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A New Disilene with π-Accepting Groups from the Reaction of Disilyne RSi≡SiR (R = Si i Pr[CH(SiMe 3 ) 2 ]) with Isocyanides

https://doi.org/10.1021/ja212065a

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Structural Chemistry of Organic Silicon Compounds

inferredcites →https://doi.org/10.1002/0470857269.ch5openalex-snapshot

Recent Advances in the Chemistry of Silicon–Silicon Multiple Bonds

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Synthesis and Characterization of a Digermanium Analogue of an Alkyne

inferredcites →https://doi.org/10.1002/9780470669266openalex-snapshot

Organometallic Compounds of Low‐Coordinate Si, Ge, Sn and Pb

inferredcites →https://doi.org/10.1002/anie.199414891openalex-snapshot

Stable Tetrakis(trialkylsilyl)disilenes; Synthesis, X‐Ray Structures, and UV/VIS Spectra

inferredcites →https://doi.org/10.1002/anie.200353347openalex-snapshot

A Silicon Analogue of Vinyllithium: Structural Characterization of a Disilenide

inferredcites →https://doi.org/10.1002/poc.1617openalex-snapshot

Reactivity of the disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]2) toward bis(silylcyanide) forming a 1,4‐diaza‐2,3‐disilabenzene analog

inferredcites →https://doi.org/10.1002/zaac.200400177openalex-snapshot

Disilynes. III [1] A Relatively Stable Disilyne RSi≡SiR (R = SiMe(SitBu3)2)

inferredcites →https://doi.org/10.1007/s11201-006-9011-xopenalex-snapshot

Tetrasila-1,3-butadiene and its transformation to disilenyl anions

inferredcites →https://doi.org/10.1016/j.jorganchem.2010.07.008openalex-snapshot

Silicon version of enamines: Amino-substituted disilenes by the reactions of the disilyne RSi SiR (R = Si Pr[CH(SiMe3)2]2) with amines

inferredcites →https://doi.org/10.1016/j.synthmet.2009.01.007openalex-snapshot

Interaction of π-bonds of the silicon–silicon triple bond with alkali metals: An isolable anion radical upon reduction of a disilyne

inferredcites →https://doi.org/10.1016/s0065-3055(05)54003-6openalex-snapshot

Progress in the Chemistry of Stable Disilenes

inferredcites →https://doi.org/10.1016/s0065-3055(08)60469-4openalex-snapshot

Chemistry of Stable Disilenes

inferredcites →https://doi.org/10.1021/ja00159a023openalex-snapshot

Group IV double bonds: shape deformation and substituent effects

inferredcites →https://doi.org/10.1021/ja00179a057openalex-snapshot

Substituent effects on the geometries and energies of the silicon-silicon double bond

inferredcites →https://doi.org/10.1021/ja00197a061openalex-snapshot

Trans-bending at double bonds. Occurrence and extent

inferredcites →https://doi.org/10.1021/ja00252a002openalex-snapshot

Nonclassical distortions at multiple bonds

inferredcites →https://doi.org/10.1021/ja011956sopenalex-snapshot

Possible Strategies toward the Elusive Tetraaminodisilene

inferredcites →https://doi.org/10.1021/ja0257164openalex-snapshot

Synthesis and Characterization of 2,6-Dipp 2 -H 3 C 6 SnSnC 6 H 3 -2,6-Dipp 2 (Dipp = C 6 H 3 -2,6-Pr i 2 ): A Tin Analogue of an Alkyne

inferredcites →https://doi.org/10.1021/ja055372sopenalex-snapshot

Reactions of the Heavier Group 14 Element Alkyne Analogues Ar‘EEAr‘ (Ar‘ = C6H3-2,6(C6H3-2,6-Pri2)2; E = Ge, Sn) with Unsaturated Molecules: Probing the Character of the EE Multiple Bonds

inferredcites →https://doi.org/10.1021/ja057205yopenalex-snapshot

Synthesis and Properties of a New Kinetically Stabilized Digermyne: New Insights for a Germanium Analogue of an Alkyne

inferredcites →https://doi.org/10.1021/ja065817sopenalex-snapshot

Solid-State 29Si NMR Study of RSiSiR: A Tool for Analyzing the Nature of the Si−Si Bond

inferredcites →https://doi.org/10.1021/ja066762xopenalex-snapshot

An Isolable Disilyne Anion Radical and a New Route to the Disilenide Ion upon Reduction of a Disilyne

inferredcites →https://doi.org/10.1021/ja072759hopenalex-snapshot

Reactivity of a Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) toward π-Bonds: Stereospecific Addition and a New Route to an Isolable 1,2-Disilabenzene

inferredcites →https://doi.org/10.1021/ja107160gopenalex-snapshot

An N-Heterocyclic Carbene−Disilyne Complex and Its Reactivity toward ZnCl2

inferredcites →https://doi.org/10.1021/ja1091744openalex-snapshot

Unsymmetrically Substituted Disilyne Dsi2iPrSi—Si≡Si—SiNpDsi2 (Np = CH2tBu): Synthesis and Characterization

inferredcites →https://doi.org/10.1021/ja202605xopenalex-snapshot

Unusual Reactivity of a Disilyne with 4-Dimethylaminopyridine: Formation of an Intramolecularly N-Coordinated Silylene and Its Isomerization to a Zwitterionic Silyl Anion

inferredcites →https://doi.org/10.1021/ja8061002openalex-snapshot

Synthesis and Reactions of a Stable 1,2-Diaryl-1,2-dibromodisilene: A Precursor for Substituted Disilenes and a 1,2-Diaryldisilyne

inferredcites →https://doi.org/10.1021/ja807974aopenalex-snapshot

Reactivity of the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) toward Silylcyanide: Two Pathways To Form the Bis-Adduct [RSiSiR(CNSiMe3)2] with Some Silaketenimine Character and a 1,4-Diaza-2,3-disilabenzene Analogue

inferredcites →https://doi.org/10.1021/ja910157hopenalex-snapshot

Addition of Amines and Hydroborane to the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) Giving Amino- and Boryl-Substituted Disilenes

inferredcites →https://doi.org/10.1021/ja9108566openalex-snapshot

Reactivity of an Aryl-Substituted Silicon−Silicon Triple Bond: Reactions of a 1,2-Diaryldisilyne with Alkenes

inferredcites →https://doi.org/10.1021/ja992150jopenalex-snapshot

Reversible Transformation between a Diaminosilylene and a Novel Disilene

inferredcites →https://doi.org/10.1021/ja993346mopenalex-snapshot

Synthesis and Characterization of 2,6-Trip 2 H 3 C 6 PbPbC 6 H 3 -2,6-Trip 2 (Trip = C 6 H 2 -2,4,6- i -Pr 3 ): A Stable Heavier Group 14 Element Analogue of an Alkyne

inferredcites →https://doi.org/10.1021/om040056sopenalex-snapshot

Disilenyllithium from Tetrasila-1,3-butadiene: A Silicon Analogue of a Vinyllithium

inferredcites →https://doi.org/10.1021/om200106hopenalex-snapshot

Hydroboration of Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2), Giving Boryl-Substituted Disilenes

inferredcites →https://doi.org/10.1021/om900164hopenalex-snapshot

Reactivity of the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) toward Nitriles: Unexpected Formation of Triaza-1,4-disilabicyclo[2.2.2]octa-2,5,7-triene Derivatives

inferredcites →https://doi.org/10.1039/b612202gopenalex-snapshot

Lewis base induced tuning of the Ge–Ge bond order in a “digermyne”

inferredcites →https://doi.org/10.1039/c0dt00115eopenalex-snapshot

Reactivity of an aryl-substituted silicon–silicon triple bond: 1,2-disilabenzenes from the reactions of a 1,2-diaryldisilyne with alkynes

inferredcites →https://doi.org/10.1039/c0nj00027bopenalex-snapshot

Addition of methyllithium to disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]), giving a disilenyllithium, and its unexpected isomerization to a disilacyclopropylsilyllithium

inferredcites →https://doi.org/10.1126/science.1102209openalex-snapshot

A Stable Compound Containing a Silicon-Silicon Triple Bond

inferredcites →https://doi.org/10.1126/science.214.4527.1343openalex-snapshot

Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond

inferredcites →https://doi.org/10.1246/cl.2005.1564openalex-snapshot

Disilenyl Anions Derived from Reduction of Tetrakis(di-tert-butylmethylsilyl)disilene with Metal Naphthalenide through a Disilene Dianion Intermediate: Synthesis and Characterization

inferredcites →https://doi.org/10.1246/cl.2008.1044openalex-snapshot

An Isolable Boryl-substituted Disilene from the Reaction of an sp2-type Silyl Anion with Haloboranes: Synthesis and Characterization

inferredcites →https://doi.org/10.1351/pac200880030447openalex-snapshot

Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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A New Strategy for Coupling Amides or Nitriles with Diarylketones Promoted by Samarium Metal Under the Catalysis of Cui

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Reversible, vollständige Spaltung von SiSi‐Bindungen durch Isocyanidinsertion

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Von einem elektronenreichen Bis(boraketenimin) zu einem elektronenarmen Diboren

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Reversible, Complete Cleavage of SiSi Double Bonds by Isocyanide Insertion

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From an Electron‐Rich Bis(boraketenimine) to an Electron‐Poor Diborene

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Formation and Reactivity of Electron‐Precise B−B Single and Multiple Bonds

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Bonding Relationship between Silicon and Germanium with Group 13 and Heavier Elements of Groups 14–16

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The Addition of Nitriles to Tetramesityldisilene: A Comparison of the Reactivity between Surface and Molecular Disilenes

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Coordination Chemistry of Main Group Metals with Organic Isocyanides

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Anorganische Chemie 2012

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Broadband‐Solubility Diketopyrrolopyrrole Derivative with Both Polar Cyano and Nonpolar Alkyl Groups for Stable Organic Photosensors and Diffusion‐Processed Organic Solar Cells

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Multiple Bonds with Silicon: Recent Advances in Synthesis, Structure, and Functions of Stable Disilenes

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A Quest for (sila)0-4cyclopentasilylenes and their Arduengo Analogs by DFT

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Multiple Bonds to Silicon (Recent Advances in the Chemistry of Silicon Containing Multiple Bonds)

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29 Si NMR Spectroscopy

inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00174-8openalex-snapshot

Low-Valent Silicon Compounds

inferred← citeshttps://doi.org/10.1016/j.chempr.2024.01.007openalex-snapshot

Substituent exchange between an imino(silyl)silylene and aryl isocyanides

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NHCs in Main Group Chemistry

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Reactivity of a Phosphinoamidinate-Stabilized Disilylene toward H–X Bonds

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Comparison of RNC Coupling and CO Coupling Mediated by Cr–Cr Quintuple Bond and B–B Multiple Bonds: Main Group Metallomimetics

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Flash Communication: Dual Geminal sp 3 C–H Activation of a TREN TMS Ce-benzyl Complex and Dearylation of the Ylide

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Ketenes and Other Cumulenes as Reactive Intermediates

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Mechanisms of Reactions of Open-Shell, Heavier Group 14 Derivatives with Small Molecules: n−π* Back-Bonding in Isocyanide Complexes, C–H Activation under Ambient Conditions, CO Coupling, and Ancillary Molecular Interactions†This Award Article summarizes, including more recent results, one of the…

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(NHC)Si═C═N–R: A Two-Coordinated Si0-Isocyanide Compound as Si(NHC) Transfer Reagent

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Disilicon Dicarbonyl Complex: Synthesis and Protonation of CO with O–H Bond

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Isolation of a Diborane(6) Dication: Formation and Cleavage of an Electron-Precise B(sp 3 )–B(sp 3 ) Bond

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NHC-Stabilized Silicon–Carbon Mixed Cumulene

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Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron

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Synthesis of Less-Substituted Borirenes Enabled by a Crystalline Arylhalohydroborane Reagent

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Stable Push–Pull Disilene: Substantial Donor–Acceptor Interactions through the Si═Si Double Bond

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Synthesis of Silaketenimine Anion and Its Coupling with Isocyanide

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Synthesis of Dibenzo[b,f]silepins with a Benzoquinolyl Ligand

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Carbon, silicon, germanium, tin and lead

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Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements

inferred← citeshttps://doi.org/10.1039/c7dt01796kopenalex-snapshot

Carbene stabilized interconnected bis-germylene and its silicon analogue with small methyl substituents

inferred← citeshttps://doi.org/10.1039/c7dt02357jopenalex-snapshot

Heteroaryldisilenes: heteroaryl groups serve as electron acceptors for SiSi double bonds in intramolecular charge transfer transitions

inferred← citeshttps://doi.org/10.1039/d1sc02947aopenalex-snapshot

On 1,3-phosphaazaallenes and their diverse reactivity

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Yb/Si frustrated Lewis pairs with a labile naphthalenyl bridge

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4.4.24.3 Silyl Cyanides (Update 2017)

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Recent Developments in the Reactivity of Stable Disilynes

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Activation of Isocyanides and Hydrosilanes by a Cationic [CCH] Subunit in a Tetrairon–Tetracarbon Cluster

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Highly Coplanar (E)-1,2-Di(1-naphthyl)disilene Involving a Distinct CH–π Interaction with the Perpendicularly Oriented Protecting Eind Group

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