Derivatives
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b02896openalex-snapshot
Metal-Free Decarboxylative Alkoxylation of 2-Picolinic Acid and Its Derivatives with Cyclic Ethers: One Step Construction of C–O and C–Cl Bonds
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b03043openalex-snapshot
Transition-Metal-Free Decarboxylative Arylation of 2-Picolinic Acids with Arenes under Air Conditions
inferred← citeshttps://doi.org/10.1021/cr8005087openalex-snapshot
Beyond Conventional N -Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization
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Switching between κ2and κ3Bis(pyrazol-1-yl)acetate Ligands by Tuning Reaction Conditions: Synthesis, Spectral, Electrochemical, Structural, and Theoretical Studies on Arene-Ru(II) Derivatives of Bis(azol-1-yl)acetate Ligands
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Experimental and Computational Investigation of C−N Bond Activation in Ruthenium N-Heterocyclic Carbene Complexes
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Ruthenium-Mediated C–H Functionalization of Pyridine: The Role of Vinylidene and Pyridylidene Ligands
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Iridium-Catalyzed Asymmetric Hydrogenation of 2-Pyridyl Cyclic Imines: A Highly Enantioselective Approach to Nicotine Derivatives
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Imidazol-2-yl Complexes of Cp*Ir as Bifunctional Ambident Reactants
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From N-Alkylimidazole Ligands at a Rhenium Center: Ring Opening or Formation of NHC Complexes
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Isolation of Free Phenylide-like Carbanions with N-Heterocyclic Carbene Frameworks
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Metal–Ligand Proton Tautomerism, Electron Transfer, and C(sp 3 )–H Activation by a 4-Pyridinyl-Pincer Iridium Hydride Complex
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A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition
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Ir(III)-Catalyzed Aromatic C–H Bond Functionalization via Metal Carbene Migratory Insertion
inferred← citeshttps://doi.org/10.1021/om100431uopenalex-snapshot
Pyridine-Derived N-Heterocyclic Carbenes: An Experimental and Theoretical Evaluation of the Bonding in and Reactivity of Selected Normal and Abnormal Complexes of Nickel(II) and Palladium(II)
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On the Existence of an N-Metalated N-Heterocyclic Carbene: A Theoretical Study
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Trapping of Pyrid-2-ylidenes by [Ru3(CO)12]: Orthometalated Pyrid-2-ylidenes in Triruthenium Clusters
inferred← citeshttps://doi.org/10.1021/om101130gopenalex-snapshot
Reactivity of Cationic Triruthenium Carbonyl Clusters: From Pyrimidinium Ligands to N-Heterocyclic Carbenes
inferred← citeshttps://doi.org/10.1021/om101173eopenalex-snapshot
Osmium NHC Complexes from Alcohol-Functionalized Imidazoles and Imidazolium Salts
inferred← citeshttps://doi.org/10.1021/om200983aopenalex-snapshot
Reaction of [Ru3(CO)12] with Phenazine: Synthesis of C-Metalated Derivatives That Formally Arise from a C–H Oxidative Addition or a Long-Distance C-to-N Prototropy
inferred← citeshttps://doi.org/10.1021/om3000554openalex-snapshot
Coupling of Aromatic Aldehydes with CO2Me-Substituted TpMe2Ir(III) Metallacyclopentadienes
inferred← citeshttps://doi.org/10.1021/om301058nopenalex-snapshot
Alkenylation of 2-Methylpyridine via Pyridylidene–Osmium Complexes
inferred← citeshttps://doi.org/10.1021/om400968sopenalex-snapshot
Tautomerization of Pyridine and 2-Substituted Pyridines to Pyridylidene Ligands by the Iridium(I)–Diene Complex TpMe2Ir(η4-CH2═C(Me)C(Me)═CH2)
inferred← citeshttps://doi.org/10.1021/om500204sopenalex-snapshot
Selective meta-C–H Bond Activation of Substituted 1,3-Chlorobenzenes Promoted by an Osmium Pyridyl Complex
inferred← citeshttps://doi.org/10.1021/om8000839openalex-snapshot
Synthesis of a Benzodiazepine-Derived Rhodium NHC Complex by C−H Bond Activation
inferred← citeshttps://doi.org/10.1021/om800285nopenalex-snapshot
Isolation and Interconversion of Protic N-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation of N -(2-Pyridyl)benzimidazole and Allyl Alcohol
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Cβ(sp2)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carbyne, and NH-Tautomerized α-Substituted Pyridine Ligands
inferred← citeshttps://doi.org/10.1021/om800706gopenalex-snapshot
Aromatic C−H Bond Activation of 2-Methylpyridine Promoted by an Osmium(VI) Complex: Formation of an η2(N,C)-Pyridyl Derivative
inferred← citeshttps://doi.org/10.1021/om8007772openalex-snapshot
NH-Tautomerization of 2-Substituted Pyridines and Quinolines on Osmium and Ruthenium: Determining Factors and Mechanism
inferred← citeshttps://doi.org/10.1021/om8011954openalex-snapshot
NH-Tautomerization of Quinolines and 2-Methylpyridine Promoted by a Hydride-Iridium(III) Complex: Importance of the Hydride Ligand
inferred← citeshttps://doi.org/10.1021/om900335bopenalex-snapshot
Stoichiometric and Catalytic Deuteration of Pyridine and Methylpyridines by H/D Exchange with Benzene-d6 Promoted by an Unsaturated Osmium Tetrahydride Species
inferred← citeshttps://doi.org/10.1021/om900541ropenalex-snapshot
Ethylene Coordination and Acetylene Dimerization at Tp′IrIII Centers
inferred← citeshttps://doi.org/10.1021/om900635popenalex-snapshot
Olefin−Alkylidene Equilibrium of 2-Vinylpyridine in Osmium- and Ruthenium-Hydrido-Tris(pyrazolyl)borate and Osmium-Cyclopentadienyl Complexes
inferred← citeshttps://doi.org/10.1039/b804931aopenalex-snapshot
Hydrogen bonding-assisted tautomerization of pyridine moieties in the coordination sphere of an Ir(i) complex
inferred← citeshttps://doi.org/10.1039/b909837bopenalex-snapshot
Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine
inferred← citeshttps://doi.org/10.1039/b915085dopenalex-snapshot
Modular syntheses of chiral and achiral C,N-chelated Pd(ii)-pyridinylidenes
inferred← citeshttps://doi.org/10.1039/b926542bopenalex-snapshot
Mechanism for C–H bond activation in ethylene in the gas phase vs. in solution – vinylic or agostic? Revisiting the case of protonated Cp*Rh(C2H4)2
inferred← citeshttps://doi.org/10.1039/c0cc03935gopenalex-snapshot
A simple, general route to 2-pyridylidene transition metal complexes
inferred← citeshttps://doi.org/10.1039/c2dt31754kopenalex-snapshot
Iridium(iii) complexes with polypyridine ligands coordinated as N-heterocyclic carbenes. Synthesis, structure and photophysical properties
inferred← citeshttps://doi.org/10.1039/c3cc42655fopenalex-snapshot
Pyridine-based dicarbene ligand: synthesis and structure of a bis-2-pyridylidene palladium complex
inferred← citeshttps://doi.org/10.1039/c4cc04457fopenalex-snapshot
Metal–ligand bifunctional reactivity and catalysis of protic N-heterocyclic carbene and pyrazole complexes featuring β-NH units
inferred← citeshttps://doi.org/10.1039/c4cc10109jopenalex-snapshot
Imine-functionalised protic NHC complexes of Ir: direct formation by C–H activation
inferred← citeshttps://doi.org/10.1039/d0cc03480kopenalex-snapshot
Conventional and unconventional alkyne activations by Ru and Os for unprecedented dimetalated quinolizinium complexes
inferred← citeshttps://doi.org/10.1039/d2nj06026dopenalex-snapshot
A rollover Ir( iii ) complex of 2-(6-bromopyridin-2-yl)imidazo[1,2- a ]pyridine
inferred← citeshttps://doi.org/10.1039/d6cc01865copenalex-snapshot
Decarboxylative arylation and alkoxylation of pyridine-2-carboxylic acid N -oxide derivatives via electrophilic carbene: access to lucidimine E and australine
inferred← citeshttps://doi.org/10.1107/s2053229615023797openalex-snapshot
Comparison of thallium(I) complexes with mesityl-substituted tris(pyrazolyl)hydroborate ligands, [Tl{HB(3-Ms-5-Mepz)3}] and [Tl{HB(3-Ms-5-Mepz)2(3-Me-5-Mspz)}]
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