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A Study Toward Synthesis of Triaryl(Fluorinated)-Gallium, Their Rollover and Classic Cyclometallated Species and Aryl-Ga Clusters

https://doi.org/10.2139/ssrn.4475968
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Rollover‐Assisted C(sp2)C(sp3) Bond Formation
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Platinum(II), palladium(II) and gold(III) adducts and cyclometalated derivatives of 6-methoxy-2,2′-bipyridine: A comparative study
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Bidentate BODIPY-appended 2-pyridylimidazo[1,2-a]pyridine ligand and fabrication of luminescent transition metal complexes
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Photocatalytic Aerobic Dehydrogenation of N-Heterocycles with Ir(III) Photosensitizers Bearing the 2(2′-Pyridyl)benzimidazole Scaffold
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Enhanced Photocatalytic Activity of TiO2 Modified with GaI toward Environmental Application
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Preparation and Photophysical Properties of Bis(tridentate) Iridium(III) Emitters: Pincer Coordination of 2,6-Di(2-pyridyl)phenyl
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Rh(III)-Catalyzed Oxidative Annulation of 2-Phenylimidazo[1,2-a]pyridines with Alkynes: Mono versus Double C–H Activation
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Osmium- and Iridium-Promoted C–H Bond Activation of 2,2′-Bipyridines and Related Heterocycles: Kinetic and Thermodynamic Preferences
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Pyrazole-Based PCN Pincer Complexes of Palladium(II): Mono- and Dinuclear Hydroxide Complexes and Ligand Rollover C–H Activation
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Rhodium(III)-Catalyzed Oxidative Annulation of 7-Azaindoles and Alkynes via Double C–H Activation
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Novel Quinoline-based Ir(III) Complexes Exhibit High Antitumor Activity in Vitro and in Vivo
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A carbon-bonded tris(2,2'-bipyridine)iridium(III) complex: (2,2'-bipyridinyl-C3,N')bis(2,2'-bipyridine-N,N')iridium(III) perchlorate-water (3/1)
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Analysis of the proton and carbon-13 NMR spectra of [Ir(Hbpy-C3,N')(bpy-N,N')2]3+: evidence for a carbon-bonded structure
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Solution structure and properties of the [(2,2'-bipyridinyl-C3,N')bis(2,2'-bipyridine-N,N')iridium(III)](2+) hydrate ion, "pseudo-[Ir(bpy)3(OH)]2+"
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Rollover Cyclometalation with 2-(2′-Pyridyl)quinoline
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Luminescent and Redox-Active Iridium(III)-Cyclometalated Compounds with Terdentate Ligands
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A stable monodentate 2,2'-bipyridine complex of iridium(III): a model for reactive intermediates in ligand displacement reactions of tris-2,2'-bipyridine metal complexes
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Triphenylgallium1
inferredcites →https://doi.org/10.1021/ja0646592openalex-extracted
Iridium(III)-Induced Isomerization of 2-Substituted Pyridines to N-Heterocyclic Carbenes
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Intramolecular C−H Activation Directed Self-Assembly of an Organoplatinum(II) Molecular Square
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Rearrangement of Pyridine to Its 2-Carbene Tautomer Mediated by Iridium
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Rollover Cyclometalation Pathway in Rhodium Catalysis: Dramatic NHC Effects in the C–H Bond Functionalization
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Rh(III)-Catalyzed C–H Bond Activation along with “Rollover” for the Synthesis of 4-Azafluorenes
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Cyclopalladation of 6-Substituted-2,2‘-bipyridines. Metalation of Unactivated Methyl Groups vs Aromatic C−H Activation
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Main-group chemistry of the 2,4,6-tris(trifluoromethyl)phenyl substituent: x-ray crystal structures of [2,4,6-(CF3)3C6H2]2Zn, [2,4,6-(CF3)3C6H2]2Cd(MeCN) and [2,4,6-(CF3)3C6H3]2Hg
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Multiple C−H Bond Activation. Threefold-Deprotonated 6-Phenyl-2,2‘-bipyridine as a Bridging Ligand in Dinuclear Platinum(II) Derivatives
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Activation of a C−H Bond in a Pyridine Ring. Reaction of 6-Substituted 2,2‘-Bipyridines with Methyl and Phenyl Platinum(II) Derivatives: N‘,C(3)-“Rollover” Cyclometalation
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Stoichiometric Oxy Functionalization and CH Activation Studies of Cyclometalated Iridium(III) 6-Phenyl-2,2‘-Bipyridine Hydrocarbyl Complexes
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Intramolecular C(sp2)−H Bond Activation in 6,6′-Dimethoxy-2,2′-Bipyridine with Gold(III). Crystal and Molecular Structure of the First N′,C(3) “Rollover” Cycloaurated Derivative
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Heterobimetallic Rollover Derivatives
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Mesoionic Complexes of Platinum(II) Derived from “Rollover” Cyclometalation: A Delicate Balance between Pt–C(sp3) and Pt–C(sp2) Bond Cleavage as a Result of Different Reaction Conditions
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Oxidative Addition of MeI to a Rollover Complex of Platinum(II): Isolation of the Kinetic Product
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Cyclometalation of 2,2′-Bipyridine. Mono- and Dinuclear C,N Platinum(II) Derivatives
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Cyclometalation of 6-Phenyl-2,2′-Bipyridine and Iridium: Synthesis, Characterization, and Reactivity Studies
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Versatile, Selective, and Switchable Coordination Modes of Pincer Click Ligands
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Reaction of tris-arylgallium(iii) with water: biaryl coupling versus Ga–C hydrolysis
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New seven membered palladacycles: C–Br bond activation of 2-bromo-pyridine derivative by Pd(II)
inferredcites →https://doi.org/10.1039/c39850000609openalex-extracted
‘Roll-over’ 3-metallation of co-ordinated 2,2′-bipyridyl in the thermal rearrangement of diary(bipyridyl)platinum( II ) complexes: molecular structure of (µ-bidyl)[PtPh(Bu t py)] 2
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Hemilability of P(X)N-type ligands (X = O, N–H): rollover cyclometalation and benzene C–H activation from (P(X)N)PtMe 2 complexes
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Assembly of symmetrical and unsymmetrical platinum( ii ) rollover complexes with bidentate phosphine ligands
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Rh I /Rh III catalyst-controlled divergent aryl/heteroaryl C–H bond functionalization of picolinamides with alkynes
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A direct access to heterobimetallic complexes by roll-over cyclometallation
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C–H addition reactivity of 2-phenylpyridine and 2,2′-bipyridine with pentaphenylborole
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C sp2 –Br bond activation of Br-pyridine by neophylpalladacycle: formation of binuclear seven-membered palladacycle and bipyridine species
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A serendipitous self-assembly synthesis of CNN–Pt pincer complexes
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A rollover Ir( iii ) complex of 2-(6-bromopyridin-2-yl)imidazo[1,2- a ]pyridine
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OLEX2 : a complete structure solution, refinement and analysis program
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A dicationic gallium–oxo–hydroxide cage compound
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Diphenylmercury, redetermined at 120 K: sheets built from a single C—H...π(arene) hydrogen bond
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A short history of SHELX
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Diphenylmercury: a refinement
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Crystal structure of di-p-tolyl mercury
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Rhodium-catalyzed and Coordination-assisted Regioselective Alkenylation of Aromatic C–H Bonds with Terminal Silylacetylenes
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