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Phenolate Hydroxylation in a Bis(μ-oxo)dicopper(III) Complex: Lessons from the Guanidine/Amine Series

https://doi.org/10.1021/ja807809x
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Reactivity of Copper(I) Complexes Towards Dioxygen
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Oxygen Binding, Activation, and Reduction to Water by Copper Proteins
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Mechanism of the Aliphatic Hydroxylation Mediated by a Bis(μ‐oxo)dicopper( III ) Complex
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Crystallographic Characterization of a Synthetic 1:1 End‐On Copper Dioxygen Adduct Complex
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The First Crystal Structure of Tyrosinase: All Questions Answered?
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Reactions of a Copper(II) Superoxo Complex Lead to CH and OH Substrate Oxygenation: Modeling Copper‐Monooxygenase CH Hydroxylation
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Tyrosinase‐Like Reactivity in a CuIII2(μ‐O)2 Species
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Monooxygenase Activity of Type 3 Copper Proteins
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Tuning of Copper( I )–Dioxygen Reactivity by Bis(guanidine) Ligands
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Orthoamide, XL. Herstellung von 1,1,2,3,3‐pentasubstituierten und 1,1,2,2,3,3‐hexasubstituierten Guanidiniumsalzen sowie von 1,1,2,3,3‐Pentaalkylguanidinen
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Stereochemistry of guanidine–metal interactions: Implications for L ‐arginine–metal interactions in protein structure and function
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Copper-Dioxygen and Copper-Oxo Species Relevant to Copper Oxygenases and Oxidases
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Bioinorganic Chemistry of Copper
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Validation of density functional modeling protocols on experimental bis(μ-oxo)/μ-η2:η2-peroxo dicopper equilibria
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Controlling the acidity of the carboxylic group by a ferrocene based redox switch
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Hydroxylation of a methyl group: synthesis of [Cu2(btmmO)2I]+ and of [Cu2(btmmO)2]2+ containing the novel ligand {bis(trimethylmethoxy)guanidino}propane (btmmO) by copper-assisted oxygen activation
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Modeling tyrosinase activity. Effect of ligand topology on aromatic ring hydroxylation: An overview
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Dioxygen activation by copper sites: relative stability and reactivity of (μ-η2:η2-peroxo)- and bis(μ-oxo)dicopper cores
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Ligand Influences in Copper-Dioxygen Complex-Formation and Substrate Oxidations
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Biomimetic modeling of copper oxidase reactivity
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Monooxygenase Activity of Type 3 Copper Proteins
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Making and Breaking the Dioxygen O−O Bond: New Insights from Studies of Synthetic Copper Complexes
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Monooxygenase Activity of Octopus vulgaris Hemocyanin
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Recent Structural Work on the Oxygen Transport Protein Hemocyanin
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Copper-Dioxygen Complexes. Inorganic and Bioinorganic Perspectives
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Structure and Spectroscopy of Copper−Dioxygen Complexes
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Reactivity of Dioxygen−Copper Systems
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Proton-Coupled Electron Transfer
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Proton-Coupled Electron Transfer
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Chemical Redox Agents for Organometallic Chemistry
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Multicopper Oxidases and Oxygenases
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Solvent Effects on the Conversion of Dicopper(II) μ-η2:η2-Peroxo to Bis-μ-oxo Dicopper(III) Complexes: Direct Probing of the Solvent Interaction
inferredcites →https://doi.org/10.1021/ic052185mopenalex-snapshot
Copper−Dioxygen Adducts and the Side-on Peroxo Dicopper(II)/Bis(μ-oxo) Dicopper(III) Equilibrium: Significant Ligand Electronic Effects
inferredcites →https://doi.org/10.1021/ja002527hopenalex-snapshot
Differential Reactivity between Interconvertible Side-On Peroxo and Bis-μ-oxodicopper Isomers Using Peralkylated Diamine Ligands
inferredcites →https://doi.org/10.1021/ja012732copenalex-snapshot
Proton-Coupled Electron Transfer versus Hydrogen Atom Transfer in Benzyl/Toluene, Methoxyl/Methanol, and Phenoxyl/Phenol Self-Exchange Reactions
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Oxygenation of Phenols to Catechols by A (μ-η2:η2-Peroxo)dicopper(II) Complex: Mechanistic Insight into the Phenolase Activity of Tyrosinase
inferredcites →https://doi.org/10.1021/ja015721sopenalex-snapshot
C−H Bond Activation of External Substrates with a Bis(μ-oxo)dicopper(III) Complex
inferredcites →https://doi.org/10.1021/ja029380+openalex-snapshot
Oxidation Mechanism of Phenols by Dicopper−Dioxygen (Cu2/O2) Complexes
inferredcites →https://doi.org/10.1021/ja045191aopenalex-snapshot
Substrate Oxidation by Copper−Dioxygen Adducts: Mechanistic Considerations
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μ-η2:η2-Peroxodicopper(II) Complex with a Secondary Diamine Ligand: A Functional Model of Tyrosinase
inferredcites →https://doi.org/10.1021/ja9717673openalex-snapshot
Cu K-Edge XAS Study of the [Cu2(μ-O)2] Core: Direct Experimental Evidence for the Presence of Cu(III)
inferredcites →https://doi.org/10.1021/ja972946nopenalex-snapshot
Irreversible Reduction of Dioxygen by Simple Peralkylated Diamine−Copper(I) Complexes: Characterization and Thermal Stability of a [Cu2(μ-O)2]2+ Core
inferredcites →https://doi.org/10.1021/ja983635vopenalex-snapshot
Exogenous Substrate Reactivity with a [Cu(III)2O2]2+ Core: Structural Implications
inferredcites →https://doi.org/10.1021/ja9918425openalex-snapshot
Spectroscopic and Electronic Structural Studies of the Cu(III)2Bis-μ-oxo Core and Its Relation to the Side-On Peroxo-Bridged Dimer
inferredcites →https://doi.org/10.1021/ja992003lopenalex-snapshot
Resonance Raman Spectroscopy as a Probe of the Bis(μ-oxo)dicopper Core
inferredcites →https://doi.org/10.1021/ja993134popenalex-snapshot
A Systematic K-edge X-ray Absorption Spectroscopic Study of Cu(III) Sites
inferredcites →https://doi.org/10.1021/jp056791eopenalex-snapshot
Theoretical Models on the Cu2O2 Torture Track: Mechanistic Implications for Oxytyrosinase and Small-Molecule Analogues
inferredcites →https://doi.org/10.1021/jp983819wopenalex-snapshot
One-Electron Redox Potentials of Phenols in Aqueous Solution
inferredcites →https://doi.org/10.1038/4193openalex-snapshot
Crystal structure of a plant catechol oxidase containing a dicopper center
inferredcites →https://doi.org/10.1039/b002554mopenalex-snapshot
1,3-Bis(N,N,N′,N′-tetramethylguanidino)propane: synthesis, characterization and bonding properties of the first bidentate, peralkylated guanidine ligand †
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The phenol ortho-oxygenation by mononuclear copper(i) complexes requires a dinuclear µ-η2∶η2-peroxodicopper(ii) complex rather than mononuclear CuO2 species
inferredcites →https://doi.org/10.1039/b300201mopenalex-snapshot
Complexity with simplicity: a steric continuum of chelating diamines with copper( i ) and dioxygen
inferredcites →https://doi.org/10.1039/b406692hopenalex-snapshot
Spectroscopic characterization of the oxo-transfer reaction from a bis(μ-oxo)dicopper( iii ) complex to triphenylphosphine
inferredcites →https://doi.org/10.1039/b617136bopenalex-snapshot
Structural variation in copper( i ) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ 4
inferredcites →https://doi.org/10.1039/b715590eopenalex-snapshot
Synthesis and reactivity of copper( i ) complexes with an ethylene-bridged bis(imidazolin-2-imine) ligand
inferredcites →https://doi.org/10.1039/c39910001611openalex-snapshot
A tyrosinase model system. Phenol ortho-hydroxylation by a binuclear three-coordinate copper(I) complex and dioxygen
inferredcites →https://doi.org/10.1074/jbc.m509785200openalex-snapshot
Crystallographic Evidence That the Dinuclear Copper Center of Tyrosinase Is Flexible during Catalysis
inferredcites →https://doi.org/10.1107/s0108270104007012openalex-snapshot
N,N′-Bis(dipiperidin-1-ylmethylene)propane-1,3-diamine andN,N′-bis(1,3-dimethylperhydropyrimidin-2-ylidene)propane-1,3-diamine
inferredcites →https://doi.org/10.1107/s0108767307043930openalex-snapshot
A short history of SHELX
inferredcites →https://doi.org/10.1126/science.1112081openalex-snapshot
Tyrosinase Reactivity in a Model Complex: An Alternative Hydroxylation Mechanism
inferredcites →https://doi.org/10.1126/science.271.5254.1397openalex-snapshot
Reversible Cleavage and Formation of the Dioxygen O-O Bond Within a Dicopper Complex
inferredcites →https://doi.org/10.1246/cl.2000.1172openalex-snapshot
Tetrahedral Distortion in Copper(II) Complexes of (−)-Sparteine and Its Effect on the Oxygen Adduct Formation

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Benzylic Ligand Hydroxylation Starting from a Dicopper μ‐η2:η2 Peroxo Intermediate: Dramatic Acceleration of the Reaction by Hydrogen‐Atom Donors
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Selective Ortho‐Hydroxylation–Defluorination of 2‐Fluorophenolates with a Bis(μ‐oxo)dicopper(III) Species
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inferred← citeshttps://doi.org/10.1007/s00214-013-1336-xopenalex-snapshot
Dancing multiplicity states supported by a carboxylated group in dicopper structures bonded to O2
inferred← citeshttps://doi.org/10.1007/s00775-016-1420-5openalex-snapshot
High-valent copper in biomimetic and biological oxidations
inferred← citeshttps://doi.org/10.1007/s00775-021-01849-9openalex-snapshot
Room temperature stable multitalent: highly reactive and versatile copper guanidine complexes in oxygenation reactions
inferred← citeshttps://doi.org/10.1007/s10904-010-9431-0openalex-snapshot
Interesting Copper(I) Coordination Polymers of Heterocyclic Monothioether Ligand Containing Long S-Hexadecyl Chain: Syntheses, Structures and Properties
inferred← citeshttps://doi.org/10.1016/b978-0-08-097774-4.00321-1openalex-snapshot
Small Molecule Models: Cu, Ni, Co
inferred← citeshttps://doi.org/10.1016/b978-0-12-409547-2.11554-9openalex-snapshot
Tyrosinase Models: Synthesis, Spectroscopy, Theory and Catalysis
inferred← citeshttps://doi.org/10.1016/b978-0-12-409547-2.14904-2openalex-snapshot
Dioxygen-Binding in Metalloproteins and Corresponding Models
inferred← citeshttps://doi.org/10.1016/bs.adioch.2017.04.001openalex-snapshot
O–O Bond Activation in Cu- and Fe-Based Coordination Complexes: Breaking It Makes the Difference
inferred← citeshttps://doi.org/10.1016/j.ccr.2015.07.019openalex-snapshot
Recent advances in transition-metal-catalyzed selective oxidation of substituted phenols and methoxyarenes with environmentally benign oxidants
inferred← citeshttps://doi.org/10.1016/j.ccr.2019.06.006openalex-snapshot
Recent progress of d10 iodoargentate(I)/iodocuprate(I) hybrids: Structural diversity, directed synthesis, and photochromic/thermochromic properties
inferred← citeshttps://doi.org/10.1016/j.ccr.2024.216301openalex-snapshot
Coupled binuclear copper sites in biology: An experimentally-calibrated computational perspective
inferred← citeshttps://doi.org/10.1016/j.comptc.2021.113524openalex-snapshot
Theoretical studies on dicopper(II) complexes of phenoxido-bridged ligands: Magneto-structural correlations
inferred← citeshttps://doi.org/10.1016/j.ica.2011.02.061openalex-snapshot
Bidentate guanidine ligands with ethylene spacer in copper-dioxygen chemistry: Structural characterization of bis(μ-hydroxo) dicopper complexes
inferred← citeshttps://doi.org/10.1016/j.ica.2014.06.026openalex-snapshot
Preparation of chiral imidazolin-2-imine ligands and their application in ruthenium-catalyzed transfer hydrogenation
inferred← citeshttps://doi.org/10.1016/j.ica.2015.03.015openalex-snapshot
A panel of peralkylated sulfur–guanidine type bases: Novel pro-ligands for use in biomimetic coordination chemistry
inferred← citeshttps://doi.org/10.1016/j.ica.2017.05.073openalex-snapshot
Synthesis and structural characterization of a new high-valent bis(oxo)-bridged manganese(IV) complex and its catechol oxidase activity
inferred← citeshttps://doi.org/10.1016/j.ica.2017.07.010openalex-snapshot
A cryostat for low temperature resonance Raman measurements on operando oxygenated bioinorganic model complexes
inferred← citeshttps://doi.org/10.1016/j.ica.2017.08.017openalex-snapshot
Aggregation of mononuclear copper complexes by metal-oxidation-induced ligand deprotonation
inferred← citeshttps://doi.org/10.1016/j.ica.2017.08.061openalex-snapshot
Preparation of a coordinatively saturated μ-η2:η2-peroxodicopper(II) compound
inferred← citeshttps://doi.org/10.1016/j.ica.2017.09.020openalex-snapshot
Syntheses, characterization, and reactivity of copper complexes with camphor-like tetramethylguanidine ligands
inferred← citeshttps://doi.org/10.1016/j.ijms.2009.11.006openalex-snapshot
Coordination chemistry of nickel(II) nitrate with superbasic guanidines as studied by electrospray mass spectrometry
inferred← citeshttps://doi.org/10.1016/j.jcat.2014.12.005openalex-snapshot
A room temperature catalyst for toluene aliphatic C–H bond oxidation: Tripodal tridentate copper complex immobilized in mesoporous silica
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2021.111541openalex-snapshot
Influence of the amine donor on hybrid guanidine-stabilized Bis(μ-oxido) dicopper(III) complexes and their tyrosinase-like oxygenation activity towards polycyclic aromatic alcohols
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2021.111544openalex-snapshot
Characterization of copper complexes with derivatives of the ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) and their reactivity towards oxygen
inferred← citeshttps://doi.org/10.1016/j.molcata.2009.10.012openalex-snapshot
New insights into the lactide polymerisation with neutral N-donor stabilised zinc complexes: Comparison of imidazolin-2-imine vs. guanidine complexes
inferred← citeshttps://doi.org/10.1016/j.poly.2012.05.013openalex-snapshot
Adenine supported hydroxyl-bridged dicopper core as a catalytically competent unit for phenol oxidation
inferred← citeshttps://doi.org/10.1021/acs.accounts.5b00187openalex-snapshot
Structural and Reactivity Models for Copper Oxygenases: Cooperative Effects and Novel Reactivities
inferred← citeshttps://doi.org/10.1021/acs.cgd.7b00296openalex-snapshot
3D Inorganic Cuprous Iodide Open-Framework Templated by In Situ N-Methylated 2,4,6-Tri(4-pyridyl)-1,3,5-triazine
inferred← citeshttps://doi.org/10.1021/acs.chemrev.6b00636openalex-snapshot
Copper–Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00074openalex-snapshot
Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00368openalex-snapshot
Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O 2 Model Systems to Organometallic Transformations
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c00320openalex-snapshot
Characterization and Reactivity Studies of Mononuclear Tetrahedral Copper(II)–Halide Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c03914openalex-snapshot
Generation and Reactivity of μ-1,2-Peroxo CuIICuII and Bis-μ-oxo CuIIICuIII Species and Catalytic Hydroxylation of Benzene to Phenol with Hydrogen Peroxide
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b01297openalex-snapshot
A Biomimetic Mechanism for the Copper-Catalyzed Aerobic Oxygenation of 4-tert-Butylphenol
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b02205openalex-snapshot
Synthesis and Catalytic Reactivity of a Dicopper(II) μ-η2:η2-Peroxo Species Supported by 1,4,7-Tri-tert-butyl-1,4,7-triazacyclononane
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b01154openalex-snapshot
Tetrahedral Copper(II) Complexes with a Labile Coordination Site Supported by a Tris-tetramethylguanidinato Ligand
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.8b01529openalex-snapshot
Effects of Charged Ligand Substituents on the Properties of the Formally Copper(III)-Hydroxide ([CuOH] 2+ ) Unit
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.9b03175openalex-snapshot
Tuning Inner-Sphere Electron Transfer in a Series of Copper/Nitrosoarene Adducts
inferred← citeshttps://doi.org/10.1021/acs.jpcc.9b09970openalex-snapshot
Molecular Doping of PCPDT–BT Copolymers: Comparison of Molecular Complexes with and without Integer Charge Transfer
inferred← citeshttps://doi.org/10.1021/bk-2011-1063.ch011openalex-snapshot
Zinc Complexes with Mono- and Polydentate Behaving Guanidine Ligands and Their Application in Lactide Polymerization
inferred← citeshttps://doi.org/10.1021/cr200177jopenalex-snapshot
Proton-Coupled Electron Transfer
inferred← citeshttps://doi.org/10.1021/ic101249kopenalex-snapshot
Dinuclear Copper Complexes Based on Parallel β-Diiminato Binding Sites and their Reactions with O 2 : Evidence for a Cu−O−Cu Entity
inferred← citeshttps://doi.org/10.1021/ic101515gopenalex-snapshot
Bis(μ-oxo) Dicopper(III) Species of the Simplest Peralkylated Diamine: Enhanced Reactivity toward Exogenous Substrates
inferred← citeshttps://doi.org/10.1021/ic3013848openalex-snapshot
Modeling Tyrosinase and Catecholase Activity Using Newm-Xylyl-Based Ligands with Bidentate Alkylamine Terminal Coordination
inferred← citeshttps://doi.org/10.1021/ic501461nopenalex-snapshot
Geometric Control of Nuclearity in Copper(I)/Dioxygen Chemistry
inferred← citeshttps://doi.org/10.1021/ic9002466openalex-snapshot
Effects of Electron-Deficient β-Diketiminate and Formazan Supporting Ligands on Copper(I)-Mediated Dioxygen Activation
inferred← citeshttps://doi.org/10.1021/ja1034667openalex-snapshot
Synthesis and Characterization of a Coupled Binuclear CuI/CuIII Complex
inferred← citeshttps://doi.org/10.1021/ja201663popenalex-snapshot
Proton-Coupled Electron Transfer Reactions at a Heme-Propionate in an Iron-Protoporphyrin-IX Model Compound
inferred← citeshttps://doi.org/10.1021/ja406721aopenalex-snapshot
Access to a Cu II –O–Cu II Motif: Spectroscopic Properties, Solution Structure, and Reactivity
inferred← citeshttps://doi.org/10.1021/ja508630dopenalex-snapshot
Primary Amine Stabilization of a Dicopper(III) Bis(μ-oxo) Species: Modeling the Ligation in pMMO
inferred← citeshttps://doi.org/10.1021/ja907198nopenalex-snapshot
Pd(II)-Catalyzed Hydroxylation of Arenes with 1 atm of O2 or Air
inferred← citeshttps://doi.org/10.1021/jacs.1c07076openalex-snapshot
Concerted Multiproton–Multielectron Transfer for the Reduction of O 2 to H 2 O with a Polyoxovanadate Cluster
inferred← citeshttps://doi.org/10.1021/jacs.4c07777openalex-snapshot
Expanding the Clip-and-Cleave Concept: Approaching Enantioselective C–H Hydroxylations by Copper Imine Complexes Using O2 and H2O2 as Oxidants
inferred← citeshttps://doi.org/10.1021/jacs.5b08347openalex-snapshot
Factors That Control C–C Cleavage versus C–H Bond Hydroxylation in Copper-Catalyzed Oxidations of Ketones with O2
inferred← citeshttps://doi.org/10.1021/jacs.8b11525openalex-snapshot
Bioinspired Metal–Organic Framework Catalysts for Selective Methane Oxidation to Methanol
inferred← citeshttps://doi.org/10.1021/jp911086nopenalex-snapshot
Solvent Dependence of the Kinetic Isotope Effect in the Reaction of Ascorbate with the 2,2,6,6-Tetramethylpiperidine-1-oxyl Radical: Tunnelling in a Small Molecule Reaction
inferred← citeshttps://doi.org/10.1021/om1005726openalex-snapshot
Unexpected C carbene −X (X: I, Br, Cl) Reductive Elimination from N-Heterocyclic Carbene Copper Halide Complexes Under Oxidative Conditions
inferred← citeshttps://doi.org/10.1038/nchem.1284openalex-snapshot
Self-assembly of the oxy-tyrosinase core and the fundamental components of phenolic hydroxylation
inferred← citeshttps://doi.org/10.1038/s42004-019-0115-6openalex-snapshot
Cupric-superoxide complex that induces a catalytic aldol reaction-type C–C bond formation
inferred← citeshttps://doi.org/10.1039/9781837677955-00266openalex-snapshot
Molecular Mechanism of Phenolase Activity of Tyrosinase
inferred← citeshttps://doi.org/10.1039/b911881kopenalex-snapshot
Construction and property investigation of transition-metal complexes modified octamolybdate hybrid materials based on V-shaped organic ligands
inferred← citeshttps://doi.org/10.1039/b918386hopenalex-snapshot
Copper
inferred← citeshttps://doi.org/10.1039/b920671jopenalex-snapshot
Reaction mechanisms in solution
inferred← citeshttps://doi.org/10.1039/c0cs00202jopenalex-snapshot
Copper–O2 reactivity of tyrosinase models towards external monophenolic substrates: molecular mechanism and comparison with the enzyme
inferred← citeshttps://doi.org/10.1039/c3cc46893copenalex-snapshot
Hiking on the potential energy surface of a functional tyrosinase model – implications of singlet, broken-symmetry and triplet description
inferred← citeshttps://doi.org/10.1039/c5cp05009jopenalex-snapshot
Donor-driven conformational flexibility in a real-life catalytic dicopper( ii ) peroxo complex
inferred← citeshttps://doi.org/10.1039/c5dt00822kopenalex-snapshot
Catalytic aerobic oxidation of phenols to ortho-quinones with air-stable copper precatalysts
inferred← citeshttps://doi.org/10.1039/c6sc04820jopenalex-snapshot
Acid/base triggered interconversion of μ-η 2 :η 2 -peroxido and bis(μ-oxido) dicopper intermediates capped by proton-responsive ligands
inferred← citeshttps://doi.org/10.1039/c7cp04686copenalex-snapshot
Relativistic effects at the Cu 2 O 2 core – a density functional theory study
inferred← citeshttps://doi.org/10.1039/c8dt04938fopenalex-snapshot
Tuning a robust system: N,O zinc guanidine catalysts for the ROP of lactide
inferred← citeshttps://doi.org/10.1039/c8ob02240bopenalex-snapshot
Metal-catalysed reactions enabled by guanidine-type ligands
inferred← citeshttps://doi.org/10.1039/c9ce00911fopenalex-snapshot
Stoichiometry mechanosynthesis and interconversion of metal salts containing [CuCl 3 (H 2 O)] − and [Cu 2 Cl 8 ] 4−
inferred← citeshttps://doi.org/10.1039/d1dt01354hopenalex-snapshot
On the metal–ligand bonding in dinuclear complexes with redox-active guanidine ligands
inferred← citeshttps://doi.org/10.1039/d1dt04084gopenalex-snapshot
Tris(imidazolyl) dicopper( i ) complex and its reactivity to exert the catalytic oxidation of sterically hindered phenol substrates via a [Cu 2 O] 2+ core
inferred← citeshttps://doi.org/10.1039/d1fd00071copenalex-snapshot
Phenolate-bonded bis(μ-oxido)-bis-copper( iii ) intermediates: hydroxylation and dehalogenation reactivities
inferred← citeshttps://doi.org/10.1039/d2fd00162dopenalex-snapshot
The bridge towards a more stable and active side-on-peroxido (Cu 2 II (µ-η 2 :η 2 -O 2 )) complex as a tyrosinase model system
inferred← citeshttps://doi.org/10.1039/d2ra02032gopenalex-snapshot
Protonation-induced charge transfer and polaron formation in organic semiconductors doped by Lewis acids
inferred← citeshttps://doi.org/10.1055/s-0037-1609635openalex-snapshot
Cu(III)-Mediated Aerobic Oxidations
inferred← citeshttps://doi.org/10.1055/s-0037-1610297openalex-snapshot
Advances in Catalytic Aerobic Oxidations by Activation of Dioxygen-Monooxygenase Enzymes and Biomimetics
inferred← citeshttps://doi.org/10.1080/00958972.2010.503273openalex-snapshot
Monooxygenation of external phenolic substrates in small-molecule dicopper complexes: implications on the reaction mechanism of tyrosinase
inferred← citeshttps://doi.org/10.1107/s1600536811014577openalex-snapshot
2-[2-(Benzylsulfanyl)phenyl]-1,1,3,3-tetramethylguanidine
inferred← citeshttps://doi.org/10.1107/s1600536811014929openalex-snapshot
N-[Bis(dimethylamino)methylidene]-2-[(triphenylmethyl)sulfanyl]ethanaminium hexafluorophosphate
inferred← citeshttps://doi.org/10.1107/s1600536811039183openalex-snapshot
N-Trityl-2-(tritylsulfanyl)aniline
inferred← citeshttps://doi.org/10.1107/s1600536812046387openalex-snapshot
Bis(2-{[bis(dimethylamino)methylidene]amino-κN}benzenesulfonato-κN)copper(II)
inferred← citeshttps://doi.org/10.1107/s1600536812050428openalex-snapshot
The mixed-valent copper thiolate complex hexakis{μ3-2-[(1,3-dimethylimidazolidene)amino]benzenethiolato}dicopper(II)tetracopper(I) bis(hexafluoridophosphate) acetonitrile disolvate dichloromethane disolvate
inferred← citeshttps://doi.org/10.1515/revic.2011.003openalex-snapshot
(Guanidine)copper complexes: structural variety and application in bioinorganic chemistry and catalysis
inferred← citeshttps://doi.org/10.3390/catal13040773openalex-snapshot
Non-Noble Metal Aromatic Oxidation Catalysis: From Metalloenzymes to Synthetic Complexes
inferred← citeshttps://doi.org/10.3390/inorganics6040114openalex-snapshot
Fluorescent Bis(guanidine) Copper Complexes as Precursors for Hydroxylation Catalysis
inferred← citeshttps://doi.org/10.5560/znb.2012-0061openalex-snapshot
Orthoamide und Iminiumsalze, LXXIX [1]. N-[w-(Dimethylamino)alkyl]-N´,N´,N´´,N´´-tetramethylguanidine und davon abgeleitete Guanidiniumsalze: Synthese und Kristallstrukturen/ Orthoamides and Iminium Salts, LXXIX [1]. N-[w-(Dimethylamino)alkyl]-N´,N´,N´´,N´´- tetramethylguanidines and Salts Derived…
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